Physical Sciences and Mathematics Commons^™

Non Linear Electronic And Optical Processes In Fullerene Thin Films, Siobhan Phelan

Masters

In this study the current voltage characteristics of C60 thin film sandwich structures fabricated by vacuum deposition on indium tin oxide (ITO) with an aluminium top electrode are presented and discussed. A strongly non-linear behaviour and a sharp increase in the device conductivity was observed at relatively low voltages, at both room and low temperatures (30K). At room temperature the system is seen to collapse. In situ Raman measurements indicate that the collapse is the result of a solid state reduction of the fullerene thin film to a polymeric state. The high conductivity state was seen to be stable at …

Crash Analysis: An Investigation Of Current Speed Estimation Techniques, Robert Rice

Masters

The increasing number of cars and collisions on the roads of Europe ensure that the need for accurate speed estimation is an ever-more pressing requirement. This requirement has provided the motivation for an investigation into the accuracy and reliability of existing crash models An in-depth literature review was undertaken to create a greater understanding of the structural collapse behaviour of vehicles during full frontal collisions. It was decided to concentrate the work on frontal collisions as this type of accident makes up the majority of road accidents. This review underlined some of the phenomena that need to be considered when …

Electronic Speckle Pattern Shearing Interferometer With A Photopolymer Holographyc Grating, Emilia Mihaylova, Izabela Naydenova, Suzanne Martin, Vincent Toal

Articles

A photopolymer holographic grating is used to produce the two sheared images in an electronic speckle pattern shearing interferometer. A ground glass screen following the grating serves the purpose of eliminating unwanted diffraction orders and to remove the requirement for the CCD camera to resolve the diffraction grating’s pitch. The sheared images on the ground glass are further imaged onto the CCD camera. The fringe pattern contrast was estimated to be above 90%. A validation of the system was done by comparing the theoretical phase difference distribution with the experimental data from the three point bending test.

First-Principles Study Of Magnetism In (112̄0) Zn1−Xmnxo Thin Film, Q. Wang, Puru Jena

Physics Publications

First-principles calculations of total energies and magnetism of Zn1−xMnxOthin film are performed by simulating it with a slab consisting of seven layers along (112̄0). It is shown that a single Mn atom shows very little preference for the site it occupies. This is consistent with the experimental finding that Mn atoms are homogeneously distributed in ZnO films. As the concentration of Mn atoms increases, antiferromagnetic coupling between Mn atoms becomes more favorable, and there is a tendency for Mn atoms to form clusters around oxygen, in agreement with recent experiments.

Metastability Of A Gold Nanoring: Density-Functional Calculations, Q. Sun, Q. Wang, Puru Jena, R. Note, J-Z. Yu, Y. Kawazoe

Physics Publications

First-principles calculations based on gradient corrected density functional theory show that a cluster of as few as 90 gold atoms can be stabilized in a ring structure having fcc (111) motif with the binding energy/atom and interatomic distance approaching 91% and 96% of the bulk values, respectively. Although the ring structure lies 0.139eV/atom higher in energy than a polyicosahedral structure, the calculated frequencies are real. Thus under appropriate experimental conditions it may still be possible to synthesize a metastable form of gold nanoring, as found in the recent experiment.

Carrier-Mediated Ferromagnetism In N Codoped (Zn,Mn)O (101¯0) Thin Films, Q. Wang, Q. Sun, Puru Jena, Y. Kawazoe

Physics Publications

Using first principles calculations based on the density functional theory and generalized gradient approximation we show that the ground state of Mn doped ZnO (101¯0) thin film changes from antiferromagnetic to ferromagnetic when codoped with N. The ferromagnetic coupling between Mn spins arises due to the overlap between N 2p and Mn 3d electrons in the spin up band, rendering the system half-metallic character.

Hydrogen Adsorption And Magnetic Behavior Of Fen And Con Clusters: Controlling The Magnetic Moment And Anisotropy One Atom At A Time, N. O. Jones, M. R. Beltran, Shiv N. Khanna, T. Baruah, M. R. Pederson

Physics Publications

Theoretical studies to investigate the effect of H absorption on the magnetic moment of small Fen and Con clusters have been carried out using gradient corrected density-functional approach. Our studies on clusters containing up to four transition metal and 2 H atoms show that the successive addition of H atoms can lead to monotonic or oscillatory change from the free cluster magnetic moment. A detailed analysis of the density of electronic states shows that the variations in the magnetic moment can be related to the location of the lowest unoccupied molecular orbital in the parent cluster. It is shown that …

Ferromagnetism In Cr-Doped Gan: A First-Principles Calculation, G. P. Das, B. K. Rao, Puru Jena

Physics Publications

Electronic structure, energy bands, and magnetic properties of Cr-doped GaN have been calculated from first principles using a 32 atom supercell within the frame work of linearized muffin-tin orbital tight binding method and gradient-corrected density-functional theory. The coupling between Cr atoms is found to be ferromagnetic with a magnetic moment of 2.69μB at each Cr site. The magnetic moments of Ga and N sites are rather small, namely, 0.025μB and −0.025μB, respectively, yielding a total moment of 6μB per supercell. Parallel calculations done on small clusters of Cr-doped GaN also yield similar results indicating that magnetic coupling between Cr atoms …

The Changing Role Of Non-Co2 Greenhouse Gases, M. A. K. Khalil

Physics Faculty Publications and Presentations

During the last century, the concentrations of several greenhouse gases have increased considerably - most notably carbon dioxide, methane and nitrous oxide. In addition, new, entirely man-made gases have been put into the atmosphere that also cause the greenhouse effect; these include the chlorofluorocarbons. Calculations have shown that during the last century the non-CO₂ greenhouse gases could together be almost as effective as the increase of carbon dioxide in causing global warming. These and similar gases were therefore included in the Kyoto Protocol to develop a comprehensive plan for controlling potentially unfavorable climatic change. Studies show however that the other …

Environmental Swap Energy And Role Of Configurational Entropy In Transfer Of Small Molecules From Water Into Alkanes, Pavel Smejtek, Robert Campbell Word

Physics Faculty Publications and Presentations

We studied the effect of segmented solvent molecules on the free energy of transfer of small molecules from water into alkanes (hexane, heptane, octane, decane, dodecane, tetradecane, and hexadecane). For these alkanes we measured partition coefficients of benzene, 3-methylindole (3MI), 2,3,4,6-tetrachlorophenol (TeCP), and 2,4,6-tribromophenol (TriBP) at 3, 11, 20, 3, and 47 °C. For 3MI, TeCP, and TriBP the dependence of free energy of transfer on length of alkane chains was found to be very different from that for benzene. In contrast to benzene, the energy of transfer for 3MI, TeCP, and TriBP was independent of the number of carbons …

Bounds On Relic Neutrino Masses In The Z-Burst Model, Gabriele U. Varieschi

Physics Faculty Works

No abstract provided.

Order-Parameter Symmetry And Mode-Coupling Effects At Dirty Superconducting Quantum Phase Transitions, Rastko Sknepnek, Thomas Vojta, Rajesh Narayanan

Physics Faculty Research & Creative Works

We derive an order-parameter field theory for a quantum phase transition between a disordered metal and an exotic (non- s -wave) superconductor. Mode coupling effects between the order parameter and other fermionic soft modes lead to an effective long-range interaction between the anomalous density fluctuations which is reflected in singularities in the free energy functional. However, this long-range interaction is not strong enough to suppress disorder fluctuations. The asymptotic critical region is characterized by run-away flow to large disorder. For weak coupling, this asymptotic region is very narrow. It is preempted by a wide crossover regime with mean-field critical behavior …

Excimer Emission From Cathode Boundary Layer Discharges, Mohamed Moselhy, Karl H. Schoenbach

Bioelectrics Publications

The excimer emission from direct current glow discharges between a planar cathode and a ring-shaped anode of 0.75 and 1.5 mm diameter, respectively, separated by a gap of 250 μm, was studied in xenon and argon in a pressure range from 75 to 760 Torr. The thickness of the “cathode boundary layer” plasma, in the 100 μm range, and a discharge sustaining voltage of approximately 200 V, indicates that the discharge is restricted to the cathode fall and the negative glow. The radiant excimer emittance at 172 nm increases with pressure and reaches a value of 4 W/cm² for …

Revolving Door Scenario For Congressional Fellows, David W. Hafemeister

Physics

No abstract provided.

Age Differences In Central (Semantic) And Peripheral Processing: The Importance Of Considering Both Response Times And Errors, Philip A. Allen, Martin D. Murphy, Miron Kaufman, Karen E. Groth, Ana Begovic

Physics Faculty Publications

In this project we examined the effect of adult age on visual word recognition by using combined reaction time (RT) and accuracy methods based on the Hick–Hyman law. This was necessary because separate Brinley analyses of RT and errors resulted in contradicting results. We report the results of a lexical decision task experiment (with 96 younger adults and 97 older adults). We transformed the error data into entropy and then predicted RT by using entropy values separately for exposure duration (thought to influence peripheral processes) and word frequency (thought to influence central processes). For exposure duration, the entropy–RT functions indicate …

Variable-Temperature Scanning Optical And Force Microscope, Petru S. Fodor, H. Zhu, N. G. Patil, J. Levy

Physics Faculty Publications

The implementation of a scanning microscope capable of working in confocal, atomic force and apertureless near field configurations is presented. The microscope is designed to operate in the temperature range 4–300 K, using conventional helium flow cryostats. In atomic force microscope(AFM) mode, the distance between the sample and an etchedtungsten tip is controlled by a self-sensing piezoelectrictuning fork. The vertical position of both the AFM head and microscope objective can be accurately controlled using piezoelectric coarse approach motors. The scanning is performed using a compact XYZ stage, while the AFM and optical head are kept fixed, allowing scanning probe and …

Asymmetry Of Above-Threshold Ionization Of Metal Clusters In Two-Color Laser Fields: A Time-Dependent Density-Functional Study, H. S. Nguyen, A. D. Bandrauk, Carsten A. Ullrich

Physics Faculty Research & Creative Works

A spherical jellium model and time-dependent density functional theory for two-color ultrashort laser pulses as a function of phase difference between two fields were used to calculate the above threshold ionization (ATI) spectra of small metal clusters. ATI spectra and the ionized electrons fluxes were obtained in the two opposite directions of the linearly polarized laser fields. It is found that ATI spectra has long energy plateaus, with cutoffs up to 30-40 times the ponderomotive energy Up. However, no extended plateaus were observed in high-harmonic generation spectra.

Variational Considerations In The Study Of Carrier Transport In Organic Crystals, V. M. Kenkre, Paul Ernest Parris

Physics Faculty Research & Creative Works

A variational approach is used to investigate consequences of electron-phonon interactions between a charge carrier and multiple (specifically two) phonon branches. Phase diagrams are obtained and the nature of the transition from undressed to dressed phases of the carrier is studied with their help. No sharp transition between singly dressed and doubly dressed phases occurs. The effective carrier bandwidth, reduced by strong coupling to the high-frequency branch is found to be stable with respect to small to intermediate values of additional coupling to the low-frequency branch. This finding lends support to transport calculations based on the idea that carriers in …

Measurement Of Beam-Spin Asymmetries For Π⁺ Electroproduction Above The Baryon Resonance Region, K. V. Dharmawardane, G. E. Dodge, C. E. Hyde-Wright, S. E. Kuhn, L. M. Qin, F. Sabatié, L. B. Weinstein, J. Yun, Et Al., Clas Collaboration

Physics Faculty Publications

We report the first evidence for a nonzero beam-spin azimuthal asymmetry in the electroproduction of positive pions in the deep-inelastic kinematic region. Data for the reaction e^→pe'π⁺X have been obtained using a polarized electron beam of 4.3 GeV with the CEBAF Large Acceptance Spectrometer at the Thomas Jefferson National Accelerator Facility. The amplitude of the sin ᵠ modulation increases with the momentum of the pion relative to the virtual photon, z. In the range z = 0.5-0.8 the average amplitude is 0.038 ± 0.005 ± 0.003 for a missing mass M_x > 1.1 GeV and 0.037 …

Scattering Of Shock Waves In Qcd, Ian Balitsky

Physics Faculty Publications

The cross section of heavy-ion collisions is represented as a double functional integral with the saddle point being the classical solution of the Yang-Mills equations with boundary conditions/sources in the form of two shock waves corresponding to the two colliding ions. I develop the expansion of this classical solution in powers of the commutator of the Wilson lines describing the colliding particles and calculate the first two terms of the expansion.

Polarimetric Characterization Of Random Electromagnetic Beams And Applications, Mircea Mujat

Electronic Theses and Dissertations

Polarimetry is one of the principal means of investigating the interaction of light with matter. Theoretical models and experimental techniques are presented in this dissertation for polarimetric characterization of random electromagnetic beams and of signatures of random media in different scattering regimes and configurations. The degree of polarization rather than the full description of the state of polarization is of interest in multiple scattering and free space propagation where the statistical nature and not the deterministic component of light bears the relevant information. A new interferometric technique for determining the degree of polarization by measuring the intensity fluctuations in a …

Mononuclear Nitrogen/Sulfur-Ligated Cobalt(Ii) Methoxide Complexes: Structural, Epr, Paramagnetic 1h Nmr, And Electrochemical Investigations, Kyle J. Tubbs, Ewa Szajna, Brian Bennett, Jason A. Halfen, Rex W. Watkins, Atta M. Arif, Lisa M. Berreau

Physics Faculty Research and Publications

The first examples of mononuclear nitrogen/sulfur-ligated Co(II) alkoxide complexes, species of relevance to a reactive intermediate observed for Co(II)-substituted liver alcohol dehydrogenase, have been isolated and characterized by multiple methods including X-ray crystallography, EPR, paramagnetic ¹H NMR, and cyclic voltammetry.

Solution Of The Schrödinger Equation With One And Two Timensional Double-Well Potentials, Ramazan Koç, Derya Haydargi̇l

Turkish Journal of Physics

The Schrödinger equation with one and two dimensional potentials are solved in the framework of the sl_2(R) Lie algebra. Eigenfunctions of the Schrödinger equation for various asymmetric double-well potentials have been determined and the eigenstates are expressed in terms of the orthogonal polynomials. The solution of the double-well potential in two dimension have been analyzed.

On Electron Mobility In A Rectangular Quantum Wire Due To Alloy Disorder, Guseyn Behbudoglu Ibragimov

Turkish Journal of Physics

Analytic expressions are derived to describe the electron mobility and relaxation rate in the rectangular quantum wire experiencing scattering due to alloy disorder. The dependence of electron mobility on the temperature and transverse dimension is numerically evaluated and it is found that the mobility increases continuously with temperature, because there is no new intersubband scattering with increase in temperature. It is shown that the alternating increase/decrease in the mobility---depending on the transverse dimension of the quantum wire---occurs due to intersubband scattering. It is found that the mobility in a quantum wire is significantly greater than mobility in a quantum well.

Multi-Path Differential Optical Absorption Spectroscopy, John Gerard Murphy

Theses

A number of potential methods for the production of multiple light beams for long- path differential absorption spectroscopy have been considered and analysed. The system deemed most suitable has been designed, constructed and tested over two adjacent measurement paths.

The system was built in Cork Institute of Technology to the west of Cork City, Ireland during the period 2000 - 2004. The system has been tested during the winter period of 2003/2004 and ambient concentrations of SO₂ and NO₂ have been measured and are reported. The measurement of additional gaseous species and suspended particulate matter was excluded from …

Microscopic Analysis For Water Stressed By High Electric Fields In The Prebreakdown Regime, R. P. Joshi, J. Qian, K. H. Schoenbach, E. Schamiloglu

Bioelectrics Publications

Analysis of the electrical double layer at the electrode-water interface for voltages close to the breakdown point has been carried out based on a static, Monte Carlo approach. It is shown that strong dipole realignment, ion-ion correlation, and finite-size effects can greatly modify the electric fields and local permittivity (hence, leading to optical structure) at the electrode interface. Dramatic enhancements of Schottky injection, providing a source for electronic controlled breakdown, are possible. It is also shown that large pressures associated with the Maxwell stress tensor would be created at the electrode boundaries. Our results depend on the ionic density, and …

Kinetics Of Binary Nucleation Of Vapors In Size And Composition Space, Sergey P. Fisenko, Gerald Wilemski

Physics Faculty Research & Creative Works

We reformulate the kinetic description of binary nucleation in the gas phase using two natural independent variables: the total number of molecules g and the molar composition x of the cluster. The resulting kinetic equation can be viewed as a two-dimensional Fokker-Planck equation describing the simultaneous Brownian motion of the clusters in size and composition space. Explicit expressions for the Brownian diffusion coefficients in cluster size and composition space are obtained. For characterization of binary nucleation in gases three criteria are established. These criteria establish the relative importance of the rate processes in cluster size and composition space for different …

Study Of Structural And Magnetic Properties Of Iron-Rich Mixed Rare-Earth Nddyfe (17-Y-X)Coxsiy Compounds, Kishore Kamaraju, Jinbo Yang, William B. Yelon, Oran Allan Pringle, M. S. Kim, Qingsheng Cai, William Joseph James

Physics Faculty Research & Creative Works

A series of NdDyFe(17-y-x)CoxSiy solid solutions with = 2 and 3 and = 0.5 1.0 and 1.5 were prepared by induction melting stoichiometric amounts of high-purity elements. The postannealed samples consist of two phases belonging to the space groups R3 m and P63 mmc . The lattice parameters and the unit cell volumes were calculated from the refinements of the magnetic and structural unit cells using the FULLPROF version of the Rietveld program. For a fixed content of Co, the maximum Curie temperatures (305 C to 405 C) were observed in samples with = 1 and having two phases, a …

Traversal Times For Random Walks On Small-World Networks, V. M. Kenkre, Paul Ernest Parris

Physics Faculty Research & Creative Works

We study the mean traversal time tau for a class of random walks on Newman-Watts small-world networks, in which steps around the edge of the network occur with a transition rate F that is different from the rate f for steps across small-world connections. when f>>F, the mean time tau to traverse the network exhibits a transition associated with percolation of the random graph (i.e., small-world) part of the network, and a collapse of the data onto a universal curve. This transition was not observed in earlier studies in which equal transition rates were assumed for all allowed steps. …

First Determination Of The Strange And Light Quark Masses From Full Lattice Qcd, James E. Hetrick, C. Aubin

All Faculty Articles - School of Engineering and Computer Science

We compute the strange quark mass ms and the average of the u and d quark masses m̂ using full lattice QCD with three dynamical quarks combined with experimental values for the pion and kaon masses. The simulations have degenerate u and d quarks with masses mu=md≡m̂ as low as ms/8, and two different values of the lattice spacing. The bare lattice quark masses obtained are converted to the $\msbar$ scheme using perturbation theory at O(alphas). Our results are: $m_s^\msbar$(2 GeV) = 76(0)(3)(7)(0) MeV, $\hat m^\msbar$(2 GeV) = 2.8(0)(1)(3)(0) MeV and ms/m̂ = 27.4(1)(4)(0)(1), where the errors are from statistics, …