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Full-Text Articles in Physical Sciences and Mathematics

An Archaeological And Archaeoseismological Perspective On Earthquakes In The Coastal Cities Of Western Anatolia In The 3rd Millennium Bce: Settlement Abandonment And Changes In Social Structures, Ümi̇t Gündoğan Sep 2024

An Archaeological And Archaeoseismological Perspective On Earthquakes In The Coastal Cities Of Western Anatolia In The 3rd Millennium Bce: Settlement Abandonment And Changes In Social Structures, Ümi̇t Gündoğan

Turkish Journal of Earth Sciences

This study investigates the impact of the earthquakes that occurred in the first half of the 3rd millennium BCE on Western Anatolian settlements, aiming to determine the dates of the earthquakes that happened during the prehistoric period using the earthquake layers of the settlements and associated C14 data. The focus of the paper is the investigation of the effects of two earthquakes that occurred in the region during the first half of the 3rd millennium BCE on the settlements of the region. The first earthquake occurred around 2800 BCE and damaged settlements in the area of İzmir. Evidence of this …


Sequence Stratigraphy And Hydrocarbon Potential Of The Paleozoic Successions On The Arabian Platform And Southeast Türkiye, Muhi̇tti̇n Şenalp, Sema Teti̇ker Sep 2024

Sequence Stratigraphy And Hydrocarbon Potential Of The Paleozoic Successions On The Arabian Platform And Southeast Türkiye, Muhi̇tti̇n Şenalp, Sema Teti̇ker

Turkish Journal of Earth Sciences

In 1989, the first prolific hydrocarbon reservoirs were discovered by Saudi Aramco in the highly porous and permeable friable continental sandstones (Unayzah reservoirs) and shallow marine carbonates (Khuff reservoirs) of the Paleozoic successions in south of Riyadh, Central Arabia. These successions were strongly affected by tectonic movements (Caledonian and Hercynian orogenesis) and Early and Late Paleozoic Gondwana glaciations. Therefore, some sections were fully eroded or significantly reduced in their thickness. The sequence stratigraphic interpretation of the Paleozoic successions helped to understand the depositional environments and regional distribution of the source, reservoir and cap rock facies in an improved palynologic studies. …


Detecting Edges Of Geologic Sources From Gravity Or Magnetic Anomalies Through A Novel Algorithm Based On Hyperbolic Tangent Function, Hanbing Ai, Yunus Levent Eki̇nci̇, Ahmad Alvandi, Hazel Deni̇z Toktay, Çağlayan Balkaya, Arka Roy Sep 2024

Detecting Edges Of Geologic Sources From Gravity Or Magnetic Anomalies Through A Novel Algorithm Based On Hyperbolic Tangent Function, Hanbing Ai, Yunus Levent Eki̇nci̇, Ahmad Alvandi, Hazel Deni̇z Toktay, Çağlayan Balkaya, Arka Roy

Turkish Journal of Earth Sciences

Directional derivative-based edge detectors are commonly used to outline the abrupt lateral variations in densities or magnetizations of geologic sources from potential-field datasets. Some subtle traces of faults, lithological contacts, and lineaments can be made more visible on anomaly maps using these algorithms. However, these algorithms generally suffer from common limitations such as blurry edges with low-resolution or faulty boundaries. To minimize these challenges, we proposed a new efficient edge detector that benefits from the hyperbolic tangent function. The performance of this detector was tested on the responses of a synthetic gravity model and Bishop's complex magnetic model. A Gaussian …


Corrigendum To “A Two-Stage Deformation Of The Anatolian Plate Deduced Frompaleomagnetic Signals: The Initial Age Of The Anatolian’S Escape” [Turkish Journal Ofearth Sciences 33 (3) 2024 243-259 ], Mualla Cengi̇z, Savaş Karabulut Sep 2024

Corrigendum To “A Two-Stage Deformation Of The Anatolian Plate Deduced Frompaleomagnetic Signals: The Initial Age Of The Anatolian’S Escape” [Turkish Journal Ofearth Sciences 33 (3) 2024 243-259 ], Mualla Cengi̇z, Savaş Karabulut

Turkish Journal of Earth Sciences

This corrigendum is to address an issue regarding the manuscript's previous title. The authors have regrettably noticed that the title is incorrect in the original published version of this paper. To rectify this oversight and ensure the accuracy of the published work, the title has been corrected for your reference below: A two-stage deformation of the Anatolian plate deduced from paleomagnetic signals: the initial age of the Anatolian escape.

Link to the original submission: https://journals.tubitak.gov.tr/earth/vol33/iss3/2/


Assessment Of Water Pollution In A Waste Storage Drainage Area (A Case Study In Eskişehir, Türkiye), Ali̇ Kayabaşi, Özlem Toygar Sağin, Candan Gökçeoğlu Sep 2024

Assessment Of Water Pollution In A Waste Storage Drainage Area (A Case Study In Eskişehir, Türkiye), Ali̇ Kayabaşi, Özlem Toygar Sağin, Candan Gökçeoğlu

Turkish Journal of Earth Sciences

Before 2016, the Eskişehir city landfill was an irregular landfill. Since then, it has been transformed into a regulated landfill. This study aimed to investigate the presence of pollution in the landfill drainage area. For this purpose, water samples were collected from the landfill drainage area and the Kadirbey Farm Spring, upstream of the landfill area, during the rainy and dry seasons of 2021. Analyses of the heavy metal content, total dissolved soil (TDS), chemical oxygen demand, biochemical oxygen demand, pH, phenol material content, ammonia nitrogen content, and conductivity were conducted on the samples. Electrical resistivity tomography (ERT) measurements were …


Top To Bottom Interactive Velocity Analysis Using Travel-Time Ellipses And First Break Times From Walkaway Vertical Seismic Profiling Data: A Synthetic Study, Cemal Erdemi̇r Sep 2024

Top To Bottom Interactive Velocity Analysis Using Travel-Time Ellipses And First Break Times From Walkaway Vertical Seismic Profiling Data: A Synthetic Study, Cemal Erdemi̇r

Turkish Journal of Earth Sciences

An interactive velocity analysis method is introduced in this paper and its efficacy is tested on various walkaway vertical seismic profile (WVSP) modeled data sets. In WVSP surveys, interval velocity profiles are determined fairly accurately along the VSP borehole using first break travel time picks from the zero-offset VSP (ZVSP) data. However the accuracy of these vertical velocities fade away quickly as the source distance (offset) from the VSP borehole increases due to possible horizontal changes in the geology or dips of the horizons. If the layer boundaries are not known, a simple approach type of ray tracing using horizontally …


Enhancing Dtc Control Of Im Using Fuzzy Logic And Three-Level Inverter: A Comparative Study, Siham Mencou, Majid Benyakhlef, Elbachir Tazi Sep 2024

Enhancing Dtc Control Of Im Using Fuzzy Logic And Three-Level Inverter: A Comparative Study, Siham Mencou, Majid Benyakhlef, Elbachir Tazi

Turkish Journal of Electrical Engineering and Computer Sciences

Direct torque control is the most appropriate strategy for induction motor drive systems, due to its considerable ability to reduce the impact of of machine parameter variations, while offering fast dynamic response and simplified control implementation. However, persistent problems associated with high torque ripple and variable switching frequencies prevent its widespread adoption. To overcome these limitations, several techniques have been developed, in particular the use of multi-level inverters and fuzzy logic algorithms. This article proposes an in-depth evaluation of these techniques in a MATALB/Simulink environment, under various operational conditions. The main objective is to provide a detailed performance analysis of …


Power Quality Enhancement In Hybrid Pv-Bes System Based On Ann-Mppt, Heli̇n Bozkurt, Özgür Çeli̇k, Ahmet Teke Sep 2024

Power Quality Enhancement In Hybrid Pv-Bes System Based On Ann-Mppt, Heli̇n Bozkurt, Özgür Çeli̇k, Ahmet Teke

Turkish Journal of Electrical Engineering and Computer Sciences

Battery energy systems (BESs) assisted photovoltaic (PV) plants are among the popular hybrid power systems in terms of energy efficiency, energy management, uninterrupted power supply, grid-connected and off-grid availability. The primary objective of this study is to enhance the power quality of a grid-tied PV-BES hybrid system by developing an operation strategy based on Artificial Neural Network (ANN) based maximum power point tracking (MPPT) method. A test system comprising a 10-kWh BES and a 12.4 kW PV plant is structured and simulated on the MATLAB/Simulink platform. The hybrid system is validated with three different cases: constant radiation, rapid changing radiation, …


Finger Movement Recognition Using Machine Learning Algorithms With Tree-Seed Algorithm, Muhammed Sami̇ Karakul, Ahmet Gökçen Sep 2024

Finger Movement Recognition Using Machine Learning Algorithms With Tree-Seed Algorithm, Muhammed Sami̇ Karakul, Ahmet Gökçen

Turkish Journal of Electrical Engineering and Computer Sciences

Electromyography (EMG) signals have been used to recognize various actions of hand movements, finger movements, and hand gestures. This paper aims to improve the classification accuracy of EMG signals while decreasing the number of features using the Tree-Seed Algorithm. The dataset containing EMG signals utilized in this investigation is derived from a publicly accessible source. The rationale for selecting the Tree-Seed Algorithm centers on its ability to enhance classification accuracy while minimizing the dimensionality of feature sets. The object function and Tree-Seed Algorithm's nature avoids the results to have low accuracy with fewer features. The aim is not just to …


Mention Detection In Turkish Coreference Resolution, Şeni̇z Demi̇r, Hani̇fi̇ İbrahi̇m Akdağ Sep 2024

Mention Detection In Turkish Coreference Resolution, Şeni̇z Demi̇r, Hani̇fi̇ İbrahi̇m Akdağ

Turkish Journal of Electrical Engineering and Computer Sciences

A crucial step in understanding natural language is detecting mentions that refer to real-world entities in a text and correctly identifying their boundaries. Mention detection is commonly considered a preprocessing step in coreference resolution which is shown to be helpful in several language processing applications such as machine translation and text summarization. Despite recent efforts on Turkish coreference resolution, no standalone neural solution to mention detection has been proposed yet. In this article, we present two models designed for detecting Turkish mentions by using feed-forward neural networks. Both models extract all spans up to a fixed length from input text …


A Single Operational Amplifier-Based Grounded Meminductor Mutators And Their Applications, Shalini Gupta, Kunwar Singh, Shireesh Kumar Rai Sep 2024

A Single Operational Amplifier-Based Grounded Meminductor Mutators And Their Applications, Shalini Gupta, Kunwar Singh, Shireesh Kumar Rai

Turkish Journal of Electrical Engineering and Computer Sciences

In this work, three simple configurations of meminductor mutator are presented. The first two configurations of meminductor mutator have been implemented utilizing one CMOS-based operational amplifier, one memristor, one capacitor, and five resistors, while the third configuration of meminductor mutator is implemented utilizing one CMOS based operational amplifier, two memristors, one capacitor, and four resistors. The implementation and simulation of the proposed configurations are done by using LTspice tool. The viability of the proposed circuits is demonstrated by utilizing TSMC 180 nm CMOS technology parameters. The proposed circuits of the meminductor have a simple structure in contrast to many of …


The Heat Kernel On A Finite Graph In Different Time-Scales, Yang Chen, Jay Jorgenson, Luis Lopez, Lejla Smajlovic Sep 2024

The Heat Kernel On A Finite Graph In Different Time-Scales, Yang Chen, Jay Jorgenson, Luis Lopez, Lejla Smajlovic

Turkish Journal of Mathematics

Let G be a finite, weighted graph, and let [[EQUATION]] be a Time-scale with a fixed point [[EQUATION]] such that sup[[EQUATION]]. In this paper we construct the heat kernel on G in Time-scale [[EQUATION]] in terms of a certain convolution series involving he heat operator acting on a parametrix, which is a fairly general function depending on the vertex set of G and the time variable [[EQUATION]]. We develop some applications by choosing different parametrices and various Time-scales. The results we obtain here do extend, in part, aspects of the recent articles in that the Time-scale considered in this paper …


Φ−Pluriharmonicity And Φ−Invariance Of Pointwise Bislant Riemanniansubmersions, Grayson Light, Cem Sayar, Mehmet Aki̇f Akyol Sep 2024

Φ−Pluriharmonicity And Φ−Invariance Of Pointwise Bislant Riemanniansubmersions, Grayson Light, Cem Sayar, Mehmet Aki̇f Akyol

Turkish Journal of Mathematics

In this research, we investigate the intriguing realm of pointwise bislant Riemannian submersions, a generalizationof many previous submersions, such as antiinvariant, slant, semislant, pointwise slant, pointwise semislant,and bislant submersions, within the framework of almost product manifolds. After giving an original example, wedelve into the submersion’s integrability conditions and geodesics. We explore the concept of φ−pluriharmonicity andφ−invariance within this context. The study sheds light on the profound interplay between pointwise bislant submersions’fibers and their being either geodesic or mixed geodesic, offering valuable insights into these intriguing mappings’geometric properties.


Ideals In Semigroups Of Partial Transformations With Invariant Set, Jitsupa Srisawat, Yanisa Chaiya Sep 2024

Ideals In Semigroups Of Partial Transformations With Invariant Set, Jitsupa Srisawat, Yanisa Chaiya

Turkish Journal of Mathematics

This paper explores the ideals and their structural properties in two generalizations of the partial transformationsemigroup. Furthermore, principal, maximal, and minimal ideals within these semigroups are elucidated.


Transmission Eigenvalues Problem Of A Schrödinger Equation, Emel Yildirim, Elgiz Bairamov Sep 2024

Transmission Eigenvalues Problem Of A Schrödinger Equation, Emel Yildirim, Elgiz Bairamov

Turkish Journal of Mathematics

In this paper, transmission eigenvalues of a Schrödinger equation have been studied by constructing a new inner product and using Weyl theory. Necessary conditions for these eigenvalues to be negative, real and finite have been examined. This method has provided a new framework related to transmission eigenvalue problems and investigation of their properties. The conclusions has been verified for special case of the problem.


Comprehensive Computational Study On Transient Heat Transfer In Functionally Graded Longitudinal Fins Under Time-Varying Laser Heating, Hüseyi̇n Demi̇r, İnci̇ Çi̇li̇ngi̇r Süngü, İbrahi̇m Keleş Sep 2024

Comprehensive Computational Study On Transient Heat Transfer In Functionally Graded Longitudinal Fins Under Time-Varying Laser Heating, Hüseyi̇n Demi̇r, İnci̇ Çi̇li̇ngi̇r Süngü, İbrahi̇m Keleş

Turkish Journal of Mathematics

The present study assumes that the material properties of the fin vary by a force rule in the axial direction, with the exception of the thermal relaxation coefficient, which is assumed to be constant. The temperature distribution in the longitudinal fin with homogeneous cross-section exposed to the laser heat source is numerically investigated. This is because these constraints lead to a linear differential equation with partial solutions that can't be analytically resolved using conventional methods, except for a few elementary order functions. Consequently, a linear or non-linear system of equations as a function of time is obtained by transforming a …


A Short Note On Generalized Robertson Walker Spacetimes, Uday Chand De, Aydin Gezer Sep 2024

A Short Note On Generalized Robertson Walker Spacetimes, Uday Chand De, Aydin Gezer

Turkish Journal of Mathematics

In this article, generalized Robertson Walker spacetimes are investigated in light of perfect fluid spacetimes. First, we establish that a perfect fluid spacetime with non-vanishing vorticity whose associated scalars are constant along the velocity vector field becomes a generalized Robertson Walker spacetime. Among others, it is also shown that a Ricci parallel perfect fluid spacetime is either a generalized Robertson Walker spacetime or a static spacetime. Finally, we acquire that in a conformally semi-symmetric generalized Robertson Walker spacetime of dimension $4$, the scalar curvature vanishes and the spacetime is locally isometric to the Minkowski spacetime, provided the electric part of …


Individual Stability Of Representations Of Abelian Semigroups, Heybetkulu Mustafayev Sep 2024

Individual Stability Of Representations Of Abelian Semigroups, Heybetkulu Mustafayev

Turkish Journal of Mathematics

Let S be a suitable subsemigroup of a locally compact abelian group and let T={T(s)}s(-S be a bounded and strongly continuous trepresentation of S on a Banach space X. In this note, we study the spectral conditions on T and the ergodic conditios on x in X which will imply that T(s)x-->0 strongly as s--> infinity through S.


A Non-Newtonian Conics In Multiplicative Analytic Geometry, Aykut Has, Beyhan Yilmaz Sep 2024

A Non-Newtonian Conics In Multiplicative Analytic Geometry, Aykut Has, Beyhan Yilmaz

Turkish Journal of Mathematics

In this study, conics (circle, ellipse, hyperbola) are characterized by taking into account basic multiplicationoperations in multiplicative space. For this purpose, firstly multiplicative axes and regions are introduced. Additionally,the multiplicative cone definition is given and visualized on the figure. General definitions and theorems of non-Newtonianconics are given. Additionally, examples were given and drawings were made to make the resulting characterizations andtheorems more memorable.


On The Connection Between Σϵ(A1 ⊗ A2) And Σϵ(A1), Σϵ(A2) For Certain Specialoperators, Fati̇h Yilmaz Sep 2024

On The Connection Between Σϵ(A1 ⊗ A2) And Σϵ(A1), Σϵ(A2) For Certain Specialoperators, Fati̇h Yilmaz

Turkish Journal of Mathematics

In this paper, the connection between the ϵ -pseudospectrum of the tensor product operator A1 ⊗ A2 andthe ϵ -pseudospectrums of operators A1 and A2 has been investigated and some results are given about this connectionunder certain conditions.


Rings And Finite Fields Whose Elements Are Sums Or Differences Of Tripotents And Potents, Adel Abyzov, Stephen Cohen, Peter Danchev, Daniel Tapkin Sep 2024

Rings And Finite Fields Whose Elements Are Sums Or Differences Of Tripotents And Potents, Adel Abyzov, Stephen Cohen, Peter Danchev, Daniel Tapkin

Turkish Journal of Mathematics

We significantly strengthen results on the structure of matrix rings over finite fields and applythem to describe the structure of the so-called weakly n-torsion clean rings. Specifically, we establish that, forany field F with either exactly seven or strictly more than nine elements, each matrix over F is presentableas a sum of of a tripotent matrix and a q-potent matrix if and only if each element in F is presentable as asum of a tripotent and a q-potent, whenever q > 1 is an odd integer. In addition, if Q is a power of an oddprime and F is a field …


Spherical Product Hypersurfaces In Euclidean Spaces, Sezgi̇n Büyükkütük, Günay Öztürk Sep 2024

Spherical Product Hypersurfaces In Euclidean Spaces, Sezgi̇n Büyükkütük, Günay Öztürk

Turkish Journal of Mathematics

Spherical product surfaces are obtained with the help of a special product by considering two curves inn−dimensional space. One of their special cases is rotational surface. The reason why the present study is significantthat the spherical product is used to construct hypersurfaces. (n−1)−curves are needed during this construction. Firstly,the spherical product hypersurfaces are defined in E4 , Gaussian and mean curvature are yielded and then conditionsbeing flat or minimal are examined. Moreover, superquadrics, which are associated with spherical product, are handledfor the first time in hypersurface form and give some examples. Finally, spherical product hypersurfaces are generalizedto n−dimensional Euclidean space …


A Sufficient Condition For The Wildness Of An Automorphism Of A Free Leibnizalgebra, Zeynep Özkurt Sep 2024

A Sufficient Condition For The Wildness Of An Automorphism Of A Free Leibnizalgebra, Zeynep Özkurt

Turkish Journal of Mathematics

In this paper, we apply the criterion of Mikhalev and Umirbaev for the invertibility of an endomorphismof a finitely generated free Leibniz algebra via its Jacobian matrix to determine whether a given endomorphism is anautomorphism. Moreover, it is shown that the invertibility of the determinant of the Jacobian matrix of an automorphismimplies its wildness.


A Note On The Hull And Linear Complementary Pair Of Cyclic Codes, Zohreh Aliabadi, Tekgül Kalayci Sep 2024

A Note On The Hull And Linear Complementary Pair Of Cyclic Codes, Zohreh Aliabadi, Tekgül Kalayci

Turkish Journal of Mathematics

The Euclidean hull of a linear code C is defined as C ∩ C⊥ , where C⊥ denotes the dual of C underthe Euclidean inner product. A linear code with the trivial hull is called a linear complementary dual (LCD) code. Apair (C,D) of linear codes of length n over the finite field Fq is called a linear complementary pair (LCP) of codes ifC ⊕ D = Fnq. More generally, a pair (C,D) of linear codes of the same length over Fq is called a linear ℓ -intersectionpair of codes if C ∩D has dimension ℓ as a vector space …


Exploring The Efficiency Of Nitrogenated Carbon Quantum Dots/Tio2 S-Scheme Heterojunction In Photodegradation Of Ciprofloxacin In Aqueous Environments, Yilmaz Ateş, Zafer Eroğlu, Özkan Açişli, Önder Meti̇n, Semra Karaca Aug 2024

Exploring The Efficiency Of Nitrogenated Carbon Quantum Dots/Tio2 S-Scheme Heterojunction In Photodegradation Of Ciprofloxacin In Aqueous Environments, Yilmaz Ateş, Zafer Eroğlu, Özkan Açişli, Önder Meti̇n, Semra Karaca

Turkish Journal of Chemistry

The usability of polyvinyl chloride-based quaternary triethanol ammonium chloride anionite (PVC-TEAC) as a potential extractant for tungstate was investigated to recover tungstate from Gabal Qash Amir, Egypt, assaying 70.91% WO3. Structure elucidation for PVC-TEAC anionite was successfully carried out using several techniques. Experimental measurements, such as pH, agitation time, initial tungsten concentration, anionite dose, co-ions, temperature, and eluting agents, have been optimized. It was found that PVC-TEAC anionite has a maximum capacity of 63 mg per gram. From the distribution isotherm modeling, Langmuir’s model fits the experimental results better than Freundlich’s, with a theoretical value of 61.728 mg g–1. According …


Synthesis And Characterization Of New Hexahydroquinoline Derivatives, Evaluation Of Their Cytotoxicity, Intracellular Ros Production And Inhibitory Effects On Inflammatory Mediators, Ezgi̇ Pehli̇vanlar, Deni̇z Arca Çakir, Sonia Sanajou, Hülya Tezel Yalçin, Terken Baydar, Pinar Erkekoğlu, Hani̇fe Avci, Rahi̇me Şi̇mşek Aug 2024

Synthesis And Characterization Of New Hexahydroquinoline Derivatives, Evaluation Of Their Cytotoxicity, Intracellular Ros Production And Inhibitory Effects On Inflammatory Mediators, Ezgi̇ Pehli̇vanlar, Deni̇z Arca Çakir, Sonia Sanajou, Hülya Tezel Yalçin, Terken Baydar, Pinar Erkekoğlu, Hani̇fe Avci, Rahi̇me Şi̇mşek

Turkish Journal of Chemistry

Inflammation is a response to injury and infection in the organism. It can be categorized as acute and chronic inflammation. Chronic inflammation is the underlying cause of many diseases such as Alzheimer's, diabetes, rheumatoid arthritis, atherosclerosis and cardiovascular diseases. Recent studies have proven the anti-inflammatory properties of 1,4-dihydropyridines (1,4-DHPs) and its derivatives, which have many biological properties including calcium channel blockers. The structures of the synthesized compounds were elucidated by IR, 1H-NMR, 13C-NMR and HRMS methods. The cytotoxic properties of the compounds were determined by 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) method in 3T3 cell line. Among the 15 compounds, the three compounds …


Preparation Of A Chiral Hyperbranched Polymer Based On Cinchona Alkaloids And Investigation Of Its Catalytic Activity In Asymmetric Reactions, Rafiqul Islam, Mohammad Shahid Ullah, Abdus Salam, Shinichi Itsuno Aug 2024

Preparation Of A Chiral Hyperbranched Polymer Based On Cinchona Alkaloids And Investigation Of Its Catalytic Activity In Asymmetric Reactions, Rafiqul Islam, Mohammad Shahid Ullah, Abdus Salam, Shinichi Itsuno

Turkish Journal of Chemistry

Cinchona alkaloid-derived sulfonamides and ester dimers containing chiral hyperbranched polymers have been successfully synthesized and applied as catalysts in asymmetric reactions. Several hyperbranched polymers derived from cinchona alkaloids, incorporating sulfonamides and esters, were synthesized through Mizoroki–Heck coupling polymerization. These polymers were subsequently applied in enantioselective Michael addition reactions. As the prepared polymers are not soluble in frequently used organic solvents, they act as efficient catalysts in the enantioselective reaction of β-ketoesters to nitroolefins, achieving up to 99% enantioselectivity with good yields. The insoluble property allows them to better satisfy “green chemistry” requirements and be used several times without losing the …


Synthesis, Characterization, And Physico-Chemical Aspects Of A New Pvc-Based Quaternary Triethanol Ammonium Chloride Anionite For Tungsten Recovery, Bahig Atia Aug 2024

Synthesis, Characterization, And Physico-Chemical Aspects Of A New Pvc-Based Quaternary Triethanol Ammonium Chloride Anionite For Tungsten Recovery, Bahig Atia

Turkish Journal of Chemistry

The usability of polyvinyl chloride-based quaternary triethanol ammonium chloride anionite (PVC-TEAC) as a potential extractant for tungstate was investigated to recover tungstate from Gabal Qash Amir, Egypt, assaying 70.91% WO3. Structure elucidation for PVC-TEAC anionite was successfully carried out using several techniques. Experimental measurements, such as pH, agitation time, initial tungsten concentration, anionite dose, co-ions, temperature, and eluting agents, have been optimized. It was found that PVC-TEAC anionite has a maximum capacity of 63 mg per gram. From the distribution isotherm modeling, Langmuir’s model fits the experimental results better than Freundlich’s, with a theoretical value of 61.728 mg g–1. According …


Liquefaction Optimization Of Grape Pulp Using Response Surface Methodology For Biopolyol Production And Bio-Based Polyurethane Foam Synthesis, Furkan Çolakoğlu, Emre Akdoğan, Murat Erdem Aug 2024

Liquefaction Optimization Of Grape Pulp Using Response Surface Methodology For Biopolyol Production And Bio-Based Polyurethane Foam Synthesis, Furkan Çolakoğlu, Emre Akdoğan, Murat Erdem

Turkish Journal of Chemistry

Both environmental and economic disadvantages of using petroleum-based products have been forcing researchers to work on environmentally friendly, sustainable, and economical alternatives. The purpose of this study is to optimize the solvothermal liquefaction process of grape pomace using response surface methodology coupled with a central composite design. After investigating the physicochemical properties of the liquified products (biopolyol) in detail, a bio-based rigid polyurethane foam (RPUF) was synthesized and characterized. The hydroxyl and acid numbers and viscosity values of all the biopolyols were analyzed. According to variance analysis results (%95 confidence range), both the reaction temperature and catalyst loading were determined …


New Imidazolidindionedioximes And Their Pt(Ii) Complexes: Synthesis And Investigation Of Their Antitumoral Activities On Breast Cancer Cells, Emrah Karahan, Tuğba Gençoğlu Katmerli̇kaya, Emel Önal, Aydan Dağ, Ayşe Gül Gürek, Vefa Ahsen Aug 2024

New Imidazolidindionedioximes And Their Pt(Ii) Complexes: Synthesis And Investigation Of Their Antitumoral Activities On Breast Cancer Cells, Emrah Karahan, Tuğba Gençoğlu Katmerli̇kaya, Emel Önal, Aydan Dağ, Ayşe Gül Gürek, Vefa Ahsen

Turkish Journal of Chemistry

Breast cancer is one of the most common types of cancer worldwide and has the most lethality ratio for females among all cancers. Although current cancer therapeutics have made considerable advancements, there is still room for improvement in terms of efficacy. Many anticancer drugs have a risk of causing serious adverse effects due to their non-specific cytotoxic effects on both tumor and healthy cells. New therapeutics might have a greater ability to kill cancer cells, reduce the volume of tumors, and improve overall therapy response rates. Herein, we report the efficient synthesis and characterization of three amphi vic-dioximes and their …