Physical Sciences and Mathematics | Open Access Articles

Synthesis Of Malathion, Malaoxon, And Isomalathion Enantiomers And Examination Of Their Interactions With Acetylcholinesterase, Clifford E. Berkman

Dissertations

No abstract provided.

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Detection Of Oh+ In Its A 1-Delta State By Far Infrared Laser Magnetic Resonance, Thomas Varberg, K. M. Evenson, J. M. Brown

Thomas D. Varberg

No abstract provided.

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Gas Phase Clustering Of N2 Molecules On To Tio+: Comparison With Ti+ And Evidence For The Octahedral Structure Of Tio+(N2)5, George M. Daly, M. Samy El-Shall

Chemistry Publications

A striking difference in the clustering efficiency of Ti⁺ and TiO⁺ toward N₂ or O₂ has been observed in a laser vaporizationhigh pressure mass spectrometric source. Evidence for the magic number n=5 within the sequence TiO⁺(N₂)_nis presented. The results are consistent with an octahedral structure for TiO⁺(N₂)₅.

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Ab Initio Equilibrium Constants For H2o–H2o And H2o–Co2, Nancy Renyou Zhang, Donald D. Shillady

Chemistry Publications

Ab initio 6‐31G** electronic structure calculations have been used to determine the minimum energy geometries and vibrational frequencies of molecular clusters of water and carbon dioxide. Application of statistical thermodynamics leads to theoretical equilibrium constants for gas phase dimerization of water and the formation of an adduct of carbon dioxide with water.The low energy vibrations of the clusters lead to much larger contributions to the vibrational partitioning of the energy than do the fundamental vibrations of the monomeric species. A new ‘‘Harmonic‐Morse’’ formula is derived to estimate anharmonicity from optimized harmonic frequencies and two additional values on the potential surface …

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Dynamic Phenomena In Superconducting Oxides By Esr, Juana Vivó Acrivos, Lei Chen, C. M. Burch, P. Metcalf, J. M. Honig, R. S. Liu, K. K. Singh

Faculty Publications, Chemistry

Dynamic electron spin resonance (ESR) measurements compare the paramagnetic and antiferromagnetic (AF) properties of superconducting oxides in the range 4 K to room temperature, at 8 MHz and 9.36 GHz. Two are derivatives of YBa2Cu30 7: 1: Nd(Nd0.05Ba0.95 )2Cu30 7, Te0 =72 K and II: Y0.2Cao.8Sr2[Cu2(Tlo.5Pb0.5 )]07, Te0 =108 K and two are cases where AF ordering dominates the weak superconductivity: III: Nb01.1> 1. 25 ~Teo~ 10 K and IV: La2Ni04.00, 70 K :::: Teo:::: 40 K. At temperatures 298:::: T:::: 64 K, the ESR absorption by I indicates orthorhombic symmetry. The peaks at Ke =2.06, gb =2.13, and Ka …

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The Processing Pathway Of Prelamin A, Michael Sinensky, K. Fantle, M. Trujillo, T. Mclain, A. Kupfer, M. Dalton

Faculty Publications, Biological Sciences

The conversion of mammalian prelamin A to mature lamin A proceeds through the removal of 18 amino acids from the carboxyl terminus. The initial step in this processing is the isoprenylation of a CAAX box cysteine. This proteolytic event is distinctive for prelamin A among the known prenylated mammalian proteins. Since the carboxyl terminus of prelamin A is removed during maturation, it is not obvious that this protein would undergo the two reactions subsequent to prenylation observed in other CAAX box proteins-the endoproteolytic removal of the carboxyl-terminal 3 amino acids and the subsequent methylation of the now carboxyl-terminal cysteine. To …

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Electromagnetic Dissociation Of 238u At 120 Mev/A, M. L. Justice, Y. Blumenfeld, N. Colonna, D. N. Delis, G. Guarino, K. Hanold, J. C. Meng, Graham F. Peaslee, G. J. Wozniak, L. G. Moretto

Faculty Publications

Electromagnetic fission cross sections of a 120 MeV/nucleon U238 beam incident on five targets, Be9, Al27, Cunat, Agnat, and Unat, have been extracted from measurements of projectile velocity fission fragments. The nuclear interaction contributions to the experimentally observed cross sections were determined by extrapolation from the Be target data using a geometrical scaling model and by an empirical decomposition of the fission charge distributions. The results are compared to model calculations in which electric quadrupole excitations have been included.

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Expression Of Prelamin A Confers Sensitivity Of Dna Biosynthesis To Lovastatin On F9 Teratocarcinoma Cells, Michael Sinensky, T. Mclain, K. Fantle

Faculty Publications, Biological Sciences

No abstract provided.

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Flash Pyrolysis-Gas Chromatography/Mass Spectrometry Of Lower Kittanning Vitrinites: Changes In The Distributions Of Polyaromatic Hydrocarbons As A Function Of Coal Rank, Michael A. Kruge, David F. Bensley

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Chemical analyses restricted to a single coal maceral permit a focus on rank effects without concern for variations in organic matter type. Vitrinite concentrates of high purity were isolated from coal samples of the Lower Kittanning seam by multi-step density gradient centrifugation, with reflectances ranging from 0.66 to 1.39% Rmax. In addition to the previously recognized losses of phenolic compounds, the vitrinite pyrolyzates exhibit marked increases in relative concentrations of tri- and tetraaromatic hydrocarbons (especially benzo[a]fluorene, methyl-phenanthrenes, methylfluorenes and methylchrysenes) above 0.9% Rmax, i.e., beyond the "second coalification jump" of Teichmüller. Thus, petrographically-recognizable physical transformations are shown …

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Serravallian Shales In The Monte Dei Corvi Pelagic Sequence (Ancona, Italy): An Organic Geochemical Perspective, Michael A. Kruge, B Artur Stankiewicz, Alessandro Montanari

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

In addition to the predominant marly lithologies, the Serravallian-Tortonian sequence at Monte dei Corvi (MDC), south of Ancona, Italy, contains at least 85 thin, dark calcareous shales. Such shales, averaging 14 cm in thickness, comprise 9% of the total Serravallian sequence. Sixteen of them were sampled for a preliminary organic geochemical evaluation. All the MDC shales appear to have been deposited during periodic anoxic events, as demonstrated by the presence of significant quantities of organic matter and authigenic pyrite. The degree of anoxicity (and thus the amount of organic matter preserved) appears to have differed from one event to the …

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Dynamic Phenomena In Superconducting Oxides By Esr, Juana Vivó Acrivos, Lei Chen, C. M. Burch, P. Metcalf, J. M. Honig, R. S. Liu, K. K. Singh

Juana Vivó Acrivos

Dynamic electron spin resonance (ESR) measurements compare the paramagnetic and antiferromagnetic (AF) properties of superconducting oxides in the range 4 K to room temperature, at 8 MHz and 9.36 GHz. Two are derivatives of YBa2Cu30 7: 1: Nd(Nd0.05Ba0.95 )2Cu30 7, Te0 =72 K and II: Y0.2Cao.8Sr2[Cu2(Tlo.5Pb0.5 )]07, Te0 =108 K and two are cases where AF ordering dominates the weak superconductivity: III: Nb01.1> 1. 25 ~Teo~ 10 K and IV: La2Ni04.00, 70 K :::: Teo:::: 40 K. At temperatures 298:::: T:::: 64 K, the ESR absorption by I indicates orthorhombic symmetry. The peaks at Ke =2.06, gb =2.13, and Ka …

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Expression Of Prelamin A Confers Sensitivity Of Dna Biosynthesis To Lovastatin On F9 Teratocarcinoma Cells, Michael Sinensky, T. Mclain, K. Fantle

Michael Sinensky

No abstract provided.

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The Processing Pathway Of Prelamin A, Michael Sinensky, K. Fantle, M. Trujillo, T. Mclain, A. Kupfer, M. Dalton

Michael Sinensky

The conversion of mammalian prelamin A to mature lamin A proceeds through the removal of 18 amino acids from the carboxyl terminus. The initial step in this processing is the isoprenylation of a CAAX box cysteine. This proteolytic event is distinctive for prelamin A among the known prenylated mammalian proteins. Since the carboxyl terminus of prelamin A is removed during maturation, it is not obvious that this protein would undergo the two reactions subsequent to prenylation observed in other CAAX box proteins-the endoproteolytic removal of the carboxyl-terminal 3 amino acids and the subsequent methylation of the now carboxyl-terminal cysteine. To …

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Correlation Between Electron Capture Negative Chemical Ionization Mass Spectrometric Fragmentation And Calculated Internal Energies For Polychlorinated Biphenyls, John Greaves, Ellen Harvey, William G. Macintyre

VIMS Articles

Correlations between molecular structure and fragmentation observed in electron capture negative chemical ionization mass spectra (moderator gas = methane) of 49 selected tetrachlorinated, pentachlorinated, and hexachlorinated biphenyls have been investigated by using molecular modeling. The semiempirical general molecular orbital program MOPAC was used to calculate molecular properties for biphenyl and the 209 polychlorinated biphenyls. The mass spectrometric ionization and fragmentation processes were found to be linked to the number of chlorine atoms present on the biphenyl, and to the number of those chlorine atoms in the ortho (2, 2', 6, and 6') positions. The intensity of molecular ions increased with …

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Catalytic Oxidation Of Chlorinated Hydrocarbons Over Powdered Transition Metal Oxide, Sanmei Xu

Theses

This study addresses the ability of powdered transition metal oxides such as manganese oxide, iron oxide and copper oxide to catalytically oxidize low concentrations of chlorinated hydrocarbons with air. The catalytic oxidation of trichloroethylene and dichloromethane in a tubular reactor system was evaluated experimentally as a function of temperature and space velocity. Gas chromatography with electron capture detector and flame ionization detector was used for quantitative analysis of feed and product streams. Gas chromatography/mass spectrometry and gas chromatography/Fourier transform infrared spectroscopy were used to identify all oxidation products. The results indicate that over 99% conversion of trichloroethylene is achieved at …

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Segmental Motions Of Oxidized Human Erythrocyte Spectrin-Actin: A Spin Label Epr Study, Benito O. Kalaw

Dissertations

No abstract provided.

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An Investigation Into Clay Intrinsic Properties, Surface Modifications And Applications, G Robert Goss

Dissertations

No abstract provided.

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Resonance Raman Investigation Of The Radical Cation Of 1,3,5-Hexatriene, Tamas Keszthelyi, Robert Wilbrandt, Robert J. Cave, Jenifer L. Johnson

All HMC Faculty Publications and Research

The resonance Raman spectrum of the 1,3,5-hexatriene radical cation generated by v-irradiation in a Freon glass is reported. The spectrum is excited at 395 nm in resonance with the second absorption band. Identical spectra are obtained from ionized (E)- and (Z)-1,3,5-hexatriene. The presence of more than one rotamer has to be assumed to account for all the observed resonance Raman bands. The bands are assigned to a mixture of the two rotamers, calculated at lowest energy, the ttt an tct rotamers, on the basis of ab initio ROHF/6-31G calculated harmonic frequencies. The spectrum indicates that …

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Tucson Intersection Study Of Automobile Emissions, Amber K. Hodgson, Yi Zhang, Donald H. Stedman

Fuel Efficiency Automobile Test Publications

No abstract provided.

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On-Road Nox Emissions Intercomparison Of On-Board Measurements And Remote Sensing, James W. Butler, Christine A. Gierczak, Gerald Jesion, Donald H. Stedman, Jon M. Lesko

Fuel Efficiency Automobile Test Publications

No abstract provided.

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Automobile Emissions In Tulsa, Oklahoma, Donald H. Stedman, Peter J. Popp, Paul L. Guenther

Fuel Efficiency Automobile Test Publications

No abstract provided.

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On-Road Carbon Monoxide And Hydrocarbon Remote Sensing In The Chicago Area In 1992, Donald H. Stedman, Yi Zhang, Gary A. Bishop, Stuart P. Beaton, Paul L. Guenther

Fuel Efficiency Automobile Test Publications

No abstract provided.

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Molecular Modeling Studies Of Hemoglobin Crosslinking Reactions, Patricia A. Pavlik

Master's Theses

No abstract provided.

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A Theoretical Investigation Of The Stability Of Hpc, Hannah S. Hong, Robert J. Cave

All HMC Faculty Publications and Research

Several ab initio methods are applied to the study of two linear isomers of methylidyne phosphine, HCP, and HPC. Single-reference correlation methods ranging from second-order Møller-Plesset theory to coupled cluster singles and doubles theory with noninterative inclusion of connected triple excitations were applied in a variety of basis sets of increasing size. In addition, complete active space self-consistent field wave functions, multireference singles and doubles configuration interaction, and averaged coupled pair functional theory were also applied to HPC. For HPC comparison of the single-reference based results is made with experimental data and previous theory to assess the accuracy …

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Synthesis, Structure, And Properties Of The Organic Conductor (Bedt-Ttf)2br2secn, Urs Geiser, H. Hau Wang, John A. Schlueter, Jack M. Williams, James L. Smart, Alan C. Cooper, S. Kalyan Kumar, Maria Caleca, James D. Dudek, K. Douglas Carlson, J. Ren, M. H. Whangbo, J. E. Schirber, W. R. Bayless

Faculty Publications - Department of Biological & Molecular Science

No abstract provided.

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Gender And Aphasia In The Stroke Data Bank, Daniel B. Hier, William B. Yoon, J. P. Mohr, Thomas R. Price, Philip A. Wolf

Chemistry Faculty Research & Creative Works

Aphasia Was Present in 19.4% of the Men and 22.5% of the Women in the Stroke Data Bank. There Were No Gender Differences in Aphasia Incidence among the Intracerebral Hemorrhages. Aphasia Was More Frequent among Women with Infarcts (37.0%) Than Men (28.3%). When Stroke Mechanism Was Controlled For, There Was an Excess of Aphasia among the Women with Stroke Due to Cardiac Embolism. When Stroke Site Was Controlled For, There Were No Gender Differences in Aphasia Frequency. Wernicke′s, Global, and Anomic Aphasias Were More Common in Women Than Men; Broca′s Aphasia Was Somewhat More Common in Men. Although There Were …

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A Prospective Community-Based Study Of Stroke In Warsaw, Poland, Anna Czlonkowska, Danuta Ryglewicz, Thomas Weissbein, Maria Baranska-Gieruszczak, Daniel B. Hier

Chemistry Faculty Research & Creative Works

Background and Purpose Poland is a Country with High Morbidity and Mortality Rates from Cardiovascular Diseases. No Recent Studies Have Evaluated the Contribution of Cerebrovascular Diseases to This Morbidity and Mortality. Our Aim Was to Accurately Determine Stroke Incidence Rates in Warsaw, Poland. Methods a 2-Year Prospective and Population-Based Stroke Registry Was Maintained for Health Care Units 2 and 3 in Warsaw, Poland (Population, 182 285). Case Subjects Were Ascertained by Surveying Hospital Admissions, Outpatient Visits, and Death Certificates. Results during the 2 Years of the Study (1991 to 1992), 633 Cases of First-Event Strokes Were Registered, 462 of Which …

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Hammett Correlations Of Half-Wave Reduction Potentials In A Series Of N-(Aryl Substituted)-Dichloronicotinamides, Cecil C. Persons, Ali U. Shaikh, Julie Shiflett, Frank L. Setliff

Journal of the Arkansas Academy of Science

Excellent correlations of Hammett substituent constants (sigmaR) of a series of N-(R-substituted aryl) -2,6-, 2,5-, and 5,6- dichloronicotinamides with polarographic half-wave potentials were observed. Although the correlations demonstrate that all three series of amides experience comparable sensitivity to the R groups at the carbonyl reduction site, the relative ease of reduction varies according to the chlorine substitution pattern on the pyridine ring. These differences are suggested to be due to combinations of mesomeric, inductive, and field effects which operate differently in the three systems. Correlation analysis also revealed that Hammett heteroatomic replacement constants previously determined by NMR studies are valid …

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Reaction Of Titanocene Dichloride With Acetylenedicarboxylate, Tanya L. Hagler, Mark Draganjac, Paul M. Nave, J. Ed Bennett, Farooq Kahn, Robert Engelken, Gerard Williams, Chris Poole, Kwok Fai Yu

Journal of the Arkansas Academy of Science

The reaction of Cp2TiCl2 with either the mono- or dipotassium salt of acetylenedicarboxylic acid (ADC) gives high yields of an insoluble orange product. The insoluble compound shows potential semiconductor behavior, as evidenced by an apparent bandgap in the orange region of the visible spectrum. Under N2 ,the compound decomposes at 238° C, eventually losing approximately 46% total mass up to 1350° C. The exothermic decomposition in air, beginning at 235° C, results in the formation of titanium oxides.

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Purification And Analysis Of Protein Synthetic Initiation Factors From Volvox Carteri, Kathie L. Pooler

Honors Theses

Volvox carteri, a multi-celled green algae, can grow synchronously given a sixteen hour light period followed by an eight hour dark period, a cycle which is repeated for a 48 hour growth cycle total. Near the end of each light period, reproductive cells divide rapidly resulting in the differentiation of ceIls. When the dark period begins, this differentiation stops and the cells remain dormant with little protein synthesis or differentiation occurring. Immediately after the lights come back on, however, the cells again undergo rapid protein synthesis and complete their differentiation. Previous studies have concluded that Volvox carteri discontinue protein synthesis …

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Full-Text Articles in Physical Sciences and Mathematics

Synthesis Of Malathion, Malaoxon, And Isomalathion Enantiomers And Examination Of Their Interactions With Acetylcholinesterase, Clifford E. Berkman

Dissertations

Detection Of Oh+ In Its A 1-Delta State By Far Infrared Laser Magnetic Resonance, Thomas Varberg, K. M. Evenson, J. M. Brown

Thomas D. Varberg

Gas Phase Clustering Of N2 Molecules On To Tio+: Comparison With Ti+ And Evidence For The Octahedral Structure Of Tio+(N2)5, George M. Daly, M. Samy El-Shall

Chemistry Publications

Ab Initio Equilibrium Constants For H2o–H2o And H2o–Co2, Nancy Renyou Zhang, Donald D. Shillady

Chemistry Publications

Dynamic Phenomena In Superconducting Oxides By Esr, Juana Vivó Acrivos, Lei Chen, C. M. Burch, P. Metcalf, J. M. Honig, R. S. Liu, K. K. Singh

Faculty Publications, Chemistry

The Processing Pathway Of Prelamin A, Michael Sinensky, K. Fantle, M. Trujillo, T. Mclain, A. Kupfer, M. Dalton

Faculty Publications, Biological Sciences

Electromagnetic Dissociation Of 238u At 120 Mev/A, M. L. Justice, Y. Blumenfeld, N. Colonna, D. N. Delis, G. Guarino, K. Hanold, J. C. Meng, Graham F. Peaslee, G. J. Wozniak, L. G. Moretto

Faculty Publications

Expression Of Prelamin A Confers Sensitivity Of Dna Biosynthesis To Lovastatin On F9 Teratocarcinoma Cells, Michael Sinensky, T. Mclain, K. Fantle

Faculty Publications, Biological Sciences

Flash Pyrolysis-Gas Chromatography/Mass Spectrometry Of Lower Kittanning Vitrinites: Changes In The Distributions Of Polyaromatic Hydrocarbons As A Function Of Coal Rank, Michael A. Kruge, David F. Bensley

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Serravallian Shales In The Monte Dei Corvi Pelagic Sequence (Ancona, Italy): An Organic Geochemical Perspective, Michael A. Kruge, B Artur Stankiewicz, Alessandro Montanari

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Dynamic Phenomena In Superconducting Oxides By Esr, Juana Vivó Acrivos, Lei Chen, C. M. Burch, P. Metcalf, J. M. Honig, R. S. Liu, K. K. Singh

Juana Vivó Acrivos

Expression Of Prelamin A Confers Sensitivity Of Dna Biosynthesis To Lovastatin On F9 Teratocarcinoma Cells, Michael Sinensky, T. Mclain, K. Fantle

Michael Sinensky

The Processing Pathway Of Prelamin A, Michael Sinensky, K. Fantle, M. Trujillo, T. Mclain, A. Kupfer, M. Dalton

Michael Sinensky

Correlation Between Electron Capture Negative Chemical Ionization Mass Spectrometric Fragmentation And Calculated Internal Energies For Polychlorinated Biphenyls, John Greaves, Ellen Harvey, William G. Macintyre

VIMS Articles

Catalytic Oxidation Of Chlorinated Hydrocarbons Over Powdered Transition Metal Oxide, Sanmei Xu

Theses

Segmental Motions Of Oxidized Human Erythrocyte Spectrin-Actin: A Spin Label Epr Study, Benito O. Kalaw

Dissertations

An Investigation Into Clay Intrinsic Properties, Surface Modifications And Applications, G Robert Goss

Dissertations

Resonance Raman Investigation Of The Radical Cation Of 1,3,5-Hexatriene, Tamas Keszthelyi, Robert Wilbrandt, Robert J. Cave, Jenifer L. Johnson

All HMC Faculty Publications and Research

Tucson Intersection Study Of Automobile Emissions, Amber K. Hodgson, Yi Zhang, Donald H. Stedman

Fuel Efficiency Automobile Test Publications

On-Road Nox Emissions Intercomparison Of On-Board Measurements And Remote Sensing, James W. Butler, Christine A. Gierczak, Gerald Jesion, Donald H. Stedman, Jon M. Lesko

Fuel Efficiency Automobile Test Publications

Automobile Emissions In Tulsa, Oklahoma, Donald H. Stedman, Peter J. Popp, Paul L. Guenther

Fuel Efficiency Automobile Test Publications

On-Road Carbon Monoxide And Hydrocarbon Remote Sensing In The Chicago Area In 1992, Donald H. Stedman, Yi Zhang, Gary A. Bishop, Stuart P. Beaton, Paul L. Guenther

Fuel Efficiency Automobile Test Publications

Molecular Modeling Studies Of Hemoglobin Crosslinking Reactions, Patricia A. Pavlik

Master's Theses

A Theoretical Investigation Of The Stability Of Hpc, Hannah S. Hong, Robert J. Cave

All HMC Faculty Publications and Research

Synthesis, Structure, And Properties Of The Organic Conductor (Bedt-Ttf)2br2secn, Urs Geiser, H. Hau Wang, John A. Schlueter, Jack M. Williams, James L. Smart, Alan C. Cooper, S. Kalyan Kumar, Maria Caleca, James D. Dudek, K. Douglas Carlson, J. Ren, M. H. Whangbo, J. E. Schirber, W. R. Bayless

Faculty Publications - Department of Biological & Molecular Science

Gender And Aphasia In The Stroke Data Bank, Daniel B. Hier, William B. Yoon, J. P. Mohr, Thomas R. Price, Philip A. Wolf

Chemistry Faculty Research & Creative Works

A Prospective Community-Based Study Of Stroke In Warsaw, Poland, Anna Czlonkowska, Danuta Ryglewicz, Thomas Weissbein, Maria Baranska-Gieruszczak, Daniel B. Hier

Chemistry Faculty Research & Creative Works

Hammett Correlations Of Half-Wave Reduction Potentials In A Series Of N-(Aryl Substituted)-Dichloronicotinamides, Cecil C. Persons, Ali U. Shaikh, Julie Shiflett, Frank L. Setliff

Journal of the Arkansas Academy of Science

Reaction Of Titanocene Dichloride With Acetylenedicarboxylate, Tanya L. Hagler, Mark Draganjac, Paul M. Nave, J. Ed Bennett, Farooq Kahn, Robert Engelken, Gerard Williams, Chris Poole, Kwok Fai Yu

Journal of the Arkansas Academy of Science

Purification And Analysis Of Protein Synthetic Initiation Factors From Volvox Carteri, Kathie L. Pooler

Honors Theses