Physical Sciences and Mathematics Commons^™

Organochlorine Residues In Soil And Plant., Tony Albertsen

Experimental Summaries - Plant Research

Trial 5812

To determine the relationship between soil and plant Dieldrin contamination in vegetables.

Location: Bunbury Regional Office (experimental site)

Agronomic Practices To Improve Or Maintain The Protein Content Of High Yielding, Long Season Wheats., Wayne Smith

Experimental Summaries - Plant Research

Trial 90SG8, 90SG9, 90ES9, 90ES11, 90MT8, 90KO2

Wheat variety * Time of sowing

Location: Salmon Gums Research Station, Mt. Ridley, East Gibson, Mt Barker Research Station, Kojaneerup Research Station

The aim is to define the optimum heading/flowering date on the South Coast. This trial also provides information on the performance of the varieties and new cross-breds at various sowing times.

Trial 90E10, 90ES12, 90ES13, 90ES14, 90ES15, 90ES16, 90SG10, 90SG11, 90MT10, 90KO3, 90KO4

Wheat protein on the South Coast

Location: Esperance Downs Research Station, Gibson, Neridup, Mt Ridley, Salmon Gums Research Station, Mt Barker Research Station, Kojaneerup Research Station

The Australian …

Weed Control In Crops And Pasture., J. Buckley

Experimental Summaries - Plant Research

Trial 90WH74

Crop establishment trial

Location: Wongan Hills Research Station.

To assess the effect of timing of roundup and sprayseed application and cultivation on crop growth.

Trial 90AB19

Ryegrass control in wheat using slow release trifluralin.

Location: Katanning.

To compare 2 experimental formulations of controlled release trifluralin at 4 rates and 2 timings with some commonly used herbicides for the control of ryegrass in wheat.

Trial 90ME84

Early application of 2, 4-D to wheat.

Location: Corrigin.

To assess the use of 2,4-D.amine at early times of application for the control of broadleaf weeds in wheat.

Trial 90WH92

Early application of …

Single And Double Nucleophilic-Addition To Coordinated Pi-Hydrocarbons - Manganese-Mediated Functionalization Of Arenes, Robert D. Pike, D. A. Sweigart

Arts & Sciences Articles

A range of carbon-donor nucleophiles add to the arene ring in (arene)Mn(CO)2L+ cations to give neutral cyclohexadienyl complexes that liberate monofunctionalized arenes upon oxidative removal of the metal. Treatment of the cyclohexadienyl complexes with the nitrosonium salt NOPF6 affords cationic metal nitrosyl complexes that are attacked by a second nucleophile to give cis- and trans-difunctionalized 1,3-cyclohexadienes. When the metal center is chiral, this procedure provides a route to enantiomerically pure cyclohexadienes. 1. Introduction 2. Mechanism of Nucleophilic Addition 3. Single Nucleophilic Addition 4. Double Nucleophilic Addition 5. Conclusions

Structure Of Ba2cu(Bo3)2, Robert W. Smith, Douglas A. Keszler

Chemistry Faculty Publications

As part of our program in the synthesis and characterization of new solid-state borates, we recently synthesized the polymorphic compound Sr2Cu(BO3)2 (Smith & Keszler, 1989) which undergoes a first-order phase transition from a low-temperature form to a high-temperature form at 1073 K. The high-temperature beta form exhibits larger coordination numbers for the Sr atoms and a substantial rearrangement of the copper borate network relative to that of the low-temperature... form.

Deep Banding Phosphate For Lupins. 1990 Results., R. J. Jarvis

Experimental Summaries - Plant Research

Trials 90SC1, 90SC21, 90SC12, 88SC28, 90WH73

There is no doubt that deep banding is the only effective way to provide an efficient supply of phosphorus for lupins in the eastern wheatbelt.

Location: Carrabin, Wongan Hills.

Getting The Best Out Of Our Wheats., Brenda Shackley, L. Lambert

Experimental Summaries - Plant Research

Trials: 90KA82 (TOS1), 90KA83 (TOS 2), 90KA84 (TOS 3)
90LG4 (TOS 1), 90LG45 (TOS 2), 90LG46 (TOS 3)
90LG47 (TOS 1), 90LG48 (TOS 2), 90LG49 (TOS 3)
90N42 (TOS 1), 90N43 (TOS 2), 90N44 (TOS 3)

Variety * time of sowing (TOS)

Locations: Wagin, Tarin Rock, Newdegate Research Station and Lake Varley.

Determine the optimum sowing date for maximum yield for a range of released and unreleased wheat cultivars.

Trials: 90KA79, 90LG50, 90LG51, 90N62

Nitrogen application.

Locations: Wagin, Tarin Rock, Newdegate Station and Lake Varley.

Determine the response of released and unreleased wheat cultivars to the application of nitrogen.

Trials: …

Development Of Herbicide Tolerant Lupin Varieties., J. Cooper

Experimental Summaries - Plant Research

Trial 90GL26

Effect of growth stage at application of response to atrazine.

To determine the optimum stage for application of atrazine to show the most consistent and maximum differences between varieties of lupins in glasshouse tolerance trials.

Trial 90GL28

Response to lupin varieties to metribuzin applied post emergence.

This is an initial quick screening to determine if the same pattern of responses occurs when metribuzin is applied as when simazine/atrazine is used. Field rates were used assuming that there are 1,250,000 pots/ha. The recommended rate applied to peas is 300g/ha so this was used as an estimate of the amount …

Investigating Poor Pasture Productivity., J. W. Bowden, R. J. Lunt, C. Broun

Experimental Summaries - Plant Research

Trial 90N06

Location: West Dale

To determine the reason for poor pasture productivity in medium rainfall zone. Specifically why the pastures are dominated by the poorly productive species Trifolium suffocatum and why there was a large response to phosphorous fertilizer at 50 ppm P in the soil.

Potassium Nutrition Of Lupins On The Sandplain Soils Of Western Australia., N. K. Edwards

Experimental Summaries - Plant Research

Aim: Develop recommendations for optimal potassium fertilizer application strategies for lupin production. Further develop soil and tissue test calibrations for lupin grain production.

Trial 89EC32

Potassium nutrition of lupins on sandplain soils.

Location: East Chapman Research Station.

Fertilizer: At sowing: 50 kg/ha DAP, 50 kg/ha Urea topdressed. 100 kg/ha Urea topdressed 10/7.

Trial 89GE90

Potassium nutrition of lupins on sandplain soils.

Location: Allanooka

Fertilizer: At sowing: 120 kg/ha Agras No. 1. 100 kg/ha Urea topdressed 10/7.

Trial 89MO51

Potassium nutrition of lupins on sandplain soils.

Location: Lancelin.

Fertilizer: At sowing: 110 kg/ha Agras No. 1. 60 kg/ha Urea topdressed 10/7. …

National Subterranean Clover Improvement Programme., P. G. H. Nichols

Experimental Summaries - Plant Research

The National Subterranean Clover Improvement Programme (NSCIP) aims to develop, by breeding and selection, better adapted and more productive low—oestrogen cultivars of subterranean clover for a range of environments in southern Australia. The programme is a collaborative one with the University of Western Australia and consists of two phases: (i) early generation selection, which involves selecting varieties satisfying primary selection criteria; and (ii) field evaluation of advanced lines, which is conducted by the Departments of Agriculture in each State and co—ordinated by the Plant Breeder.

The first phase is conducted at the University Field Station (UFS) and is continued until …

Pursuit For Weed Control In Peas., S. Curtin

Experimental Summaries - Plant Research

All trials were located in Merredin.

Trial 90ME86

This trial was one of the best demonstrations of pursuits effectiveness against mustard in particular. Other weeds were rough poppy and ryegrass and a small amount of cereal and doublegee.

250 ml applied immediate before seeding (IBS) was by far the best treatment with 100% control of mustard and poppy and good ryegrass control. This is in contract to 375 ml most emergent which had good control of mustard (77%) and suppression of ryegrass. There was no yield advantage from the post emergent treatment but there was a 55% yield increase from …

Depth Of Placement And Rates Of Nitrogen For Lupins On The South Coast., M. Seymour

Experimental Summaries - Plant Research

Trial 90E13

Starter nitrogen for lupins, rates x depth of placement.

To determine if the application of nitrogen at seeding will enable lupins to grow vigorously at the beginning of the season, and have better growth at flowering. Deep placement is used to reduce the effects of high nitrogen fertiliser on plant establishment.

Herbicide Resistance In Weeds., G. S. Gill

Experimental Summaries - Plant Research

Trial 90WH76

Alternative herbicides for diclofop-methyl resistant annual ryegrass in wheat.

Location: Wongan Hills Research Station.

To investigate the performance of alternative herbicides for the control of diclofop-methyl resistant annual ryegrass in wheat.

Trial 90WH80

Alternative herbicides for diclofop-methyl resistant annual ryegrass in lupins.

Location: Wongan Hills Research Station.

To investigate the performance of alternative herbicides for the control of diclofop-methyl resistant annual ryegrass in lupins

Trial 90A15

Alternative herbicides for Diclofop-methyl resistant wild oats in wheat.

Location: Avondale Research Station.

To investigate the performance of alternative herbicides for the control of diclofop-methyl resistant wild oats in wheat.

Trial 90A17 …

Weed Control In Cereals And Pastures Including Declared Plants., J. Peirce, B. J. Rayner

Experimental Summaries - Plant Research

Trial 90C49

Grass and broad leaved weed control in direct sown crops.

Location: Chapman Valley Research Station.

The low rate of sprayseed with diuron was not as effective on the grasses. It may indicate some antagonism within the mix as the same rate of sprayseed with metribuzin did not cause any drop in grass control. The addition of 2, 4-D amine may have boosted the mixes activity on capeweed as the sprayseed metribuzin mix was not very good on capeweed.

Trial 90EB37

Grass and broad leaved weed control in direct sown crops.

Location: East Beverley Annex.

Part of the trial …

Insecticides Based On Differences In Metabolic Pathways, Richard T. Mayer, G N. Cunningham, John T. Gupton

Chemistry Faculty Publications

Insects have been major pests of humankind at least since the beginning of recorded history. To this day insects continue to cause problems in domestic, agricultural, and health situations. It is no wonder that people have continually sought new solutions to controlling insect pests. Even when new control methods are discovered and established, insects evolve into resistant species so that the method is only of real value for a few brief years. Modern science and technology are now enabling scientists to tear away the fabric that has so long masked physiological and biochemical events critical to insects. Armed with this …

The Effects Of Crosslinking On The Stability And Autoxidation Rate Of Human Hemoglobin A, Thao Yang

Dissertations

No abstract provided.

Palladium (Ii) Catalyzed Oxidation, Isomerization And Exchange Of Olefins Allylic Alcohols And Allylic Ethers In Water And Methanol Solvents, John Wayne Francis

Dissertations

No abstract provided.

Substituent Effects On The Stereochemistry Of 1,3-Dipolar Cycloadditions To 7-Substituted Norbornadienes, Ramakrishnan Subramanian

Dissertations

No abstract provided.

Design Of A Viscometer Using Magnetostriction Of Ferromagnetic Probes, Subhendra Nath Sarkar

Journal of the Arkansas Academy of Science

On-line measurement of viscosity of process liquids at process temperature is difficult though industrially very important. A viscometer is designed which can do this up to about 300 °C almost on-line within about 1-8% accuracy except for very viscous liquids like glucose. It uses a ferromagnetic probe designed to mechanically vibrate in the ultrasonic frequency range. An excitation coil sends repeated excitation current pulses to induce mechanical vibration in the probe tip. When placed in a process fluid, the vibration amplitude is damped due to the viscosity of the fluid, and the damped vibration is sensed by Faraday's principle by …

Characterization Of Organic Sulfur Compounds In Coals And Coal Macerals, Stephen R. Palmer, Edwin J. Hippo, Michael A. Kruge, John C. Crelling

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Peroxyacetic acid oxidation has been used to investigate the type and distribution of organic sulfur species in samples of vitrinite, sporinite and inertinite, separated from the Herrin No.6 and an Indiana No.5 coal seam. It was established that organic sulfur species were selectively preserved during oxidation and their analysis led to some of the first sulfur-33 NMR spectra obtained for coal. The effects of maceral separation processes on model compounds were also studied. Results from our studies support the following conclusions: 1). Different macerals have different distributions and types of organic sulfur species. 2). Organic sulfur compounds in coal occur …

Intermolecular Potential Of The Methane Dimer And Trimer, M. M. Szczesniak, G. Chalansinski, S. M. Cybulski, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

The Heitler–London (HL) exchange energy is responsible for the anisotropy of the pair potential in methane. The equilibrium dimer structure is that which minimizes steric repulsion between hydrogens belonging to opposite subsystems. Dispersion energy, which represents a dominating attractive contribution, displays an orientation dependence which is the mirror image of that for HL exchange. The three‐body correction to the pair potential is a superposition of HL and second‐order exchange nonadditivities combined with the Axilrod–Teller dispersion nonadditivity. A great deal of cancellation between these terms results in near additivity of methane interactions in the long and intermediate regions.

Stress-Induced Infrared Frequency Shifts In Polyethylene, George A. Pfeffer, Donald W. Noid

Chemistry Faculty Publications

The molecular dynamics technique is used to study the spectral response of a polyethylene chain in a crystal environment under a mechanical deformation. The MUSIC method, which was previously shown to accurately compute dispersion curves from the time-dependent structure factor, is used. A complete characterization of frequency shifts is presented for various lamellar thickness, temperatures, stress (or pressure), and mass defects.

Geochemistry Of Selected Maine Peat Deposits, Stephen A. Norton

Maine Collection

Geochemistry of Selected Maine Peat Deposits

by Steven Allen Norton

Maine Geological Survey, Department of Conservation, Augusta, Maine, 1990.

Contents: Introduction / Purpose of Study / Location of Study Sites / Methods / Acknowledgements / Results / Water Chemistry / Dating of Short Cores / Chemistry of Short Cores / Core Interpretations / Summary / References Cited

The Imidization Of Pmr-15 Aromatic Thermosetting Polyimide, Thomas Clifton Prettyman

Dissertations, Theses, and Masters Projects

No abstract provided.

The Preparation Of And Upper Atmospheric Effects On Kevlar Films, Patricia Lynne Pate

Dissertations, Theses, and Masters Projects

No abstract provided.

Solid State Effects In The Reactions Of The Meta And Pura Trifluorodiazomethane/Beta-Cyclodextrin Inclusion Complexes, Shelley Hunnings Smith

Dissertations, Theses, and Masters Projects

No abstract provided.

Substituent Effects On The Electronic Spectroscopy Of Tryptophan Derivatives In Jet Expansions, John R. Cable, Michael J. Tubergen, Donald H. Levy

Chemistry Faculty Publications

Electronic excitation spectra of seven tryptophan derivatives entrained in a supersonic expansion have been recorded using both resonantly enhanced two-photon ionization and laser induced fluorescence. Two derivatives, tryptophan amide and tryptophan methyl amide, were found to have substantial low frequency vibrational progressions in their excitation spectra, yet in both compounds this behavior was apparent in only one conformer. Other derivatives did not display as much vibronic activity. Conformers which had vibrational progressions were found to emit in a broad band far to the red of excitation. All other conformers were found to fluoresce most strongly in resonance with excitation. The …

Indirect Photometric Chromatography Of Inorganic And Organic Anions Using Benzoate As An Eluent, Shahab A. Shamsi

Masters Theses

For many years the determination of common inorganic and organic anions was hindered by the lack of adequately sensitive analytical techniques. The determination of these anions was laborious and time consuming (e.g. titration, precipitaion, gravimetric analysis etc.). Because of the development of high-performance liquid chromatography, the anion exchange separation of simple inorganic and organic anions is now possible. Now, there are a broad and ever-increasing array of chromatographic methods supplanting these older chemical methods. However, detection is still a problem, but indirect detection provides a practical route for the detection of non-chromophoric inorganic and organic anions.

This dissertation describes the …

Biological Activity And Conformational Analysis Of Nikkomycins And Their Analogs, Eduardo Krainer

Dissertations, Theses, and Capstone Projects

Nikkomycins and polyoxins are peptidyl nucleoside antibiotics produced by Streptomyces species. They are potent inhibitors of chitin synthetases from pathogenic fungi, and polyoxins have been used in Japan for many years as agricultural fungicides and for insect control. Since chitin synthetase is not found in mammals and both families of antibiotics are not toxic, these inhibitors are potentially attractive for clinical use. Unfortunately these compounds seem to have only a fungistatic action, and they are not used clinically at present.

A procedure for efficiently obtaining nikkomycins X and Z of very high purity from crude antibiotic is described. These nikkomycins …