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Articles 1081 - 1110 of 8897
Full-Text Articles in Physical Sciences and Mathematics
Electrostatic Design And Characterization Of A 200 Kev Photogun And Wien Spin Rotator, Gabriel G. Palacios Serrano
Electrostatic Design And Characterization Of A 200 Kev Photogun And Wien Spin Rotator, Gabriel G. Palacios Serrano
Electrical & Computer Engineering Theses & Dissertations
High-energy nuclear physics experiments at the Jefferson Lab Continuous Electron Beam Accelerator Facility (CEBAF) require high spin-polarization electron beams produced from strained super-lattice GaAs photocathodes activated to negative electron affinity in a high voltage photogun operating at 130 kV dc. A pair of Wien filter spin rotators in the injector provides precise control of the electron beam polarization at the end station target. An upgrade of the CEBAF injector to better support the upcoming Moller experiment requires increasing the electron beam energy to 200 keV, resulting in better transmission through injector apertures and improved photocathode lifetime. In addition, the energy …
Commissioning & Characterization Of Magnetized Gridded Thermionic Electron Source, Mark Stefani
Commissioning & Characterization Of Magnetized Gridded Thermionic Electron Source, Mark Stefani
Electrical & Computer Engineering Theses & Dissertations
Collaborative efforts to design and fabricate a magnetized gridded thermionic electron source have been conducted between Xelera and Jefferson Lab. Commissioning and characterization of an electron gun fabricated by Xelera was performed to benchmark the viability of future electron source designs and capabilities. The work involved simulation, installation, trouble-shooting, modifications of the design, commissioning, characterization, and magnetization of the electron beam produced. A specially designed cavity as well as novel diagnostic tools and methods were developed, implemented, and experimentally tested. Finally, the gun was used to demonstrate a previously unachieved current of magnetized electron beam from a gridded thermionic source …
Polymer Based Triboelectric Nanogenerator For Cost‐Effective Green Energy Generation And Implementation Of Surface‐Charge Engineering, Diana Lopez, Aminur Rashid Chowdhury, Abu Masa Abdullah, Muhtasim Ul Karim Sadaf, Isaac Martinez, Brishty Deb Chowdhury, Serena Danti, Christopher J. Ellison, Karen Lozano, Mohammed Jasim Uddin
Polymer Based Triboelectric Nanogenerator For Cost‐Effective Green Energy Generation And Implementation Of Surface‐Charge Engineering, Diana Lopez, Aminur Rashid Chowdhury, Abu Masa Abdullah, Muhtasim Ul Karim Sadaf, Isaac Martinez, Brishty Deb Chowdhury, Serena Danti, Christopher J. Ellison, Karen Lozano, Mohammed Jasim Uddin
Chemistry Faculty Publications and Presentations
Performance of triboelectric nanogenerators for harvesting mechanical energy from the ambient environment has been limited by structural complexity, cost-effectiveness, and mechanical weakness of materials. Herein, a cost-effective vertical contact separation mode triboelectric nanogenerator using polyethylene (PE) and polycarbonate (PC) in a regular digital versatile disc is reported. This cost-effective nanogenerator with simplified structures is able to generate an open-circuit voltage of 215.3 V and short-circuit current of 80 μA. The effects of the distance of impact and the air gap between the triboelectric layers have also been tested from 3 to 9 cm, and 0.25 to 1 cm, respectively. It …
Adventuring Into Complexity By Exploring Data: From Complicity To Sustainability, Tim Lutz
Adventuring Into Complexity By Exploring Data: From Complicity To Sustainability, Tim Lutz
Northeast Journal of Complex Systems (NEJCS)
Problems of sustainability are typically represented by major present-day challenges such as climate change, biodiversity loss, and environmental and social injustice. Framed this way, sustainable lives and societies depend on finding solutions to each problem. From another perspective, there is only one problem behind them all, stated by Gregory Bateson as: “…the difference between how nature works and the way people think,” and complexity provides a way to define and approach this problem. I extend Edgar Morin’s conceptions of restricted and general complexity into pedagogy to address problems of simplicity and reductionist teaching. The proposed pedagogy is based on long …
Flocc: From Agent-Based Models To Interactive Simulations On The Web, Scott Donaldson
Flocc: From Agent-Based Models To Interactive Simulations On The Web, Scott Donaldson
Northeast Journal of Complex Systems (NEJCS)
Agent-based modeling (ABM) is a computational technique wherein systems are represented through the actions and interactions of many individual entities (‘agents’) over time. ABM often attempts to elucidate the unpredictable, high-level behavior of systems through the predictable, low-level behavior of actors within the system. There are currently few software or frameworks for ABM that allow modelers to design and build interactive models on the web, for a wide audience as well as a scientifically literate audience well-versed in complexity, models, and simulations. Flocc is a novel framework for agent-based modeling written in JavaScript, the lingua franca programming language of the …
Integrated Cyberattack Detection And Handling For Nonlinear Systems With Evolving Process Dynamics Under Lyapunov-Based Economic Model Predictive Control, Keshav Kasturi Rangan, Henrique Oyama, Helen Durand
Integrated Cyberattack Detection And Handling For Nonlinear Systems With Evolving Process Dynamics Under Lyapunov-Based Economic Model Predictive Control, Keshav Kasturi Rangan, Henrique Oyama, Helen Durand
Chemical Engineering and Materials Science Faculty Research Publications
Safety-critical processes are becoming increasingly automated and connected. While automation can increase effciency, it brings new challenges associated with guaranteeing safety in the presence of uncertainty especially in the presence of control system cyberattacks. One of the challenges for developing control strategies with guaranteed safety and cybersecurity properties under suffcient conditions is the development of appropriate detection strategies that work with control laws to prevent undetected attacks that have immediate closed-loop stability consequences. Achieving this, in the presence of uncertainty brought about by plant/model mismatch and process dynamics that can change with time, requires a fundamental understanding of the characteristics …
Network-Based Analysis Of Early Pandemic Mitigation Strategies: Solutions, And Future Directions, Pegah Hozhabrierdi, Raymond Zhu, Maduakolam Onyewu, Sucheta Soundarajan
Network-Based Analysis Of Early Pandemic Mitigation Strategies: Solutions, And Future Directions, Pegah Hozhabrierdi, Raymond Zhu, Maduakolam Onyewu, Sucheta Soundarajan
Northeast Journal of Complex Systems (NEJCS)
Despite the large amount of literature on mitigation strategies for pandemic spread, in practice, we are still limited by naive strategies, such as lockdowns, that are not effective in controlling the spread of the disease in long term. One major reason behind adopting basic strategies in real-world settings is that, in the early stages of a pandemic, we lack knowledge of the behavior of a disease, and so cannot tailor a more sophisticated response. In this study, we design different mitigation strategies for early stages of a pandemic and perform a comprehensive analysis among them. We then propose a novel …
Development Of A Real-Time Single-Lead Single-Beat Frequency-Independent Myocardial Infarction Detector, Harold Martin
Development Of A Real-Time Single-Lead Single-Beat Frequency-Independent Myocardial Infarction Detector, Harold Martin
FIU Electronic Theses and Dissertations
The central aim of this research is the development and deployment of a novel multilayer machine learning design with unique application for the diagnosis of myocardial infarctions (MIs) from individual heartbeats of single-lead electrocardiograms (EKGs) irrespective of their sampling frequencies over a given range. To the best of our knowledge, this design is the first to attempt inter-patient myocardial infarction detection from individual heartbeats of single-lead (lead II) electrocardiograms that achieves high accuracy and near real-time diagnosis. The processing time of 300 milliseconds to a diagnosis is just at the time range in between extremely fast heartbeats of around 300 …
Virtual Network Function Embedding Under Nodal Outage Using Deep Q-Learning, Swarna Bindu Chetty, Hamed Ahmadi, Sachin Sharma, Avishek Nag
Virtual Network Function Embedding Under Nodal Outage Using Deep Q-Learning, Swarna Bindu Chetty, Hamed Ahmadi, Sachin Sharma, Avishek Nag
Articles
With the emergence of various types of applications such as delay-sensitive applications, future communication networks are expected to be increasingly complex and dynamic. Network Function Virtualization (NFV) provides the necessary support towards efficient management of such complex networks, by virtualizing network functions and placing them on shared commodity servers. However, one of the critical issues in NFV is the resource allocation for the highly complex services; moreover, this problem is classified as an NP-Hard problem. To solve this problem, our work investigates the potential of Deep Reinforcement Learning (DRL) as a swift yet accurate approach (as compared to integer linear …
Strategies In Botnet Detection And Privacy Preserving Machine Learning, Di Zhuang
Strategies In Botnet Detection And Privacy Preserving Machine Learning, Di Zhuang
USF Tampa Graduate Theses and Dissertations
Peer-to-peer (P2P) botnets have become one of the major threats in network security for serving as the infrastructure that responsible for various of cyber-crimes. Though a few existing work claimed to detect traditional botnets effectively, the problem of detecting P2P botnets involves more challenges. In this dissertation, we present two P2P botnet detection systems, PeerHunter and Enhanced PeerHunter. PeerHunter starts from a P2P hosts detection component. Then, it uses mutual contacts as the main feature to cluster bots into communities. Finally, it uses community behavior analysis to detect potential botnet communities and further identify bot candidates. Enhanced PeerHunter is an …
Are Terrorist Networks Just Glorified Criminal Cells?, Elie Alhajjar, Ryan Fameli, Shane Warren
Are Terrorist Networks Just Glorified Criminal Cells?, Elie Alhajjar, Ryan Fameli, Shane Warren
Northeast Journal of Complex Systems (NEJCS)
The notions of organized crime and terrorism have an old and rich history around the globe. Researchers and practitioners have been studying events and phenomena related to these notions for a long time. There are pointers in the literature in which it is misleading to see the unfair comparison between terrorist and criminal networks with the argument that all actors involved in these networks are simply evil individuals. In this paper, we conduct a systematic study of the operational structure of such networks from a network science perspective. We highlight some of the major differences between them and support our …
Temperature-Immune Self-Referencing Fabry–Pérot Cavity Sensors, Hengky Chandrahalim, Jonathan W. Smith
Temperature-Immune Self-Referencing Fabry–Pérot Cavity Sensors, Hengky Chandrahalim, Jonathan W. Smith
AFIT Patents
A passive microscopic Fabry-Pérot Interferometer (FPI) sensor an optical fiber a three-dimensional microscopic optical structure formed on a cleaved tip of an optical fighter that reflects a light signal back through the optical fiber. The reflected light is altered by refractive index changes in the three-dimensional structure that is subject to at least one of: (i) thermal radiation; and (ii) volatile organic compounds.
Implementing Inverse Design Tools For Plasmonic Digital Logic Devices, Krishna Narayan, Mark C. Harrison
Implementing Inverse Design Tools For Plasmonic Digital Logic Devices, Krishna Narayan, Mark C. Harrison
Engineering Faculty Articles and Research
Despite the benefits that optics and photonics have brought to improving communications, there remains a lack of commercialized optical computing devices and systems, which reduces the benefits of using light as an information-carrying medium. We are developing architectures and designs of photonic logic gates for creating larger-scale functional photonic logic circuits. In contrast to other approaches, we are focusing on the development of logic devices which can be cascaded in arbitrary ways to allow for more complex photonic integrated circuit design. Additionally, optical computing often uses on-off keying, which fails to take advantage of denser encoding schemes often used to …
Emerging Challenges In Smart Grid Cybersecurity Enhancement: A Review, Fazel Mohammadi
Emerging Challenges In Smart Grid Cybersecurity Enhancement: A Review, Fazel Mohammadi
Electrical and Computer Engineering Publications
In this paper, a brief survey of measurable factors affecting the adoption of cybersecurity enhancement methods in the smart grid is provided. From a practical point of view, it is a key point to determine to what degree the cyber resilience of power systems can be improved using cost-effective resilience enhancement methods. Numerous attempts have been made to the vital resilience of the smart grid against cyber-attacks. The recently proposed cybersecurity methods are considered in this paper, and their accuracies, computational time, and robustness against external factors in detecting and identifying False Data Injection (FDI) attacks are evaluated. There is …
Zinc Gallate Spinel Dielectric Function, Band-To-Band Transitions, And Γ-Point Effective Mass Parameters, Matthew J. Hilfiker, Megan Stokey, Rafal Korlacki, Ufuk Kilic, Zbigniew Galazka, Klaus Irmscher, Stefan Zollner, Mathias Schubert
Zinc Gallate Spinel Dielectric Function, Band-To-Band Transitions, And Γ-Point Effective Mass Parameters, Matthew J. Hilfiker, Megan Stokey, Rafal Korlacki, Ufuk Kilic, Zbigniew Galazka, Klaus Irmscher, Stefan Zollner, Mathias Schubert
Department of Electrical and Computer Engineering: Faculty Publications
We determine the dielectric function of the emerging ultrawide bandgap semiconductor ZnGa2O4 from the near-infrared (0.75 eV) into the vacuum ultraviolet (8.5 eV) spectral regions using spectroscopic ellipsometry on high quality single crystal substrates. We perform density functional theory calculations and discuss the band structure and the Brillouin zone Γ-point band-to-band transition energies, their transition matrix elements, and effective band mass parameters. We find an isotropic effective mass parameter (0.24me) at the bottom of the Γ-point conduction band, which equals the lowest valence band effective mass parameter at the top of the highly anisotropic …
Optical Study Of 2-D Detonation Wave Stability, Eulaine T. Grodner
Optical Study Of 2-D Detonation Wave Stability, Eulaine T. Grodner
Theses and Dissertations
Fundamental optical detonation study of detonations constricted to a 2-d plane propagation, and detonations propagating around a curve. All images were processed using modern image processing techniques. The optical techniques used were shadowgraph, Schlieren, and chemiluminescence. In the 2-Dstraight channels, it was determined wave stability was a factor of cell size. It was also determined the detonation wave thickness (area between the combustion and shockwave) was a factor of how much heat available for the detonation. For the detonations propagating around a curve, it was determined the three main classifications of wave stability were stable, unstable, and detonation wave restart. …
Deep Learning For Anisoplanatic Optical Turbulence Mitigation In Long-Range Imaging, Matthew A. Hoffmire, Russell C. Hardie, Michael A. Rucci, Richard Van Hook, Barry K. Karch
Deep Learning For Anisoplanatic Optical Turbulence Mitigation In Long-Range Imaging, Matthew A. Hoffmire, Russell C. Hardie, Michael A. Rucci, Richard Van Hook, Barry K. Karch
Electrical and Computer Engineering Faculty Publications
We present a deep learning approach for restoring images degraded by atmospheric optical turbulence. We consider the case of terrestrial imaging over long ranges with a wide field-of-view. This produces an anisoplanatic imaging scenario where turbulence warping and blurring vary spatially across the image. The proposed turbulence mitigation (TM) method assumes that a sequence of short-exposure images is acquired. A block matching (BM) registration algorithm is applied to the observed frames for dewarping, and the resulting images are averaged. A convolutional neural network (CNN) is then employed to perform spatially adaptive restoration. We refer to the proposed TM algorithm as …
Indoor Navigation Using Convolutional Neural Networks And Floor Plans, Ricky D. Anderson
Indoor Navigation Using Convolutional Neural Networks And Floor Plans, Ricky D. Anderson
Theses and Dissertations
The goal of this thesis is to evaluate a new indoor navigation technique by incorporating floor plans along with monocular camera images into a CNN as a potential means for identifying camera position. Building floor plans are widely available and provide potential information for localizing within the building. This work sets out to determine if a CNN can learn the architectural features of a floor plan and use that information to determine a location. In this work, a simulated indoor data set is created and used to train two CNNs. A classification CNN, which breaks up the floor plan into …
Studying The Conditions For Magnetic Reconnection In Solar Flares With And Without Precursor Flares, Seth H. Garland
Studying The Conditions For Magnetic Reconnection In Solar Flares With And Without Precursor Flares, Seth H. Garland
Theses and Dissertations
Forecasting of solar flares remains a challenge due to the limited understanding of the triggering mechanisms associated with magnetic reconnection, the primary physical phenomenon connected to these events. Consequently, methods continue to rely on the climatology of solar flare events as opposed to the underlying physics principles. Models of magnetic reconnection in the solar atmosphere places the null point of the reconnection within the corona. Though as of now the coronal magnetic field cannot be directly measured, the field is tied to the photospheric magnetic field, which can be. This study utilized data from the Solar Dynamics Observatory Helioseismic and …
Laser Illuminated Imaging: Beam And Scene Deconvolution Algorithm, Benjamin W. Davis
Laser Illuminated Imaging: Beam And Scene Deconvolution Algorithm, Benjamin W. Davis
Theses and Dissertations
Laser illuminated imaging systems deal with several physical challenges that must be overcome to achieve high-resolution images of the target. Noise sources like background noise, photon counting noise, and laser speckle noise will all greatly affect the imaging systems ability to produce a high-resolution image. An even bigger challenge to laser illuminated imaging systems is atmospheric turbulence and the effect that it will have on the imaging system. The illuminating beam will experience tilt, causing the beam to wander off the center of the target during propagation. The light returning to the detector will similarly be affected by turbulence, and …
Computational Electromagnetic Modeling Of Metasurface Optical Devices With Defect Study, Carlos D. Diaz
Computational Electromagnetic Modeling Of Metasurface Optical Devices With Defect Study, Carlos D. Diaz
Theses and Dissertations
One of the first fabricated metasurface optical devices, the in-plane V-antenna lenses, were plagued by a fundamental transmission limit (<25 >). Two distinct sets of Out-of-Plane phase elements were designed with improved transmission (~60 ). These were fabricated as beamsteerers and characterized in terms of their Bidirectional Transmittance Distribution Function measured as a function of scatter angle. Experimental data from the beamsteerers was analyzed via simulations using a finite element method (FEM). The measurements showed the designed beamsteering, but also a strong zero-order diffraction not present in the simulations, which motivated this study to understand what was causing these differences. …25>
The Wargaming Commodity Course Of Action Automated Analysis Method, William T. Deberry
The Wargaming Commodity Course Of Action Automated Analysis Method, William T. Deberry
Theses and Dissertations
This research presents the Wargaming Commodity Course of Action Automated Analysis Method (WCCAAM), a novel approach to assist wargame commanders in developing and analyzing courses of action (COAs) through semi-automation of the Military Decision Making Process (MDMP). MDMP is a seven-step iterative method that commanders and mission partners follow to build an operational course of action to achieve strategic objectives. MDMP requires time, resources, and coordination – all competing items the commander weighs to make the optimal decision. WCCAAM receives the MDMP's Mission Analysis phase as input, converts the wargame into a directed graph, processes a multi-commodity flow algorithm on …
Color-Compressive Bilateral Filter And Nonlocal Means For High-Dimensional Images, Christina Karam, Kenjiro Sugimoto, Keigo Hirakawa
Color-Compressive Bilateral Filter And Nonlocal Means For High-Dimensional Images, Christina Karam, Kenjiro Sugimoto, Keigo Hirakawa
Electrical and Computer Engineering Faculty Publications
We propose accelerated implementations of bilateral filter (BF) and nonlocal means (NLM) called color-compressive bilateral filter (CCBF) and color-compressive nonlocal means (CCNLM). CCBF and CCNLM are random filters, whose Monte-Carlo averaged output images are identical to the output images of conventional BF and NLM, respectively. However, CCBF and CCNLM are considerably faster because the spatial processing of multiple color channels are combined into a single random filtering process. This implies that the complexity of CCBF and CCNLM is less sensitive to color dimension (e.g., hyperspectral images) relatively to other BF and NLM methods. We experimentally verified that the execution time …
Comparison Of Conic Ray Tracing For Occlusion Determination On 3d Point Cloud Data, Henry Cho
Comparison Of Conic Ray Tracing For Occlusion Determination On 3d Point Cloud Data, Henry Cho
Theses and Dissertations
The US Air Force has been increasing the use of automation in its weapon systems to include the remotely piloted aircraft (RPA) platforms. The RPA career field has had issues with poor pilot retention due to job stressors. For example, RPA operators spend a lot of time and attention surveilling a suspect on the ground for many hours, so adding automation to this activity could help improve pilot retention. The research problem in this thesis attempted to automate the process of observing a ground target. This thesis presents a method termed conic ray tracing for determining visibility and occlusion of …
Syntheses Of Na3V2(Po4)2O2F As A Cathode For Sodium Ion Battery Application, Kai Wu
Syntheses Of Na3V2(Po4)2O2F As A Cathode For Sodium Ion Battery Application, Kai Wu
Journal of Electrochemistry
High-temperature solid-state method, hydro-thermal method and solvo-thermal method have been mainly employed to synthesize Na3V2(PO4)2O2F (NVPF) cathode materials. However, these methods are energy consuming and complicated, which is not applicable for a large scale industrial production. In this study, a rather low-temperature (70℃) co-precipitation strategy was proposed to synthesize NVPF cathode materials. The as-prepared NVPF cathode materials showed a spherical shape with a diameter of 400 ~ 500 nm, and exhibited a sodium storage of 105.6 mAh·g-1 and an efficiency of 90.06%. After a simple thermal process, the specific …
Preparations And Electrochemical Properties Of Bc/Coni2S4@Ppy Flexible Composites For Supercapacitors, Si-Yuan Peng, Shi-Run Yang, Jing-Hong Zhou, Zhi-Jun Sui, Tao Zhang, Yi Shi, Xing-Gui Zhou
Preparations And Electrochemical Properties Of Bc/Coni2S4@Ppy Flexible Composites For Supercapacitors, Si-Yuan Peng, Shi-Run Yang, Jing-Hong Zhou, Zhi-Jun Sui, Tao Zhang, Yi Shi, Xing-Gui Zhou
Journal of Electrochemistry
Flexible supercapacitor is one of the most promising energy storage devices for portable and wearable electronic products due to its advantages of high power density, fast charging and long cycle life. Therefore, self-supporting flexible electrode materials with high performance have attained more and more attention both in academia and in industry recently. In this work, using bacterial cellulose (BC) as a flexible substrate, the bacterial cellulose/nickel-cobalt sulfide@polypyrrole (BC/CoNi2S4@PPy) flexible composites with three-dimensional porous network and good conductivity were prepared by a combined solvothermal-in-situ polymerization-vacuum filtration method. The samples were characterized by X-ray diffraction, …
Influence Of Resveratrol On Performance Of Long-Term Storage’S Lithium-Ion Battery Electrolyte, Lei Zhang, Xu-Ping Zhang, Si-Wei Zhang, Quan-Chao Zhuang
Influence Of Resveratrol On Performance Of Long-Term Storage’S Lithium-Ion Battery Electrolyte, Lei Zhang, Xu-Ping Zhang, Si-Wei Zhang, Quan-Chao Zhuang
Journal of Electrochemistry
Electrolyte of lithium-ion battery usually goes through processes of filling, transportation and storage from the completion of manufacture to the use. Understanding the influence of long-term storage process on performance of lithium-ion battery electrolyte is of theoretical significance for production of lithium-ion battery. Scanning electron microscope (SEM) images showed that the solid electrolyte interface (SEI) film formed on the surface of the graphite electrode was thicker in the base electrolyte after 6 months of storage. The charge/discharge test results showed that the reversible cycle capacity and cycle stability (capacity retention rate) of graphite electrode decreased significantly after 6 months of …
Research Progress In Electrodeposition Technology Of Titanium-Based Iridium Oxide Electrode, Dan-Dan Wu, Xu Wu
Research Progress In Electrodeposition Technology Of Titanium-Based Iridium Oxide Electrode, Dan-Dan Wu, Xu Wu
Journal of Electrochemistry
Titanium-based iridium oxide electrode has been widely used in various fields, such as electrocatalytic oxidation, biomedical applications, hydrometallurgical metal recovery, electro-osmotic dewatering, etc. At present, it is mainly prepared by traditional thermal decomposition method, however, which has high cost, cumbersome process, mainly relying on manual labor and cannot be mass-produced yet. It is, therefore, urgently necessary to explore new preparation technologies by focusing on electrodeposition technology, with technological characteristics such as eco-friendly and sustainable development. This article systematically discusses the research progress in iridium oxide electrodeposition preparation technology from the aspects of deposition solution formulation, base material selection and treatment, …
Preparation Of Pdcoir Tetrahedron Nanocatalysts And Its Performance Toward Ethanol Oxidation Reaction, Zhi-Yuan Yu, Rui Huang, Jie Liu, Guang Li, Qian-Tong Song, Shi-Gang Sun
Preparation Of Pdcoir Tetrahedron Nanocatalysts And Its Performance Toward Ethanol Oxidation Reaction, Zhi-Yuan Yu, Rui Huang, Jie Liu, Guang Li, Qian-Tong Song, Shi-Gang Sun
Journal of Electrochemistry
As a new energy conversion device, direct ethanol fuel cells (DEFCs) are widely concerned because of their remarkable advantages such as high theoretical energy density and wide fuel sources. However, the rapid development of DEFCs has been severely impeded due to the sluggish kinetic process and toxic intermediates especially in their anodic reactions. Palladium (Pd)-based materials are considered to be excellent anode catalysts for DEFCs, especially under alkaline conditions. And further improving their performance is an important direction to promote the development of DEFCs. Surface structure and composition are the key factors affecting the performance of catalysts which can be …
Preparation And Performance Investigation Of Li-Sgo Doped Semi-Ipns Porous Single Ion Conducting Polymer Electrolyte, Yun-Feng Zhang, Jia-Ming Dong, Chang Tan, Shi-Kang Huo, Jia-Ying Wang, Yang He, Ya-Ying Wang
Preparation And Performance Investigation Of Li-Sgo Doped Semi-Ipns Porous Single Ion Conducting Polymer Electrolyte, Yun-Feng Zhang, Jia-Ming Dong, Chang Tan, Shi-Kang Huo, Jia-Ying Wang, Yang He, Ya-Ying Wang
Journal of Electrochemistry
Herein, the lithiated sulfonated graphene oxide (Li-SGO) was successfully prepared via three steps by sulfonation of graphene oxide with 3-merraptnpropylt rimethnxysilane, oxidation of thiol into sulfonate with hydrogen peroxide and lithiation of sulfonate with aqueous lithium hydroxide. The as-prepared Li-SGO was then introduced into the semi-interpenetrating networks of single ion conducting polymer electrolyte (Li-SGO-FPAS) and poly vinylidenefluoride-hexafluoro propylene (PVDF-HFP) binder by in-situ polymerization to fabricate the porous single ion conducting polymer electrolyte membrane (Li-SGO-po-FPAS) generated from the poor compatibility between aromatic Li-SGO-FPAS and aliphatic PVDF-HFP binder. The key properties such as morphology, porosity, solvent uptake, mechanical …