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Full-Text Articles in Physical Sciences and Mathematics

2017 Fall Engr333 Project Final Report (Section A), Trevor Nyeholt, Francis Kapesa, Justin Thalmayer, Erik Karlson, Kyle Van Veen, Kirk Brink, Steven Tarske, Brent Homan, Nathan De Haan, Paul Bootsma, Megan Anders, Philip Holmes, Melanie Fox, Noah Pirrotta, Abigail Berkompas, Ben Wellman, Halley Press, Christopher Greaves, Josh Templeman, Tim Bosch, Jake Zandstra, Hendrik Vermeulen Dec 2017

2017 Fall Engr333 Project Final Report (Section A), Trevor Nyeholt, Francis Kapesa, Justin Thalmayer, Erik Karlson, Kyle Van Veen, Kirk Brink, Steven Tarske, Brent Homan, Nathan De Haan, Paul Bootsma, Megan Anders, Philip Holmes, Melanie Fox, Noah Pirrotta, Abigail Berkompas, Ben Wellman, Halley Press, Christopher Greaves, Josh Templeman, Tim Bosch, Jake Zandstra, Hendrik Vermeulen

ENGR 333

Calvin College currently spends $836,000 annually on natural gas consumption. The engineering 333-A class was tasked with the question, "What would it take for Calvin College to save $75,000 per year on natural gas costs". The class was split into five groups (Boilers, Dorms and Dining Hall, Academic Buildings, Finance, and PE Complex) to research possible areas of savings. Through the class' research, it was determined that Calvin College has the potential savings of $87,000 a year through the reduction of natural gas usage.


Synthesis And Characterization Of Thermoresponsive Hydrogels Based On N-Isopropylacrylamide Crosslinked With 4,4′-Dihydroxybiphenyl Diacrylate, Shuo Tang, Martha Floy, Rohit Bhandari, Manjula Sunkara, Andrew J. Morris, Thomas D. Dziubla, J. Zach Hilt Dec 2017

Synthesis And Characterization Of Thermoresponsive Hydrogels Based On N-Isopropylacrylamide Crosslinked With 4,4′-Dihydroxybiphenyl Diacrylate, Shuo Tang, Martha Floy, Rohit Bhandari, Manjula Sunkara, Andrew J. Morris, Thomas D. Dziubla, J. Zach Hilt

Chemical and Materials Engineering Faculty Publications

A novel crosslinker [4,4′-dihydroxybiphenyl diacrylate (44BDA)] was developed, and a series of temperature-responsive hydrogels were synthesized through free radical polymerization of N-isopropylacrylamide (NIPAAm) with 44BDA. The temperature-responsive behavior of the resulting gels was characterized by swelling studies, and the lower critical solution temperature (LCST) of the hydrogels was characterized through differential scanning calorimetry. Increased content of 44BDA led to a decreased swelling ratio and shifted the LCST to lower temperatures. These novel hydrogels also displayed resiliency through multiple swelling–deswelling cycles, and their temperature responsiveness was reversible. The successful synthesis of NIPAAm-based hydrogels crosslinked with 44BDA has led to a …


College Of Engineering Senior Design Competition Fall 2017, University Of Nevada, Las Vegas Dec 2017

College Of Engineering Senior Design Competition Fall 2017, University Of Nevada, Las Vegas

Fred and Harriet Cox Senior Design Competition Projects

Part of every UNLV engineering student’s academic experience, the senior design project stimulates engineering innovation and entrepreneurship. Each student in their senior year chooses, plans, designs, and prototypes a product in this required element of the curriculum. A capstone to the student’s educational career, the senior design project encourages the student to use everything learned in the engineering program to create a practical, real world solution to an engineering challenge. The senior design competition helps focus the senior students in increasing the quality and potential for commercial application for their design projects. Judges from local industry evaluate the projects on …


2017 Fall Engr333 Poster (Section B), Eric Ball, Mitchell Debruin, Raymond Kolocek, Edwin Kpodzro, Jacob Vandekieft, Nate Anderson, Brennan Steenhoek, Darbi Meyer, Derek Vermerris, Jessica Bouma, Devon Loerop, Reuben Saarloos, Richard Amoh, Matthew Boelens, Tyson Butler, Laura Van Winkle, Alex Keizer, Kwame Ohemeng, Cameron Richman, Julie Van De Riet Dec 2017

2017 Fall Engr333 Poster (Section B), Eric Ball, Mitchell Debruin, Raymond Kolocek, Edwin Kpodzro, Jacob Vandekieft, Nate Anderson, Brennan Steenhoek, Darbi Meyer, Derek Vermerris, Jessica Bouma, Devon Loerop, Reuben Saarloos, Richard Amoh, Matthew Boelens, Tyson Butler, Laura Van Winkle, Alex Keizer, Kwame Ohemeng, Cameron Richman, Julie Van De Riet

ENGR 333

Previously, Calvin College had a cogeneration system with the purpose of generating electricity and heat, through the combustion of natural gas, for Calvin’s campus. The original co-gen system was removed in 2017 due to high costs associated with maintenance and operations. Without a co-gen system, Calvin College is fully dependent on the grid. To save money and help in the President’s Carbon Commitment, PCC, the mechanical engineering students of ENGR 333 (section B) propose the implementation of a new co-gen system.


2017 Fall Engr333 Seminar Preservation, Trevor Nyeholt, Erik Karlson, Cam Richman, Tyson Butler Dec 2017

2017 Fall Engr333 Seminar Preservation, Trevor Nyeholt, Erik Karlson, Cam Richman, Tyson Butler

ENGR 333

File for student presentation, given by students in the Fall 2017 class of ENGR333.


2017 Fall Engr333 Poster (Section A), Trevor Nyeholt, Francis Kapesa, Justin Thalmayer, Erik Karlson, Kyle Van Veen, Kirk Brink, Steven Tarske, Brent Homan, Nathan De Haan, Paul Bootsma, Megan Anders, Philip Holmes, Melanie Fox, Noah Pirrotta, Abigail Berkompas, Ben Wellman, Halley Press, Christopher Greaves, Josh Templeman, Tim Bosch, Jake Zandstra, Hendrik Vermeulen Dec 2017

2017 Fall Engr333 Poster (Section A), Trevor Nyeholt, Francis Kapesa, Justin Thalmayer, Erik Karlson, Kyle Van Veen, Kirk Brink, Steven Tarske, Brent Homan, Nathan De Haan, Paul Bootsma, Megan Anders, Philip Holmes, Melanie Fox, Noah Pirrotta, Abigail Berkompas, Ben Wellman, Halley Press, Christopher Greaves, Josh Templeman, Tim Bosch, Jake Zandstra, Hendrik Vermeulen

ENGR 333

Calvin College uses 161,000 MMBTU of natural gas per year, which correlates to $836,000 of annual expenses. However Calvin could save as much as $240,000 on natural gas if they were as efficient as the top performer in an energy audit of similar colleges and universities in the Midwest, conducted by Sightlines Institute. The goal of this project was to see what actions could be taken to save the college $75,000 in annual natural gas costs.


Threshold Free Detection Of Elliptical Landmarks Using Machine Learning, Lifan Zhang Dec 2017

Threshold Free Detection Of Elliptical Landmarks Using Machine Learning, Lifan Zhang

Theses and Dissertations

Elliptical shape detection is widely used in practical applications. Nearly all classical ellipse detection algorithms require some form of threshold, which can be a major cause of detection failure, especially in the challenging case of Moire Phase Tracking (MPT) target images. To meet the challenge, a threshold free detection algorithm for elliptical landmarks is proposed in this thesis. The proposed Aligned Gradient and Unaligned Gradient (AGUG) algorithm is a Support Vector Machine (SVM)-based classification algorithm, original features are extracted from the gradient information corresponding to the sampled pixels. with proper selection of features, the proposed algorithm has a high accuracy …


Speckle Effects In Target-In-The-Loop Laser Beam Projection Systems, Mikhail Vorontsov Dec 2017

Speckle Effects In Target-In-The-Loop Laser Beam Projection Systems, Mikhail Vorontsov

Electro-Optics and Photonics Faculty Publications

In target-in-the-loop laser beam projection scenarios typical of remote sensing, directed energy, and adaptive optics applications, a transmitted laser beam propagates through an optically inhomogeneous medium toward a target, scatters off the target’s rough surface, and returns back to the transceiver plane. Coherent beam scattering off the randomly rough surface results in strong speckle modulation in the transceiver plane. This speckle modulation has been a long-standing challenge that limits performance of remote sensing, active imaging, and adaptive optics techniques. Using physics-based models of laser beam scattering off a randomly rough surface, we show that received speckle-field spatial and temporal characteristics …


Multiple Content Adaptive Intelligent Watermarking Schemes For The Protection Of Blocks Of A Document Image, Chetan Kr Mr., S Nirmala Dr. Dec 2017

Multiple Content Adaptive Intelligent Watermarking Schemes For The Protection Of Blocks Of A Document Image, Chetan Kr Mr., S Nirmala Dr.

Journal of Digital Forensics, Security and Law

Most of the documents contain different types of information such as white space, static information and dynamic information or mix of static and dynamic information. In this paper, multiple watermarking schemes are proposed for protection of the information content. The proposed approach comprises of three phases. In Phase-1, the edges of the source document image are extracted and the edge image is decomposed into blocks of uniform size. In Phase-2, GLCM features like energy, homogeneity, contrast and correlation are extracted from each block and the blocks are classified as no-information, static, dynamic and mix of static and dynamic information content …


Design And Implementation Of A Multi-Port Solid State Transformer For Flexible Der Integration, Mohammad Rashidi Dec 2017

Design And Implementation Of A Multi-Port Solid State Transformer For Flexible Der Integration, Mohammad Rashidi

Theses and Dissertations

Conventional power system includes four major sections, bulk generation, transmission network, distribution network, and loads. The main converter in the conventional electric grid is the low-frequency passive transformer providing galvanic isolation and voltage regulation for various voltage zones. In this configuration, small-scale renewable energy resources are generally connected to the power system at low voltage zones or inside microgrids.

Recent developments in the design of power electronic elements with higher voltage and power ratings and medium/high frequency enable making use of solid state transformer at different voltage levels in the distribution system and microgrid design. In this work, the concept …


Generalized Ellipsometry On Complex Nanostructures And Low-Symmetry Materials, Alyssa Mock Dec 2017

Generalized Ellipsometry On Complex Nanostructures And Low-Symmetry Materials, Alyssa Mock

Department of Electrical and Computer Engineering: Dissertations, Theses, and Student Research

In this thesis, complex anisotropic materials are investigated and characterized by generalized ellipsometry. In recent years, anisotropic materials have gained considerable interest for novel applications in electronic and optoelectronic devices, mostly due to unique properties that originate from reduced crystal symmetry. Examples include white solid-state lighting devices which have become ubiquitous just recently, and the emergence of high-power, high-voltage electronic transistors and switches in all-electric vehicles. The incorporation of single crystalline material with low crystal symmetry into novel device structures requires reconsideration of existing optical characterization approaches. Here, the generalized ellipsometry concept is extended to include applications for materials with …


Recursive Non-Local Means Filter For Video Denoising, Redha A. Ali, Russell C. Hardie Dec 2017

Recursive Non-Local Means Filter For Video Denoising, Redha A. Ali, Russell C. Hardie

Electrical and Computer Engineering Faculty Publications

In this paper, we propose a computationally efficient algorithm for video denoising that exploits temporal and spatial redundancy. The proposed method is based on non-local means (NLM). NLM methods have been applied successfully in various image denoising applications. In the single-frame NLM method, each output pixel is formed as a weighted sum of the center pixels of neighboring patches, within a given search window.

The weights are based on the patch intensity vector distances. The process requires computing vector distances for all of the patches in the search window. Direct extension of this method from 2D to 3D, for video …


Free-Space Measurements Of Dielectrics And Three-Dimensional Periodic Metamaterials, Clifford E. Kintner Dec 2017

Free-Space Measurements Of Dielectrics And Three-Dimensional Periodic Metamaterials, Clifford E. Kintner

Graduate Theses and Dissertations

This thesis presents the free-space measurements of a periodic metamaterial structure. The metamaterial unit cell consists of two dielectric sheets intersecting at 90 degrees. The dielectric is a polyetherimide-based material 0.001” thick. Each sheet has a copper capacitively-loaded loop (CLL) structure on the front and a cut-wire structure on the back. Foam material is used to support the unit cells. The unit cell repeats 40 times in the x-direction, 58 times in the y-direction and 5 times in the z-direction. The sample measures 12” × 12” × 1” in total. We use a free-space broadband system comprised of a pair …


Asynchronous 3d (Async3d): Design Methodology And Analysis Of 3d Asynchronous Circuits, Francis Corpuz Sabado Dec 2017

Asynchronous 3d (Async3d): Design Methodology And Analysis Of 3d Asynchronous Circuits, Francis Corpuz Sabado

Graduate Theses and Dissertations

This dissertation focuses on the application of 3D integrated circuit (IC) technology on asynchronous logic paradigms, mainly NULL Convention Logic (NCL) and Multi-Threshold NCL (MTNCL). It presents the Async3D tool flow and library for NCL and MTNCL 3D ICs. It also analyzes NCL and MTNCL circuits in 3D IC. Several FIR filter designs were implement in NCL, MTNCL, and synchronous architecture to compare synchronous and asynchronous circuits in 2D and 3D ICs. The designs were normalized based on performance and several metrics were measured for comparison. Area, interconnect length, power consumption, and power density were compared among NCL, MTNCL, and …


Carbide-Derived Carbon By Electrochemical Etching Of Vanadium Carbides, Luis G.B. Camargo, Benjamin G. Palazzo, Greg Taylor, Zach A. Norris, Yash K. Patel, Jeffrey D. Hettinger, Lei Yu Nov 2017

Carbide-Derived Carbon By Electrochemical Etching Of Vanadium Carbides, Luis G.B. Camargo, Benjamin G. Palazzo, Greg Taylor, Zach A. Norris, Yash K. Patel, Jeffrey D. Hettinger, Lei Yu

Jeffrey Hettinger

Carbide-derived Carbon (CDC) has been demonstrated to be an excellent electrode material for electrochemical devices including supercapacitors due to its chemical and electrochemical stability, large specific surface area and controllable pore size and morphology. Currently, CDC is prepared from metal carbides by chlorination in a chlorine gas atmosphere at temperatures of 350°C or higher. In this paper, conversion using electrochemical methods is reported, which can be achieved by oxidizing vanadium carbides (VC or V2C) in aqueous solutions at room temperature and a mild electrode potential to prepare CDC thin film as electrode materials for “on-chip” supercapacitiors. It was found that …


High Consequence Scenarios For North Korean Atmospheric Nuclear Tests With Policy Recommendations For The U.S. Government, Thomas S. Popik, Jordan T. Kearns, George H. Baker Iii, Henry F. Cooper, William R. Harris Nov 2017

High Consequence Scenarios For North Korean Atmospheric Nuclear Tests With Policy Recommendations For The U.S. Government, Thomas S. Popik, Jordan T. Kearns, George H. Baker Iii, Henry F. Cooper, William R. Harris

Department of Integrated Science and Technology - Faculty Scholarship

The government of North Korea has declared high-altitude EMP-capability to be a “strategic goal” and has also threatened an atmospheric test of a hydrogen bomb. Atmospheric nuclear tests have the potential to cripple satellites and the undersea cable networks critical to communication, and navigation necessary for trans-Pacific trade among the U.S., China, and other nations. When a nuclear warhead is detonated at high altitude, a series of electromagnetic pulses radiate downward within the line of sight of the blast. These pulses can disable equipment with miniature electronics and long conductors. Electric grid controls and transmission systems are especially vulnerable. Intense …


Graph-Based Latent Embedding, Annotation And Representation Learning In Neural Networks For Semi-Supervised And Unsupervised Settings, Ismail Ozsel Kilinc Nov 2017

Graph-Based Latent Embedding, Annotation And Representation Learning In Neural Networks For Semi-Supervised And Unsupervised Settings, Ismail Ozsel Kilinc

USF Tampa Graduate Theses and Dissertations

Machine learning has been immensely successful in supervised learning with outstanding examples in major industrial applications such as voice and image recognition. Following these developments, the most recent research has now begun to focus primarily on algorithms which can exploit very large sets of unlabeled examples to reduce the amount of manually labeled data required for existing models to perform well. In this dissertation, we propose graph-based latent embedding/annotation/representation learning techniques in neural networks tailored for semi-supervised and unsupervised learning problems. Specifically, we propose a novel regularization technique called Graph-based Activity Regularization (GAR) and a novel output layer modification called …


Load Model Verification, Validation And Calibration Framework By Statistical Analysis On Field Data, Xiangqing Jiao, Yuan Liao, Thai Nguyen Nov 2017

Load Model Verification, Validation And Calibration Framework By Statistical Analysis On Field Data, Xiangqing Jiao, Yuan Liao, Thai Nguyen

Electrical and Computer Engineering Faculty Publications

Accurate load models are critical for power system analysis and operation. A large amount of research work has been done on load modeling. Most of the existing research focuses on developing load models, while little has been done on developing formal load model verification and validation (V&V) methodologies or procedures. Most of the existing load model validation is based on qualitative rather than quantitative analysis. In addition, not all aspects of model V&V problem have been addressed by the existing approaches. To complement the existing methods, this paper proposes a novel load model verification and validation framework that can systematically …


Design And Simulation Of A Miniature Cylindrical Mirror Auger Electron Energy Analyzer With Secondary Electron Noise Suppression, Jay A. Bieber Nov 2017

Design And Simulation Of A Miniature Cylindrical Mirror Auger Electron Energy Analyzer With Secondary Electron Noise Suppression, Jay A. Bieber

USF Tampa Graduate Theses and Dissertations

In the nanoscale metrology industry, there is a need for low-cost instruments, which have the ability to probe the structrure and elemental composition of thin films. This dissertation, describes the research performed to design and simulate a miniature Cylindrical Mirror Analyzer, (CMA), and Auger Electron Spectrometer, (AES). The CMA includes an integrated coaxial thermionic electron source. Electron optics simulations were performed using the Finite Element Method, (FEM), software COMSOL. To address the large Secondary Electron, (SE), noise, inherent in AES spectra, this research also included experiments to create structures in materials, which were intended to suppress SE backgound noise in …


Investigating Scalable Manufacturing Of High-Conductivity Wires And Coatings From Ultra-Long Carbon Nanotubes, Pouria Khanbolouki Nov 2017

Investigating Scalable Manufacturing Of High-Conductivity Wires And Coatings From Ultra-Long Carbon Nanotubes, Pouria Khanbolouki

Mechanical Engineering ETDs

Carbon nanotubes (CNTs) are a promising candidate for next generation of electrical wirings and electromagnetic interference (EMI) shielding materials due to their exceptional mechanical and electrical properties. Wires and coatings from ultralong nanotubes that are highly crystalline, well-aligned and densely packed can achieve this goal. High-performance CNT conductors will be relatively lightweight and resistant to harsh conditions and therefore can potentially replace current conductors in many industries including aerospace, automotive, gas and oil.

This thesis investigates a new manufacturing approach, based on conventional solution coating and wire drawing methods, to fabricate high conductivity wires and coatings from ultra-long carbon nanotubes. …


Analysis Of The Joint Impact Of Atmospheric Turbulence And Refractivity On Laser Beam Propagation, Victor A. Kulikov, Mikhail Vorontsov Nov 2017

Analysis Of The Joint Impact Of Atmospheric Turbulence And Refractivity On Laser Beam Propagation, Victor A. Kulikov, Mikhail Vorontsov

Electro-Optics and Photonics Faculty Publications

A laser beam propagation model that accounts for the joint effect of atmospheric turbulence and refractivity is introduced and evaluated through numerical simulations. In the numerical analysis of laser beam propagation, refractive index inhomogeneities along the atmospheric propagation path were represented by a combination of the turbulence-induced random fluctuations described in the framework of classical Kolmogorov turbulence theory and large-scale refractive index variations caused by the presence of an inverse temperature layer. The results demonstrate that an inverse temperature layer located in the vicinity of a laser beam’s propagation path may strongly impact the laser beam statistical characteristics including the …


Evolution And Rationale For United States Department Of Defense Electromagnetic Pulse Protection Standard, George H. Baker Iii Nov 2017

Evolution And Rationale For United States Department Of Defense Electromagnetic Pulse Protection Standard, George H. Baker Iii

George H Baker

The United States (US) Department of Defense (DoD) Electromagnetic Pulse (EMP) protection standard offers a solid basis for protecting commercial communication, data, and control facilities. Because of the standard’s shielded barrier and test requirements, it is not surprising that there is a strong temptation within industry and government to dismiss the MIL-STD 188-125 approach in favor of less rigorous protection methods. It is important to understand that US DoD EMP protection standard for fixed facilities, MIL-STD-188-125, reflects an evolution by trial and error that spanned a period of decades beginning with the acquisition of the Minuteman Missile System in the …


Proposal For A Dod Combined Battlefield Electromagnetic Environmental Effects (E3) Initiative, George H. Baker Iii Nov 2017

Proposal For A Dod Combined Battlefield Electromagnetic Environmental Effects (E3) Initiative, George H. Baker Iii

George H Baker

The presentation emphasizes the growing importance of electromagnetic survivability and compatibility. Operation Desert Storm demonstrated the clear military advantage provided by sophisticated electronic weapon and communication systems. In addition, the offensive tactic of taking out the enemy's eyes and ears during the air war paid off, giving our military decisive air superiority. The lessons for the future are clear. High-tech electronics now so dominates the battlefield that the outcome of future conflicts could well be decided by electronics attrition rather than human casualties. Our Desert Storm experience thus accentuates the importance of guaranteeing that our electronic systems will not be …


Testimony Of Dr. George H. Baker, Senior Advisor To The Congressional Emp Commission, George H. Baker Iii Nov 2017

Testimony Of Dr. George H. Baker, Senior Advisor To The Congressional Emp Commission, George H. Baker Iii

George H Baker

This is the script of testimony before the Federal Energy Regulatory Commission. It offers a vision for a future in which our electric power systems will be able to operate through or quickly recover from catastrophic failure due to electromagnetic pulse (EMP), cyber, and physical attacks. The scope of the term ‘EMP’ used in this testimony includes both naturally occurring solar storms and the more energetic man-made EMP hazards. The vision has been discussed with members of the electric power industry, and prominent EMP/cyber/physical protection advocates who find it to be supportable and actionable. The nature of EMP, cyber, and …


Template Induced Fabrication Of Nitrogen Doped Carbon Sheets As Electrode Materials In Supercapacitors, Tao Huang, Guang-Zhi Tao, Chong-Qing Yang, Deng Lu, Lie Ma, Dong-Qing Wu Oct 2017

Template Induced Fabrication Of Nitrogen Doped Carbon Sheets As Electrode Materials In Supercapacitors, Tao Huang, Guang-Zhi Tao, Chong-Qing Yang, Deng Lu, Lie Ma, Dong-Qing Wu

Journal of Electrochemistry

Due to the good electrical conductivity, high specific surface area, and excellent chemical/mechanical stability, carbon nanomaterials with two-dimensional morphology have gradually become the hot topic of the research on supercapacitors. Herein, we report for the first time the fabrication of nitrogen doped carbon sheets (NCSs). In our approach, the sheet-like magnisum aluminum (MgAl) layered double hydroxide was used as the hard template, which was mixed with o-phenylene diamine and iron chloride. The following thermal treatment could render the polymerization and carbonization of o-phenylene diamine. The NCSs with ordered hexagonal architectures were formed by final etching process of the thermally treated …


Preparation And Characterization Of Cellulose Acetate-Based Separator For Lithium-Ion Batteries, Hua-Feng Luo, Yuan-Dong Qiao Oct 2017

Preparation And Characterization Of Cellulose Acetate-Based Separator For Lithium-Ion Batteries, Hua-Feng Luo, Yuan-Dong Qiao

Journal of Electrochemistry

To improve the electrolyte wettability and thermal resistance of separators used for lithium-ion battery, a novel cellulose acetate (CA)-based separator is facilely prepared by non-solvent induced phase separation (NIPS) wet-process and investigated in lithium-ion batteries. Systematical investigations including morphological characterization, electrolyte wettability and thermal resistance testing were carried out. The results demonstrated that the CA-based separator exhibited well developed three-dimensional porous structures with porosity up to 65%, which is 1.5 times higher than that of PE separator. The CA separator also showed excellent electrolyte uptake (285%) and thermal stability at 150 oC for 30 min. Compared with the commercial …


Special Issue On Supercapacitors, Xiao-Gang Zhang Oct 2017

Special Issue On Supercapacitors, Xiao-Gang Zhang

Journal of Electrochemistry

Supercapacitors (SCs) have become a new bright spot in electrochemical power source due to their high power density, long cycling life and wide operation temperature. As the high-power density energy storage devices, SCs have been widely applied in electric vehicle, modern communication, aerospace, defense, and many other emerging fields. The markets for SCs are continuously increasing. However, the commercialization of SCs suffers from a lower energy density and higher cost. Thus, one great challenge for the supercapacitor (SC) technology is to improve the energy density without sacrificing the power density and cycle life. To address this critical issue, the worldwide …


Porous Carbon Materials Produced By Koh Activation For Supercapacitor Electrodes, Jiang-Lin Ye, Yan-Wu Zhu Oct 2017

Porous Carbon Materials Produced By Koh Activation For Supercapacitor Electrodes, Jiang-Lin Ye, Yan-Wu Zhu

Journal of Electrochemistry

Porous carbon materials with high specific surface area and excellent conductivity have wide applications in supercapacitor electrodes. Much effort has been made to synthesize and tailor the microstructures of porous carbon materials via various activation procedures (physical and chemical activations). In particular, the chemical activation using potassium hydroxide (KOH) as an activating reagent is promising because of the well-defined micropore size distribution and ultrahigh specific surface area up to 3000 m2·g-1 of the resulting porous carbons. Based mainly on the previous works taken by the authors and collaborators in the field, we have summarized the activation mechanism …


Lithium Ion Hybrid Capacitor With High Energy Density, Xian-Zhong Sun, Xiong Zhang, Kai Wang, Yan-Wei Ma Oct 2017

Lithium Ion Hybrid Capacitor With High Energy Density, Xian-Zhong Sun, Xiong Zhang, Kai Wang, Yan-Wei Ma

Journal of Electrochemistry

Lithium ion hybrid capacitors are electrochemical energy storage devices combining the advantages of both Li-ion battery and electrochemical capacitor. They can be extensively used in many fields. However, the commercialization of lithium ion hybrid capacitor has been encountered several problems, e.g., the device structure design, the screening of materials, the pre-lithiation process, and the interface between electrolyte and electrode, etc. This review summarizes the recent research advances in lithium ion hybrid capacitor with high energy density, including the selection of the active materials in cathode/anode and the separator, the pre-lithiation method using the three-electrode structure, the high- and low-temperature performances, …


Recent Advances On Carbon And Transition Metallic Compound Electrodes For High-Performance Supercapacitors, Dun Lin, Xi-Yue Zhang, Yin-Xiang Zeng, Ming-Hao Yu, Xi-Hong Lu, Ye-Xiang Tong Oct 2017

Recent Advances On Carbon And Transition Metallic Compound Electrodes For High-Performance Supercapacitors, Dun Lin, Xi-Yue Zhang, Yin-Xiang Zeng, Ming-Hao Yu, Xi-Hong Lu, Ye-Xiang Tong

Journal of Electrochemistry

Supercapacitors (SCs) have stimulated intensive interests for their promising applications in electric vehicles and portable electronics, etc. Electrode material is the most important key component of SCs, which vastly determines the performance of SCs. Carbon and transition metallic compound materials have attracted considerable attention and been widely explored as electrode materials. However, the insufficient capacitance of carbon materials and unsatisfactory conductivity and cyclic stability of transition metallic compounds severely limit their implementation as robust SC electrodes. Herein, we highlight our recent efforts to boost the capacitive performance of carbon and metal oxide/nitride electrodes by rationally structural and componential design. The …