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Articles 361 - 390 of 36514
Full-Text Articles in Physical Sciences and Mathematics
Probing Shielding Tensor Components Of Amino Acids Using Nuclear Magnetic Resonance, Shiva Agarwal, Sungsool Wi, Michael Famiano, John Miller, Zbigniew Chajecki
Probing Shielding Tensor Components Of Amino Acids Using Nuclear Magnetic Resonance, Shiva Agarwal, Sungsool Wi, Michael Famiano, John Miller, Zbigniew Chajecki
Waldo Library Student Exhibits
Amino acids combine to form proteins in living organisms; most are chiral. On Earth amino acids appear only in the L- form, which is likely due to the amplification of enantiomeric excess (ee). However, a small ee for the L-form of amino acids has been observed in meteorites that have fallen on Earth. One possibility for this ee is the effect of antisymmetric components of the magnetic shielding tensor for 14N nuclei in amino acids, which in NMR manifests as the antisymmetric chemical shift (ACS). This can result in preferential destruction of their D-form through interactions with polarized leptons (e.g., …
Development Of On-The-Fly Quasi-Steady State Approximation For Chemical Kinetics In Cfd, Abhinav Balamurugan
Development Of On-The-Fly Quasi-Steady State Approximation For Chemical Kinetics In Cfd, Abhinav Balamurugan
Doctoral Dissertations and Master's Theses
This study analyzes the feasibility of On-The-Fly Quasi-Steady-State Approximation (OTF-QSSA) application for solving chemical kinetics within Computational Fluid Dynamics (CFD) simulations, aiming to reduce the computational demand of detailed mechanisms. An algorithm that dynamically identifies and designates Quasi-Steady-State (QSS) species at specific grid locations and instances during the simulation was developed. With this information, our method pseudo-delays the advancement of concentrations for these QSS species—effectively setting their rate of concentration change to zero for a set number iteration before updating using the detailed mechanism and thereby omitting the computationally intensive processes typically required for their calculation during those skipped iteration. …
Low Cost Magnetometer Calibration And Distributed Simultaneous Multipoint Ionospheric Measurements From A Sounding Rocket Platform, Joshua W. Milford
Low Cost Magnetometer Calibration And Distributed Simultaneous Multipoint Ionospheric Measurements From A Sounding Rocket Platform, Joshua W. Milford
Doctoral Dissertations and Master's Theses
Low-cost and low-size-weight-and-power (SWaP) magnetometers can provide greater accessibility for distributed simultaneous measurements in the ionosphere, either onboard sounding rockets or on CubeSats. The Space and Atmospheric Instrumentation Laboratory (SAIL) at Embry-Riddle Aeronautical University has launched a multitude of sounding rockets in recent history: one night-time mid-latitude rocket from Wallops Flight Facility in August 2022 and three mid-latitude rockets from White Sands Missile Range during the October 2023 annular solar eclipse. All rockets had a comprehensive suite of instruments for electrodynamics and neutral dynamics measurements. Among this suite was one science-grade three-axis fluxgate magnetometer (Billingsley TFM65VQS / TFM100G2) and up …
Reevaluating The Origin Of Detectable Cataclysmic Variables In Globular Clusters: Testing The Importance Of Dynamics, Liliana Rivera Sandoval, Diogo Belloni, Miriam Ramos Arevalo
Reevaluating The Origin Of Detectable Cataclysmic Variables In Globular Clusters: Testing The Importance Of Dynamics, Liliana Rivera Sandoval, Diogo Belloni, Miriam Ramos Arevalo
Physics and Astronomy Faculty Publications and Presentations
Based on the current detectable cataclysmic variable (CV) population in Galactic globular clusters (GCs), we show that there is not a clear relation between the number of sources per unit of mass and the stellar encounter rate, the cluster mass, or the cluster central density. If any, only in the case of core-collapsed GCs could there be an anticorrelation with the stellar encounter rate. Our findings contrast with previous studies where clear positive correlations were identified. Our results suggest that correlations between faint X-ray sources, from which often conclusions for the CV population are drawn, and the GC parameters considered …
Modeling And Numerical Analysis Of The Cholesteric Landau-De Gennes Model, Andrew L. Hicks
Modeling And Numerical Analysis Of The Cholesteric Landau-De Gennes Model, Andrew L. Hicks
LSU Doctoral Dissertations
This thesis gives an analysis of modeling and numerical issues in the Landau-de Gennes (LdG) model of nematic liquid crystals (LCs) with cholesteric effects. We derive various time-step restrictions for a (weighted) $L^2$ gradient flow scheme to be energy decreasing. Furthermore, we prove a mesh size restriction, for finite element discretizations, that is critical to avoid spurious numerical artifacts in discrete minimizers that is not well-known in the LC literature, particularly when simulating cholesteric LCs that exhibit ``twist''. Furthermore, we perform a computational exploration of the model and present several numerical simulations in 3-D, on both slab geometries and spherical …
Spectroscopy Of Atmospheres, Randika Dodangodage
Spectroscopy Of Atmospheres, Randika Dodangodage
Physics Theses & Dissertations
Spectroscopic methods are used to study planetary and stellar atmospheres. The information obtained from spectroscopic studies provides insight into atmospheric compositions and dynamics, which can be used to model and characterize atmospheres and climates. Laboratory-recorded absorption cross-sections are needed to interpret the recorded spectra of planets and stars. High resolution ethane, neopentane, propene, and n-butane spectra have been recorded, and absorption cross-sections have been provided for different temperatures and total pressures with different broadening gases, including hydrogen, helium, and nitrogen. The Atmospheric Chemistry Experiment (ACE) satellite orbits Earth and records spectra through solar occultation limb observations. HOCl is a chlorine …
Development Of One And Two Current Transition Amplitudes With Two Body Final States, Keegan H. Sherman
Development Of One And Two Current Transition Amplitudes With Two Body Final States, Keegan H. Sherman
Physics Theses & Dissertations
One of the biggest challenges facing modern day nuclear physics is understanding the structure of states within the hadronic spectrum of Quantum Chromodynamics (QCD). We have shown this spectrum to be quite rich with hundreds of allowed states; however, if we wish to better grasp the dynamics of QCD, then it is necessary that we start investigating the internal structure of these states. This may be done by probing these states with external currents, but this requires a description of the intersection of QCD with the electroweak sector. This work acts as a stepping stone in this direction. Working to …
Quantum Realities: A Comparative Analysis Of Interpretations Addressing The Measurement Problem In Quantum Mechanics, Adib Kabir
Student Publications
This paper examines the measurement problem in quantum mechanics and evaluates three major interpretations: the Copenhagen interpretation, the Many-Worlds Interpretation (MWI), and the Pilot-Wave theory. The Copenhagen interpretation posits that particles exist in superposition until measured, at which point their wave functions collapse. MWI suggests that all possible outcomes occur in separate, non-interacting branches of the universe, eliminating wave function collapse but introducing an infinite number of unobservable universes. The Pilot-Wave theory reintroduces determinism through hidden variables, guiding particles along definite paths. The paper concludes that the Copenhagen interpretation is the most plausible, balancing empirical adequacy, ontological clarity, and simplicity.
Longitudinal Solid Polarized Target For Clas12 And Study Of Spin Structure Of Nucleons, Pushpa Pandey
Longitudinal Solid Polarized Target For Clas12 And Study Of Spin Structure Of Nucleons, Pushpa Pandey
Physics Theses & Dissertations
A suite of experiments measuring target-spin observables in electron-nucleon scattering (dubbed Run Group C) was conducted at Jefferson Lab’s Hall B in Newport News, VA with a new polarized nuclear target known as ‘APOLLO’ (Ammonia Polarized Longitudinally). This innovative target is engineered to seamlessly integrate with the advanced 12 GeV CEBAF (Continuous Electron Beam Accelerator Facility) accelerator and the Hall B CLAS12 (12 GeV CEBAF Large Acceptance Spectrometer) detector array. The ‘APOLLO’ target harnesses the power of Dynamic Nuclear Polarization (DNP) to achieve longitudinal polarization of solid ammonia, thereby creating a net polarization in both protons (NH3) and …
Application Of The Fokker-Planck Equation For Quantifying Initial Condition Uncertainty Of Reversible Dynamic Systems, Troy S. Newhart
Application Of The Fokker-Planck Equation For Quantifying Initial Condition Uncertainty Of Reversible Dynamic Systems, Troy S. Newhart
Mechanical & Aerospace Engineering Theses & Dissertations
Characterizing the behavior of dynamic systems requires the inclusion of initial conditions to propagate behavior forward in time. More realistic representations of system behavior quantify uncertainty about the initial conditions to assess sensitivity, reliability, and other stochastic response parameters. In many engineering applications, the uncertain initial conditions may be unknown given a desired response. This research applies the Fokker-Planck equation to reversible dynamic systems of select multi-dimensional nonlinear differential equations as a means for predicting the uncertainty about initial conditions. An alternating directions implicit numerical scheme is used to numerically solve the Fokker-Planck equation for both forward and reversed equations …
Analyzing The Influence Of Design And Operating Conditions On Combustion And Emissions In Premixed Turbulent Flames: A Comprehensive Review, Medhat Elkelawy Prof. Dr. Eng., E. A. El Shenawy Prof. Dr., Hagar Alm-Eldin Bastawissi, Ibrahim Ali Mousa Eng., Mohamed M. Abdel-Raouf Ibrahim Dr. Eng.
Analyzing The Influence Of Design And Operating Conditions On Combustion And Emissions In Premixed Turbulent Flames: A Comprehensive Review, Medhat Elkelawy Prof. Dr. Eng., E. A. El Shenawy Prof. Dr., Hagar Alm-Eldin Bastawissi, Ibrahim Ali Mousa Eng., Mohamed M. Abdel-Raouf Ibrahim Dr. Eng.
Journal of Engineering Research
Recently, premixed combustion has dominated the field of combustion research worldwide. The current work is a review that addresses the effects of design and operating regimes on the combustion and emission characteristics of premixed turbulent flames. The study accounts for recent developments aimed at overcoming combustor operability issues that influence emissions and flame stability. Various experimental setups have been utilized in investigations, with results pertaining to performance and emissions concerning premixed turbulent flames. Thus, the objective of this paper is to provide a comprehensive review of the effects of swirl vane angles and equivalence fuel-air ratios for tests conducted both …
Effect Of Fabrication Parameters On The Ferroelectricity Of Hafnium Zirconium Oxide Films: A Statistical Study, Guillermo A. Salcedo, Ahmad E. Islam, Elizabeth Reichley, Michael Dietz, Christine M. Schubert Kabban, Kevin D. Leedy, Tyson C. Back, Weison Wang, Andrew Green, Timothy S. Wolfe, James M. Sattler
Effect Of Fabrication Parameters On The Ferroelectricity Of Hafnium Zirconium Oxide Films: A Statistical Study, Guillermo A. Salcedo, Ahmad E. Islam, Elizabeth Reichley, Michael Dietz, Christine M. Schubert Kabban, Kevin D. Leedy, Tyson C. Back, Weison Wang, Andrew Green, Timothy S. Wolfe, James M. Sattler
Faculty Publications
Ferroelectricity in hafnium zirconium oxide (Hf1−xZrxO2) and the factors that impact it have been a popular research topic since its discovery in 2011. Although the general trends are known, the interactions between fabrication parameters and their effect on the ferroelectricity of Hf1−xZrxO2 require further investigation. In this paper, we present a statistical study and a model that relates Zr concentration (x), film thickness (tf), and annealing temperature (Ta) with the remanent polarization (Pr) in tungsten (W)-capped Hf1−xZrxO2. …
Advancements In Characterization Of Ancient Potteries From Southeast Asia: A Review Of Analytical Techniques, Chitnarong Sirisathitkul
Advancements In Characterization Of Ancient Potteries From Southeast Asia: A Review Of Analytical Techniques, Chitnarong Sirisathitkul
Makara Journal of Science
Ancient potteries offer valuable information regarding technological advancements, life dynamics, cultural diversity, and trade routes in the past. Earthenware, stoneware, and porcelain from Southeast Asia have been characterized using several analytical techniques, as reviewed in this article. Fluorescent and diffracted X-rays give rise to elemental and phase compositions, respectively. Examination of molecular bonds requires vibrational spectroscopy, which is useful for the identification of organic materials in ancient potteries. With the advent of portable X-ray fluorescence and Raman spectrometry, on-site analysis of archeological ceramics is now possible. For in-depth analysis, synchrotron light sources can provide new insights into artifacts through X-ray …
Synthesis, Structural And Thermal Studies Of Dl-Alanine Potassium Di- Chromate Single Crystals, Sundararaj Lincy Mary Ponmani, Soundararajan Gnanakkan Pushpalatha Gracelin, Somasundaram Selvakumar, Subbaiah Chelladurai Vella Durai
Synthesis, Structural And Thermal Studies Of Dl-Alanine Potassium Di- Chromate Single Crystals, Sundararaj Lincy Mary Ponmani, Soundararajan Gnanakkan Pushpalatha Gracelin, Somasundaram Selvakumar, Subbaiah Chelladurai Vella Durai
Makara Journal of Science
Amino acids and their complexes are organic or semiorganic materials that have attracted considerable attention because they can be easily used in optical storage devices. DL-alanine is one of the rare amino acids that crystallizes in anoncentrosymmetric group. This article demonstrates how DL-alanine potassium dichromate (DAPC) single crystals have shown sufficient growth. DAPC crystals were analyzed by single crystal X-ray diffraction and powder X-ray diffraction. Using thermogravimetric analysis/differential thermal analysis (TGA/DTA) and differential scanning calorimetry, this work also examined the melting point, thermal stability, decomposition point, and other thermal parameters of the DAPC crystals. Results show that the decomposition point …
Investigation Of Gas Dynamics In Water And Oil-Based Muds Using Das, Dts, And Dss Measurements, Temitayo S. Adeyemi
Investigation Of Gas Dynamics In Water And Oil-Based Muds Using Das, Dts, And Dss Measurements, Temitayo S. Adeyemi
LSU Master's Theses
Reliable prediction of gas migration velocity, void fraction, and length of gas-affected region in water and oil-based muds is essential for effective planning, control, and optimization of drilling operations. However, there is a gap in our understanding of gas behavior and dynamics in water and oil-based muds. This is a consequence of the use of experimental systems that are not representative of field-scale conditions. This study seeks to bridge the gap via the well-scale deployment of distributed fiber-optic sensors for real-time monitoring of gas behavior and dynamics in water and oil-based mud. The aforementioned parameters were estimated in real-time using …
Characterizing And Mitigating Transient Noise In Ligo Observatories For Gravitational Wave Detection, Jane Glanzer
Characterizing And Mitigating Transient Noise In Ligo Observatories For Gravitational Wave Detection, Jane Glanzer
LSU Doctoral Dissertations
The existence of gravitational waves is predicted by Albert Einstein's Theory of General Relativity. Commonly referred to as "ripples in spacetime", these waves are generated by some of the most violent and energetic processes in the universe. Despite their theoretical prediction over a century ago, it wasn't until 2015 that the Advanced LIGO (aLIGO) interferometers in Hanford, WA and Livingston, LA directly detected gravitational waves for the first time, confirming Einstein's theory and ushering in a new era of astrophysics.
Detecting gravitational waves requires incredible precision. Because of the extreme sensitivity required, it is possible for the gravitational wave data …
A Joint Fermi-Gbm And Swift-Bat Analysis Of Gravitational-Wave Candidates From The Third Gravitational-Wave Observing Run, C. Fletcher, J. Wood, R. Hamburg, Michael G. Benjamin, Teviet Creighton, Mario C. Diaz, Francisco Llamas, Soma Mukherjee, Gaukhar Nurbek, Volker Quetschke, Wenhui Wang
A Joint Fermi-Gbm And Swift-Bat Analysis Of Gravitational-Wave Candidates From The Third Gravitational-Wave Observing Run, C. Fletcher, J. Wood, R. Hamburg, Michael G. Benjamin, Teviet Creighton, Mario C. Diaz, Francisco Llamas, Soma Mukherjee, Gaukhar Nurbek, Volker Quetschke, Wenhui Wang
Physics and Astronomy Faculty Publications and Presentations
We present Fermi Gamma-ray Burst Monitor (Fermi-GBM) and Swift Burst Alert Telescope (Swift-BAT) searches for gamma-ray/X-ray counterparts to gravitational-wave (GW) candidate events identified during the third observing run of the Advanced LIGO and Advanced Virgo detectors. Using Fermi-GBM onboard triggers and subthreshold gamma-ray burst (GRB) candidates found in the Fermi-GBM ground analyses, the Targeted Search and the Untargeted Search, we investigate whether there are any coincident GRBs associated with the GWs. We also search the Swift-BAT rate data around the GW times to determine whether a GRB counterpart is present. No counterparts are found. Using both the Fermi-GBM Targeted Search …
Interfacial Magnetism And Anisotropy In Dirac And Weyl Semimetals, Noah Schulz
Interfacial Magnetism And Anisotropy In Dirac And Weyl Semimetals, Noah Schulz
USF Tampa Graduate Theses and Dissertations
Semimetals have gained intense interest recently due to their exotic magnetic and electronic properties. One of the most widely studied semimetals is graphene, a Dirac semimetal. The utilization of graphene in devices and sensors requires interfacing it with other materials, which may induce potentially strong interfacial effects. Furthermore, graphene alone does not possess magnetic order. Studying the interfacial effects between graphene and magnetic materials is therefore of great importance in the application of graphene to meet modern technological needs. Furthermore, by understanding the fundamental interfacial physics between graphene and magnetic materials, new properties can be unlocked, broadening the possible applications …
Toward Local Madelung Mechanics In Spacetime, Mordecai Waegell
Toward Local Madelung Mechanics In Spacetime, Mordecai Waegell
Mathematics, Physics, and Computer Science Faculty Articles and Research
It has recently been shown that relativistic quantum theory leads to a local interpretation of quantum mechanics wherein the universal wavefunction in configuration space is entirely replaced with an ensemble of local fluid equations in spacetime. For want of a fully relativistic quantum fluid treatment, we develop a model using the nonrelativistic Madelung equations, and obtain conditions for them to be local in spacetime. Every particle in the Madelung fluid is equally real, and has a definite position, momentum, kinetic energy, and potential energy. These are obtained by defining quantum momentum and kinetic energy densities for the fluid and separating …
Size Limits And Fission Channels Of Doubly Charged Noble Gas Clusters, Ianessa Stromberg, Stefan Bergmeister, Lisa Ganner, Fabio Zappa, Paul Scheier, Olof Echt, Elisabeth Gruber
Size Limits And Fission Channels Of Doubly Charged Noble Gas Clusters, Ianessa Stromberg, Stefan Bergmeister, Lisa Ganner, Fabio Zappa, Paul Scheier, Olof Echt, Elisabeth Gruber
Faculty Publications
Small, highly charged liquid droplets are unstable with respect to spontaneous charge separation when their size drops below the Rayleigh limit or, in other words, their fissility parameter X exceeds the value 1. The absence of small doubly charged atomic cluster ions in mass spectra below an element-specific appearance size na has sometimes been attributed to the onset of barrierless fission at X = 1. However, more realistic models suggest that na marks the size below which the rate of fission surpasses that of competing dissociative channels, and the Rayleigh limit of doubly charged van der Waals clusters …
X-Currents And Extreme Brightening Events, Abrielle Tio An Mei Wang, Gerard J. Fasel, Audrey Daucher, Makena Swenski, Andrea Black, John Mann, Maame Osei-Tutu
X-Currents And Extreme Brightening Events, Abrielle Tio An Mei Wang, Gerard J. Fasel, Audrey Daucher, Makena Swenski, Andrea Black, John Mann, Maame Osei-Tutu
Seaver College Research And Scholarly Achievement Symposium
The solar-terrestrial interaction is a dynamic process which manifests itself in the ionosphere. Interplanetary (IP) shocks or solar wind dynamic pressure pulses can generate enhanced brightening in dayside aurora. Foreshock transients are capable of inducing pressure changes, larger in magnitude than solar wind pressure pulses, which also contribute to intensifying dayside aurora. These pressure variations can accelerate particles into the ionosphere, generating field- aligned currents that produce magnetic impulse events and enhanced dayside auroral activity with periods of increased brightening. This study presents several dayside auroral brightening events which are not associated with IP shocks or solar wind dynamic pressure …
Coomassie Brilliant Blue Dye As A Method For Analyzing Fracture Markings In Bone, Abigail Hoffmeister, David Harutunyan, Matthew Aizawa, Everett Baker, Brandon Mendoza, Chase Freeman, Siran Iskanian
Coomassie Brilliant Blue Dye As A Method For Analyzing Fracture Markings In Bone, Abigail Hoffmeister, David Harutunyan, Matthew Aizawa, Everett Baker, Brandon Mendoza, Chase Freeman, Siran Iskanian
Seaver College Research And Scholarly Achievement Symposium
Coomassie Brilliant Blue Dye is a dye commonly used to stain proteins. Because of its ability to adhere to proteins, this research has focused on perfecting a method of dyeing a fractured flat bone in order to most accurately observe and analyze fracture markings within the trabecular layer. Stereoscopic microscopy was the chosen technique of analysis for this research because of its proven effectiveness in glass and ceramic fractography to observe varying depths. In order to most effectively apply stereoscopic microscopy to this research, the following variables were manipulated to maximize color contrast in the trabecular layer in order to …
Machine Learning Prediction Of Photoluminescence In Mos2: Challenges In Data Acquisition And A Solution Via Improved Crystal Synthesis, Ethan Swonger, John Mann, Jared Horstmann, Daniel Yang
Machine Learning Prediction Of Photoluminescence In Mos2: Challenges In Data Acquisition And A Solution Via Improved Crystal Synthesis, Ethan Swonger, John Mann, Jared Horstmann, Daniel Yang
Seaver College Research And Scholarly Achievement Symposium
Transition metal dichalcogenides (TMDCs) like molybdenum disulfide (MoS2) possess unique electronic and optical properties, making them promising materials for nanotechnology. Photoluminescence (PL) is a key indicator of MoS2 crystal quality. This study aimed to develop a machine-learning model capable of predicting the peak PL wavelength of single MoS2 crystals based on micrograph analysis. Our limited ability to consistently synthesize high-quality MoS2 crystals hampered our ability to create a large set of training data. The project focus shifted towards improving MoS2 crystal synthesis to generate improved training data. We implemented a novel approach utilizing low-pressure chemical vapor deposition (LPCVD) combined with …
Mechanistic Investigation Of C—C Bond Activation Of Phosphaalkynes With Pt(0) Complexes, Roberto M. Escobar, Abdurrahman C. Ateşin, Christian Müller, William D. Jones, Tülay Ateşin
Mechanistic Investigation Of C—C Bond Activation Of Phosphaalkynes With Pt(0) Complexes, Roberto M. Escobar, Abdurrahman C. Ateşin, Christian Müller, William D. Jones, Tülay Ateşin
Research Symposium
Carbon–carbon (C–C) bond activation has gained increased attention as a direct method for the synthesis of pharmaceuticals. Due to the thermodynamic stability and kinetic inaccessibility of the C–C bonds, however, activation of C–C bonds by homogeneous transition-metal catalysts under mild homogeneous conditions is still a challenge. Most of the systems in which the activation occurs either have aromatization or relief of ring strain as the primary driving force. The activation of unstrained C–C bonds of phosphaalkynes does not have this advantage. This study employs Density Functional Theory (DFT) calculations to elucidate Pt(0)-mediated C–CP bond activation mechanisms in phosphaalkynes. Investigating the …