Physical Sciences and Mathematics Commons^™

Chiral Light Intrinsically Couples To Extrinsic/Pseudo-Chiral Metasurfaces Made Of Tilted Gold Nanowires, Alessandro Belardini, Marco Centini, Grigore Leahu, David C. Hooper, Roberto Li Voti, Eugenio Fazio, Joseph W. Haus, Andrew Sarangan, Ventsislav K. Valev, Concita Sibilia

Andrew Sarangan

Extrinsic or pseudo-chiral (meta)surfaces have an achiral structure, yet they can give rise to circular dichroism when the experiment itself becomes chiral. Although these surfaces are known to yield differences in reflected and transmitted circularly polarized light, the exact mechanism of the interaction has never been directly demonstrated. Here we present a comprehensive linear and nonlinear optical investigation of a metasurface composed of tilted gold nanowires. In the linear regime, we directly demonstrate the selective absorption of circularly polarised light depending on the orientation of the metasurface. In the nonlinear regime, we demonstrate for the first time how second harmonic …

Application Of Composite Ionic Liquid In Electro-Oxidation Activation Of A C-H Bond, Zi-Ying Chen, Qian-Qian Wu, Jian-Qing Zhang, Ying-Hong Zhu, Chun-An Ma

Journal of Electrochemistry

In this paper, the ionic liquid/carbon nanotube composite material was prepared through modifying the ionic liquid 1-ethyl-3-methylimidazolium acetate to multi-walled carbon nanotubes. The electro-oxidation properties of p-methoxy toluene (p-MT) were studied using the composite as an electrolyte. The effects of scanning speed, temperature and substrate concentration were studied by cyclic voltammetry and chronoamperometry. The electrochemical kinetics of p-MT in this system was also studied. The results showed that the electrochemical oxidation of p-MT in the composite electrolyte solution was irreversible. The process was mainly controlled by diffusion, and the diffusion coefficient (D) was 7.69×10-10 cm2.s-1. Increasing the reaction temperature and …

Electrochemical Nucleation Of Invar Alloy On Glassy Carbon Electrode, Xian-Jie Huang, Hui Yan, Shuai-Shuai Huang, Fang-Zu Yang, Zhong-Qun Tian, Shao-Min Zhou

Journal of Electrochemistry

Abstract: The linear sweep voltammetry, cyclic voltammetry and potential step methods were used to study the electrodeposition mechanism of Invar nickel-iron alloy (the mass fraction of nickel was 32~36%) on glassy carbon electrode surface in the weak acidic bath. The results demonstrate that the electrodeposition is was a diffusion controlled irreversible electrode process in this system. The Scharifker-Hill (SH) theory theoritic model (SH) were was used employed to fitting the experimental data and the result shows that the codeposition of Invar alloy on glassy carbon electrode surface conformed to the diffusion controlled three-dimensional instantaneous nucleation mechanism. The kinetic parameters were …

Sn-Doped Α-Fe2O3 Photocatalyst Containing Oxygen Vacancy For Water-Splitting, Zu-Hua Wang, Dong-Fang Niu, Hui-Cheng Li, Rong-Bin Du, Heng Xu, Xin-Sheng Zhang

Journal of Electrochemistry

The α-Fe₂O₃ nanoparticles containing oxygen vacancies were synthesized in atmospheric N₂ by dip-dropping method without a high vacuum employed before annealing. The influences of annealing atmosphere and Sn-doping on the photocatalytic performance of α-Fe₂O₃ nanoparticles were studied by annealing the photocatalyst in N₂ or air and adding SnCl₄ to the precursor directly. The results showed that the current density of Sn-doping α-Fe₂O₃ annealed in N₂ at 550 °C and 1.23 V (vs. RHE) was 35 times greater than that of pristine α-Fe_{2 …}

Direct Electrochemistry Of Glucose Oxidase Based On Ws2 Quantum Dots And Its Biosensing Application, Chen-Lu Li, Hua-Ping Peng, Zhong-Nan Huang, Yi-Lun Sheng, Pei-Wen Wu, Xin-Hua Lin

Journal of Electrochemistry

In this study, a novel electrochemical glucose biosensor has been developed by immobilizing glucose oxidase (GOx) on tungsten disulfide quantum dots (WS₂ QDs) on the surface of glassy carbon electrode (GCE). Transmission electron microscopy, UV-vis spectroscopy and cyclic voltammetry were employed to characterize the morphology, structure, and electrochemical behaviors of the as-prepared WS₂ QDs and the biofilm modified electrode. The results suggested that the WS₂ QDs could accelerate the electron transfer between the electrode and the immobilized enzyme, which enabled the direct electrochemistry of GOx without any electron mediator. Besides, the immobilized GOx in WS₂ QDsfilm …

Effects Of Flame Retardant On The Rate Capability And Safety Performances Of The Soft-Package 5ah Lithium Ion Battery, Yan-Zhuo Lv, Xiao-He Wang, Yi-Ming Qin, Zhen-Bo Wang, Ke Ke

Journal of Electrochemistry

The 5 Ah soft packed lithium ion batteries with LiNi _0.4Co_0.2Mn_0.4 O₂ as the positive electrode material and the organic electrolytes with different amounts of fire retardants as the electrolyte solution were prepared. The effects of the fire retardant amount (5 %，10 %，20 %) of the fire retardants on the rate performances, short-circuit characteristics and overcharged behaviors of the 5 Ah soft packed lithium ion battery were investigated by electrochemical methods. The results indicated that the best rate performances were obtained by adding 5 vol.% of the fire retardants in the electrolyte solution when the …

An Investigation In The Performance Of Lithium Sulfur Battery With A Tic Coated Separator, Jian-Hua Fang, Yong Cao, Mao-Ping Yang, Ming-Sen Zheng, Quan-Feng Dong

Journal of Electrochemistry

To improve the specific capacity and cycle stability of lithium-sulfur (Li-S) battery, a TiC/Celgard coating separator was developed and its performance in Li-S battery was investigated. The electrochemical test results confirmed that the TiC coating layer could significantly increase the capacity and cycle stability. At a high rate of 2C, it still delivered the capacity of 650 mAh?g-1. At 0.5C, the specific capacity was maintained at 841.3 mAh?g-1 after 100 cycles.

The Problem Of The Anode Electrolyte In H-Type Electrolytic Cell For Electrochemical Reduction Of Carbon Dioxide, Rui Zhang, Wei-Xin Lv, Li-Xu Lei

Journal of Electrochemistry

Electrochemical reduction of carbon dioxide (CO₂) was studied in the H-type electrolytic cell. It was found that the voltage between the cathode and the anode would increase during the long time electrolysis process, for this reason the electrolytic process would be unsustainable. After the experimental investigations carried out by constant potential electrolysis, constant current electrolysis, pH test and KHCO₃ concentration analysis of anode electrolyte before and after the electrolysis, the increase in cell voltage might be caused by the following process: H⁺, that was generated from the anodic oxygen evolution reaction, reacted with HCO_{3 …}

Application Of Adamantane Schiff Base Nickel Complexes/Graphene Oxide/Glassy Carbon Modified Electrode In Detection Of Carmine, Peng Guo, Zheng Liu, Hai-Ying Li, Li-Ming Ma

Journal of Electrochemistry

The Schiff base nickel complexes/graphene oxide/glassy carbon electrodes were prepared by embedded method and electrodeposition on which were used to quantitatively detect the contents of carmine. Cyclic voltammetry, chronoamperometry, scanning electron microscopy (SEM) and other methods were employed to characterize properties and morphologies of the modified electrodes. The results show that the adamantane double Schiff base nickel complexes/graphene oxide/glassy carbon electrode had high electric catalytic activity toward carmine oxidation reaction, and might provide an easy and quick way to detect carmine content with good reproducibility.

Preparation And Electrochemical Properties Of Attapulgite-Supported Nitrogen-Doped Carbon@Nico2O4Composites For Supercapacitors, Hui Wan, Zong-Rong Ying, Xin-Dong Liu, Jian-Jian Lu, Wen-Wen Zhang

Journal of Electrochemistry

In this work, the attapulgite-supported nitrogen-doped carbon (ANC) was prepared by in-situ chemically polymerizing polyaniline coating upon attapulgite, followed by high temperature heat treatment, and then NiCo₂O₄was reacted onto the surface of ANC by a combination of hydrothermal reaction and calcination to synthesize ANC@NiCo₂O₄ composites. The chemical composition and morphology of the samples were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and N₂ adsorption/desorption. The electrochemical properties were evaluated by means of constant current charge discharge (GCD) and cyclic voltammetry (CV). …

Electrochemical Synthesis Of Porous Polyaniline Electrodes Using Hkust-1 As A Template And Their Electrochemical Supercapacitor Property, Qiong Luan, Chun-Feng Xue, Hong-Ye Zhu, Fu-Juan Yang, Xu-Li Ma, Xiao-Gang Hao

Journal of Electrochemistry

Excellent electrode plays vital important role in the performance of supercapacitors. Polyaniline (PANI) with good conductivity is often used to prepare electrode. However, its available surface is limited and results in a poor supercapacitance in many cases. It is desirable to fabricate an electrode containing electroactive PANI with high surface area deriving from its porous structure. Here, the metal-organic framework (MOF) material with high surface area was selected as a hard template for synthesizing porous PANI. Microporous PANI composite electrodes (Micro-PANI/CC) were fabricated by depositing aniline on to carbon cloth (CC) pre-coated with MOF material of HKUST-1 using a unipolar …

Women In It: Be The Change, Marcia L. Dority Baker

Information Technology Services: Publications

The influence of established women in IT — specifically Florence Hudson and Melissa Woo — encouraged a librarian to apply for a position in Information Technology Services at the University of Nebraska–Lincoln.

A hands-on approach to planning the IT Leadership conference developed a strong collaborative network that also helped grow attendance.

Paying attention to the pros and cons of the 2016 conference guided the planners in modifying their approach to the upcoming October 2017 conference and its focus on diversity and inclusion.

A main goal for future IT Leadership conferences focusing on women and diversity in IT is providing attendees …

Block Matching And Wiener Filtering Approach To Optical Turbulence Mitigation And Its Application To Simulated And Real Imagery With Quantitative Error Analysis, Russell C. Hardie, Michael Armand Rucci, Barry K. Karch, Alexander J. Dapore

Electrical and Computer Engineering Faculty Publications

We present a block-matching and Wiener filtering approach to atmospheric turbulence mitigation for long-range imaging of extended scenes. We evaluate the proposed method, along with some benchmark methods, using simulated and real-image sequences. The simulated data are generated with a simulation tool developed by one of the authors. These data provide objective truth and allow for quantitative error analysis. The proposed turbulence mitigation method takes a sequence of short-exposure frames of a static scene and outputs a single restored image. A block-matching registration algorithm is used to provide geometric correction for each of the individual input frames. The registered frames …

Simulation Of Anisoplanatic Imaging Through Optical Turbulence Using Numerical Wave Propagation With New Validation Analysis, Russell C. Hardie, Jonathan D. Power, Daniel A. Lemaster, Douglas R. Droege, Szymon Gladysz, Santasri Bose-Pillai

Electrical and Computer Engineering Faculty Publications

We present a numerical wave propagation method for simulating imaging of an extended scene under anisoplanatic conditions. While isoplanatic simulation is relatively common, few tools are specifically designed for simulating the imaging of extended scenes under anisoplanatic conditions. We provide a complete description of the proposed simulation tool, including the wave propagation method used. Our approach computes an array of point spread functions (PSFs) for a two-dimensional grid on the object plane. The PSFs are then used in a spatially varying weighted sum operation, with an ideal image, to produce a simulated image with realistic optical turbulence degradation. The degradation …

2017 Spring Engr333 Project Assignment, Matthew K. Heun

ENGR 333

The Spring 2017 ENGR333 project focused on campus energy consumption.

I asked the students “Can you construct a fine-grained, bottom-up electricity demand model that predicts the annual electricity consumption for the dormitories (section A) and the PE complex (section B) for each year of the last decade with an accuracy of ±2%?”

Customer

The customer for this project was Jack Phillips, Assistant Director (Mechanical) at Calvin’s Physical Plant.

Design Of Radio-Frequency Arrays For Ultra-High Field Mri, Ian R O Connell

Electronic Thesis and Dissertation Repository

Magnetic Resonance Imaging (MRI) is an indispensable, non-invasive diagnostic tool for the assessment of disease and function. As an investigational device, MRI has found routine use in both basic science research and medicine for both human and non-human subjects.

Due to the potential increase in spatial resolution, signal-to-noise ratio (SNR), and the ability to exploit novel tissue contrasts, the main magnetic field strength of human MRI scanners has steadily increased since inception. Beginning in the early 1980’s, 0.15 T human MRI scanners have steadily risen in main magnetic field strength with ultra-high field (UHF) 8 T MRI systems deemed to …

Thermal And Waveguide Optimization Of Broad Area Quantum Cascade Laser Performance, Matthew Suttinger

Electronic Theses and Dissertations

Quantum Cascade Lasers are a novel source of coherent infrared light, unique in their tunability over the mid-infrared and terahertz range of frequencies. Advances in bandgap engineering and semiconductor processing techniques in recent years have led to the development of highly efficient quantum cascade lasers capable of room temperature operation. Recent work has demonstrated power scaling with broad area quantum cascade lasers by increasing active region width beyond the standard ~10 ?m. Taking into account thermal effects caused by driving a device with electrical power, an experimentally fitted model is developed to predict the optical power output in both pulsed …

Photothermal Lensing In Mid-Infrared Materials, Justin Cook

Electronic Theses and Dissertations

A thorough understanding of laser-materials interactions is crucial when designing and building optical systems. An ideal test method would probe both the thermal and optical properties simultaneously for materials under large optical loads where detrimental thermal effects emerge. An interesting class of materials are those used for infrared wavelengths due to their wide spectral transmission windows and large optical nonlinearities. Since coherent sources spanning the mid-wave and long-wave infrared wavelength regions have only become widely available in the past decade, data regarding their thermal and optical responses is lacking in literature. Photothermal Lensing (PTL) technique is an attractive method for …

High Dynamic Range Display Systems, Ruidong Zhu

Electronic Theses and Dissertations

High contrast ratio (CR) enables a display system to faithfully reproduce the real objects. However, achieving high contrast, especially high ambient contrast (ACR), is a challenging task. In this dissertation, two display systems with high CR are discussed: high ACR augmented reality (AR) display and high dynamic range (HDR) display. For an AR display, we improved its ACR by incorporating a tunable transmittance liquid crystal (LC) film. The film has high tunable transmittance range, fast response time, and is fail-safe. To reduce the weight and size of a display system, we proposed a functional reflective polarizer, which can also help …

Novel Photonic Resonance Arrangements Using Non-Hermitian Exceptional Points, Hossein Hodaei

Electronic Theses and Dissertations

In recent years, non-Hermitian degeneracies also known as exceptional points (EPs) have emerged as a new paradigm for engineering the response of optical systems. EPs can appear in a wide class of open non-Hermitian configurations. Among different types of non-conservative photonic systems, parity-time (PT) symmetric arrangements are of particular interest since they provide an excellent platform to explore the physics of exceptional points. In this work, the intriguing properties of exceptional points are utilized to address two of the long standing challenges in the field of integrated photonics- enforcing single mode lasing in intrinsically multimode cavities and enhancing the sensitivity …

Laser-Induced Crystallization Mechanisms In Chalcogenide Glass Materials For Advanced Optical Functionality, Laura Sisken

Electronic Theses and Dissertations

Glass-ceramics (GC) are promising candidates for gradient refractive index (GRIN) optics. These multi-phase, composite materials also exhibit improved physical properties as compared to the parent base glass resulting from the formation of a secondary crystalline phase(s). Nanocrystal phase formation in a multi-component chalcogenide glass (ChG), (GeSe2-3As2Se3)(1-x)-(PbSe)x glass where x = 0-40 has been investigated, and the role of the starting material morphology has been correlated to the resulting composite's optical properties including refractive index, transmission, dispersion, and thermo-optic coefficient. Optical property evolution was related to the type and amount of the crystal phases formed, since through control of the local …

Advanced Liquid Crystal Displays With Supreme Image Qualities, Haiwei Chen

Electronic Theses and Dissertations

Several metrics are commonly used to evaluate the performance of display devices. In this dissertation, we analyze three key parameters: fast response time, wide color gamut, and high contrast ratio, which affect the final perceived image quality. Firstly, we investigate how response time affects the motion blur, and then discover the 2-ms rule. With advanced low-viscosity materials, new operation modes, and backlight modulation technique, liquid crystal displays (LCDs) with an unnoticeable image blur can be realized. Its performance is comparable to an impulse-type display, like cathode ray tube (CRT). Next, we propose two novel backlight configurations to improve an LCD's …

Generation Of High-Flux Attosecond Pulses And Towards Attosecond-Attosecond Pump-Probe Experiments, Yang Wang

Electronic Theses and Dissertations

At present, the energy of a single isolated attosecond pulse is limited to nanojoule levels. As a result, an intense femtosecond pulse has always been used in combination with a weak attosecond pulse in time-resolved experiments. To reach the goal of conducting true attosecond pump-attosecond probe experiments, a high flux laser source has been developed that can potentially deliver microjoule level isolated attosecond pulses in the 50 eV range, and a unique experimental end station has been fabricated and implemented that can provide precision control of the attosecond-attosecond pump-probe pulses. In order to scale up the attosecond flux, a unique …

Design Of A Hydrogen-Filled Hollow-Core Fiber Raman Laser, Yangyang Qin

Electronic Theses and Dissertations

The purpose of this study is to investigate the design of a Raman fiber laser based on a molecule hydrogen-filled hollow-core fiber with non-touching single ring of capillaries structure. O-hydrogen vibrational frequency shift of 4155 cm-1 and rotational frequency shift of 587 cm-1 were employed to generate Raman scattering from a 1064nm pump source. A thorough exploration was made to show how all Raman fiber laser components made up: gas chamber, hollow-core fibers, windows. The whole process of chamber design, modification and fabrication were demonstrated. Besides, two kinds of anti-resonant hollow-core fibers were studied and tested. The transmission and loss …

System For Metal Coated Fiber Fabrication, Da Zhang

Electronic Theses and Dissertations

For many specific applications, such as sensors, aerospace, chemical industry, deep-well oil-field industry, metal-coated fiber shows strong abilities to satisfy people's requirement. With in-line coating technology, we are able to coat Aluminum on the fibers. Using electromagnetic induction, we can easily heat an electrically conducting thing such as a metal with the eddy current. This process is defined as Induction heating. And we will melt the Aluminum by this induction heating during drawing the fibers on the tower. Introduce the fiber tower system. The drawing process of in-line technology is formed of the following steps: Position, Melting, Forming into fibers, …

Band-To-Band Transitions, Selection Rules, Effective Mass, And Excitonic Contributions In Monoclinic Β-Ga2o3, Alyssa Mock, Rafal Korlacki, Chad Briley, Vanya Darakchieva, Bo Monemar, Yoshinao Kumagai, Ken Goto, Masataka Higashiwaki, Mathias Schubert

Department of Electrical and Computer Engineering: Faculty Publications

We employ an eigenpolarization model including the description of direction dependent excitonic effects for rendering critical point structures within the dielectric function tensor of monoclinic β-Ga₂O₃ yielding a comprehensive analysis of generalized ellipsometry data obtained from 0.75–9 eV. The eigenpolarization model permits complete description of the dielectric response. We obtain, for single-electron and excitonic band-to-band transitions, anisotropic critical point model parameters including their polarization vectors within the monoclinic lattice. We compare our experimental analysis with results from density functional theory calculations performed using the Gaussian-attenuation-Perdew-Burke-Ernzerhof hybrid density functional. We present and discuss the order of the …

Anisotropy, Phonon Modes, And Lattice Anharmonicity From Dielectric Function Tensor Analysis Of Monoclinic Cadmium Tungstate, Alyssa Mock, Rafal Korlacki, Sean Knight, Mathias Schubert

Department of Electrical and Computer Engineering: Faculty Publications

We determine the frequency dependence of four independent Cartesian tensor elements of the dielectric function for CdWO₄ using generalized spectroscopic ellipsometry within mid-infrared and far-infrared spectral regions. Different single crystal cuts, (010) and (001), are investigated. From the spectral dependencies of the dielectric function tensor and its inverse we determine all long-wavelength active transverse and longitudinal optic phonon modes with A_u and B_u symmetry as well as their eigenvectors within the monoclinic lattice. We thereby demonstrate that such information can be obtained completely without physical model line-shape analysis in materials with monoclinic symmetry. We then augment the …

Smart Underground Antenna Arrays: A Soil Moisture Adaptive Beamforming Approach, Abdul Salam, Mehmet C. Vuran

CSE Technical Reports

In this paper, a novel framework for underground beamforming using adaptive antenna arrays is presented. Based on the analysis of propagation in wireless underground channel, a theoretical model is developed which uses soil moisture information and feedback mechanism to improve performance wireless underground communications. Array element in soil has been analyzed empirically and impacts of soil type and soil moisture on return loss and resonant frequency are investigated. Beam patterns are investigated to communicate with both underground and above ground devices. Depending on the incident angle, refraction from soil-air interface has the adverse effects in the UG communications. It is …

Wireless Underground Channel Diversity Reception With Multiple Antennas For Internet Of Underground Things, Abdul Salam, Mehmet C. Vuran

CSE Conference and Workshop Papers

Internet of underground things (IOUT) is an emerging paradigm which consists of sensors and communication devices, partly or completely buried underground for real-time soil sensing and monitoring. In this paper, the performance of different modulation schemes in IOUT communications is studied through simulations and experiments. The spatial modularity of direct, lateral, and reflected components of the UG channel is exploited by using multiple antennas. First, it has been shown that bit error rates of $10^{-3}$ can be achieved with normalized delay spreads ($\tau_d$) lower than $0.05$. Evaluations are conducted through the first software-defined radio-based field experiments for UG channel. Moreover, …

Towards Internet Of Underground Things In Smart Lighting: A Statistical Model Of Wireless Underground Channel, Abdul Salam, Mehmet C. Vuran, Suat Irmak

CSE Conference and Workshop Papers

The Internet of Underground Things (IOUT) has many applications in the area of smart lighting. IOUT enables communications in smart lighting through underground (UG) and aboveground (AG) communication channels. In IOUT communications, an in-depth analysis of the wireless underground channel is important to design smart lighting solutions. In this paper, based on the empirical and the statistical analysis, a statistical channel model for the UG channel has been developed. The parameters for the statistical tapped-delay-line model are extracted from the measured power delay profiles (PDP). The PDP of the UG channel is represented by the exponential decay of the lateral, …