Physical Sciences and Mathematics Commons^™

Characterization And Determination Of Aldehydes By The Ultraviolet Spectral Changes Resulting From Acetal Formation, Edwin Patrick Crowell

Master's Theses

Aldehydes are a very important group of organic compounds because they have been round to contribute t the flavor and odor of many foods and plants . To the organic chemist, aldehydes are important because of their reactivity and interesting chemistry.

Because aldehydes are so prevalent in natural products and because they have . wide use in industrial and synthetic chemistry, their analytical chemistry is extensive . Despite this, there is still a need for rapid, simple, and general procedure for characterization or aldehydes that is not subject to extensive interferences.

The primary purpose of this study was to develop …

The Synthesis And Medicinal Chemical Study Of Some Pyridazones, Winnifred M. Osner

Chemistry and Chemical Biology ETDs

An examination of the literature revealed that the majority of pyridazines prepared were substituted in the three and six positions. Therefore, it appeared appropriate to prepare four and five substituted pyridazines.

Cobalt : Its Use To Control Wasting Disease, Laurence C. Snook

Journal of the Department of Agriculture, Western Australia, Series 4

FOR many years it was assumed that in Western Australia cobalt deficient areas were restricted to a coastal fringe which rarely extended more than 20 miles inland.

This has proved a costly false assumption. During recent years cobalt deficiency has been diagnosed over extensive areas of inland country.

Low Temperature Infrared Cell And Its Application In Isoprene And Nitrogen Dioxide Reaction Studies, Gunars Vilcins

Master's Theses

The purpose of this research was to explore the application of low temperature infrared spectroscopy to the study of several chemical problems. In particular the following items were investigated:

1. The design, manufacture, and operation of a low temperature optical cell suitable for infrared spectroscopic studies or gas-solid samples at liquid nitrogen temperature (-196°c) and above.

2. The recording and study of the infrared spectra or nitrogen dioxide and isoprene at 25°c and at lower temperatures.

3. A preliminary study of the reaction between nitrogen dioxide and isoprene at various temperatures using infrared techniques.

In recent years infrared studies have …

Electron Transport Particles From Bacillus Stearothermophilus, Ronald J. Downey, Carl E. Georgi, Walter E. Militzer

Chemistry Department: Faculty Publications

DOWNEY, RONALD J. (University of Nebraska, Lincoln), CARL E. GEORGI, AND WALTER E. MILITZER. Electron transport particles from Bacillus stearothermophilus. J. Bacteriol. 83:1140- 1146. 1962-Electron-transport particles (ETP) have been isolated from Bacillus stearothermophilus. They are capable of oxidizing such substrates as succinate, malate, diphosphopyridine nucleotide, p-phenylenediamine, and hydroquinone. Difference spectra indicated bands of cytochromes a₃, b, and c. A chromatographic procedure for purification of cytochrome c has been described.

The role of quinonelike intermediates in the ETP was implied by the restorative effect of coenzyme Q and vitamin K₁ on material treated …

Application Of The Sideband Technique To Wide-Line Nmr Spectra, Juana Vivó Acrivos

Faculty Publications, Chemistry

No abstract provided.

Soft Water For Dairy Cleaning, Department Of Agriculture, Western Australia

Journal of the Department of Agriculture, Western Australia, Series 4

CLEAN utensils are essential for the production of high quality dairy products.

Cleanliness of dairy equipment depends a lot on how efficiently the detergent can do its job.

Application Of The Sideband Technique To Wide-Line Nmr Spectra, Juana Vivó Acrivos

Juana Vivó Acrivos

No abstract provided.

A Review Of The 1961-1962 Silage Competition, H G. Elliott

Journal of the Department of Agriculture, Western Australia, Series 4

FOR the past five years the Australian Dairy Produce Board Pasture Improvement Committee (W.A.) has sponsored a silage competition in the dairying areas.

Judging is done by the officers of the Dairy Division of the Department of Agriculture and prize money totalling £175 is awarded.

A New Approach To General Chemistry Laboratory In College (With) A Laboratory Manual For General Chemistry, Constantine G. Vlassis

University of the Pacific Theses and Dissertations

Statement of the problem. This study was carried out to determine: (1) what advantages a laboratory-centered general chemistry course might have over the conventional laboratory course, and (2) whether improved understanding of laboratory work leads to better learning of chemistry. The four following questions were raised in connection with the study or this problem:

1. What is the need for a laboratory-centered course?
2. What has been done in the past to meet this need?
3. Can students learn chemistry more effectively in a laboratory-centered course as compared to the conventional course?
4. Is a laboratory-centered course to be preferred over the conventional course …

A Laboratory-Centered General Chemistry Course For College Freshmen, Alexander Vavoulis

University of the Pacific Theses and Dissertations

In order to give the laboratory-centered course a trial run and to compare it with a lecture-centered course it seemed necessary to the author that both courses should be taught and compared. The latter gave rise to the following hypotheses:

1. Students in a laboratory-centered general chemistry course show more favorable attitudes toward chemistry than do students in a lecture-centered course.
2. Students in a laboratory-centered course show as good a subject-matter mastery as students in a lecture-centered course.

Determination Of Indium Using The Dead Stop End Point, Laurence Stanley Martens

University of the Pacific Theses and Dissertations

As the importance of indium for research and industry grows, the need for rapid, accurate analysis of the metal Increases. The dead stop titration method, which has been used for other metals, will now be applied to the quantitative determination of indium ion in aqueous solution.

The uses of indium. Indium metal las found increased used during the last few years and is now comercially available. For a long time after its spectroscopic discovery in 1863 by Reich and Richter, it was regarded as little ore than further substantiation of the chemist's periodic classification of the elements. The first major …

The Dielectric Strength Of Some Anti-Corrosive Paints, George Albert Chappell Iii

Masters Theses

"Corrosion has been one of the costly problems to industry because each year losses due to corrosion are in excess of six billion dollars. Corrosion is caused by the tendency of all metals to become oxidized and return to their natural state. Oxidation may be suppressed by restraining the flow of electrons from the system, thereby inhibiting corrosion.

One effective means to prevent rusting is by applying a barrier of paint between the system and the corrosive atmosphere. Not all paints, however, are equally effective as corrosion inhibitors. At present, the only effective means of determining the corrosion resistant ability …

Studies Involving Modification Of The Megregian Method Of Fluoride Determination And Application To Fluoride Balance Studies In Infants, Gene R. Wright

Masters Theses

Introduction

At the request of Dr. Frederick Margolis, M.D., and in association with The Upjohn Company, this research problem was initiated as a participation in the investigation of whether or not fluoride ingested as a constituent of the Upjohn 47-M liquid vitamin preparation is retained in an infant's body to the same extent as is fluoride ingested as the sodium salt by itself--either in solution or in tablet form. The retention patterns may be studied indirectly by measuring the amounts of fluoride excreted in the urine and in the feces during each of a series of equal time intervals after …

The Reaction Of N-Magnesium Halides On Nitriles In The Synthesis Of Amidines, Robert Bauer

Masters Theses

Introduction

Compounds of the amidine class have long been of interest because of their therapeutic and pharmacological properties. Members of this class of compounds have been shown to be effective in combating pathological conditions ranging from virus (11), bacterial (12), and protozoal infections (7) to diseases of the circulatory system (6), neoplasms (5) and hyperglucemia (21), Since many basic nitrogen compounds have been of interest in cancer chemotherapy, such as a variety of amino alcohols shown by the Upjohn Company to have anti-tumoral activity, it was felt that additional investigations into the use of amidines and amino amidines in this …

The Separation Of Germanium From Lead, Cadmium, And Zinc By Ion Exchange, Myra Sue Anderson

Masters Theses

"The object of this study was to investigate the ion exchange behavior of germanium in order to find a quantitative separation method applicable to the analysis of germanium in zinc ores.

Germanium had been predicted and described as eka-silicon by Mendeleeff, and was discovered by Winkler in 1886. The importance of the metal has increased very much since World War II because of its use as a semiconductor in diodes and transistors.

All commercial scale germanium is now produced as a by-product of base metal processing. Although the United States Bureau of Mines is conducting a program for the recovery …

A Study Of The Colloidal Properties Of Zirconium And Promethium By Electrodialysis And Liquid-Liquid Extraction, James N. Click

Masters Theses

"The purpose of this investigation was to study the solution chemistry of zirconium by investigating the colloidal behavior of natural zirconium and zirconium-95, utilizing electrodialysis and liquid-liquid extraction techniques. Also incorporated into this study was the investigation of optimum conditions for the extraction of the natural zirconium and zirconium-95 with thenoyl trifluoracetone. A limited amount of work was done on the colloidal nature of promethium-147"--Introduction, pages 2-3.

A Study Of The Behavior Of Zirconium In Aqueous Solutions And The Separation Of Radioactive Zirconium By Electrodialysis, Charles William Brauer Jr.

Masters Theses

"Nuclear reactor installations designed for power production must of necessity operate at higher energy levels than their experimental precursors. As these facilities increase in number, better solutions must be found for both technical and economic problems.

The disposal of waste materials is of primary importance and will require greater effort if satisfactory disposal methods are to keep pace with the increase of waste materials, produced by the increasing number of new nuclear facilities. The radioactive materials present in this waste material may constitute a valuable by-product from these operations if suitable and economic recovery procedures are developed. If the development …

Flame Photometric Studies: Part A: Studies Of The Extraction And Flame Emission Of Yttrium; Part B: Droplet Size Of Aerosols In Flame Photometry; Part C: Studies Of The Reaction Zone Of An Oxygen­ Acetylene Flame, William Joseph Carnes

Doctoral Dissertations

Although the flame spectrum of yttrium has been well defined in previous work, very little information was available in regard to the effect of spectral and radiation interferences, other than the rare earths, upon the emission of yttrium. Information regarding the optimum conditions for the flame-photometric determination of yttrium was lack­ing also. The main objective of this phase of work was clarification of these points. Development of a suitable method of analysis for yttrium was also considered.

Some Reactions Of Phenothiazine And Certain Benzophenothiazines, John Charles Gilmer

Doctoral Dissertations

Summary

The consideration of the medical importance of phenothiazine derivatives and the known cancer chemotherapeutic value of the nitrogen mustards made the synthesis of some nitrogen mustard derivatives of the phenothiazines of particular interest. In the course of this research the N-{2-[bis-(2-chloroethyl)amino]ethyl} derivatives of phenothiazine, 7H-benzo[c]phenothiazine, 7H-dibenzo[c, h] phenothiazine, and 14H-dibenzo[a, h] phenothiazine were synthesized for anticancer evaluation. Also submitted to the Cancer Chemotherapy National Service Center for testing were the N-(2-chloroethyl) monofunctional nitrogen mustard derivatives of the first three phenothiazines mentioned above.

Hyperfine Splitting In Aromatic Free Radicals, Juana Acrivos

Faculty Publications, Chemistry

No abstract provided.

Buttressing Effect In 3, 3' -Disubstituted-2, 2' -Three-Carbon-Atom Bridged Biphenyls, Yunn Hui Chiang

Masters Theses

Introduction

The configuration of biphenyl has been the subject of much investigation and many recent reviews (1, 5, 6, 7, 8, 17, 21, 22). Of particular interest has been the configuration of 2,2' -bridged biphenyl derivatives. The preparation of an optically active 2,2' -three-carbon-atom-bridged biphenyl having an ultraviolet absorption maximum at 250 mμ, has been recently described (14). Although the compound was easily racemized, this property requires that a non-planar configuration be assigned to this biphenyl (I). Furthermore, this ultraviolet spectra indicates that inter-ring conjugation must exist in the non-planar configuration.

A Thermodynamic Study Of Step-Wise Complex Formation In Several Aqueous Copper (Ii)-Amino Acid Systems, Vipin M. Kothari

Theses and Dissertations

pK_n values for step-wise dissociation of protons from the protonated ligands (glycine, α-amino isobutyric acid, sarcosine and theonine) were determined potentiometrically with a Beckman Model GS pH meter in aqueous solution at 10, 20, 30 and 40° C. Log K values for step-wise interaction of glycine, α-amino isobutyric acid, sarcosine and threonine with copper(II) ion were also determined potentiometrically with a pH meter at 10, 20, 30 and 40° C. The standard free energy of formation for the step-wise interaction of copper(II) with each of the above ligands was calculated from the values of log K. Enthalpy and entropy changes …

4th Annual Rocky Mountain Spectroscopy Conference

Rocky Mountain Conference on Magnetic Resonance

Abstracts of papers presented at the 4th annual meeting of the Rocky Mountain Spectroscopy Conference, sponsored by the Rocky Mountain Section of the Society for Applied Spectroscopy. Held in Denver, Colorado, August 10-11, 1961.

A Study Of Catalytic Reactions On Semiconductors: Hydrogen Deuterium Exchange And Formic Acid Decomposition On Chemically-Doped Germanium, George Edward Moore

Doctoral Dissertations

Summary: Rates and activation energies for the hydrogen-deuterium exchange and formic acid vapor decomposition were measured on a series of chemically-doped germanium catalyst over the temperature range 100° to 400°. The germanium catalyst were intrinsic, and n or p-type extrinsic semiconductors; the position of the Fermi level of the solid was located suitably on the forbidden energy gap.

Kinetic parameters of the exchange and decomposition reactions were related to the Fermi level (electronic chemical potential) of the solid. Their dependence suggested that the rate-limiting processes involved electronic charge shifts between adsorbate and semiconductor.

Two different rate processes appeared to …

Competitive Catalytic Hydrogenation Of Benzene, Toluene, And The Polymethylbenzenes On Platinium, Charles Phillip Rader

Doctoral Dissertations

Introduction: This investigation embraced a comparison of the relative rates of hydrogenation on platinum of benzene and several of its methyl-substituted derivatives with their relative strengths of adsorption on the active spots of the catalyst surface. It consisted of the determination of the rate of reduction of the individual hydrocarbons and a variety of their binary mixtures. Its ultimate goal was to aid in the elucidation of the mechanism by which the benzene nucleus accepts hydrogen on a platinum surface.

Investigation Of The Platinum-Rich Portion Of The Platinum-Tantalum Phase Diagram, Bob Dean Browning

Theses and Dissertations

The Pt-Ta binary system was investigated at two isotherms;1000°C and 1500°C, and at eleven alloy compositions in the range of 50 to 100 atomic percent platinum. The alloys were examined by x-ray diffraction and metallography. Three intermetallic compounds, Pt₂Ta, Pt₃Ta, and Pt₄Ta were found to exist in this composition range. The Pt₄Ta intermetallic appeared only at the 1500°C isotherm. Platinum dissolved tantalum substitutionally to 90 atomic percent at 1500 °C and to approximately 80 atomic percent at 1000 °C.

A Thermodynamic Study Of Complex Formation In Aqueous Solution.|Ni.|Pthe Hg(Ii)-, Zn(Ii)-, Cd(Ii)-, Ag(I)-Serine Systems.|Nii.|Pthe Hg(Ii)-, Zn(Ii)-, Cd(Ii)-, In(Iii)- Thioglycollic Acid System :|Ba Study Of The Effect Of D[Pi]-D[Pi] Bonding On These Complexes, Marriner Lee Morrell

Theses and Dissertations

Thermodynamic equilibrium constants were obtained potentiometrically using a Beckman pH meter for metal-serine and metal-thioglycolloc acid complexes to study the thermodynamic properties of the complexes and the effect of dπ - dπ bonding on the equilibrium constants. The following calculations were made: 1. The stepwise dissociation of protons from serine at 10, 20, 30, and 40°C and the stepwise dissociation of protons from thioglycollic acid at 20, 30, and 40°C. 2. The thermodynamic formation constants for Zn(II), Cd(II), Hg(II), and Ag(I) with serine at 10, 20, 30, and 40°C and at two ionic strengths. 3. The thermodynamic formation constants for …

The Influence Of Temperature And Some Other Factors On The Biological And Nonbiological Oxidation Of Chalcopyrite, Pyrite And Copper Sulfide, Ezra Revier Palmer

Theses and Dissertations

The purpose of this study was: (1) to find the effect of temperature on the wet oxidation of chalcopyrite, pyrite, and copper sulfide over the biological and nonbiological range; (2) to determine the influence of ferrous and ferric iron and free oxygen(air) on the oxidation. The sulfide minerals studied were oxidized over a range of temperatures between 25° to 75° C. The optimum biological oxidation occurred near 35° C. The nonbiological oxidation was very slow at low temperatures but increased with increasing temperature. The effect of solutions used in leaching the various sulfides over the temperature range differred. A synthetic …

Perfection Of The Lattice Of Dislocation-Free Silicon, Studied By The Lattice-Constant And Density Method, Martin E. Straumanis, Pierre Borgeaud, William Joseph James

Materials Science and Engineering Faculty Research & Creative Works

The lattice-constant and density method revealed that a high-purity silicon crystal free of dislocations has a perfect lattice without an excess of vacant sites or interstitials (n′=8.0000 4) within the limits of error, in agreement with the results obtained with the decoration method. The lattice constant of vacuum heated silicon powder of semiconductor purity was 5.43070±0.00004 A; that of the nonheat-treated powder was 5.43081 A at 25°C. The constants determined from crystal chips by the rotating crystal method were lower: between 5.43028-5.43048 A at 25°C. As the constants of each series of measurements could be reproduced very well (s=±0.00004 A), …