Physical Sciences and Mathematics Commons^™

The Electrochemical Behavior Of The Lead-Thallium System In Acidic Sulfate Solutions, Pedro Juan Aragon

Doctoral Dissertations

"Although the literature involving the corrosion of pure lead in sulfuric acid solutions is extensive, such studies still constitute an active field of investigation and debate. Much of the effort expended on this subject is due to the need of a better understanding of the reaction in lead storage batteries as well as of the mode of electrocrystallization processes. The resistance of lead to attack by sulfuric acid renders it an important coating material in this media. It is also often used in electrochemical synthesis because of its overvoltage characteristics. Unfortunately its mechanical properties are poor, and many ways have …

The Ultraviolet Absorption Spectra Of Solutions Of 2, 4, 6-Trimethoxybenzoic Acid In Sulfuric Acid, Kathy Show-Shing Ho

Masters Theses

"Studies of the ultraviolet and proton magnetic resonance spectra of solutions of 2,4,6-tribromo-, trichloro-, trimethyl- and trinitro-benzoic acids dissolved in concentrated sulfuric acid by Dr. D. W. Beistel and his coworkers lead to the synthesis of the corresponding benzoate esters. In the present work the nature of ionic species formed in mixtures of sulfuric acid and 2,4,6-trimethoxybenzoic acid was examined, The spectral data suggest the presence of species similar to those assigned for the previous trisubstituted analogs, together with a species capable of fluorescence in the 2400 Å region. The reason of this unprecedented fluorescence has not been established"--Abstract, Page …

The Electrochemical Oxidation Of 1-Pentyne On Platinum And Gold, Michael Jensen Danielson

Doctoral Dissertations

"The anodic oxidation of 1-pentyne was studied at 70°C on Pt and Au electrodes in solutions of H₂SO₄, K₂SO₄, K₂CO₃, and KOH. Pt was studied in a pH range of 0.35 - 12.7 and Au in a range of 10.9 - 12.7. Reaction rates were measured as a function of potential, pH, temperature, and 1-pentyne partial pressure. The coulombic efficiencies for the oxidation to CO₂ were 77 percent in 1 N H₂SO₄ and 69 percent in 1 N KOH on Pt and 43 percent in 1 N KOH on Au. The kinetic parameters on Pt were [partial derivative]V/[partial derivative]log i …

The Semibullvalene Question: A Semi-Empirical Molecular Orbital And Bond Energy Approach, Shiow Yeh Lee

Masters Theses

"Semi-empirical molecular orbital calculations of the Extended Ruckel and MIND0/1 type have been performed on semibullvalene and the supposed transition state for its degenerate [3,3] sigmatropic rearrangement. The results have been coupled with bond energy calculations to ascertain whether semibullvalene is homo-aromatic or is undergoing a rearrangement of exceedingly low activation energy. A preponderance of the resulting data suggests that semibullvalene is homo-aromatic"--Abstract, page ii.

The Orientation Of Crystallites In Molded Graphites, David R. Schryer

Dissertations, Theses, and Masters Projects

No abstract provided.

Studies On The Thiocyanato Complexes Of Niobium, Richard Paul Barrett

Dissertations, Theses, and Masters Projects

No abstract provided.

Investigation Of The Alpha-Sub-Gamma Phase In Alnico 6, Cortez Samuel

Dissertations and Theses

The purpose of this research project was to study the αᵧ phase in Alnico 6. Other phases were studies for comparison. Also the effect of an applied magnetic field on the formation of the αᵧ phase was investigated.

Three single crystals of Alnico 6 were heat treated for one hour—one at 1250°C, one at 1000°C, and one at 800°C—and water-quenched. The microstructure of each sample was observed with the optical microscope, and X-ray diffraction patterns were taken to determine the crystal structure of the phases present.

Several single crystal samples of Alnico 6 were heat treated at 1000°C and furnace-cooled. …

Amino Acid Sequence Of An Iodotyrosyl-Containing Peptide Produced By Tryptic Digestion Of Thyroglobulin, Pai-Chun Chiang

Masters Theses

"Thyroglobulin was digested with trypsin. An iodotyrosyl-containing peptide was isolated from tryptic digests by a combination of electrophoresis and paper chromatography. The amino acid sequence of this peptide was determined by applying the Edman degradation and by using the proteolytic enzyme, carboxypeptidase A. The sequence of this peptide is: NH₂-Ala-Ile(Leu)-Ala-Ser-Phe-Gly-Asp-Tyr-Glu-Phe-COOH The importance of the position of the tyrosyl residue which is iodinated to form monoiodotyrosine (MIT) , diiodotyrosine (DIT) , and thyroxine (T₄) is considered in connection with the structure-activity relationship of the protein"--Abstract, page ii.

The Possible Correlation Of Carcinogenic Activity With Electronic Structure Of Benz(A)Anthracene, Patricia Joan Blair

Masters Theses

"The electronic structure of benz(a)anthracene based on the sigma and pi electrons was predicted by the modified intermediate neglect of differential overlap (MINDO) molecular orbital method and compared with the pi electronic structure determined by the Pople method. The crystalline molecular structure was used for both methods. The Pople calculation was also done on the aromatic molecular structure and a combination structure which assumed the bond lengths of the crystal structure and the bond angles of the aromatic structure. Chemical properties predicted by the MINDO and POPLE electronic structures were compared; the MINDO results provided the best agreement with experimental …

Mass Spectrometric Study Of "Anomalous" Water, Bernard Jean Bouy

Masters Theses

"Considerable interest has developed recently in a material called "polywater" or "anomalous water". This material has properties quite different from those normally associated with liquid water. The purpose of this study is to give some mass spectrometric observations of "polywater". The "polywater" samples were produced within silica capillaries. These capillaries were heated by means of a helical coil to vaporize the "polywater". The vapor was directed into the source of a mass spectrometer. The results of this study show that a significant portion of the "anomalous water" samples is composed of a polymer of dimethylsiloxane. To date, the observations are …

The Radial Distribution Curve Of "Anomalous" Water By X-Ray Diffraction, Jerome Dechelette

Masters Theses

"Amorphous and liquid samples, believed to be "anomalous" water were studied by X-ray diffraction. A diffusion ring, characteristic of liquids and glass was observed at Θ =10.5º. For purposes of comparison an X-ray diffraction pattern was obtained for pure water under nearly identical conditions. By means of a microdensitometer, X-ray intensity curves were prepared from the diffraction patterns and corrected for absorption and polarization. From the Fourier transform of the intensities, we obtained the radial distribution curves. The radial distribution curve for water, obtained in previous work, shows an initial peak at 2.9Å. This peak is due to the nearest …

A Study Of The Oxygen Exchange Between Chromate Ion And Water, James Hsiao-Hsin Chiang

Masters Theses

"The kinetics of the isotopic exchange reaction between O¹⁸-enriched chromate ion and solvent water have been measured as a function of pH and chromate ion concentration. The exchange kinetics can be explained in terms of the dimerization equilibria HCrO_4̄ + Cr₂O[subscript 7 with double dash above] [double arrows] Cr₂O[subscript 7 with double dash above] + OH⁻ and 2HCrO_4̄ [double arrows] Cr₂O[subscript 7 with double dash above] + H₂O except at high pH, where it is independent of pH. Rate constants at 30ºC for the reactions of the dimerization equilibria and the first order reaction at the high pH …

Enhanced Evaporation Of Water Droplets Due To Surface Contamination, Robert Bernard Hughes

Masters Theses

"Experimental evidence for enhanced evaporation of small (3-9 µ radius) water droplets are presented. Both "pure" droplets and droplets contaminated with surface active materials fell into air of known relative humidity (96-99 per cent) at an ambient temperature of 29.9C and evaporated. The rates of evaporation were determined by photographing the evaporating drops, measuring the distance a drop fell during a fixed time interval, and applying Stokes law. The contaminated droplets exhibited a rate of evaporation 1.8µ² sec⁻¹ faster than "pure" drops. This can be compared with rates for pure drops of 1.9 and 5.7µ² sec⁻¹ at 0.1 and 0.3C …

A Study Of The Esterification Of 2,2,4,4-Tetramethyl-1,3-Cyclobutanediol, Lewis Metzler Naylor

Dissertations and Theses @ UNI

The purpose of this research was to prepare, identify, and characterize 2,2,4,4-tetramethyl-1,.3-cyclobutanediol bischloroacetate using 2,2,4,4-tetramethyl-1,3-cyclobutanediol and monochloroacetic acid as starting materials. The synthesis of this diester has not been reported previously.

Catalyzed and uncatalyzed reactions were attempted, with the uncatalyzed having, in general, the better yield. The diester, trans-2,2,4,4-tetrametbyl-1,3-cyclobutanediol bischloroacetate (mp, 103.5-104; n²², 1.516-1.520), was isolated from a mixture of the isomers. The trans configuration of the diester was confirmed by comparing known nuclear magnetic resonance spectra to that of the diester. Infrared spectroscopy was used to confirm functional groups. Standard analytical techniques were used to determine chloride …

Ua66/7/2 Newsletter, Wku Chemistry

WKU Archives Records

Newsletter created by and about the WKU Chemistry department.

Dimethyl Sulfoxide Oxydation Of Hydroxy-Steroids And Studies On The Oxidation Of The 5’–Hydroxy Group Of Nucleosides, Carmen V. Zenarosa

Dissertations

Introduction

In our earlier work we demonstrated the usefulness of the acidcatalyzed reaction between N-(p -tolyl)diphenylketenimine (21) and dimethyl sulfoxide (DMSO) for the oxidation of secondary alcohols. This was exemplified by the oxidation of 2',3'-O-isopropylideneadenosine and other secondary alcohols.¹ We have now extended this procedure to the oxidation of hydroxy-steroids.

Alkynylamines or ynamines can be written in two resonance forms: R-C≡C-N R'₂ and R-C=C=NR'₂. Because of the close similarity between the latter structure and the structure of a ketenimine (R₂C=C=N-R') and the ability of sulfoxide-ketenimine to effect the oxidation of secondary alcohols, we …

Transpiration Measurements Of The Decomposition Pressures Of Barium Hexafluorosilicate, Kemal Cankaya

Masters Theses

No abstract provided.

Simultaneous Knudsen- And Torsion- Effusion Measurements Of The Vapor Pressures Of Tetraphenyltin And Hexaphenylditin, Dale Keiser

Masters Theses

No abstract provided.

The Effect Of The Rate Of Formation On The Structure And Properties Of Paper, William M. Reif

Masters Theses

Paper contains an uneven distribution of fiber fractions through its cross section. The objective of this study was to determine how the rate of formation affected the structure and properties of paper. The structure of paper was analyzed with reference to the cross-sectional distribution of fines and the fines to long fibers ratio in the paper.

The formation rate and distribution of fins were varied by applying a vacuum to the British sheetmold system. As the fines were a different color than the long fibers, their distribution was determined by analyzing the brightness values of layers split from the paper. …

Preparation And Lead Tetraacetate Oxidation Of Aldehydic Hydrazones, Alan J. Quarfoot

Masters Theses

No abstract provided.

The Isoelectronic Principle And The Accuracy Of Binding Energies In The Hückel Method, Jerry Goodisman

Chemistry - All Scholarship

In the Hükkel and other methods, binding energies are calculated by subtracting the sum of orbital electronic energies for the molecule from the sum of orbital electronic energies for the separated atoms, and not considering the internuclear repulsion. Since this last may be several orders of magnitude greater than the binding energy, reasonable results could not be obtained without an approximate cancellation with another neglected term. It is shown that such a cancellation is a consequence of the isoelectronic principle (invariance of binding energy to change in atomic number of constituent atom). Numerical examples are given.

Mössbauer Effect In The Ferroelectric Pbtio₃-Bifeo₃ Solid Solutions, C. M. Yagnik, James P. Canner, Robert Gerson, William Joseph James

Physics Faculty Research & Creative Works

The Mössbauer spectra of the system (PbTiO₃)_0.95(BiFeO₃)_0.05 have been studied from room temperature to 585°C. From the isomer-shift of 0.491±0.02 mmsec^-1 at room temperature, the ionicity is found to be 60% ± 20%. A discontinuity in the plot of isomer-shift versus temperature at T_c is observed. The quadrupole splitting at room temperature is 0.295 ± 0.02 mm/sec^-1. A dip in the Mössbauer fraction is observed at the Curie temperature.

Quasilattice Interpretation Of The Thermodynamic Properties Of Mixing Of Binary Alkali-Metal Systems, J. Bevan Ott, J. Rex Goates

Faculty Publications

Quasilattice theory was applied to heats of mixing in the six systems formed from the binary combinations of Na, K, Rb, and Cs. The alkali-metal systems are particularly well suited for a critical test of the quasi-crystalline assumption since the theoretical model for these systems is relatively simple and the thermodynamic data are fairly complex. Very good fits of the heat-of-mixing data were achieved by assuming that the larger atom in the binary system covered multiple sites on the quasilattice. The values of the empirically determined constants appear to fit the physical significance accorded to them by the quasilattice model. …

11th Annual Rocky Mountain Spectroscopy Conference

Rocky Mountain Conference on Magnetic Resonance

Program and abstracts from the 11th annual meeting of the Rocky Mountain Spectroscopy Conference, sponsored by the Rocky Mountain Section of the Society for Applied Spectroscopy. Held in Denver, Colorado, August 4-5, 1969.

Data Retrieval In Mass Spectrometry By An Optical Coincidence System, Cynthia Helmintoller O'Donohue

Master's Theses

The object of this work was to develop an information storage and retrieval system for use in mass spectroscopy. The information to be stored was the compound's name, the mass spectrum, and distinctive physical and chemical properties. It was desirable that the system be one that could be used in the mass spectral laboratory. At the time this project was initiated, no system for mass spectroscopy had been developed with the characteristics of simplicity, rapid retrieval, and practicality of use in the laboratory without elaborate and space consuming equipment. Thus, a system was needed to aid the laboratory personnel in …

The Wittig Reaction Of Stabalized Phosphonium Ylids With Derivatives Of D-Ribose, George Robert Wellman

Masters Theses

No abstract provided.

Solid-Liquid Phase Equilibria Of The Sodium-Rubidium And Sodium-Potassium-Rubidium Alloy Systems, Chen-Chao Hsu

Theses and Dissertations

Thermal methods were used, to determine with high precision, the solid-liquid phase equilibria diagrams for the sodium-rubidium and sodium-potassium-rubidium systems. In the sodium-rubidium system, the results differ greatly from those of earlier works, especially near the eutectic composition where differences in freezing points as large as 25°K occur. A detailed search was made for possible intermetallic compounds (especially Na2Rb). Neither slow temperature cycling in the temperature range where compound formation could occur nor extended periods of annealing just above the eutectic temperature produced any evidence for compound formation in the sodium-rubidium system. A 2:1 (sodium to rubidium) sample was subjected …

The Effects Of Herbicides On Three Soil Inhabiting Blue Green Algal Species, Lee C. Darlington

All Master's Theses

The object of this study was to examine the effects of varying concentrations of 2, 4-D, Dalapon, and Tordon on the growth of several nitrogen-fixing blue-green algal species obtained from soil samples and grown under culture conditions in the laboratory.

Estimations Of The Effective Electrolytic Surface Area Of Rough And Porous Silver Electrodes ; Ii. Potentiostatic Oxidation Of Silver In Alkaline Electrolyte, James Glenn Bearss

Theses and Dissertations

This dissertation is written in two sections. The first section deals with the development of methods for the estimation of the effective electrolytic surface area of rough and porous silver electrodes in alkaline electrolyte. Data are presented comparing the results of three different methods of surface area estimation. Model pore electrodes were also prepared and oxidized to study the reactions in a pore. Data for constant current oxidations of these electrodes is given. The second section deals with the potentiostatic oxidations of silver in alkaline electrolyte. Data are presented on the total charge acceptance versus applied potential for a potential …

The Attempted Synthesis Of Ethylenimine, Rabindranath Patnaik

Masters Theses & Specialist Projects

The object of this investigation was to study the homogeneously catalyzed reaction of acetylene and ammonia and particularly to attempt to synthesize ethylamine by the reaction of acetylene and ammonia.