Physical Sciences and Mathematics Commons^™

Synthesis Of Derivatives Of Pyrido [3,4-D]Pyridazines, Diane (D'Ottavio) Martin

Chemistry and Chemical Biology ETDs

The current interest in the biological activity of certain 1 ,4-disubstituted pyrido[2 ,3-d]pyridazines prompted the investigation of various derivatives of the isomeric pyrido[3,4-d]pyridazine ring system. Thus, 1,4 ­ dichloro[3,4-d]pyridazine was treated with thiourea and the intermediate thiouronium salt hydrolyzed to give pyrido[3, 4-d]pyridazine-1,4(2H,3H)-dithione which was subsequently alkylated to give 1,4-bis(alkylthio)pyrido­[3,4-d]pyridazines. On the other hand, 1,4-bis(arylthio)­pyrido[3,4-d]pyridazines were prepared by the reaction of 1,4-dichloropyrido[3,4-d]pyridazine with various substituted thiophenols. Furthermore, treatment of 1,4-dichloropyrido[3,4-d]­pyridazine with a variety of substituted anilines gave the corresponding 1,4-disubstituted aniline derivatives, whereas reaction with alkylamines afforded only the 1(4)-chloro-4(1)-alkylaminopyrido[3,4-d]pyridazines. When 1-chloropyrido[3,4-d]pyridazine-4(3H)-one or 4-chloropyrido[3,4-d]pyridazine-1(2H)-one was treated with hydrazine, the corresponding …

Geology And Ore Deposits Of The Southwest Nacimiento Range, Sandoval County, New Mexico, Otto L. Schumacher

Earth and Planetary Sciences ETDs

The mapped area is in Sandoval County, New Mexico, 4 miles east of La Ventana. Precambrian rocks in the core of the Nacimiento uplift in this area consist mainly of quartz monzonite gneiss which has been intruded by granite. Hornblende schist xenoliths, zones of sheared quartz-plagioclase schistose gneiss, and mafic and leucocratic dike rocks are less abundant. Strata totaling 6200 feet, ranging from the Pennsylvanian Madera Formation through the Cretaceous Mancos Formation, are exposed in the area. Overlying the marine Madera Formation is 3400 feet of continental, marginal marine, and evaporite deposits consisting in ascending order of the Permian Abo, …

Defense Contracting Policy: An Interface Mechanism With The Defense Industry, George P. Neyman Iii

Marine Affairs Theses and Major Papers

A broad overview of the contractual relationship between the military and the defense industry with emphasis on contracting trends and the impact of these trends on the nature of the defense industry, shipbuilding in particular. A brief historical survey of government contracting from the American Revolution to the present time is designed to review the principal legislative actions developed to control the procurement process. The advantages and disadvantages of the important contract types are discussed. Defense contracting policy is found to be shifting from cost reimbursement contract to the incentive contract. The trend to contract incentives is found to be …

Micronesia: Post World War Ii Sequential Socio-Economic Development, Dale S. Brown Jr.

Marine Affairs Theses and Major Papers

An examination of the socio-economic development of the Trust Territory of the Pacific Islands (Micronesia). A section devoted to early development deals with the long history of foreign administrators who have controlled the islands. The paper deals with interaction between the Micronesians and their administrators and will focus upon relations with the current administrator, the United States, which operates in the islands under a mandate from the United Nations. At the time of the writing of this paper the Micronesians were holding a plebiscite to determine their future political direction. Consideration is given to economic trends within the islands, the …

Current Post Development Problems, Andrew J. Conklin

Marine Affairs Theses and Major Papers

The major problems confronting United States' seaports are investigated as they relate to the 1970s time frame. The influence of the merchant marine's transition to new, large and deep drafted ships is examined as it pertains to harbor and channel depth, pier and storage requirements, waterborne traffic control and port economic impact. Present seaport facilities are barely keeping abreast with new developments in cargo transportation and handling methods. Additionally, major port development problems are magnified by the recent awarenesss of the environmental value of the coastal zone. Only a limited amount of area remains in most ports, both below the …

Growth Patterns Of The World's Merchant Marine, John R. Devereaux Jr.

Marine Affairs Theses and Major Papers

Developments in the world ocean-borne transport industry since World War II are reviewed and major trends identified; based on these trends significant implications are derived. The study is limited to the deep sea segment of the shipping industry and touches on related fields, such as the coastal trades and port development, only where trends in the deep sea trade affect them. The major trends identified are the continued growth of ocean-borne trade, the ever growing ship size wherever it proves practical and economical, and the rapid evolution of ship specialization.

Lipotes Vexillifer , Robert L. Brownell Jr., Earl S. Herald

United States Department of Commerce: Staff Publications

Order Cetacea, Family Platanistidae, Subfamily Iniinae. The genus Lipotes now includes one species Lipotes vexillifer as treated below. No sub- species are recognized.

Statistical Section (June 1972), Central Bank Of Nigeria Cbn

Economic and Financial Review

The dataset set contains data from central banking, commercial banking, currency in circulation, external assets, international trade, money and capital, money supply, national savings, production and public debt covering 1966-1971.

Phyletic Trends In Certain Lineages Of Quaternary Mammals, C. Bertrand Schultz, Lloyd G. Tanner, Lary D. Martin

Bulletin of the University of Nebraska State Museum

Evolutionary trends in certain carnivores, rodents, bovids, and proboscideans are examined. Chronoclines are demonstrated for muskrats, beavers, mammoths, and bison. The Pliocene-Pleistocene boundary and Quaternary climatic fluctuations are also discussed.

The University of Nebraska State Museum contains a large stratigraphically controlled collection of Pleistocene animals. This collection provides a unique opportunity for the study of phyletic trends in certain lineages of mammals. Although a few phylogenetic lineages have been proposed (Schultz and Frankforter, 1946; Hibbard, et al., 1965), this has not been done for the vast majority of Pleistocene mammals. However, there is much more data available than this would …

Professor Leo Moser -- Reflections Of A Visit, Walter E. Mientka

Department of Mathematics: Faculty Publications

Professor Leo Moser' was known throughout the Mathematical Community as a significant researcher and excellent lecturer. I first met Leo during the Summer Research Institute in the Theory of Numbers held at the University of Colorado in 1959. After talking with him and hearing his lectures during the Institute, I felt that arrangements would have to be made in the near future for a visit to Nebraska. During the academic year 1962-63 while Professor Moser was on a lecture tour for the MAA, I invited him to present two research lectures to the Nebraska Section on May 3 and 4, …

Terminal Talk - The Wofford Connection - June 1972, Wofford College Computer Center

Terminal Talk

No abstract provided.

A Planning And Cost Allocation Procedure For Computer System Management, J. Nunamaker, A. Whinston

Department of Computer Science Technical Reports

No abstract provided.

Cationic Copolymerization Of B-Pinene And Styrene, Charles Peter Snyder

Honors Theses

Cationic polymerizations are the least understood of all polymerization reactions. Perhaps even less understood are copolymerizations using cationic catalysts. Very little can be found in the literature concerning B-pinene and styrene copolymers. This work was done to shed some light on this interesting subject.

Attempted Synthesis Of Diethyl 7-Dimethylsilabicyclo 2.2.1 Hepta-2,5-Dione-1,4-Dioate, David Kenneth Tart

Honors Theses

An attempt was made to synthesize diethyl 7-dimethylsilabicyclo [2.2.1) hepta-2,5-dione-l,4-dioate by reacting dimethyldichlorosilane with the dianion of 1,4-dicarbethoxy- 2,5-cyclohexadione. The products formed in the reaction were silicones and 0-silylated polymeric materials. If any of the desired product was formed, it was not detected.

Synthesis Of C14-Labeled Bis (P-Chlorophenyl) Acetic Acid (Dda), William Michael Silver

Honors Theses

The past three decade has seen the widespread use of DDT as an insecticide. As a persistent insecticide, its use has prompted a great amount of research into the fate of DDT in living organisms. A large number of metabolites of DDT has been found and many identified, although not all of the metabolites were found in all of the experimental bacterium, insects, or mammals.

Photochemical Solvolysis Of Optically Active 3,5-Dimethoxy-Α-D-Benzyl Acetate, Peter Jerry Frank

Honors Theses

The purpose of this work was the stereochemical study of the photochemical solvolytic reaction of 3,5-dimethoxybenzoic acid, optically active 3,5-dimethoxy-α-d-benzyl alcohol was prepared. The specific rotation of the alcohol was compared to the alcohol produced from the photochemical solvolytic reaction of 3,5-dimethoxy-α-d-benzyl acetate.

The Preparation And Kinetics Of Sterically Hindered Gold (Iii) Complexes, David Luther Fant

Honors Theses

The purpose of this research was to prepare and study complexes with steric hindrance greater than that of the dien complex but less than that of the Et4dien complex.

The Prairie Naturalist Volume 4, No. 2. June 1972

The Prairie Naturalist

EDITORIAL: Coordination: A Step for Environmental Protection ▪ Paul B. Kannowski

AN ANALYSIS OF BARN OWL AND GREAT HORNED OWL PELLETS FROM WESTERN NEBRASKA ▪ Eric A. Rickart

SUMMER OBSERVATIONS OF THE SHORT-EARED OWL IN THE RED RIVER VALLEY ▪ W. J. Walley

ADDITIONAL GLAUCOUS GULL RECORD FOR NORTH DAKOTA ▪ B. J. Rose

MIGRATION OF BIRDS IN NORTH DAKOTA DURING FALL 1971 ▪ Douglas H. Johnson, John T. Lokemoen and Paul F. Springer

WIDGEONGRASS BALLS ON ALKALI LAKES ▪ George A. Swanson and Paul F. Springer

A PROBABLE INSTANCE OF SONGBIRD COLLISION MORTALITY ▪ R. Wayne Weier

MUNICIPAL FLOODPLAIN …

Synthetic Approaches To Certain Acenapthalene Drivatives, Douglas Jeffrey Binder

Honors Theses

The purpose of this investigation is the synthesis of bis- acenaphth- (1, 2a)- acenaphthene. The experimental procedures used generally follow those of previous workers. The use of 1, 8- dibromonaphthalene is necessary throughout the synthesis. The preparation used follows that of letsinger, after a preferred synthesis of 8- bromo- 1- naphthotic acid. The latter compound reacted via a modified Hunsdiecker reaction to yield 1, 8- dibromo- naphthalene. Other approaches tried never seemed to result in improved yields, or were successful. Besides this approach to 1, 8- dibromonaphthalene, an attempt to circumvent its need has been made by running a dilute …

1-3 Dipolar Cycloadditions Of Nitrile Ylides, Steven Paul Braff

Honors Theses

1-3 dipolar cycloaddition is the union of a 1-3 dipole, a-b-c, with a system containing a multiple bond, d-e, to form a five membered ring. In this scheme, center c contains an electron sextet, and concommitant positive charge, while center c contains an unshared pair of electrons and is the anionic center of the dipole. In the cycloaddition reaction, the 1-3 dipole and the multiple bond system (called the dipolarophile), collapse to form a five membered ring with loss of all formal charges. All together, eighteen 1-3 dipolar systems have been mentioned. The synthetic potential with respect to heterocyclic adducts …

The Developement [Sic] Of Phosphorometric, Fluorometric And Absorption Analyses For The Measurement Of Carbamates And Carbamic Acids As An Explanation Of Carbon Dioxide Transport In Blood, Edward Theodore Gray

Honors Theses

Phosphorometric, flourometric, and absorption analyses have been developed for the measurement of amino acids, carbamic acids, and carbamates. The absorption analysis may be done in any solvent while the other two methods are limited to non-re-emitting solvents. Water is not excluded in any of the analyses. A carbamate or carbamic acid can be detected even in the presence of amino acids as low as 0.5%, with an overall accuracy of ± 0.3)%. Tentative assignments have been made for the n, π* direct triplet excitation bands for the carbonyls of glycine and its carbamic acid, acetyl chloride, ethyl acetate, and acetamide. …

Some Aspects Of Quantum Mechanics In Chemical Theory, Thomas Freeman Babson

Honors Theses

The physics of microscopic phenomena is called quantum mechanics. When quantum mechanics is extended to the macroscopic scale, the classical macroscopic physics results. Atomic interactions such as the formation of bonds between atoms falls into the range of physics described by quantum mechanics. Because of the interest of a chemist in such interatomic effects, it seems reasonable that a chemist would be interested in quantum mechanics because it is the physics governing these effects. The point of this thesis is to present some of those aspects of quantum mechanics that are directly applicable to molecular systems and that can aid …

Research Project For Undergraduates: Ionic Thermoconductivity In Dielectrics, Richard M. Fuller, Robert Fuller

Robert G. Fuller Publications

Research projects for undergraduates should satisfy several conditions with regards to the physical insight, experimental manipulation, data analyses, and time for the experimental run that are required of the students. These conditions are satisfied by the study of dipole relaxations in dielectric materials using the method of ionic thermocurrents (ITC). ITC can be used to determine the concentration, activation energy, and relaxation time of dipoles in a dielectric. The necessary equipment and some possible research projects are discussed.

Oceanographic Data Collected In The Chesapeake Bight Of The Virginian Sea From 1966 Though 1969, E. P. Ruzecki, J. J. Norcross, F. J. Wojcik

Reports

This report is intended to make unsynthesized oceanographic data readily available to the scientific community. 3 Similar reports are envisioned which will include physical, chemical, biological and geological data collected by personnel of the Virginia Institute ·of Marine Science in areas of the continental shelf, and coastal zone to include beaches, wetlands, estuaries and tidal rivers - areas in which the Commonwealth of Virginia has a vested interest.

Instructions For Using Oceanography Form 1 (Virginia Institute Of Marine Science Hydrographic Data Form), Richard W. Moncure

Reports

Instructions for coding oceanographic data on Form 1.

Post-Abortion Counseling And Anxiety Levels Of Unmarried Adolescents Having Therapeutic Abortions, Linda Levisen

Loma Linda University Electronic Theses, Dissertations & Projects

The purpose of this study was to evaluate the effectiveness of a post-abortion counseling program. It was hypothesized that unmarried adolescents who received counseling following a therapeutic abortion would exhibit significantly fewer negative affects than those who received no counseling. The affects measured were anxiety, depression, hostility, and guilt. Twenty clients were randomly selected for this study. Prior to the abortion, the twenty clients were-tested for negative responses to the unwanted pregnancy. Ten clients received post-abortion counseling twice following the abortion and were tested at each visit for negative affective responses to the abortion. The other ten clients received no …

High-Field Mobility Effects In Junction-Gate Field-Effect Transistors, Waguih John Boctor

Archived Theses and Dissertations

No abstract provided.

Patients' Reactions To Witnessing Cardio-Pulmonary Resuscitation, Lynn Andree Finch

Loma Linda University Electronic Theses, Dissertations & Projects

The purpose of this study was to describe the reactions to stress in patients witnessing a cardio-pulmonary resuscitation, in order to determine if the witnessing patients' needs are being met adequately, and to determine the effect of a specific psychological stressor on patients.

All resuscitations ("STATS") done over a two-month period at Loma Linda University Medical Center, with oriented patients in the room, were observed and recorded on an Observation Guide. A Questionnaire was also solicited from medical-surgical nursing personnel who had observed "STATS" with witnessing patients in the last three months. The Guide and the Questionnaire were developed from …

The Development And Constitutionality Of The 1971 Delaware Coastal Zone Act, Francis Cameron

Marine Affairs Theses and Major Papers

In June 1971, the Delaware Legislature passed the Delaware Coastal Zone Act that barred heavy manufacturing industry from locating in an area one to six miles deep along the state's 115 mile coastline. The act created a State Coastal Zone Industrial Control Board to hear appeals from decisions of the State Planner. In addition, the act prohibited the construction in the bay of marine terminals for the transshipment of liquid and solid bulk materials of any substance, (specifically aimed at offshore oil and coal transfer) from vessels to onshore facilities. The law's immediate effect was to block several hundred million …

Spiny Lobster Mariculture In The State Of Florida, W. Richard Boehmer

Marine Affairs Theses and Major Papers

The purpose of this paper is to introduce the reader to the Florida spiny lobster, Panuluris argus; to show the economic potential for the mariculture of this species by exposing value and size of the U. S. spiny lobster market; to present Florida’s legal provisions for mariculture and how spiny lobster farming would be acceptable; to indicate the biological considerations for the rearing of spiny lobster larva and postlarva; and to introduce a general plan for the mariculture of spiny lobster, that considers the legal provisions of leasing wetlands in Florida and incorporates the biological considerations of spiny lobster.