Physical Sciences and Mathematics Commons^™

Characterization And Analysis Of Ultrathin Cigs Films And Solar Cells Deposited By 3-Stage Process, Grace Rajan, Krishna Aryal, Shankar Karki, Puruswottam Aryal, Robert W. Collins, Sylvain Marsillac

Electrical & Computer Engineering Faculty Publications

In view of the large-scale utilization of Cu(In,Ga)Se₂ (CIGS) solar cells for photovoltaic application, it is of interest not only to enhance the conversion efficiency but also to reduce the thickness of the CIGS absorber layer in order to reduce the cost and improve the solar cell manufacturing throughput. In situ and real-time spectroscopic ellipsometry (RTSE) has been used conjointly with ex situ characterizations to understand the properties of ultrathin CIGS films. This enables monitoring the growth process, analyzing the optical properties of the CIGS films during deposition, and extracting composition, film thickness, grain size, and surface roughness which …

Longitudinal Tracking Of Physiological State With Electromyographic Signals., Robert Warren Stallard

Electronic Theses and Dissertations

Electrophysiological measurements have been used in recent history to classify instantaneous physiological configurations, e.g., hand gestures. This work investigates the feasibility of working with changes in physiological configurations over time (i.e., longitudinally) using a variety of algorithms from the machine learning domain. We demonstrate a high degree of classification accuracy for a binary classification problem derived from electromyography measurements before and after a 35-day bedrest. The problem difficulty is increased with a more dynamic experiment testing for changes in astronaut sensorimotor performance by taking electromyography and force plate measurements before, during, and after a jump from a small platform. A …

Design And Implementation Of A Domain Specific Language For Deep Learning, Xiao Bing Huang

Theses and Dissertations

\textit {Deep Learning} (DL) has found great success in well-diversified areas such as machine vision, speech recognition, big data analysis, and multimedia understanding recently. However, the existing state-of-the-art DL frameworks, e.g. Caffe2, Theano, TensorFlow, MxNet, Torch7, and CNTK, are programming libraries with fixed user interfaces, internal representations, and execution environments. Modifying the code of DL layers or data structure is very challenging without in-depth understanding of the underlying implementation. The optimization of the code and execution in these tools is often limited and relies on the specific DL computation graph manipulation and scheduling that lack systematic and universal strategies. Furthermore, …

Advancing The Understanding Of Environmental Transformations, Bioavailability And Effects Of Nanomaterials, An International Us Environmental Protection Agency—Uk Environmental Nanoscience Initiative Joint Program, Mitch M. Lasat, Kian Fan Chung, Jamie Lead, Steve Mcgrath, Richard J. Owen, Sophie Rocks, Jason M. Unrine, Junfeng Zhang

Plant and Soil Sciences Faculty Publications

Nanotechnology has significant economic, health, and environmental benefits, including renewable energy and innovative environmental solutions. Manufactured nanoparticles have been incorporated into new materials and products because of their novel or enhanced properties. These very same properties also have prompted concerns about the potential environmental and human health hazard and risk posed by the manufactured nanomaterials. Appropriate risk management responses require the development of models capable of predicting the environmental and human health effects of the nanomaterials. Development of predictive models has been hampered by a lack of information concerning the environmental fate, behavior and effects of manufactured nanoparticles. The United …

Preparation Of Ni(Dpim)2Cl2 Complex For The Electrocatalytic Reduction Of Co2, Li-Pu Zhang, Dong-Fang Niu, Xin-Sheng Zhang

Journal of Electrochemistry

A new Ni(dpim)₂Cl₂complex using 2-(diphenylphosphino)-1-methylimidazole (dpim) as ligand was prepared and served as a catalyst for the electrochemical reduction of CO₂. The electrochemical redox behavior of Ni(dpim)₂Cl₂ in CH₃CN/TPABF₄ solution under nitrogen atmosphere showed the two-electron irreversible reduction at -0.7 V and one-electron quasi-reversible reduction at -1.3 V. After bubbling CO₂ into the electrolyte, the reduction peak appeared at -1.3 V became irreversible and the peak current increased from 0.48 mA·cm^-2 to 0.55 mA·cm^-2. Moreover, the peak current at -1.3 V could further increase …

Electrochemical Oxidation Of P-Chlorophenol On Porous Ti/Bdd Electrode Cooperated With Cathode Dechlorination, Rong-Ling Chen, Wei-Min Huang, Ya-Peng He, Jun Shi, Hai-Bo Lin

Journal of Electrochemistry

The electrochemical oxidation of p-chlorophenol on porous Ti/BDD electrode cooperated with synergistic effect of cathode dechlorination was studied. Electrochemical degradation tests of p-chlorophenol were conducted in single and double compartment electrolytic cells separately, and the results showed that the mineralization happened mainly in the anode region. The product of chloride ions produced from the cathodic reduction of 4-chlorophenol in the single cell migrated to the anode region and further generated active chlorine toward electro-catalytic oxidation. At the same time, the chloride ion produced from the cathode of the double cell was difficult to be migrated to the anode …

Simulation Analysis In Dynamic Performance Of Proton Exchange Membrane Fuel Cell Under Starting Condition, Yan Xiao, Ying-Jie Chang, Wei Zhang, Qiu-Hong Jia

Journal of Electrochemistry

Based on the equivalent circuit model, by considering both the dynamic gas pressure model and the dynamic heat transfer model, a lumped parameter model is developed. The start process of the fuel cell is simulated by using SIMULINK software. The undershoot of the voltage is observed from the simulation results, and the response time of the voltage is basically the same as that of the fuel cell temperature, which indicates that the temperature has great influence on the dynamic performance of the fuel cell. From the perspective of the temperature, the dynamic responses of the thermodynamic potential, the activation overvoltage, …

Preparation And Properties Of Manganese Oxide And Polyaniline-Carbon Composite Electrode, Tian-Tian Zhou, Bing Wu, Chao Deng, Ying Gao

Journal of Electrochemistry

The polyaniline-carbon (PAnC) electrode was prepared by the polymerization of aniline monomer and activated carbon in ice water bath, and followed by chemical deposition of manganese dioxide MnO₂-PAnC composite material. The specific capacitance of MnO₂-PAnC reached 459 F•g^-1. The cyclic voltammetric results showed a small deformation in the voltammogram curve obtained with the MnO₂-PAnC electrode at high scan rate, indicating good reversibility and capacitive properties. The AC impedance results revealed that the MnO₂-PAnC electrode displayed the smallest charge transfer resistance and the fastest diffusion
rate of surface ions than other …

Interaction Between Energy And Electrocatalysis—A Review On The 1st Young Scientist Forum On Energy Electrocatalysis, Hong Li, Wen-Bin Cai

Journal of Electrochemistry

No abstract provided.

Synthesis And Electrochemical Properties Of Li3V2(Bo3)3/C Anode Materials For Lithium-Ion Batteries, You Wang, Yi-Wen Zeng, Xing Zhong, Xing Liu, Quan Tang

Journal of Electrochemistry

The Li₃V₂(BO₃)₃/C (LVB/C) composite materials were successfully synthesized in two steps：Firstly, a stoichiomertric mixture of Li₂C₂O₄, V₂O₅, H₃BO₃, H₂C₂O₄•H₂O and ethanol was thoroughly ball-milled to get the precursors. Secondly, the precursors were post-calcinated to get the ultimate products. The calcination temperatures of 750 ℃, 800 ℃ and 850 ℃ were selected based on TG-DTA analyses. The crystal structures, surface morphologies and carbon contents of the samples calcinated at five conditions, …

Preparation Of Co3O4/Ti Electrocatalytic Membrane Electrode For Catalytic Oxidation Of Benzyl Alcohol, Yu-Mei Zheng, Zhen Yin, Hong Wang, Jian-Xin Li

Journal of Electrochemistry

The cobalt oxide(Co₃O₄) nanoparticles were loaded on microporous Ti membrane to prepare Co₃O₄/Ti electrocatalytic membrane electrode by dip-coating method. The microstructures and electrochemical properties of Co₃O₄/Ti electrocatalytic membrane were investigated. The Co₃O₄/Ti electrocatalytic membrane reactor (ECMR) assembled by using the Co₃O₄/Ti electrocatalytic membrane as an anode was adopted for catalytic oxidation of benzyl alcohol to produce benzaldehyde and benzoic acid.The effects of different operation parameters on benzyl alcohol conversion, and selectivity to benzaldehyde and benzoic acid of ECMR were studied. …

Effects Of Rotating Magnetic Fields On Pem Fuel Cell Performance, Mao-Liang Wu, En-Ze Wang, Guang-De Pan, Zhong-Jun Liu, Fei Xie

Journal of Electrochemistry

Proton Exchange Membrane (PEM) fuel cell performance may be improved by application of additional magnetic fields. In this work, one square permanent magnet, made of either 16 combination cylinder magnets with homopolarity or 16 combination cylinder magnets with heteropolarity, was exerted on the fuel cell surface to produce additional magnetic field affecting PEM fuel cell performance. The influences of magnetic field status (rotating, static and none) on polarization and power density curves measured in a PEM fuel cell were investigated. The results verified the benefit of magnetic field, proving that the magnetic field distribution could improve the fuel cell output. …

An Exploration Of The Optical Detection Of Ionizing Radiation Utilizing Modern Optics Technology, Sean D. Fournier, Adam Hecht, Cassiano De Oliveira, Jeffrey B. Martin, Richard K. Harrison, Charles Potter

Nuclear Engineering ETDs

Modern ultraviolet (UV) cameras, when combined with UV-transmitting lenses/filter arrangements, can be used to detect radiation dose in air. Ionizing radiation excites nitrogen molecules in ambient air, the resulting decay includes weak emission of ultraviolet photons. Previous work has proven this phenomenon is detectable using highly-sensitive electronically cooled cameras traditionally used in astronomy for low-background imaging. While the ability to detect the presence of radiation (i.e. qualitative measurement) has been demonstrated at Sandia National Laboratories, there are several challenges in correlating images to known dose-fields (quantitative measurement). These challenges include: a low signal to background ratio, interferences due to electronic …

Near-Optimal Control Of Switched Systems With Continuous-Time Dynamics Using Approximate Dynamic Programming, Tohid Sardarmehni

Mechanical Engineering Research Theses and Dissertations

Optimal control is a control method which provides inputs that minimize a performance index subject to state or input constraints [58]. The existing solutions for finding the exact optimal control solution such as Pontryagin’s minimum principle and dynamic programming suffer from curse of dimensionality in high order dynamical systems. One remedy for this problem is finding near optimal solution instead of the exact optimal solution to avoid curse of dimensionality [31]. A method for finding the approximate optimal solution is through Approximate Dynamic Programming (ADP) methods which are discussed in the subsequent chapters.

In this dissertation, optimal switching in switched …

A Multi-Step Nonlinear Dimension-Reduction Approach With Applications To Bigdata, R. Krishnan, V. A. Samaranayake, Jagannathan Sarangapani

Mathematics and Statistics Faculty Research & Creative Works

In this paper, a multi-step dimension-reduction approach is proposed for addressing nonlinear relationships within attributes. In this work, the attributes in the data are first organized into groups. In each group, the dimensions are reduced via a parametric mapping that takes into account nonlinear relationships. Mapping parameters are estimated using a low rank singular value decomposition (SVD) of distance covariance. Subsequently, the attributes are reorganized into groups based on the magnitude of their respective singular values. The group-wise organization and the subsequent reduction process is performed for multiple steps until a singular value-based user-defined criterion is satisfied. Simulation analysis is …

Direct Error Driven Learning For Deep Neural Networks With Applications To Bigdata, R. Krishnan, Jagannathan Sarangapani, V. A. Samaranayake

Electrical and Computer Engineering Faculty Research & Creative Works

In this paper, generalization error for traditional learning regimes-based classification is demonstrated to increase in the presence of bigdata challenges such as noise and heterogeneity. To reduce this error while mitigating vanishing gradients, a deep neural network (NN)-based framework with a direct error-driven learning scheme is proposed. To reduce the impact of heterogeneity, an overall cost comprised of the learning error and approximate generalization error is defined where two NNs are utilized to estimate the costs respectively. To mitigate the issue of vanishing gradients, a direct error-driven learning regime is proposed where the error is directly utilized for learning. It …

Controllability And Observability Of The Discrete Fractional Linear State-Space Model, Duc M. Nguyen

Masters Theses & Specialist Projects

This thesis aims to investigate the controllability and observability of the discrete fractional linear time-invariant state-space model. First, we will establish key concepts and properties which are the tools necessary for our task. In the third chapter, we will discuss the discrete state-space model and set up the criteria for these two properties. Then, in the fourth chapter, we will attempt to apply these criteria to the discrete fractional model. The general flow of our objectives is as follows: we start with the first-order linear difference equation, move on to the discrete system, then the fractional difference equation, and finally …

In Situ Extrinsic Doping Of Cdte Thin Films For Photovoltaic Applications, Imran Suhrid Khan

USF Tampa Graduate Theses and Dissertations

The Cadmium Telluride thin film solar cell is one of the leading photovoltaic technologies. Efficiency improvements in the past decade made it a very attractive and practical source of renewable energy. Considering the theoretical limit, there is still room for improvement, especially the cell’s open circuit voltage (VOC). To improve VOC, the p-type carrier concentration and minority carrier lifetime of the CdTe absorber needs to be improved. Both these parameters are directly related to the point defect distribution of the semiconductor, which is a function of deposition stoichiometry, dopant incorporation and post-deposition treatments.

CdTe films were deposited by the Elemental …

Mitigating The Effects Of Boom Occlusion On Automated Aerial Refueling Through Shadow Volumes, Zachary C. Paulson

Theses and Dissertations

In flight refueling of Unmanned Aerial Vehicles (UAVs) is critical to the United States Air Force (USAF). However, the large communication latency between a ground-based operator and his/her remote UAV makes docking with a refueling tanker unsafe. This latency may be mitigated by leveraging a tanker-centric stereo vision system. The vision system observes and computes an approaching receiver's relative position and orientation offering a low-latency, high frequency docking solution. Unfortunately, the boom -- an articulated refueling arm responsible for physically pumping fuel into the receiver -- occludes large portions of the receiver especially as the receiver approaches and docks with …

Passive Radiolocation Of Ieee 802.11 Emitters Using Directional Antennae, Bradford E. Law

Theses and Dissertations

Low-cost commodity hardware and cheaper, more capable consumer-grade drones make the threat of home-made, inexpensive drone-mounted wireless attack platforms (DWAPs) greater than ever. Fences and physical security do little to impede a drone from approaching private, commercial, or government wireless access points (WAPs) and conducting wireless attacks. At the same time, unmanned aerial vehicles (UAVs) present a valuable tool for network defenders conducting site surveys and emulating threats. These platforms present near-term dangers and opportunities for corporations and governments. Despite the vast leaps in technology these capabilities represent, UAVs are noisy and consequently difficult to conceal as they approach a …

Special Perturbations On The Jetson Tx1 And Tx2 Computers, Tyler M. Moore

Theses and Dissertations

Simplified General Perturbations Number 4 (SGP4) has been the traditional algorithm for performing Orbit Determination (OD) onboard orbiting spacecraft. However, the recent rise of high-performance computers with low Size, Weight, and Power (SWAP) factors has provided the opportunity to use Special Perturbations (SP), a more accurate algorithm to perform onboard OD. This research evaluates the most efficient way to implement SP on NVIDIA’s Jetson TX series of integrated Graphical Processing Units (GPUs). An initial serial version was implemented on the Jetson TX1 and TX2's Central Processing Units (CPUs). The runtimes of the initial version are the benchmark that the runtimes …

Analysis Of Temperature And Humidity Effects On Horizontal Photovoltaic Panels, Corey J. Booker

Theses and Dissertations

The United States Air Force seeks to address power grid vulnerability and bolster energy resilience through the use of renewable energy sources. Air Force Institute of Technology engineers designed and manufactured control systems to monitor power production from the most widely-used silicon-based solar cells at 38 testing locations around the globe spanning the majority of climate types. Researchers conducted multivariate regression analysis to establish a statistical relationship between photovoltaic power output, ambient temperature, and humidity pertaining to monocrystalline and polycrystalline photovoltaic panels. Formulated models first characterized power output globally, then by specific climate type with general inaccuracy. Location-specific models are …

Rss-Based Device-Free Passive Detection And Localization Using Home Automation Network Radio Frequencies, Tiffany M. Phan

Theses and Dissertations

This research provided a proof of concept for a device-free passive (DfP) system capable of detecting and localizing a target through exploitation of a home automation network’s radio frequency (RF) signals. The system was developed using Insteon devices with a 915 MHz center frequency. Without developer privileges, limitations of the Insteon technology like no intrinsic received signal strength (RSS) field and silent periods between messages were overcome by using software-defined radios to simulate Insteon devices capable of collecting and reporting RSS, and by creating a message generation script and implementing a calibrated filter threshold to reduce silent periods. Evaluation of …

Near Earth Space Object Detection Utilizing Parallax As Multi-Hypothesis Test Criterion, Joseph C. Tompkins

Theses and Dissertations

The US Strategic Command (USSTRATCOM) operated Space Surveillance Network (SSN) is tasked with Space Situational Awareness (SSA) for the US military. This system is made up of Electro-Optic sensors such as the Space Surveillance Telescope (SST) and Ground-based Electro-Optical Deep Space Surveillance (GEODSS) as well as RADAR based sensors such as the Space Fence. While Lockheed Martin’s Space Fence is very adept at detecting & tracking objects in Low Earth Orbit (LEO) below 3000 Km in height [1], gaps remain in the tracking of Resident Space Objects (RSO’s) in Geosynchronous Orbits (GEO) due to limitations associated with the implementation of …

Plasmonic Grating Geometrics And Wavelength-Dependent Focus Depth In Infrared Detectors, Patrick R. Kennedy

Theses and Dissertations

The objective for this research is to determine a relationship between plasmonic grating geometries and the wavelength-dependent focus depth. This research is focused on enhancing the signal collected by infrared detectors by using a metal grating as a planar lens to focus light in the detecting region of the substrate. This can be used to maintain a thinner absorbing region and possibly to create multi-color imaging in a single pixel. Simulations demonstrate that the plasmonic lens is capable of creating a wavelength dependent focus spot.

Securing Critical Infrastructure: A Ransomware Study, Blaine M. Jeffries

Theses and Dissertations

This thesis reviews traditional ransomware attack trends in order to present a taxonomy for ransomware targeting industrial control systems. After reviewing a critical infrastructure ransomware attack methodology, a corresponding response and recovery plan is described. The plan emphasizes security through redundancy, specifically the incorporation of standby programmable logic controllers. This thesis goes on to describe a set of experiments conducted to test the viability of defending against a specialized ransomware attack with a redundant controller network. Results support that specific redundancy schemes are effective in recovering from a successful attack. Further experimentation is conducted to test the feasibility of industrial …

Expected Coverage (Excov): A Proposal To Compare Fuzz Test Coverage Within An Infinite Input Space, Evan V. Swihart

Theses and Dissertations

A Fuzz test is an approach used to discover vulnerabilities by intentionally sending invalid inputs to a system for the purpose of triggering some type of fault or unintended effect that renders the system vulnerable to an exploit. Fuzz testing is an important cyber-testing technique used to find and fix vulnerabilities before they are exploited. The fuzzing of military data links presents a particular challenge because existing fuzzing tools cannot be easily applied to these systems. As a result, the tools and techniques used to fuzz these links vary widely in sophistication and effectiveness. Because of the infinite, or nearly …

Securing Data In Transit Using Two Channel Communication, Clark L. Wolfe

Theses and Dissertations

Securing data in transit is critically important to the Department of Defense in todays contested environments. While encryption is often the preferred method to provide security, there exist applications for which encryption is too resource intensive, not cost-effective or simply not available. In this thesis, a two-channel communication system is proposed in which the message being sent can be intelligently and dynamically split over two or more channels to provide a measure of data security either when encryption is not available, or perhaps in addition to encryption. This data spiting technique employs multiple wireless channels operating at the physical layer, …

Variable Speed Simulation For Accelerated Industrial Control System Cyber Training, Luke M. Bradford

Theses and Dissertations

It is important for industrial control system operators to receive quality training to defend against cyber attacks. Hands-on training exercises with real-world control systems allow operators to learn various defensive techniques and see the real-world impact of changes made to a control system. Cyber attacks and operator actions can have unforeseen effects that take a significant amount of time to manifest and potentially cause physical harm to the system, making high-fidelity training exercises time-consuming and costly. This thesis presents a method for accelerating training exercises by simulating and predicting the effects of a cyber event on a partially-simulated control system. …

Spatial Dispersion Of Index Components Required For Building Invisibility Cloak Medium From Photonic Crystals, Saeid Jamilan, George Semouchkin, Navid Gandji, Elena Semouchkina

Michigan Tech Publications

The opportunities to use dielectric photonic crystals (PhCs) as the media of cylindrical invisibility cloaks, designed using transformation optics (TO) concepts, are investigated. It is shown that TO-based prescriptions for radial index dispersion, responsible for turning waves around hidden objects, can be dropped if the PhC media support self-collimation of waves in bent crystals. Otherwise, to provide prescribed anisotropy of index dispersion, it is possible to employ PhCs with rectangular lattices. It is found, however, that at acceptable cloak thicknesses, modifications of crystal parameters do not allow for achieving the prescribed level of index anisotropy. This problem is solved by …