Physical Sciences and Mathematics Commons^™

Fungal And Trichothecenes (Tct) Contamination Of Poultry Feed From Duhok Province, Kurdistan Of Iraq, L. F. Hussei A. A. M. Saadullah

Al-Qadisiyah Journal of Pure Science

Fungi are capable of reducing the nutritional value of food for human and animals and producing many mycotoxins. Mycotoxins-contaminated animal feed has adverse effects on productivity and animal health. As well, mycotoxins may be carried over into meat and eggs when poultry are fed with contaminated feed. Data on the occurrence of T-2 and HT-2 toxins in poultry feed from Kurdistan region of Iraq are very limited. T-2 toxin is the most toxic type A trichothecene mycotoxin. It is the secondary metabolite of the Fusarium fungi, and is common in grains and animal feed. Toxic effects have been shown both …

Omitted - Value Transformation For A Complex Differential Equations, Shatha S. Alhily, Fatima Ah. Mazloum

Al-Qadisiyah Journal of Pure Science

No abstract provided.

Preparation And Study Of Tin And Gallium Thin Films On Silicon Substrates, Maher Nadher Abdullah

Al-Qadisiyah Journal of Pure Science

In this research, the ideal procedures were obtained for growth epitaxial layers of tin and gallium solutions which are solid solutions, and the two solutions of the molten material were dissolved on a silicon substrate. The results were to obtain the lowest dislocation density of thin films. The relationship between the dislocation densities of thin films and the thickness of the thin film was an exponential relationship between its variable values. Thin films with a compound containing a smooth structure varied in order were obtained by smoothly changing the lattice parameters of the gradient gap solid solution, and an ideal …

Review Of Key Derivation Functions In Cryptographic Systems, Hasan Kadhim A. Alsuwaiedi, Abdul Monem S. Rahma

Al-Qadisiyah Journal of Pure Science

Because of its significance in the formation of the core of encryption/decryption algorithms, the key derivation function (KDF) or pseudorandom number generator (PRNG) plays a major part in the cryptographic system. Random numbers are required for the usage of encryption and decryption techniques in a variety of network security applications. In this research we Focus on key generation functions, which are an important aspect of symmetric and asymmetric algorithms. Disgusting the background of PRNG basics and attempting to characterize and evaluate several publications that offer proposals for key generators.

Some Properties Of Almost Periodic Points In A Random Dynamical System, Qays Arif Wali, Ihsan Jabbar

Al-Qadisiyah Journal of Pure Science

No abstract provided.

Study Of Transitive Random Dynamical Systems, Salam T. Abbas, Ihsan J. Kadhim

Al-Qadisiyah Journal of Pure Science

No abstract provided.

Supra-Approximation Spaces Using Combined Edges Systems, Hussein R. Jaffer, Khalid Sh. Al’Dzhabri

Al-Qadisiyah Journal of Pure Science

The primary in this paper's notion, the i-space using incident edges system (resp. n-space using non-incidental edges system), is what this study is responsible for generating and investigating. Additionally, we used c-interior to define the c-lower approximations in generalized rough set theory (resp. i-interior and n-interior) Additionally, the c-upper approximations are defined using c-closure (as opposed to i-closure and n-closure), and some of its characteristics are studied.

The Refractive Index Of Photonic Crystal Fibers As A Function Of Some Parameters And Temperature, Mohammed Salim Jasim, Nadia Al-Aboody

Al-Qadisiyah Journal of Pure Science

Photonic crystal fibers in the late period occupied a wide range of studies and research because of the ease of dealing with them in terms of design and installation, as there is a group of parameters used in them that can affect the refractive index of the pulse propagation through it, including the diameter of the air holes, the distance between the air holes and their number, as this study showed in addition to the aforementioned parameters The effect of temperature on the refractive index was also studied. It has been observed that with an increase in the diameter of …

Water Quality Evaluation Of The Main Drain In Dhi-Qar Governorate, South Iraq, Ali H. Nomas, Ayser Al-Shamma

Al-Qadisiyah Journal of Pure Science

The Main Drain is one of the largest irrigation projects which is used to collect drainage water from the lands extended on both sides of the water channel and diverts it to Shatt Al-Arab and from there to the Arabian Gulf. The Main Drain passed in Dhi-Qar Governorate to the northeast of Nasiriyah oil field in the Kati’a area, which is about 38 km from the center of the city of Nasiriyah. The objective of the present research is to evaluate the water quality, and its temporal change of the Main Drain, and if there is an impact of the …

Steganography Using Syntactic Method, Saad Nasser Al.Azzam, Fahad Ali Al-Qarni

Al-Qadisiyah Journal of Pure Science

Information security, which is becoming more crucial as information sharing plays an increasingly significant part in the day-to-day activities of today's people, is one of the methods that may be used for information security. For the sake of information security, we present a method to linguistic steganography that is based on syntactic banks.

While the unprocessed input a phrase structure of the sentence is produced by parsing the sentence using the Stanford parser, which can create a phrase structure of the sentence.

They create the grammatical structure of the sentence. The input secret message is encoded using Shannon-Fano coding in …

Synthesis Of New Ligand-Based Phosphazo Ring And Its Transition Metal Complexes As Cancer Inhibitor: Spectroscopic, Dft, Antimicrobial, And Molecular Docking Investigations, Asmaa A. Hamed, Ahmed A. El-Sherif, Carmen M. Sharaby, Yousry A. Ammar, Mona F. Amine

Al-Azhar Bulletin of Science

A condensation between 2-sulfanilamidopyrimidine and a p-toluidine dimer of cyclodiazadiphosphetidine resulted in the formation of a new ligand, 2,2,4,4-tetrachloro-1,3-di-[p-tolyl]-2,4-di-[N-(pyrimidin-2-yl) benzenesulfonamide]-1,3,2,4-diazadiphosphetidine, (H2L). We investigated the chemical behavior of the newly prepared ligand was investigated by treating it with some chosen metal ions at a stoichiometric ratio of 1:2 (L:M), where M = Fe(III), Fe(II), Cu(II), Zn(II), Cd(II), and Ag(I), to provide colored complexes with accepted yields. Then, we characterized the ligand and related complexes using spectroscopic and analytical techniques. Investigations revealed that the geometrical structure of the complexes was octahedral, except for the silver complex was tetrahedral. From the spectral analyses, …

Post-Translational Modification Of Proteins Via Ambient Air Pollutants And Endogenous Reactive Species, Rachel Lauren Davey

Electronic Theses and Dissertations

Proteins can react with reactive oxygen species (ROS) and reactive nitrogen species (RNS) to form post-translational modifications (PTMs), which can affect protein structure and function. The formation of 3-nitrotyrosine (NTyr) and dityrosine (DiTyr) upon reaction of proteins with ROS/RNS are two common PTMs studied due to their stability and irreversibility, as well as their ability to enhance the allergenicity of pollen allergens upon formation. Many common techniques used to study the formation of these PTMs can reliably detect the PTMs but can only provide semi-quantitative information due to many assumptions and limitations. In Chapter 2 we present an analysis of …

Mechanistic Insights Into Mftr-Dependent Regulation Of The Redox Cofactor Mycofactocin, Aigera Mendauletova

Electronic Theses and Dissertations

Organic redox cofactors are essential for life. While classic flavins and nicotinamides are widely distributed across all domains of life, nature has also evolved niche cofactors in subsets of life domains. For example, in Actinobacteria, coenzyme F420 is commonly used in place of flavin mononucleotide in enzymes associated with carbon fixation and oxidation of secondary alcohols. The importance of niche cofactors has long been recognized however, detailed understanding about their biosynthesis and physiological uses has been lagging. One class of niche cofactors is derived from ribosomally synthesized and posttranslationally modified peptides (RiPPs). To achieve their mature form, the genetically …

A Comparison Of Tung Oil Resin Reinforcements Using Fibrous Proteins And Peptides For Biological And Materials Applications, Parker L. Williams

Electronic Theses and Dissertations

In this study a tung oil based thermoset was reinforced with collagen and fibroin, and the resulting composites were analyzed for their physical properties. Tung tree seed oil is a great candidate for biobased polymer production because its triglycerides are primarily made of alpha eleostearic acid, a fatty acid with three conjugated carbon-carbon double bonds. These double bonds allow for mechanically strong crosslinking in the polymer. It has been observed that polymerized tung oil forms a gel. This issue has been addressed using divinylbenzene (DVB) and n-butyl methacrylate (BMA) as co-monomers. Similar bio-based polymers have been studied and tend to …

Development And Praxis Of Ph Drug Delivery System Contra Zika, Julissa Rodriguez

Electronic Theses and Dissertations

As the effects of global warming continue to spread throughout the world, another critical issue is slowly gaining attention in many urban tropical countries. The Emerging Infectious Diseases/ Pathogens list from the National Institutes of Health (NIH) listed the Zika virus as a potential pandemic threat. In 2015, an outbreak of Zika was noted in several South American countries until the spread reached an all-time high of 87 countries in 2017. During the outbreaks, adults affected were noted to have joint and muscle pains, fevers, and rashes. The worst cases reported would ultimately lead to Guillain-Barre symptoms. Still, pregnant women …

The Indivisible System: Modeling The Metal-Pterin-Dithiolene System In Molybdenum And Tungsten Cofactors, Cassandra Gates

Bryn Mawr College Dissertations and Theses

Mo and W enzymes are ubiquitous in living organisms and crucial for sustaining life. Mo and W enzyme variety is diverse, but they contain a highly conserved aspect of functionality in these enzymes, the pyranopterin-dithiolene (PDT) ligand. A total of eight possible electron redox equivalents occurs between the metal center and PDT, making the molybdenum cofactor (Moco) and the tungsten cofactor (Tuco) the most redox rich cofactors in all of biology. This research focuses on the development of new pterin-dithiolene synthetic modeling systems for Moco. The knowledge gained from the characterization of these compounds is applied to the enzymes, furthering …

Structural Engineering Of Thermostable Fluorescent Proteins Tgp-E And Ytp-E And Crystal Structure Of Tgp-E, Matthew Ryan Anderson

MSU Graduate Theses

Thermostable fluorescent proteins, such as thermal green protein (TGP) and yellow thermal protein (YTP), could be used as biosensors to monitor cellular activity and as a fusion tag to monitor a protein of interest. The use of fluorescent proteins can sometimes be limited in certain organelles with low pH and in thermophilic organisms. This research aims to improve the thermal stability of TGP and YTP. TGP was created from a synthetically derived eCGP123 protein to improve solubility by substituting residues on the positively charged b- barrel surface with negatively charged glutamate (E) at Los Alamos National Lab. YTP was developed …

Translating Chemistry, Structure, And Processing To The Solid-State Morphology And Function Of Organic Semiconductors Through Computational Modeling And Simulations, Chamikara D. Karunasena

Theses and Dissertations--Chemistry

The immense synthetic design space and material versatility have driven the exploration and development of organic semiconductors (OSC) over several decades. While many OSC designs focus on the chemistries of the molecular or polymer building blocks, a priori, multiscale control over the solid-state morphology is required for effective application of the active layer in a given technology. However, molecular assembly during solid-state formation is a complex function interconnecting the building block chemistry and the processing environment. Insufficient knowledge as to how these aspects engage, especially at the atomistic and molecular scales, has so far limited the ability to predict …

Developing And Deploying Data-Driven Tools For Accelerated Design Of Organic Semiconductors, Vinayak Bhat

Theses and Dissertations--Chemistry

Organic semiconductors have gained widespread attention due to their potential applications in flexible, low-cost, lightweight electronics, energy storage and generation technologies, and sensing applications. However, developing new organic semiconductors with improved performance remains a significant challenge due to the vast chemical space of possible molecular and materials structures. Furthermore, the high cost and time-consuming nature of experimental synthesis and characterization hinder the rapid discovery of new materials. To overcome these challenges, this dissertation presents a data-driven approach to organic semiconductor discovery. The primary focus of this work is the development of data-driven tools, namely machine learning models, to predict critical …

Exploring The Role Of Ring Annulation In Polycyclic Aromatic Hydrocarbons For Organic Electronic Applications, Tanner Smith

Theses and Dissertations--Chemistry

Organic materials offer promising potential for the next generation of electronic devices, as their tunability, processability, and low-temperature manufacturing make them a cheap and versatile alternative to traditional silicon-based electronics. The ability to systematically alter the electronic properties of organic materials is vital for their incorporation into device applications. Polycyclic aromatic hydrocarbons (PAHs) are of significant interest for organic electronic applications, as relevant properties are highly dependent on their size, structure, and functionalities, and thus can be tuned to fit a wide variety of applications. Due to the enormous number of structural isomers available in larger PAHs, the development of …

Development And Biological Evaluation Of Selective Small-Molecule Inhibitors Of The Human Cytochrome P450 1b1, Austin Hachey

Theses and Dissertations--Chemistry

The human cytochrome P450 1B1 (CYP1B1) is an emerging target for small- molecule therapeutics. Several solid tumors overexpress CYP1B1 to the degree that it has been referred to as a universal tumor antigen. Conversely, its expression is low in healthy tissues. CYP1B1 may drive tumorigenesis through promoting the formation of reactive toxins from environmental pollutants or from endogenous hormone substrates. Additionally, the expression of CYP1B1 in tumors is associated with resistance to several common chemotherapies and with poor prognoses in cancer patients. However, inhibiting CYP1B1 with small molecules has been demonstrated in cellular and murine model systems to reverse this …

First Principles Calculations To Investigate Surface And Catalytic Properties Of Materials For Green Energy Generation, Keerthan Raghavendra Rao

Theses and Dissertations--Chemistry

Climate change due to greenhouse gas build up in the earth’s atmosphere is an existential threat to humanity. To mitigate climate change, a significant shift from fossil fuels is necessary. Over the years, several renewable energy sources like solar, wind, geothermal etc. have been explored with the aim providing carbon-free energy. In this work, we focus on using density functional theory (DFT) methods to investigate key functional properties of materials of interest for applications in solar cells and catalytic conversion for energy generation. We show geometric effects of carboxylic acid binding on a transition metal surface to impact the deoxygenation …

Application Of Mass Spectrometry For The Characterization Of Synthetic Oligomers And Natural Lignin, Poorya Kamali

Theses and Dissertations--Chemistry

As part of the ongoing effort to substitute finite fuel and chemical resources with renewable ones, biomass is emerging as one of the most promising sources. Biomass consists of three main components of cellulose, hemicellulose, and lignin. Traditionally, cellulose has been used extensively in pulping industry, while lignin has been considered waste and is burned to generate heat. Lignin, a complex aromatic polymer component of biomass, has the potential to be used as a source of aromatic chemicals and pharmaceutical synthons. The recalcitrant nature of lignin, the lack of effective lignin breakdown methods and analytical techniques to analyze it are …

Development Of An Effective Au:Pd Bimetallic Heterogeneous Catalyst For Oxidative Lignin Depolymerization To Low Molecular Weight Aromatics, Gayan P. Karunasinghe

Theses and Dissertations--Chemistry

The principal concept behind biorefining involves the transformation of lignocellulosic biomass into valuable products and energy resources. Historically, biorefinery strategies for lignocellulosic biomass have primarily focused on improving the conversion of cellulose into ethanol, often neglecting the underutilized lignin component. Lignin consists of phenolic subunits, from which it follows that value-added products can be obtained from lignin depolymerization. Unfortunately, lignin utilization is particularly challenging due to its high structural irregularity and recalcitrance. The goal of this study was to develop an AuPd/Li-Al layered double hydroxide (LDH) bimetallic catalyst for efficient lignin depolymerization, resulting in the production of high-value aromatic compounds. …

A Developmental Investigation Of Separation And Analysis Of Molecular Mass 302 Da Polyaromatic Hydrocarbons Using High Performance Liquid Chromatography And Chiral Stationary Phase, James Janesko

Electronic Theses and Dissertations, 2020-2023

High molecular weight – polycyclic aromatic hydrocarbons (HMW-PAH) are often found where air, water, and soil are subject to higher levels of industrial pollutants. These molecules are environmentally concerning due to their carcinogenic, mutagenic, and tumorigenic propensities. Furthermore, the isomers in this family are challenging to separate due to similar retention parameters, spectroscopic fingerprints, and mass spectral patterns. The primary purpose of this dissertation is to expand on the methodology for separation and analysis of the molecular mass 302 Da six-ring isomers using High Performance Liquid Chromatography. Retention behaviors of 21 commercially available isomers in synthetic mixture were collected via …

Error Rate Determination Of Latent Print Chemistry Via 1d And 2d Gas Chromatography, Jessica Kindell

Electronic Theses and Dissertations, 2020-2023

Latent print evidence collected from crime scenes are analyzed and compared by examiners using the ACE-V protocol (Analysis, Comparison, Evaluation-Verification) to identify potential suspects. However, smudged and poor-quality prints, usually deemed inconclusive, could be utilized for source association or discrimination based on the chemistry of the oils and sweat that comprises the latent print residue (LPR). For this research, LPRs were collected from various places on the face and analyzed via two-dimensional gas chromatography-mass spectrometry (2D GC-MS), one-dimensional (1D) GC-MS, and direct analysis in real time-high resolution mass spectrometry (DART-HRMS). LPR recovery with two common sample preparation methods, derivatization and …

Instrumental Approaches For High Resolution Photoluminescence Spectroscopy And Its Applications To Environmental Analysis, Anthony Santana

Electronic Theses and Dissertations, 2020-2023

Photoluminescence phenomena provide valuable information for the direct analysis of target chemicals in complex samples. To take full advantage of the information content of fluorescence and phosphorescence phenomena, the analyst should have access to instrumentation capable to record data formats in the wavelength and time domains. Previous efforts in our lab have developed laser-based instrumentation to combine spectral and lifetime information into data formats known as wavelength time matrices (WTMs) and time-resolved excitation emission matrices (TREEMs). Recording WTMs during the emission decay of the sample makes it possible to unambiguously identify chemicals on the bases of spectral and lifetime information. …

Using Wastewater-Based Epidemiology To Study Chlamydia Occurrence On A College Campus, Jessie E. Chin Quee

Honors Undergraduate Theses

Chlamydia is a sexually transmitted disease caused by Chlamydia trachomatis, commonly affecting sexually active college-aged adults. Presently, opportunistic testing, self-testing, and information campaigns are methods to screen vulnerable populations and raise awareness about chlamydia. Chlamydia remains underdiagnosed and undertested due to a lack of participation by individuals who may have been exposed to it. Wastewater-based epidemiology is a rising biomonitoring tool that detects the presence of disease- and drug-specific biomarkers in a community's wastewater. In this study, wastewater-based epidemiology was used to detect the presence of C. trachomatis on the University of Central Florida campus. Wastewater samples were collected …

Development Of A Screening Methodology For The Analysis Of Rhodamine B In Foodstuffs, George T. Knecht

Honors Undergraduate Theses

Synthetic dyes that are used as color additives in foodstuffs are regulated by the Food and Drug Administration (FDA) under the Food, Drug, and Cosmetic Act (FD&C). The use of synthetic dyes not approved by the FDA, or the addition of dyes approved by the FDA above their maximum concentration limits in foodstuffs necessarily constitutes illegal food adulteration. Recently, rhodamine B (RhB), a bright-pink synthetic dye not approved for use in foodstuffs, has become an adulterant of interest due to its discovery in a large variety of food samples, and its identity as a potential carcinogen. Numerous chromatographic and spectroscopic …

Split Catalytic Probes For The Detection Of Monkeypox Virus, Jaehyun Ahn

Honors Undergraduate Theses

The COVID-19 outbreak highlighted the important role that diagnostic tests play in the healthcare system. To reduce the impact of infectious disease outbreaks, the development of rapid and cost-effective point-of-care-tests (POCTs) is crucial. With the dissemination of the Monkeypox (Mpox) virus, it became a necessity to produce POCTS that are inexpensive and easy to use. This work explored the construction of two colorimetric assays that aim to detect Mpox genetic signatures. One is based on the split-peroxidase-like deoxyribozyme probes (sPDz), while the other utilizes a cascade system of split RNA-cleaving deoxyribozyme (sDz) and peroxidase-like deoxyribozyme (PDz). Both rely on catalytic …