Physical Sciences and Mathematics Commons^™

Synthesis Of Li_Xcoo_2 And Its Behaviour In Rechargeable Lithium Battery, Mingfeng Guo, Ruimin Yang, Zebo Zhang, Jincao Ye

Journal of Electrochemistry

The Variations of crystal lattice parameters of Li_xCoO_2 during charge anddischarge have been st ud ied by XRD and AAR spectroscopy.It was found that the Li_xCoO_2 crystalvolume expanded during charge and contracted during discharge.The crystal lattice structure wasbroken because of the formation of Co_3O_4 when deeply charge.The variation of lattice parameter C_0value in cycling process was similar to that in charge process.The variation of 006 peak was the mostsensitive in every case.In case of preheating for 20 hours at 700℃ before operating hightemperature,the 006 peak obtained an enhancement obviously.It has had the good rechargeability inmeasurement of the cyclic voltammograms,the CV …

The Catalytic Behavior For Ni-W Electrode Modified By Carbon Ion Beam Implantion, Jishuang Zhang, Yaojiao Lv, Qinglian Li

Journal of Electrochemistry

The hydrogen evolution activity in acidic and basic mediums for Ni-W electrodemodified by carbon ion beam implantation was investigated.The experimental results show thiselectrode has superior catalytic activity for the hydrogen evolution reaction than that of the unmodifiedNi-electrode.Long period testing of electrolysis under high current density show that this electrode hasalonger useful life hence it is a practical electrode material.The temperature effect of electrocatalyticproperty was also inverstigated.The experimental regularities are explained on the basis of the formation of surface m uItialloys of Ni-W-WC.

A Photoelectrochemical Investigation Of Zirconium Oxide Film, Maizhi Yang

Journal of Electrochemistry

A photoelectrochemical investigation has been carried out on zirconium initialoxide film and its oxide film grownanodically at constant rate up to different thickness. Both anodicand cathedic photocurrents on the photocurrent spectrum depended on the potential,but had littlerelation with the forming anedic films or measuring solutions. Photocurrent spectrum and photocurrenttransients suggested that the oxide films on zirconium were duplex layers structure. The internal layerwas ZrO_2 and the external layer ZrO_2·(H_2O)_n. The photocurrent included photogenerated carrier ininternal and external oxide films,as well as internal photoinjection process for electrons from thesubstrate metal into the electrode/electolyte interface reacting with the redox couple. The analysis …

Supralinear Photoconductivity Of Copper Doped Semi-Insulating Gallium Arsenide, K. H. Schoenbach, R. P. Joshi, F. Peterkin, R. L. Druce

Bioelectrics Publications

We report on the intensity dependent supralinear photoconductivity in GaAs:Si:Cu material. The results of our measurements show that the effective carrier lifetime can change over two orders of magnitude with variations in the intensity of the optical excitation. A threshold intensity level has been observed and can be related to the occupancy of the deep copper level. Numerical simulations have also been carried out to analyze the trapping dynamics. The intensity dependent lifetimes obtained from the simulations match the experimental data very well. Finally, based on the nonlinear intensity dependence of the effective lifetimes, a possible low‐energy phototransistor application for …

Hardware Assists For High Performance Computing Using A Mathematics Of Arrays, Hardy J. Pottinger, W. Eatherton, J. Kelly, T. Schiefelbein, Lenore Mullin, R. Ziegler

Electrical and Computer Engineering Faculty Research & Creative Works

Work in progress at the University of Missouri-Rolla on hardware assists for high performance computing is presented. This research consists of a novel field programmable gate array (FPGA) based reconfigurable coprocessor board (the Chameleon Coprocessor) being used to evaluate hardware architectures for speedup of array computation algorithms. These algorithms are developed using a Mathematics of Arrays (MOA). They provide a means to generate addresses for data transfers that require less data movement than more traditional algorithms. In this manner, the address generation algorithms are acting as an intelligent data prefetching mechanism or special purpose cache controller. Software implementations have been …

Analysis And Extension Of Model-Based Software Executives, Keith E. Lewis

Theses and Dissertations

This research developed a comprehensive description of the simulation environment of Architect, a domain-oriented application composition system being developed at the Air Force Institute of Technology to explore new software engineering technologies. The description combines information from several previous research efforts and Architect's source code into a single, comprehensive document. A critical evaluation of the simulation environment was also performed, identifying improvements and modifications that enhance Architecture's application execution capabilities by reducing complexity and execution time. The analysis was then taken one step further and presented extensions to the current simulation environment. The extensions included investigating the feasibility of mixed-mode …

Scanning-Tunneling-Microscopy Study Of Pb On Si(111), D. Tang, H. E. Elsayed-Ali, J. Wendelken, J. Xu

Electrical & Computer Engineering Faculty Publications

Scanning-tunneling microscopy has been used to study temperature and coverage dependence of the structure of lead on the Si(111)-7×7 surface. For low Pb coverage, the Pb atoms favored the faulted sites. The ratio between the number of Pb atoms on faulted to unfaulted sites increased after sample annealing. An energy difference of 0.05 eV associated with a Pb atom on these two sites is estimated. The mobility of Pb atoms on Si(111) was observed at a temperature as low as 260°C for a coverage of 0.1 and 1 ML. © 1995 The American Physical Society.

Electric Field Mapping System With Nanosecond Temporal Rosolution, F. E. Peterkin, R. Block, K. H. Schoenbach

Bioelectrics Publications

The electric field dependence of the absorption coefficient in semi‐insulating GaAs at the absorption edge was measured in a high‐voltage pulsed experiment. Pulse duration was kept below 50 ns in order to avoid thermal effects. A GaAs laser diode was used as a probe light source with wavelength varied from 902 to 911 nm. For fields up to 40 kV/cm the absorption coefficient increased from 3 to 17 cm⁻¹ at 902 nm, with smaller absolute increases evident at the longer wavelengths. Calculation from theory was consistent with this behavior. The spatial variation of the electric field was also recorded …

Effects Of Large Aspect Ratios And Fluctuations On Hard X-Ray-Detection In Lower Hybrid Driven Divertor Tokamaks, Linda L. Vahala, George Vahala, Paul Bonoli

Electrical & Computer Engineering Faculty Publications

It is shown that lower hybrid wave scattering from fluctuations plays a critical role in large aspect ratio divertor plasmas even through the edge density fluctuation levels are only at 1%. This is seen in the theoretically calculated electron power-density profiles which can be directly correlated to the standard experimental chordal hard x-ray profiles. It thus seems that fluctuation effects must be included in determining rf current-density profiles.

Constrained Least-Squares Digital Image Restoration, Rajeeb Hazra

Dissertations, Theses, and Masters Projects

The design of a digital image restoration filter must address four concerns: the completeness of the underlying imaging system model, the validity of the restoration metric used to derive the filter, the computational efficiency of the algorithm for computing the filter values and the ability to apply the filter in the spatial domain. Consistent with these four concerns, this dissertation presents a constrained least-squares (CLS) restoration filter for digital image restoration. The CLS restoration filter is based on a comprehensive, continuous-input/discrete- processing/continuous-output (c/d/c) imaging system model that accounts for acquisition blur, spatial sampling, additive noise and imperfect image reconstruction. The …

Beam Dynamics In The Cebaf Superconducting Cavities, Zenghai Li

Dissertations, Theses, and Masters Projects

This work is a study of beam dynamics in the CEBAF superconducting cavities under the influence of the fields generated by externally applied RF and beam particles.;A full 3-D modeling of the CEBAF 5-cell superconducting cavity is carried out. Details of the modeling with MAFIA are discussed. Multipole fields due to the asymmetric couplers are studied by means of 3-D Fourier transforms. The cavity steering and focusing of the multipole fields are studied. Experimental measurements of these effects are performed to validate the modeling. Evaluation of the cavity misalignment is discussed. The emittance degradation effects in the CEBAF superconducting linacs …

A Diamond Thin Film Flow Sensor, Sacharia Albin, John C. Hagwood, John B. Cooper, David L. Gray, Scott D. Martinson, Michael A. Scott

Electrical & Computer Engineering Faculty Publications

We present the results of theoretical modeling and experimental testing of a diamond thin film sensor for flow studies. It is shown that the high thermal conductivity of a diamond film can enhance the frequency response of the flow sensor. One-dimensional heat diffusion equation was solved using the finite difference method for determining the frequency response. Two different sensor structures were analyzed: a Ni film on a quartz substrate (Ni/Q) and an intermediate layer of diamond film between the Ni film and quartz substrate (Ni/D/Q). The theoretical model predicts a frequency response for the Ni/D/Q sensor higher than that of …

Compensation And Characterization Of Gallium Arsenide, Randy A. Roush

Electrical & Computer Engineering Theses & Dissertations

The properties of transition metals in gallium arsenide have been previously investigated extensively with respect to activation energies, but little effort has been made to correlate processing parameters with electronic characteristics. Diffusion of copper in gallium arsenide is of technological importance due to the development of GaAs:Cu bistable photoconductive devices. Several techniques are demonstrated in this work to develop and characterize compensated gallium arsenide wafers. The material is created by the thermal diffusion of copper into silicon-doped GaAs. Transition metals generally form deep and shallow acceptors in GaAs, and therefore compensation is possible by material processing such that the shallow …

The Fat-Pyramid And Universal Parallel Computation Independent Of Wire Delay, Ronald I. Greenberg

Computer Science: Faculty Publications and Other Works

This paper shows that a fat-pyramid of area Θ(A) requires only O(log A) slowdown to simulate any competing network of area A under very general conditions. The result holds regardless of the processor size (amount of attached memory) and number of processors in the competing networks as long as the limitation on total area is met. Furthermore, the result is valid regardless of the relationship between wire length and wire delay. We especially focus on elimination of the common simplifying assumption that unit time suffices to traverse a wire regardless of its length, since the assumption becomes more and more …

Optical-Fiber Preamplifiers For Ladar Detection And Associated Measurements For Improving The Signal-To-Noise Ratio, Michael S. Salisbury, Paul F. Mcmanamon, Bradley D. Duncan

Electro-Optics and Photonics Faculty Publications

In an effort to increase achievable postdetection signal-tonoise ratios (SNRs) of continuous-wave, 1-gm all-solid-state ladar systems, a prototype rare-earth-doped optical-fiber amplifier has been included in the optical return signal path of both a heterodyne and a directdetection ladar system. We provide numerical predictions for SNR increases according to our previously developed theory. We also detail our experimental efforts and provide the results of SNR measurements for four distinct cases: direct ladar detection with and without a fiber amplifier, and heterodyne ladar detection with and without a fiber amplifier. Experimentally measured increases in SNRs for ladar systems incorporating an optical-fiber amplifier …

Survey And Implementation Of Commercial Manual Controllers For A Generic Telerobotics Architecture, Thomas E. Deeter

Theses and Dissertations

The purpose of this study is to determine an input device for the Air Force's generic telerobotics architecture for large aircraft maintenance and repair. One area of concern is the human to machine interface, more specifically, which manual controller should be used for the specified tasks in this architecture. We mailed a survey to 68 companies in order to compile a list of possible input devices that the telerobotics architecture could use. 32 companies responded which gave me enough data to generate a list that described the physical traits of the input devices. We then divided the required tasks into …

Next Generation Real-Time Systems: Investigating The Potential Of Partial-Solution Tasks, Robert E. J. Caley

Theses and Dissertations

While the cyclic executive and fixed-priority scheduling strategies have been sufficient to handle traditional real- time requirements. they are insufficient for dealing with the complexities of next-generation real-time systems. New methods of intelligent control must be developed for guaranteeing on-time task completion for real-time systems that are faced with unpredictable and dynamically changing requirements. Implementing real-time processes as partial-solution tasks is one technique that may be beneficial. This type of task. when combined with intelligent control, has the potential for increasing pre-runtime schedulability, system maintainability. and runtime robustness. This research investigates the benefits of partial-solution tasks by experimentally measuring the …

Flow Visualization Of A Turbulent Shear Flow Using An Optical Wavefront Sensor, Daniel W. Jewell

Theses and Dissertations

The research reported here investigated the use of a shearing interferometer (SI) wavefront sensor to determine the effects of shear-layer turbulence on an optical wavefront. A collimated helium-neon laser beam was propagated through a plane shear-layer produced by mixing helium and nitrogen at different velocities. Since the gases have different indices of refraction, the optical wavefront was distorted by different amounts by each gas. The SI measured the wavefront slope across the sampled area of the wavefront. The shear-layer was viewed from two orthogonal directions. This document contains shadow graphs, interference patterns imaged by each of the SI's six cameras, …

Frame Selection Performance Limits For Statistical Image Reconstruction Of Adaptive Optics Compensated Images, Stephen D. Ford

Theses and Dissertations

The U.S. Air Force uses adaptive optics systems to collect images of extended objects beyond the atmosphere. These systems use wavefront sensors and deformable mirrors to compensate for atmospheric turbulence induced aberrations. Adaptive optics greatly enhance image quality; however, wavefront aberrations are not completely eliminated. Therefore, post-detection processing techniques are employed to further improve the compensated images. Typically, many short exposure images are collected, recentered to compensate for tilt, and then averaged to overcome randomness in the images and improve signal-to-noise ratio. Experience shows that some short exposure images in a data set are better than others. Frame selection exploits …

Multispectral Detection Of Ground Targets In Highly Correlated Backgrounds, Jason E. Thomas

Theses and Dissertations

Multispectral detection methods attempt to discriminate targets in a dominant clutter background using multiple images of the same real-world scene taken in different narrow spectral bands in the infrared. Detection is possible due to the empirically observed phenomenon that the radiance of man-made objects, such as a tank or truck, often lies off the main spectral correlation axis of that of natural backgrounds. Radiometric measurements of several vehicles and a tree canopy background taken over three days in June. 1994 were used to examine the factors affecting multispectral detection. Results clearly showed that the processes which provide for higher spectral …

Embedology And Neural Estimation For Time Series Prediction, Robert E. Garza

Theses and Dissertations

Time series prediction has widespread application, ranging from predicting the stock market to trying to predict future locations of scud missiles. Recent work by Sauer and Casdagli has developed into the embedology theorem, which sets forth the procedures for state space manipulation and reconstruction for time series prediction. This includes embedding the time series into a higher dimensional space in order to form an attractor, a structure defined by the embedded vectors. Embedology is combined with neural technologies in an effort to create a more accurate prediction algorithm. These algorithms consist of embedology, neural networks, Euclidean space nearest neighbors, and …

Image Perception Wavelet Simulation And Enhancement For The Visually Impaired, Lemuel Ray Myers Jr.

Theses and Dissertations

This research delves into the area of image enhancement for the visually impaired. Binocular macular degeneration a visual impairment, affects many Americans; since this condition could not be corrected with conventional glasses the literature suggested using an enhancement system which used a pre-emphasis algorithm to enhance the input image for output to the observer. The work of Dr. Eli Peli, a pioneer in the field of image enhancement, is examine and reproduced. Since his work concentrated mainly on frequency analysis of images, the bulk of this research involves using discrete wavelet analysis to augment that work. A biorthogonal wavelet set …

Biofeedback Gait Training Auditory Vs. Visual Techniques, Timothy D. Hiemenz

Electrical & Computer Engineering Theses & Dissertations

Training lower extremity amputees to walk normally is quite a difficult task. Amputees must wear a prosthesis so they can walk at all. This allows them some mobility, but their walking pattern may be unnatural. If their gait is temporally asymmetric, they need to exert more energy to move about. This research was initiated to help lower extremity amputees to walk more efficiently using biofeedback gait training. Two types of feedback were developed and tested to determine which method gave the most understandable feedback, validating its use in a clinical setting.

A normal gait cycle uses the lower limbs to …

The Current Voltage Characteristics Of Electron Beam Controlled Thin Film Diamond Switches, Christopher Anthony Molina

Electrical & Computer Engineering Theses & Dissertations

The dark current of natural diamond thin films and the induced current due to electron-beam irradiation was measured up to a range of 7000Ncm'. The contact material was aluminum, annealed and unannealed. Switching experiments were performed with electron energies ranging from 70keV to 172keV. The switching results obtained are strongly dependent on the biasing polarity, incident electron energy, and whether the contact is blocking or Ohmic in nature. A simple model which takes traps into consideration allows us to explain the various switching responses. The range of electrons which define, in part, the switch mode was measured for one sample …

Direct Relation Between Fresnel's Interface Reflection Coefficients For The Parallel And Perpendicular Polarizations: Erratum 2, R. M.A. Azzam

Electrical Engineering Faculty Publications

The record is set straight concerning two equations that determine the reflection phase shifts at a single interface from the intensity reflectances forp- and s-polarized light at one angle of incidence. These equations appeared previously in this journal [J. Opt. Soc. Am. 69, 1007 (1979); erratum, J. Opt. Soc. Am. 70, 261 (1980)].

A Diffraction-Based Model Of Anisoplanatism Effects In Adaptive Optic Systems, Steven E. Troxel

Theses and Dissertations

This dissertation presents a new model for computing the angle dependent performance measures of an adaptive-optics system. By incorporating diffraction caused by the index-of-refraction variations of the atmosphere, the phase and amplitude fluctuations of the propagating wave are computed. New theory is presented, that uses the diffraction-based propagation model to yield optical transfer function (OTF) expressions that are more accurate as compared to current theory that neglects diffraction. An evaluation method for calculating the OTF is presented that utilizes a layered atmospheric model and normalized OTF expressions. The diffraction model is also used to present the first OTF signal-to-noise ratio …

Noise Reduction For Speech Enhancement Using Non-Linear Wavelet Processing, Hassan Dehmani

Theses and Dissertations

The problem of speech enhancement presents many obstacles in the speech processing field. This thesis develops several speech de-noising systems that can be used in the time, fourier, and wavelet domains. We present two thresholding techniques soft and hard. The application of these thresholding techniques to noisy speech data is discussed. The combination of both wavelets and the Fourier domains with noisy phase restoration proves to yield the best results in terms of intelligibility. Informal listening tests were conducted in order to compare the effects and differences between the speech de-noising systems.

Spatio-Temporal Pattern Recognition Using Hidden Markov Models, Kenneth H. Fielding

Theses and Dissertations

A new spatio-temporal method for identifying 3D objects found in 2D image sequences is presented. The Hidden Markov Model technique is used as a spatio-temporal classification algorithm to identify 3D objects by the temporal changes in observed shape features. A new information theoretic argument is developed that proves identifying objects based on image sequences can lead to higher classification accuracies than single look methods. A new distance measure is proposed that analyzes the performance of Hidden Markov Models in a multi-class pattern recognition problem. A three class problem identifying moving light display objects provides experimental verification of the sequence processing …

Constraint Objects, Divesh Srivastava, Raghu Ramakrishnan, Peter Revesz

CSE Conference and Workshop Papers

We describe the Constraint Object Data Model (CODM), which enhances an object-based data model with existential constraints to naturally represent partially specified information. We present the Constraint Object Query Language (COQL), a declarative, rule-based query language that can be used to infer relationships about and monotonically refine information represented in the CODM. COQL has a model-theoretic and an equivalent fixed-point semantics, based on the notions of constraint entailment and "proofs in all possible worlds." We also provide a novel polynomial-time algorithm for quantifier elimination for set-order constraints, a restricted class of set constraints that uses membership of subset-equal.

Multirate Time-Frequency Distributions, John R. O'Hair

Theses and Dissertations

Multirate systems, which find application in the design and analysis of filter banks, are demonstrated to also be useful as a computational paradigm. It is shown that any problem which can be expressed a set of vector-vector, matrix-vector or matrix-matrix operations can be recast using multirate. This means all of numerical linear algebra can be recast using multirate as the underlying computational paradigm. As a non-trivial example, the multirate computational paradigm is applied to the problem of Generalized Discrete Time- Frequency Distributions GDTFD to create a new family of fast algorithms. The first of this new class of distributions is …