Physical Sciences and Mathematics Commons^™

Capillary-Tube Package Devices For The Quantitative Performance Evaluation Of Nuclear Magnetic Resonance Spectrometers And Pulse Sequences, Lingyu Chi, Ming Huang, Annalise R. Pfaff, Jie Huang, Rex E. Gerald Ii, Klaus Woelk

Electrical and Computer Engineering Faculty Research & Creative Works

With the increased sensitivity of modern nuclear magnetic resonance (NMR) spectrometers, the minimum amount needed for chemical-shift referencing of NMR spectra has decreased to a point where a few microliters can be sufficient to observe a reference signal. The reduction in the amount of required reference material is the basis for the NMR Capillary-tube Package (CapPack) platform that utilizes capillary tubes with inner diameters smaller than 150 µm as NMR-tube inserts for external reference standards. It is shown how commercially available electrophoresis capillary tubes with outer diameters of 360 µm are filled with reference liquids or solutions and then permanently …

Application Of Silicon Nanohair Textured P-N Junctions In A Photovoltaic Device, Michael Small

Electronic Theses and Dissertations

The goal of this project is to design and develop a fabrication process for a silicon photovoltaic device which incorporates a nanohair textured p-n junction. The silicon nanowires are etched into a silicon wafer, comprising an epitaxial p-layer on n-substrate, via metal-assisted chemical etching (MACE). The resulting nanowires contain p-n junctions that lie along the length of the vertical nanowires. This construct has the potential to increase the optical bandwidth of a silicon photovoltaic device by allowing a greater amount of short wavelength light to reach the junction. In addition, the MACE method of nanofabrication has the potential for decreasing …

A Remote Observatory For Geocoronal Hydrogen Emissions, Margaret A. Gallant

Doctoral Dissertations and Master's Theses

The Investigating Near Space Interaction Regions (INSpIRe) observatory is an adaptable research facility that is designed to use Fabry-Perot interferometer (FPI) to study the faint Balmer series emissions of the terrestrial upper thermosphere and exosphere, collectively known as the geocorona. This instrumentation is designed to be deployable to a clear-air site, necessitating remote operations of the entire observatory, including control and monitoring. The facility currently employs a siderostat to allow for pointing at sky targets, a pressure-tuned dual-etalon FPI to allow for high spectral resolution (R_80,000) measurements, and several charge-coupled device (CCD) imagers for guiding and collecting data. The environment …

Improving Detection Of Dim Targets: Optimization Of A Moment-Based Detection Algorithm, Shannon R. Young

Theses and Dissertations

Wide area motion imagery (WAMI) sensor technology is advancing rapidly. Increases in frame rates and detector array sizes have led to a dramatic increase in the volume of data that can be acquired. Without a corresponding increase in analytical manpower, much of these data remain underutilized. This creates a need for fast, automated, and robust methods for detecting dim, moving signals of interest. Current approaches fall into two categories: detect-before-track (DBT) and track-before-detect (TBD) methods. The DBT methods use thresholding to reduce the quantity of data to be processed, making real time implementation practical but at the cost of the …

Fabrication And Characterization Of Electrochemical Glucose Sensors, Mohammed Marie

Graduate Theses and Dissertations

Electrochemical sensors based on the nanostructure of the semiconductor materials are of tremendous interest to be utilized for glucose monitoring. The sensors, based on the nanostructure of the semiconductor materials, are the third generations of the glucose sensors that are fast, sensitive, and cost-effect for glucose monitoring.

Glucose sensors based on pure zinc oxide nanorods (NRs) grown on different substrates, such ITO, FTO, and Si/SiO2/Au, were investigated in this research. Silicon nanowire (NW)- based glucose sensors were also studied. First, an enzyme-based glucose sensor was fabricated out of glass/ITO/ZnO NRs/BSA/GOx/nafion membrane. The sensor was tested amperometrically at different glucose concentrations. …

Big Data And Sensor Network For Construction Material Testing, Yao Shi

Theses and Dissertations

Engineers and contractors need to have a precise understanding of the development progress of concrete strength in the natural environment, which helps to save project time and cost. However, current practice of concrete construction depends on published data, charts and curves from laboratory tests. The data would not show frequently changing environmental conditions in the real world, which can affect concrete quality significantly. The objective of this research is to design a reliable and accurate method to validate test data of the strength developments of concrete specimens in early stages. The approach includes the following tasks: (1) arrange sensors to …

Effective Magnetic And Electric Response Of Composite Materials, Mona Hassan Alsaleh

Doctoral Dissertations

Metamaterials (MMs) are nanocomposite materials consisting of metal-dielectric resonators much smaller in size than the wavelength of the incident light. Common examples of metamaterials are based on split ring resonators (SRRs), parallel wires or strips and fishnet structures. These types of materials are designed and fabricated in order to provide unique optical responses to the incident electromagnetic radiation that are not available in naturally existing materials. The MMs can exhibit unusual properties such as strong magnetism at terahertz (THz) and optical frequencies. Additionally, negative index materials (NIMs) can provide negative index of refraction which can be used in many applications …

Electromagnetic Wave-Matter Interactions In Complex Opto-Electronic Materials And Devices, Raj Kumar Vinnakota

Doctoral Dissertations

This dissertation explores the fundamentals of light-matter interaction towards applications in the field of Opto-electronic and plasmonic devices. In its core, this dissertation attempts and succeeds in the the modeling of light-matter interactions, which is of high importance for better understanding the rich physics underlying the dynamics of electromagnetic field interactions with charged particles. Here, we have developed a self-consistent multi-physics model of electromagnetism, semiconductor physics and thermal effects which can be readily applied to the field of plasmotronics and Selective Laser Melting (SLM). Plasmotronics; a sub-field of photonics has experienced a renaissance in recent years by providing a large …

Physical Electronic Properties Of Self-Assembled 2d And 3d Surface Mounted Metal-Organic Frameworks, Radwan Elzein

USF Tampa Graduate Theses and Dissertations

Metal-organic frameworks stand at the frontiers of molecular electronic research because they combine desirable physical properties of organic and inorganic components. They are crystalline porous solids constructed by inorganic nodes coordinated to organic ligands to form 1D, 2D, or 3D structures. They possess unique characteristics such as ultrahigh surface area crystal lattices up to 10000 m² g^-1, and tunable nanoporous sizes ranging from 0.2 to 50 nm. Their unprecedented structural diversity and flexibility beyond solid state materials can lead to unique properties such as tailorable electronic and ionic conductivity which can serve as interesting platforms for a …

Cost Benefit Analysis Of Led Vs Florescent Lighting, Kurtis Clark, Phillip Humphrey

Student Research

Over the last few years, the state of Oklahoma has been looking at ways to reduce expenses to address concerns about a budget deficit. There have been efforts made to reduce expenses due to the use of energy. It has been said, when the lights are on, work is getting done. Running lights is therefore the cost of doing business. Our research examines the question, “is there a way to provide better lighting while operating at a lower cost.” This research examines the current lighting at Southwestern State University, primarily fluorescent lighting (FL), and a cost benefit analysis of switching …

Creating A Computational Tool To Simulate Vibration Control For Piezoelectric Devices, Ahmet Ozkan Ozer, Emma J. Moore

Posters-at-the-Capitol

Piezoelectric materials have the unique ability to convert electrical energy to mechanical vibrations and vice versa. This project takes a stab to develop a reliable computational tool to simulate the vibration control of a novel “partial differential equation” model for a piezoelectric device, which is designed by integrating electric conducting piezoelectric layers constraining a viscoelastic layer to provide an active and lightweight intelligent structure. Controlling unwanted vibrations on piezoelectric devices (or harvesting energy from ambient vibrations) through piezoelectric layers has been the major focus in cutting-edge engineering applications such as ultrasonic welders and inchworms. The corresponding mathematical models for piezoelectric …

X-Search: An Open Access Interface For Cross-Cohort Exploration Of The National Sleep Research Resource, Licong Cui, Ningzhou Zeng, Matthew Kim, Remo Mueller, Emily Ruth Hankosky, Susan Redline, Guo-Qiang Zhang

Computer Science Faculty Publications

Background: The National Sleep Research Resource (NSRR) is a large-scale, openly shared, data repository of de-identified, highly curated clinical sleep data from multiple NIH-funded epidemiological studies. Although many data repositories allow users to browse their content, few support fine-grained, cross-cohort query and exploration at study-subject level. We introduce a cross-cohort query and exploration system, called X-search, to enable researchers to query patient cohort counts across a growing number of completed, NIH-funded studies in NSRR and explore the feasibility or likelihood of reusing the data for research studies.

Methods: X-search has been designed as a general framework with two loosely-coupled components: …

Genetic Algorithm Design Of Photonic Crystals For Energy-Efficient Ultrafast Laser Transmitters, Troy A. Hutchins-Delgado

Shared Knowledge Conference

Photonic crystals allow light to be controlled and manipulated such that novel photonic devices can be created. We are interested in using photonic crystals to increase the energy efficiency of our semiconductor whistle-geometry ring lasers. A photonic crystal will enable us to reduce the ring size, while maintaining confinement, thereby reducing its operating power. Photonic crystals can also exhibit slow light that will increase the interaction with the material. This will increase the gain, and therefore, lower the threshold for lasing to occur. Designing a photonic crystal for a particular application can be a challenge due to its number of …

End-To-End Deep Learning Systems For Scene Understanding, Path Planning And Navigation In Fire Fighter Teams, Manish Bhattarai

Shared Knowledge Conference

Firefighting is a dynamic activity with many operations occurring simultaneously. Maintaining situational awareness, defined as knowledge of current conditions and activities at the scene, are critical to accurate decision making. Firefighters often carry various sensors in their personal equipment, namely thermal cameras, gas sensors, and microphones. Improved data processing techniques can mine this data more effectively and be used to improve situational awareness at all times thereby improving real-time decision making and minimizing errors in judgment induced by environmental conditions and anxiety levels. This objective of this research employs state of the art Machine Learning (ML) techniques to create an …

A Cost Benefit Analysis Of Using A Battery Energy Storage System (Bess) Represented By A Unit Commitment Model, Nemanja Mihailovic

USF Tampa Graduate Theses and Dissertations

This thesis aims to provide a general overview of a cost and benefit analysis of incorporating a battery energy storage system within unit commitment model.

The deregulation of the electricity market in the U.S. has only been around for the last two decades. With renewable energy and energy storage systems becoming less expensive, a decentralized market scheme is becoming more popular and plausible. The scope of this work is to provide a fundamental understanding of unit commitment and a cost analysis of applying a battery energy storage system to an already established power system.

A battery energy storage system (BESS) …

Short-Term Wind Speed Forecasting Via Stacked Extreme Learning Machine With Generalized Correntropy, Xiong Luo, Jiankun Sun, Long Wang, Weiping Wang, Wenbing Zhao, Jinsong Wu, Jenq-Haur Wang, Zijun Zhang

Electrical and Computer Engineering Faculty Publications

Recently, wind speed forecasting as an effective computing technique plays an important role in advancing industry informatics, while dealing with these issues of control and operation for renewable power systems. However, it is facing some increasing difficulties to handle the large-scale dataset generated in these forecasting applications, with the purpose of ensuring stable computing performance. In response to such limitation, this paper proposes a more practical approach through the combination of extreme-learning machine (ELM) method and deep-learning model. ELM is a novel computing paradigm that enables the neural network (NN) based learning to be achieved with fast training speed and …

Effects Of Fabrication Errors On The Focusing Performance Of A Sector Metalens, S. S. Stafeev, A. G. Nalimov, Liam O’Faolain, M. V. Kotlyar

Cappa Publications

Using e-beam lithography, a 16-sector spiral metalens was fabricated in an amorphous silicon, capable of converting linearly polarized incident light into an azimuthally polarized optical vortex. When illuminated by a 633-nm linearly polarized laser beam, the metalens generated a near-surface subwavelength focal spot equal to 0.75 of the incident wavelength at full-width of half-maximum intensity. The focusing performance of the spiral metalens was numerically shown to be sensitive to the deviation of the factual microrelief from the calculated height. For the designed microrelief height, a circularly polarized incident beam was focused into a bright ring with a reverse energy flow …

Mrsh-Mem: Approximate Matching On Raw Memory Dumps, Lorenz Liebler, Frank Breitinger

Electrical & Computer Engineering and Computer Science Faculty Publications

This paper presents the fusion of two subdomains of digital forensics: (1) raw memory analysis and (2) approximate matching. Specifically, this paper describes a prototype implementation named MRSH-MEM that allows to compare hard drive images as well as memory dumps and therefore can answer the question if a particular program (installed on a hard drive) is currently running / loaded in memory. To answer this question, we only require both dumps or access to a public repository which provides the binaries to be tested. For our prototype, we modified an existing approximate matching algorithm named MRSH-NET and combined it with …

Vortex Structures Inside Spherical Mesoscopic Superconductor Plus Magnetic Dipole, A. Ludu

Publications

We investigate the existence of multivortex states in a superconducting mesoscopic sphere with a magnetic dipole placed at the center. We obtain analytic solutions for the order parameter inside the sphere through the linearized Ginzburg-Landau (GL) model, coupled with mixed boundary conditions, and under regularity conditions and decoupling coordinates approximation. The solutions of the linear GL equation are obtained in terms of Heun double confluent functions, in dipole coordinates symmetry. The analyticity of the solutions and the associated eigenproblem are discussed thoroughly. We minimize the free energy for the fully nonlinear GL system by using linear combinations of linear analytic …

Investigation On The Rons And Bactericidal Effects Induced By He + O2 Cold Plasma Jets: In Open Air And In An Airtight Chamber, Han Xu, Dingxin Liu, Weitao Wang, Zhijie Liu, Li Guo, Mingzhe Rong, Michael G. Kong

Bioelectrics Publications

He + O₂ plasma jets in open air and in an airtight chamber are comparatively studied, with respect to their production of gaseous/aqueous reactive species and their antibacterial effects. Under the same discharge power, the plasma jet in open air has higher densities of gaseous reactive species and a higher concentration of aqueous H₂O₂ but lower concentrations of aqueous OH and O₂^-. In addition, the increase in the O₂ ratio in He in both plasma jets causes a linear decrease in the population of gaseous reactive species, except for O(3p⁵P) …

Target Localization And Tracking By Fusing Doppler Differentials From Cellular Emanations With A Multi-Spectral Video Tracker, Casey D. Demars, Michael Roggemann, Adam Webb, Timothy C. Havens

Michigan Tech Publications

We present an algorithm for fusing data from a constellation of RF sensors detecting cellular emanations with the output of a multi-spectral video tracker to localize and track a target with a specific cell phone. The RF sensors measure the Doppler shift caused by the moving cellular emanation and then Doppler differentials between all sensor pairs are calculated. The multi-spectral video tracker uses a Gaussian mixture model to detect foreground targets and SIFT features to track targets through the video sequence. The data is fused by associating the Doppler differential from the RF sensors with the theoretical Doppler differential computed …

Game-Theoretic And Machine-Learning Techniques For Cyber-Physical Security And Resilience In Smart Grid, Longfei Wei

FIU Electronic Theses and Dissertations

The smart grid is the next-generation electrical infrastructure utilizing Information and Communication Technologies (ICTs), whose architecture is evolving from a utility-centric structure to a distributed Cyber-Physical System (CPS) integrated with a large-scale of renewable energy resources. However, meeting reliability objectives in the smart grid becomes increasingly challenging owing to the high penetration of renewable resources and changing weather conditions. Moreover, the cyber-physical attack targeted at the smart grid has become a major threat because millions of electronic devices interconnected via communication networks expose unprecedented vulnerabilities, thereby increasing the potential attack surface. This dissertation is aimed at developing novel game-theoretic and …

Recent Progress In Organic Redox Flow Batteries, Li-Xing Xia, Hao Liu, Lin Liu, Zhan-Ao Tan

Journal of Electrochemistry

Redox flow batteries (RFBs) are promising candidate for balancing instability of grids caused by integration of intermittent renewable energies such as solar energy and wind energy. Along with wide deployments in solar energy and wind energy due to abundance and declining installation cost, it can be predicted that RFBs will enter a period of rapid development. Basically,RFBs are electrochemical energy storage devices that decouple energy and power of the system by storing liquid electrolyte in tanks outside battery system itself. Such a unique framework makes RFBs flexible and fulfills the various demands of grids. During battery operation, redox-active species are …

The New Application Of Battery-Electrode Reaction: Decoupled Hydrogen Production In Water Electrolysis, Yuan-Yuan Ma, Zhao-Wei Guo, Yong-Gang Wang, Yong-Yao Xia

Journal of Electrochemistry

Hydrogen has been considered as a promising alternative to unsustainable fossil fuels because of its high calorific value, clean and abundant resources. Water electrolysis combined with renewable energy is regarded as the best way for hydrogen production, which will become the foundation of future hydrogen economy. For the past few years, many efforts have been employed to develop the cheap and high-performance catalyst for hydrogen evolution reaction and oxygen evolution reaction. However,the coupled hydrogen and oxygen evolution and the use of the expensive membrane have greatly restricted the flexibility of the conventional water electrolysis, and hindered the utilization of renewable …

Recent Advances In Non-Noble Metal Nanomaterials For Oxygen Evolution Electrocatalysis, Dan-Dan Zhao, Nan Zhang, Ling-Zheng Bu, Qi Shao, Xiao-Qing Huang

Journal of Electrochemistry

Hydrogen is a kind of renewable energies with the merits of environmentally friendly, abundance and high weight energy density, which can replace the fossil energy. The electrolysis of water is regarded as the most effective way to generate hydrogen. Owing to the sluggish kinetics and large overpotential of the anode oxygen evolution reaction (OER), the efficiency of the cathode hydrogen evolution reaction is greatly limited. Therefore, it is highly desirable to explore efficient, stable and low cost electrocatalysts to reduce the overpotential of OER and improve the efficiency of hydrogen evolution. Based on the natural characteristics of non-noble metal catalysts …

Design Strategies Toward Highly Active Electrocatalysts For Oxygen Evolution Reaction, Tang Tang, Wen-Jie Jiang, Shuai Niu, Jin-Song Hu

Journal of Electrochemistry

Electrocatalytic water splitting is pivotal for efficient and economical production of hydrogen and oxygen gasses. However, the efficiency of the whole device is largely limited by the oxygen evolution reaction (OER) at the anode due to its sluggish kinetics. Thus, it is imperative to develop inexpensive, highly active OER catalysts to lower the reaction barriers. By examining the underlying critical factors for OER performance, this review outlines general principles for designing efficient nanosized OER catalysts, including (1) enhancing the intrinsic activity of active site by electronic modulation, crystallinity modulation, phase control, defect engineering and spin state engineering; (2) designing appropriate …

Recent Process In Transition-Metal-Oxide Based Catalysts For Oxygen Reduction Reaction, Yao Wang, Zi-Dong Wei

Journal of Electrochemistry

Transition metal oxides (TMOs) based catalysts have become the most promising catalysts to be employed in anion exchange membrane fuel cell for the sluggish oxygen reduction reaction (ORR). However, their ORR activity is still far from that of the Pt-based catalysts. Therefore, it is important to develop high performance TMO based catalysts. Electrical conductivity and intrinsic activity have been regarded as the two keys to affect the ORR activity of the TMOs based catalysts. In this review, we focused on the recent progresses in the fundamental viewpoints on the electrical conductivity and intrinsic activity of the TMOs based ORR catalysts. …

Recent Advances In Continuous Models Of Electrochemical Supercapacitors, Hao-Tian Lu, Jing-Hong Zhou, Guang-Hua Ye, Xing-Gui Zhou

Journal of Electrochemistry

Electrochemical capacitors (supercapacitors) have been developed as a new type of energy storage device with high energy and power densities, which have the advantages of both fast charging-discharging as traditional capacitors and high energy density as batteries. Notable improvements in their electrochemical performance have been achieved in recent years owing to the recent advances in understanding of charge storage mechanisms and the development of advanced nanostructured materials. Recently, modeling and simulation of these supercapacitors has been applied as a useful approach to better understand the working mechanisms of the supercapacitors by describing the concentrations and electric fields inside the capacitors. …

Effects Of Sulfur-Containing Additive On Low Temperature Performance Of Graphite Anode, Ze-Li Wu, Ye-Zhen Zheng, Zhong-Ru Zhang, Yong Yang

Journal of Electrochemistry

The low temperature performance of lithium ion battery mainly depends on the graphite anode, and one of the research focuses is to improve the low temperature performance of the anode by additives. In this paper, the effects of different sulfur-containing functional groups such as DTD (ethylene sulfate), 1,3-PS (1,3-propane sultone) and ES (ethylene sulfite) on low temperature performances of artificial graphite materials were systematically studied. The results in density functional theory (DFT) calculations, cyclic voltammetry (CV), scanning electron microscopy (SEM) and charge-discharge measurement clearly demonstrated that all three sulfur-containing additives could participate in formation of films on the surface of …

Research Progresses In Improvement For Low Temperature Performance Of Lithium-Ion Batteries, Yue-Ru Gu, Wei-Min Zhao, Chang-Hu Su, Chuan-Jun Luo, Zhong-Ru Zhang, Xu-Jin Xue, Yong Yang

Journal of Electrochemistry

Lithium-ion batteries (LIBs) have become a new research hotspot due to their high energy density and long service life. However, the temperature characteristics, especially the poor performance at low temperatures, have seriously limited their wider applications. In this report, the research progresses in the low temperature performance of LIBs are reviewed. The main existing limitations of LIBs at low temperatures were systematically analyzed, and followed by discussion on the recent improvements in low temperature performances by developing novel cathode, electrolyte, and anode materials. The developments for improving the low temperature performance of LIBs are prospected. The three most important factors …