Physical Sciences and Mathematics Commons^™

Electrosynthesis Of A New Electroactive Poly(2,2'-Diaminophenyloxydisulfide), Yu Zhi Su, Yan Wen Rao, Ye Yang, Mei-Bing Chen, Yin Ling Qiu, Yong-Hua Zhang, Ke Cheng Gong

Journal of Electrochemistry

A new electroactive poly(2,2' diaminophenyloxydisulfide) (PDAPD) was successfully synthesized from acetonitrile(AN)/tetrahydrofuran(THF)solutions containing the supporting electrolyte(LiClO 4)and the various kinds of acids(HCl,CF 3COOH,CCl 3COOH) on Pt electrode by consecutive cyclic voltammiry. The effects of the concentrations of supporting electrolyte(LiClO 4) and acid(HCl,CF 3COOH,CCl 3COOH) on electrodepositon of PDAPD film were investigated. The best experimental conditions for electrosynthesis of a highly electroactive conducting polymer film are that the concentrations are 0.1 mol/L and between 0.05 mol/L～0.5 mol/L,respectively for LiClO 4 and HCl.

Current Oscillations In The System Of Carbon Steel/Phosphoric Acid/Platinum, Shao-Yuan Shi, Jin-Ping Wu, Jing Liu, An Lin

Journal of Electrochemistry

The periodic,aperiodic,chaotic and mixed_mode oscillations can occur in the process of the anodic electrodissolution of carbon steel in the solution of dilute phosphoric acid. More plentiful dynamic behaviors can be found in this system compared with the system of Fe/H 3PO 4/Pt.

Characterization And Electrochemical Investigation Of Boron-Doped Mesocarbon Microbeads Anode Materials For Lithium-Ion Battery, Mao-Hui Chen, Guo-Tao Wu, Guang-Ming Zhu, Jin-Kua You, Zu-Geng Lin

Journal of Electrochemistry

The anodic performances of boron doped and undoped mesocarbon microbeads(MCMBs) were comparatively studied and the structures were characterized by XPS,SEM,XRD and electrochemical measurements. It was found that boron doping samples greatly increased the degree of graphitization and the crystallite size,leading to quite different morphology. Electrochemical discharge/charge cycle tests indicate that lithium intercalation occurred at a little higher potential for the boron doped MCMBs, being attended by greater irreversible capacity loss.

Real-Time Travel Time Estimation Using Macroscopic Traffic Flow Models, Pushkin Kachroo, Kaan Ozbay, Antoine G. Hobeika

Electrical & Computer Engineering Faculty Research

This paper presents the estimation of travel time on highways based on macroscopic modelling. The focus is on real-time values as compared to average or static values. The macroscopic models are used for distributed and time/space lumped settings and corresponding travel time estimation functions and algorithms are developed. The implications of these algorithms for the implementation of various incident management and traffic control strategies are also discussed.

Microcavity Surface Emitting Laser, Stewart Feld, John P. Loehr, James A. Lott

AFIT Patents

A three-dimensional waveguiding structure for a microcavity surface-emitting laser is described in which native aluminum oxide layers provide control of intracavity waveguiding and the laser optical mode structure of the emitted beam. Microcavity lasers described herein account for the blueshift of the emission wavelength as the laser lateral dimensions are reduced to or below the emission wavelength.

Feedback Correction Of Angular Error In Grating Readout, Monish Ranjan Chatterjee, Sundaram Ramachandran

Electrical and Computer Engineering Faculty Publications

Angular and wavelength READ beam errors in holographic interconnection systems are often a recurrent problem. Several strategies have been proposed to minimize or eliminate such READOUT misalignments.

Some years ago, Chatterjee and co-workers proposed a method involving READ beam wavelength tuning to correct output angular errors. In this paper, we investigate the possibility of using an acousto-optic (A-O) Bragg cell with optoelectronic feedback to dynamically correct the scattered beam for deviations in the incidence direction of the READ beam of a hologram. The concept here is based on an acoustic frequency feedback strategy used recently by Balakshy and Kazaryan for …

Pulsed Electron Heating Of Atmospheric Pressure Air Glow Discharges, Hisham Merhi

Electrical & Computer Engineering Theses & Dissertations

By applying electric field pulses of short duration (compared to the time constant for glow-to-arc transitions) to a weakly ionized gas, the electron energy distribution can be temporarily shifted to higher energies. This effect causes a nonlinear increase in the ionization rate and consequently a larger electron decay time. This effect has been demonstrated using single pulse operation.³ In order to generate plasma with semi-continuous electron density, repetitive operation is required. As a first step towards repetitive pulsed electric field operation, the temporal development of the voltage across the plasma for two subsequent pulses was measured. The dual pulse …

Globally Convergent Approximate Dynamic Programming Applied To An Autolander, J.J. Murray, Richard Saeks, C.J. Cox, George G. Lendaris

Systems Science Faculty Publications and Presentations

A globally convergent nonlinear Approximate Dynamic Programming algorithm is described, and an implementation of the algorithm in the linear case is developed. The resultant linear Approximate Dynamic Programming algorithm is illustrated via the design of an autolander for the NASA X-43 research aircraft, without a priori knowledge of the X-43's flight dynamics.

The Effect Of Preparation Condition On The Photoelectrochemical Performance Of Both The Pani Film And Tio_2-Pani Composite Film On Au, Huai-Guo Huang, Hong-Ping Zhang, Zhi-Xin Zheng, Yan-Yan Xi, Ling-Ling Wu, Zhong-Hua Lin

Journal of Electrochemistry

Both the PANI(polyaniline) film and TiO 2_PANI composite film on the PATP(p_aminothiophenol)/Au substrate were obtained under different preparation condition by electrochemical methods, and their photoelectrochemical performances were also studied.The results showed that the photoelectrochemical performances of the films depend deeply on the comditions of preparation.The self_assembling of PATP favors the adhesion of PANI.The partially_oxidized PANI has a greater photoelectrochemical response than that of the reduced PANI and oxidized PANI.There is an optimum of film thickness for the photoelectrochemical performance of PANI film.Heat treating is in favor of the photoelectrochemical performance of TiO 2,but decreases the photocurrent response of PANI film.There …

Electrochemistry Characteristic Of Carbon Steel Under Biofilm And Sulfide Film, Ze-Hua Dong, Xing-Peng Guo, Jia-Shen Zheng, Li-Ming Xu

Journal of Electrochemistry

Wire Beam Electrode (WBE) made of Q235 carbon steel was applied to study the heterogeneous corrosion beneath biofilm formed by Sulfate Reducing Bacteria (SRB) in culture and sulfide film in solution with 1% NaCl and 300 mg/L S 2- . The potential,galvanic density mapping,as well as polarization curve and Electrochemical Impedance Spectrum (EIS) were measured to predict the localized corrosion under biofilm and sulfide film.As a result,the mapping showed the potential fluctuation on the WBE surface decreased over time due to the conductivity of the biofilm and sulfide film.Therefore,the potential mapping could not be a criterion of localized corrosion under …

Performance Of Proton Exchange Membrane Fuel Cell With Co/H_2 Fuel, Hong-Mei Yu, Zhong-Jun Hou, Bao-Lian Yi, Ke-Wan Bi, Jing-Xin Zhang, Zhi-Yin Lin, Ming Han

Journal of Electrochemistry

Fuel of proton exchange membrane fuel cell(PEMFC) mostly comes from reformate contains CO which will poison the fuel cell electrocatalyst.The effect of CO on the performance of PEMFC was studied in this paper.The results of the experiment show that when CO is fed in PEMFC,the cell voltage will be decreased violently,then it will become steady with some vibration.The poison will become more serious with higher CO content and weaker at higher temperature.The adsorption of CO on the electrocatalyst is reversible. The PtRu electrocatalyst is more suitable for the electrocatalysis of CO/H 2 than Pt electrocatalyst.

Preparation And Properties Of Separator For Lithium-Ion Battery, Xu-Mei Ren, Feng Wu, Chuan Wu, Han-Jun Li, Xue-Jie Huang

Journal of Electrochemistry

Lithium_ion batteries are well adapted to the new multimedia applications. PP/PE based microporous film is commonly used as separator in commercial lithium ion batteries. Here we report a microporous film which is superior to the commercial available separator. The microporous PVDF polymer separators were prepared by the phase inversion process. The pore size of the separator is  7 μm, and it's porosity is 75%. The membrane in LiPF 6 EC/DEC showed high ionic conductivity (above 10 -3 S/cm at room temperature), and good mechanical properties (10 3 kg/cm 2). The half_cells consisted of Li/PVDF separator/MCMB showed excellent cycling characteristics …

Study Of The Oxidation Dynamics Of Ti-Zro_2 Metal-Ceramics, Wen-Chao Li, Li-Dong Teng

Journal of Electrochemistry

The oxidation dynamics of hot pressed Ti ZrO 2 metal_ceramics with the composition of 50 vol.% Ti and 50 vol.% ZrO 2 has been studied. Thermodynamic analysis shows that Ti could react with O 2 but not with N 2 in the oxidizing process of Ti ZrO 2 composites at 0.1 MPa air. The oxidation dynamic behavior of Ti ZrO 2 composites is analogous to that of pure Ti. The activation energy for the oxygen diffusion in Ti ZrO 2 composites is higher than that in Ti solutions, for the presence of ZrO 2 restrains the oxygen diffusion in Ti …

New Progress In Studies Of Lithium Nickel Oxide As Positive Electrode Materials Of Lithium Ion Batteris, Han-San Liu, Yong Yang, Zhong-Ru Zhang, Zu-Geng Lin

Journal of Electrochemistry

Lithium nickel oxide as the positive electrode of lithium ion batteries has aroused more and more interests.This paper reviews the recent reserches on synthesis and element_substitution of LiNiO 2 cathode material,and summarizes the intrinsical relationship between properties and sturcture of the material.The developments of new synthesis methods and mutil_substitution of the material are expecting to be studied in the future research.

Performance Of A Direct Methanol Fuel Cell, Zhao-Bin Wei, Jian-Guo Liu, Ya-Guang Jiao, Wei-Jiang Zhou, Wen-Zhen Li, Li-Kang Chen, Qin Xin, Bao-Lian Yi

Journal of Electrochemistry

A direct methanol fuel cell with 9cm 2 active area consists of Pt_Ru/C anode,Pt/C cathode and Nafion 115 membrane.The effect of operating conditions:methanol solution concentration,oxygen pressure and cell temperature on the cell performances was investigated.The results show that performance of single cell was enhanced by increasing oxygen pressure and cell temperature,and a maximum power density 75 mW/cm 2 was obtained in the range of 250_300 mA/cm 2 current density,0.2 MPa oxygen pressure,1.0 mol/L methanol concentration and 75 ℃ cell temperature.When cell operating at room temperature,a relatively low,but a stable performance of cell was also observed.

Overview Of Acousto-Optic Bistability, Chaos, And Logical Applications, Monish Ranjan Chatterjee, Erol Sonmez

Electrical and Computer Engineering Faculty Publications

An overview is presented of the key results in the field of acousto-optic bistability in the past two decades. It is shown that the basic acousto-optic bistable device may be described as a nonlinear dynamical system which satisfies a quadratic map. Thereafter, details are presented of several analytical methods, computer modeling approaches, including the SPICE circuit modeling technique, and experiments that have been used to understand the phenomenon.

Extensions to logical and digital applications are also discussed.

Coherent Differential Absorption Lidar For Combined Measurement Of Wind And Trace Atmospheric Gases, Grady James Koch

Electrical & Computer Engineering Theses & Dissertations

A lidar system was developed for making combined range-resolved measurements of wind speed and direction, water vapor concentration, and carbon dioxide concentration in the atmosphere. This lidar combines the coherent Doppler technique for wind detection and the differential absorption lidar (DIAL) technique to provide a multifunctional capability. DIAL and coherent lidars have traditionally been thought of and implemented as separate instruments, but the research reported here has shown a demonstration of combining the coherent and DIAL techniques into a single instrument using solid-state lasers. The lasers used are of Ho:Tm:YLF, which operates at a wavelength of 2 μm. This wavelength …

Mitigation Of Water Vapor Interference For Infrared Polarization-Modulated Gas Filter Correlation Radiometry, David K. Lockwood

Electrical & Computer Engineering Theses & Dissertations

Gas filter correlation radiometry (GFCR) is a high-resolution, high-specificity technique for sensing gaseous species. A variation of absorption spectroscopy, GFCR has a long-proven record on orbital platforms for quantitative measurements of atmospheric constituents, as well as common usage in ground-based sensing applications. PMGFCR (Polarization-modulated GFCR) is a recent refinement of the technique with several advantages over the traditional method, including reducing the number of photodetectors required, increased sensitivity, and elimination of moving parts.

To date, no infrared remote sensors have successfully measured nitric oxide (NO) in vehicle exhaust due to spectral overlap by strong water vapor (H₂O_{v …}

An Objective Evaluation Of Four Sar Image Segmentation Algorithms, Jason B. Gregga

Theses and Dissertations

Because of the large number of SAR images the Air Force generates and the dwindling number of available human analysts, automated methods must be developed. A key step towards automated SAR image analysis is image segmentation. There are many segmentation algorithms, but they have not been tested on a common set of images, and there are no standard test methods. This thesis evaluates four SAR image segmentation algorithms by running them on a common set of data and objectively comparing them to each other and to human segmentors. This objective comparison uses a multi-metric a approach with a set of …

A Low Power Application-Specific Integrated Circuit (Asic) Implementation Of Wavelet Transform/Inverse Transform, Daniel N. Harvala

Theses and Dissertations

A unique ASIC was designed implementing the Haar Wavelet transform for image compression/decompression. ASIC operations include performing the Haar wavelet transform on a 512 by 512 square pixel image, preparing the image for transmission by quantizing and thresholding the transformed data, and performing the inverse Haar wavelet transform, returning the original image with only minor degradation. The ASIC is based on an existing four-chip FPGA implementation. Implementing the design using a dedicated ASIC enhances the speed, decreases chip count to a single die, and uses significantly less power compared to the FPGA implementation. A reduction of RAM accesses was realized …

Synthesis Of Limn_2o_(4-Δ) Cl_Δ Cathode Material By Like-Sol-Gel Methode, Zhao Yong Chen, Yi He, Xing Quan Liu, Zhi-Jie Li, Zuo-Long Yu

Journal of Electrochemistry

LiMn 2O 4 δ Cl δ was synthesized by like sol gel methode, with calculated LiOH.H 2O, Mn(No 3) 2.6H 2O and LiCl.H 2O, and made electrochemical test with these compounds as positive materials. Result demostrated that LiMn 2O 4 δ Cl δ cathode material has exellent stability and nearly no capacity loss after reaching stability.

How Can Direct Mthanol Fuel Cell Benefit From Carbonate Media, Lin Zhuang, Yang Wang, Jun Tao Lu

Journal of Electrochemistry

The kinetics of methanol oxidation and oxygen reduction in 0.5 mol/L K 2CO 3 were compared with those in 0.5 mol/L H 2SO 4. Experiments revealed that carbonate media could be more beneficial to direct methanol fuel cell(DMFC).Firstly, both electrode reactions show better performance in the carbonate than in the acid; secondly, materials other than noble metals become possible to be used as the anodic and cathodic catalysts;thirdly, the potential dectease caused by methanol crossover could be depressed by using metal oxide catalysts not stable in acid, such as MnO 2.

A Study On The Performance Of Matrix Prepared By Tape Cast And Its Molten Carbonate Fuel Cells (Mcfcs), Hua-Xin Lin, Bao Lian Yi, Li Zhou, Chang-Qing He, Lian Ying Kong, En Jun Zhang

Journal of Electrochemistry

The matrix prepared with γ LiAlO 2 powder and by tape cast displayed higher ability of preventing from gas cross over and lower ohmic polarization. The voltages of the stack (three cells,122 cm 2) stacked with the matrix were 2.02 and 1.78 V at 200 and 246 mA/cm 2, respectively, and the output power reached 53.4 W. The cell(28 cm 2) voltages were 0.85 and 0.75 V at 200 and 300 mA/cm 2, respectively,and the output power was about 6.6 W. Compensating the shrinkage of matrix in stacking cells promoted the enhancement of the MCFC performance.

Adsorption And Oxidation Of Ethanol On Nm-Pt/Gc Electrode Ii. Eqcm And In-Situ Ftir Spectroscopic Studies In Acid Media, Guo Liang Chen

Journal of Electrochemistry

The adsorption and oxidation of ethanol on nm?Pt/GC electrode in acid solutions containing 0.1 mol·L -1 H 2SO 4 +0.1 mol·L -1 CH 3CH 2OH was investigated by using cyclic voltammetry , EQCM and in?situ FTIR spectroscopy. The experimental results demonstrated that the oxidation of CH 3CH 2OH is closely relaed to solution acidity and oxygen species on electrode surface; CH 3CH 2OH was oxidized on nm?Pt/GC electrode in acidic media via a dual path reaction mechanism, i.e . CH 3CH 2OH may be oxidized into CO 2 through the dissociative adsorbate (CO) and the reactive intermediates that were determined …

The Photoelectrochemistry Of Tio_2-Polyaniline Composite Film, Huai Guo Huang, Zhi Xin Zheng, Jin Luo, Hong-Ping Zhang, Ling-Ling Wu, Zhong-Hua Lin

Journal of Electrochemistry

A TiO 2 and polyaniline (PANI) composite film was obtained by electrochemical methods. The SEM image of the composite film showed that the PANI film is almost completely covered with TiO 2. The spectra of photocurrent for the TiO 2 PANI composite film , which overlaps the TiO 2 film and PANI film, showed that the composite film is able to have higher conversion efficiency. The spectra of photocurrent for the TiO 2 PANI composite film were different from these of TiO 2 film photosensitized by PANI. The bandgap energy of TiO 2 film on partially oxidized PANI film was …

Tilted Bilayer Membranes As Simple Transmission Quarter-Wave Retardation Plates, R. M.A. Azzam, Fadi A. Mahmoud

Electrical Engineering Faculty Publications

A tilted bilayer membrane, which consists of two thin films of transparent optically isotropic materials of different refractive indices, can function as a transmission quarter-wave retarder (QWR) at a high angle of incidence. A specific design using a cryolite-Si membrane in the infrared is presented, and its tolerances to small shifts of wavelength, incidence angle, and film thickness errors are discussed. Some designs provide a dual QWR in transmission and reflection. Such devices provide simple linear-to-circular (and circular-to-linear) polarization transformers. Bilayer eighth-wave retarders without diattenuation are also introduced.

Time-Domain Electric-Field Integral Equation With Central Finite Difference, Baek Ho Jung, Tapan Kumar Sarkar

Electrical Engineering and Computer Science - All Scholarship

In this paper, we present a new formulation using the time-domain electric-field integral equation (TD-EFIE) to obtain a transient scattering response from arbitrarily shaped conducting bodies. The time derivative of the magnetic vector potential is approximated with a central finite difference, and the scalar potential is time averaged by dividing it into two terms. This approach with an implicit method using central-difference results in accurate and stable transient scattering responses from conducting objects. Detailed mathematical steps are included, and several numerical results are presented.

The Glass Bead Game, David D. Nolte

David D Nolte

Our lives are filled with images. Everyday we see signals, read signs, and learn symbols.We find our way with maps, look for news and bargains in newspapers, calculate ourbills and taxes. We turn printed music into wonderful sounds, often without consciouseffort. Icons fill our churches, synagogues and mosques, dot our computer screens, andare sprawled on billboards, on clothing and advertisement pages. Architecture and artconspire to fill our views with meaningful shapes and form. Pictures capture an instant intime, while movies and video entertain us with visual motion. We live in a visual world,full of information transmitted by light.

The Age Of Entanglement

David D Nolte

Quantum mechanics is a venerable field of study. The year 2000 marked the 100th anniversary of theoriginal quantum hypothesis proposed by Max Planck in November of 1900. Few current fields in physicsor engineering are as old as quantum mechanics. It predates relativity, both special and general. It predatesnuclear and particle physics. Quantum mechanics even predates universal acceptance of the molecularhypothesis, that is, that all matter is made up of individual molecules in thermal motion. It may be hard tobelieve, but this happened only after Einstein's paper on Brownian motion was published in his miracleyear 1905.

Study Of Dynamics And Mechanism Of Metal-Induced Silicon Growth, Elena A. Guliants, Wayne A. Anderson

Electrical and Computer Engineering Faculty Publications

The present study addresses the mechanism of metal-induced growth of device-quality silicon thin films. Si deposition was performed by magnetron sputtering on a 25-nm-thick Ni prelayer at 525–625 °C and yielded a continuous, highly crystalline film with a columnar structure. A Ni disilicide intermediate layer formed as a result of the Ni reaction with Si deposit provides a sufficient site for the Si epitaxial growth because lattice mismatch is small between the two materials. The reaction between Ni and Si was observed to progress in several stages. The NixSiy phase evolution in a Ni:Si layer was studied by x-ray photoelectron …