Physical Sciences and Mathematics Commons^™

Monsanto's Energy Conservation Program, Ray E. Doerr

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

Energy conservation is not new to Monsanto. We have had utility and process improvement programs for many years. But the motivation of these programs was to reduce our operating costs and improve profits. However, these programs did result in substantial energy savings.

Now, however, Monsanto is placing major emphasis on a broad-scale energy conservation program for all Monsanto locations. The energy saving potential is great and is necessary because of the energy shortage as well as the rapidly escalating energy costs.

Energy Conservation In The Manufacturing Process, Paul H. Kaiser

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

My presentation will cover the basic procedure used by the Emerson Electric Co. to conserve energy in Its operations. And because people frequently tell me how much they like or dislike our television sets, and how concerned they are or are not about the depth of our involvement in furnishing material for the Defense Department, at this point I would like to give a short commercial. Hopefully, it will dispel misconceptions, and define the use of energy in Emerson's operations.

An Advanced Supervisory Indication, Control & Data Acquisition System, George W. Fox

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

Electric Utility systems in the United States double in growth every ten years. This growth necessitates the construction of substations in new areas and expansion of substations in existing areas.

Troubles quite often cannot be quickly and accurately diagnosed until a sufficient number of calls have been received from customers to establish a pattern.

This paper will describe an advanced supervisory system utilizing latest state-of-the-art electronic equipment interfaced with digital computers to provide the trouble dispatcher with a rapid update as to the status of his system at all times. He will also be able to remotely control his system …

Monitoring And Control Of Electric Power Usage, Robert B. Webb

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

At the Armco Kansas City Works the consumption of Electrical Power is monitored and controlled by a General Purpose Computer located in the Electric Furnace Dept. This computer monitors the power used in the entire plant through the power metering system. The computer can limit the' power to the electric arc melting furnaces and in this manner control the demand level during peak hours. The computer can also detect meter failures. The computer system collects data which enables management to detect and analyze variations in electrical power consumption.

Development Of Industrial Energy Management Programs, Michael C. Noland

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

Energy management is a term which has only recently been entered in the business management lexicon. Until recently business managers, even the most successful ones, devoted only casual thought to the need to manage their use of fuels and electricity. Energy was cheap and plentiful. Economic sense dictated that if labor could be replaced by more energy-intense processes or equipment, the smart manager did so. Local and national policy, industrial process design, consumer habits--all these and more encouraged massive energy consumption.

Introductory Remarks, Joseph T. Zung

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

No abstract provided.

1st Umr-Mec Conference On Energy Resources -- Entire Proceedings, University Of Missouri--Rolla

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

No abstract provided.

A Solar-Hydrogen Energy Conversion Scheme For Agricultural Use, R. L. Reisbig, Jack L. Boone, Gordon E. Weiss, Thomas Van Doren

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

A solar energy activated system is presented which can produce hydrogen and hydrogen-derived fuels (methanol) for use on farms. The device, named "solar-kine", also can produce fertilizer (anhydrous ammonia) as a byproduct of the hydrogen. A cost analysis shows that solar-kine may be mass-producible and sold to farmers for between $7,200 and $14,700. This is equivalent to giving the fanner energy at a price of $1.79 to $3.66 per million BTU's (in 1974 dollars). Presently (Spring, 1974) regular gasoline used in tractors at 43¢ per gallon, represents a cost to the farmer of $3.77 per million BTU's. As oil-based fuels …

Introduction -- Solar And Wind Energy, Jack L. Boone

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

In recent years the scientific community has begun to explore the many alternatives of using solar energy in terms of solar energy conversion schemes. These, in general, may be classified according to use. We can talk about solar to low-grade thermo residential heating and cooling applications. We can talk about solar to high-grade heat for such applications as steam powered generation and certain high-temperature conversion processes. We can talk about solar to electrical for either residential or for large power production installations; and we can talk about wind to electrical and this would, of course, come in both large and …

Auditing Program For Effective Energy Conservation, S. Noble Robinson

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

Mallinckrodt Chemical Works has developed and is using a special audit format to identify conservation opportunities for all its utilities. Manufacturing, Utilities, R & D, and Engineering personnel are collected together for several days during which time a process or operation is subjected to an intense analyses of its utilities consumption, a brain-storming of conservation ideas, and then an "on-the-spot" engineering analysis of the economics and feasibility of each idea. This technique is a fast, comprehensive way to assess conservation potentials while committing the attention of those operating groups that can implement the ideas.

A Calorimetric Study Of Metal Binding In Carboxypeptidase, Carbonic Anhydrase And Concanavalin A, Gary E. Hatch

Theses and Dissertations

The purpose of this study was to perfect a new calorimetric method for identifying and counting ionizable chemical groups on proteins. To do this, calorimetric and electrometric titrations were performed (using HCl and NaOH as titrant) on native carboxypeptidase, carbonic anhydrase and concanavalin A plus their apo and organic ligand bound derivatives. Readily identifiable endpoints were seen in the calorimetric titrations and general agreement was found between ΔH values obtained in this study and literature ΔH values of model compounds undergoing the same reaction. Imidazole groups were those most easily counted. Many assumptions had to be made, however, in concluding …

Ortho-Substituent Effects On Reactivities Of Benzohydroxamic Acids, Irl E. Ward

Masters Theses

No abstract provided.

Trace Metal Analysis Of Hair By Charged Particle X-Ray Fluorescence, George M. Allison

Theses and Dissertations

A method for the trace element analysis of hair by charged particle X-ray fluorescence is presented. The validity of the method is shown by the analysis of NBS SRM 1577--Bovine Liver, obtained from the National Bureau of Standards. Excellent correlation is obtained between results from the analysis by the X-ray method and those certified by NBS. Hair samples are ashed by a low temperature oxidation process and analyzed by the X-ray method. The results from the analysis by the X-ray method are compared to those obtained from the analysis of the same hair samples by atomic absorption. Good correlation is …

Macrocyclic Polyether Sulfide Syntheses, The Preparation Of Thia-Crown-3, 4, 6, And 7 Compounds, Yau-Kwong Joseph Hui

Theses and Dissertations

Macrocyclic polyether sulfides have been prepared by reacting an oligoethylene glycol dichloride with a dithiol or sodium sulfide in ethanol. The following new compounds were prepared: 1-thia-(9-crown-3), 1,4-dithia-(9-crown-3), 1,4-dithia-(12-crown-4), 1,4,7-trithia-(12-crown-4), 1-thia-(18-crown-6), I,4-dithia-(18-crown-6), 1,7-dithia-(18-crown-6), 1,4,7-trithia-(18-crown-6), 1,7-dithia-(21-crown-7), 1,4,7-trithia-(21-crown-7). Four other previously reported macrocyclic polyether sulfides were also prepared. The symmetry of the nmr spectra of these compounds give added evidence for the proposed ring structures. The following subjects were presented and discussed: studies of cyclization by-products, dependence of cyclization yield on the size of the rings, high dilution principle and its application, medium-sized rings, effect of hetero-atoms on cyclization and melting point …

The Solution Photochemistry Of Benzaldehyde In Benzene, Ethanol, And 1-Hexyne, Ronald Douglas Knudsen

Theses and Dissertations

The photoreactions of benzaldehyde in benzene, ethanol, and 1-hexyne have been studied. Irradiation of benzaldehyde in benzene produces benzoin (I), hydrobenzoin (II), and deoxybenzoin (III). Irradiation of benzoin (I) in this solvent results in benzaldehyde formation as well as small amounts of (II) and (III). The ethanol irradiation of benzaldehyde resulted, predominantly, in the formation of (II) with (I) formed in small amounts. The photolysis of benzaldehyde in 1-hexyne produces (I), (II), (III) cis-2-heptenophenone (VII), trans-2-heptenophenone (VIII), heptanophenone (IX), and 2-(n-butyl)- 1,4-diphenyl-1,4-butanedione (X). Mechanistic pathways for the formation of these photoproducts are discussed. Separation and characterization of cis- and trans-2- …

A Systematic Approach To Organic Qualitative Analysis Using Mass And Nuclear Magnetic Resonance Spectroscopy, Duane R. Greenly

Morehead State Theses and Dissertations

A thesis presented to the faculty of the School of Science and Mathematics at Morehead State University in partial fulfillment of the requirement for the Degree of Master of Science by Duane R. Greenly on January 14, 1974.

Front Matter, University Of Missouri--Rolla

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

No abstract provided.

Oxidation Reactions Of Unsaturated Hydrocarbons For Fuel Cells, James W. Johnson, William Joseph James, A. K. Agrawal

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

The anodic oxidation of unsaturated hydrocarbons has been the subject of numerous studies, primarily on Pt and Au electrodes at low temperatures, < 100°C. The complete oxidation to CO₂ is usually the predominant reaction with both H₂O and OH^- having been proposed as the oxygen source. Usually a single study consists of a comprehensive investigation of a single compound on a single electrode or a somewhat limited study of several compounds on a single electrode. A diversity of proposed mechanisms has resulted and is illustrated by the following summary.

History Of So2 Removal System At The Meramec Plant Of Union Electric, Gerald E. Dreifke, John F. Mclaughlin, Jerrel D. Smith

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

In line with the then emerging air pollution control regulations Union Electric installed a limestone injection wet scrubber sulfur dioxide removal system on an intermediate size coal-fired utility boiler at its Meramec Power Plant on an experimental basis in September, 1968. During approximately 3 years of operation many difficulties were encountered with plugging and scaling of various system components by calcium sulphate. As a result of this experience along with related experiences by other utilities employing similar systems, the experiment was terminated in June, 1971.

As a result of the experiences gained, however, second generation experiments in sulfur dioxide removal …

Reduced Nicotinamide Adenine Dinucleotide Dehydrogenase, Piericidin Sensitivity, And Site 1 Phosphorylation In Different Growth Phases Of Candida Utilis, S. Grossman, John G. Cobley, T. P. Singer, H. Beinert

Chemistry Faculty Publications

Reports in the literature indicate that during the exponential phase of growth of Candida utilis NADH oxidation is insensitive to rotenone, that rotenone sensitivity is acquired during the transition to the late stationary phase and is again lost on catabolite repression. The acquisition and loss of rotenone sensitivity appears to be accompanied by similar changes in Site 1 phosphorylation but does not appear to be reflected in the rate of oxidation of NADH (by mitochondria) or of NAD-linked substrates (by mitochondria or whole cells). In the present paper evidence is presented that these fluctuations in sensitivity to inhibitors of NADH …

Radiation Testing Under Simulated Loca Conditions, Kenneth G. Mayhan, D. R. Edwards, W. F. Oberbeck, J. F. Montle

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

The purpose of this evaluation is to gather data to determine whether or not radiation during a simulated Loss of Coolant Accident would have any effect upon the coatings being used. Because of the concern in industry regarding the safety of nuclear power generating stations and the strong actions of the various environmentalist clubs and agencies clubs and agencies, the utilities have been required to prove the safety of the power facilities to extraordinary degrees before licensing can be obtained to operate. One of the areas regarding the safety is the necessity of proving that the coatings will remain intact …

Future United States Energy Demand Patterns, Leland Blank, Richard Riley

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

The future energy demands of the United States are forecast using a unique approach. The saturation forecasting method reflects the inability of an individual to utilize more than a limited amount of energy. This technique also allows evaluation of various conservation methods and their effects on the future energy needs.

Film Formation On Anodically Polarized Lead, H. Vaidyanathan, Ram A. Narasagoudar, Thomas J. O'Keefe, William Joseph James, James W. Johnson

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

The Effect Of Surface Impurities On The Thermal Accommodation Of Rare Gases On A Tungsten Surface, D. Vincent Roach, Louis Biolsi, Robert E. Harris

Chemistry Faculty Research & Creative Works

A Rather Comprehensive Experimental Examination of the Effect of Surface Impurities (Potassium and Cesium) on the Thermal Accommodation of Rare Gases on a Tungsten Surface Has Been Made by Roach and Thomas. the Present Work Examines These Effects from a Theoretical Viewpoint with Particular Emphasis on the Effect on the Thermal Accommodation of Helium on a Tungsten Surface Caused by the Adsorption of Cesium Ions And/or Atoms. for This Examination, the Theory of Allen and Feuer Has Been Utilized using Reasonable Values of the Interaction Parameters for Helium with the Adsorbate as Well as the Force Constant for the Adsorbate-Substrate …

Effects Of Surfactants On Atomic Absorption Analysis Of Dilute Aqueous Copper And Nickel Solutions, Raymond L. Venable, Robert V. Ballad

Chemistry Faculty Research & Creative Works

No abstract provided.

A Study Of Oxomolybdenum Chelate Compounds Of Oxidation States (V) And (Iv) When Prepared By Photochemical Reduction Of Oxomolybdenum (Vi) Complexes In Ethanol Under Inert Atmosphere And By Chemical Reduction, Richard Donald Dendinger

Electronic Theses and Dissertations

A photolysis system was designed for meticulous exclusion of oxygen and moisture. Photolyzed ethanol solutions of dioxobis(acetylacetonato)­-molybdenum(VI), Mo0₂ (acac)₂, were studied via preparation of derivatives with several uninegative bidentate ligands (chelH, cysteine was designated cystH₂) and pyridine (py). Infrared spectroscopy was a useful tool in identifying these compounds. An oxomolybdenum(IV) compound, MoO(dtc)₂ was isolated from the red photolyzed solution when dtc was the N,N-diethyldithiocarbamate ion. Tropolone, 8-hydroxyquinoline, N,N-diethyldithiocarbamate, and cysteine formed products formulated as the dioxo bridged molybdenum(V) compounds, Mo₂0₄(che1)₂. Acetylacetone, tropolone, 8-Hydroxyquinoline and N,N-diethyldithiocarbamate, formed derivatives formulated …

Chemistry Departments In Predominantly Black Institutions, James O. Wear, Nirmal K. Shastri

Journal of the Arkansas Academy of Science

Chemistry programs in 87 predominantly Black institutions were compared by questionnaire survey. Advanced undergraduate courses were offered for chemistry majors by 86% of these schools, but only 28% offered research and independent study for undergraduates. Although there were extremes, most of the faculty taught 15 to 18 contact hours and their median salaries were below the national median. Library support seemed adequate with 1 to 1.5% of the total library materials being chemistry books, texts and reference, and the libraries of most schools had holdings of 15 principal chemistry-related journals. More than 90% of the schools were well-equipped with laboratory …

Nitrous Acid Deamination Reactions Of Benzyl Amino-4,6-0-Benzylidene-D-Hexopyranosides, Wai-Pan Chan

University of the Pacific Theses and Dissertations

This study concerns an investigation of nitrous acid deamination of various amino sugar derivatives. Deamination reagents have also been used for the diazotization of aromatic compounds. Nitrous acid deamination was used in the deamination of amino acids pinacolic amino alcohols and amino sugars.

Metal Promoted Reactions Of Enamino Ketones, Suhas Satchidanand Joshi

Masters Theses

The reaction of 4-amino-3-allyl-3-penten-2-one (7) with mercuric acetate in acetic acid was found to produce 4-amino-1-pentene (12) in 70% yield. The scope of this unusual cleavage reaction was investigated by systematic variation of substituents on the enamino ketone framework, the metal salt and the solvent. The presence of the allyl group was necessary for the reaction to produce compound 12.

Under a variety of conditions there was no evidence for cyclization of 7 to give heterocyclic compounds. Neither was there evidence for cyclization in reactions of 4-amino-3-penten-2-one with vinyl acetate in the presence of mercury (II) or thallium (III) salts …

The Chemical And Electrochemical Oxidative Decarboxylation Of Methyliminodiacetic Acid In Acid Media, Rita Kathleen Hessley

Doctoral Dissertations

"Methyliminodiacetic acid (MIDA) is oxidized with cerium. (IV) in both perchloric and sulfuric acids to give sarcosine, formaldehyde, and carbon dioxide"--Abstract, page 2.