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Articles 2791 - 2820 of 2906

Full-Text Articles in Physical Sciences and Mathematics

Asymptotic Evaluation Of Wkb Matrix Elements. Ii. Use Of Langer's Uniform Asymptotic Wavefunctions, Wesley D. Smith, Russell T. Pack Feb 1970

Asymptotic Evaluation Of Wkb Matrix Elements. Ii. Use Of Langer's Uniform Asymptotic Wavefunctions, Wesley D. Smith, Russell T. Pack

Faculty Publications

An improvement in a previous procedure for the analytic asymptotic evaluation of integrals arising in the quantum-mechanical theory of inelastic molecular collisions is presented. The integrals are evaluated using Langer's uniform asymptotic wavefunctions and the higher-order saddle-point or steepest-descents method. It is found that the Langer functions give no better results than WKB functions, but the higher-order steepest-descents corrections produce a marked improvement. The result is a simple method for evaluating a large class of integrals with an error of 0.1%-2.1%.

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Proposed Thermodynamic Pressure Scale For An Absolute High-Pressure Calibration, Daniel L. Decker, J. Dean Barnett Feb 1970

Proposed Thermodynamic Pressure Scale For An Absolute High-Pressure Calibration, Daniel L. Decker, J. Dean Barnett

Faculty Publications

The field of high pressure has developed rapidly over the past few years to a point where relatively sophisticated experiments are being attempted. In many experiments it is no longer sufficient to qualitatively estimate the pressure or to base conclusions on experimental results tied to an empirical pressure parameter. One desires to accurately know the pressure dependence of physical quantities related to a true thermodynamic scale.

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Quasilattice Interpretation Of The Thermodynamic Properties Of Mixing Of Binary Alkali-Metal Systems, J. Bevan Ott, J. Rex Goates Nov 1969

Quasilattice Interpretation Of The Thermodynamic Properties Of Mixing Of Binary Alkali-Metal Systems, J. Bevan Ott, J. Rex Goates

Faculty Publications

Quasilattice theory was applied to heats of mixing in the six systems formed from the binary combinations of Na, K, Rb, and Cs. The alkali-metal systems are particularly well suited for a critical test of the quasi-crystalline assumption since the theoretical model for these systems is relatively simple and the thermodynamic data are fairly complex. Very good fits of the heat-of-mixing data were achieved by assuming that the larger atom in the binary system covered multiple sites on the quasilattice. The values of the empirically determined constants appear to fit the physical significance accorded to them by the quasilattice model. …

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A Thermodynamic Approach To The Study Of Phase Equilibria In The Sodium-Potassium Alloy System I. The Phase Diagram For Nak At Atmospheric Pressure ; Ii. High Pressure Phase Studies, Donald Ray Anderson Aug 1969

A Thermodynamic Approach To The Study Of Phase Equilibria In The Sodium-Potassium Alloy System I. The Phase Diagram For Nak At Atmospheric Pressure ; Ii. High Pressure Phase Studies, Donald Ray Anderson

Theses and Dissertations

Ultra-pure reagents, platinum resistance thermometry and modern inert atmosphere glove box facilities have made possible a detailed examination of the NaK system at atmospheric pressure. A thermoanalytical study of solid-liquid phase equilibria in the NaK alloy system was conducted in the tetrahedral press to 55 kbars to investigate possible intermediate compound formation and shifting of the invariant points at various pressures. An expected shift in the eutectic composition to lower potassium content with an increase in the halt temperature on increasing pressure was confirmed. A merging of the meritectic and eutectic points at 343 ±2°K and 37 ±3 kbars occurred …

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Solid-Liquid Phase Equilibria Of The Sodium-Rubidium And Sodium-Potassium-Rubidium Alloy Systems, Chen-Chao Hsu Aug 1969

Solid-Liquid Phase Equilibria Of The Sodium-Rubidium And Sodium-Potassium-Rubidium Alloy Systems, Chen-Chao Hsu

Theses and Dissertations

Thermal methods were used, to determine with high precision, the solid-liquid phase equilibria diagrams for the sodium-rubidium and sodium-potassium-rubidium systems. In the sodium-rubidium system, the results differ greatly from those of earlier works, especially near the eutectic composition where differences in freezing points as large as 25°K occur. A detailed search was made for possible intermetallic compounds (especially Na2Rb). Neither slow temperature cycling in the temperature range where compound formation could occur nor extended periods of annealing just above the eutectic temperature produced any evidence for compound formation in the sodium-rubidium system. A 2:1 (sodium to rubidium) sample was subjected …

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The Catalytic Hydrogenation Of Benzodiazines.|Ni.|Pphthlazine.|Nii.|Pquinazoline, Danny Lee Elder Aug 1969

The Catalytic Hydrogenation Of Benzodiazines.|Ni.|Pphthlazine.|Nii.|Pquinazoline, Danny Lee Elder

Theses and Dissertations

Quinazoline and phthalazine were hydrogenated at low pressure and temperature (60 psi, room temperature) and high pressure and temperature (2000 psi, 100°C, 150°C} in neutral and acidic solvents over 5% Pd/C, 5% Ru/C, 5% Rh/Al2O3 , 5% Rh/C, and 5% Pt/C. Chromatographic methods for determining the qualitative and quantitative composition of hydrogenation mixtures were developed. The compositions of quinazoline and phthalazine-hydrogenation mixtures were determined. Eight phthalazine-hydrogenation products were detected and isolated: (1) 1,2-dihydrophthalazine, (2) 1,2,3,4-tetrahydrophthalazine, (3) a,a'-diamino-o-xylene, (4) o-methylbenzylamine, (5) 1,3-dihydroisoindole, (6) o-xylene, (7 and 8) cis- and trans- 1,2-dimethylcyclohexane. These products were identified by isolating them from reaction mixtures …

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Estimations Of The Effective Electrolytic Surface Area Of Rough And Porous Silver Electrodes ; Ii. Potentiostatic Oxidation Of Silver In Alkaline Electrolyte, James Glenn Bearss Aug 1969

Estimations Of The Effective Electrolytic Surface Area Of Rough And Porous Silver Electrodes ; Ii. Potentiostatic Oxidation Of Silver In Alkaline Electrolyte, James Glenn Bearss

Theses and Dissertations

This dissertation is written in two sections. The first section deals with the development of methods for the estimation of the effective electrolytic surface area of rough and porous silver electrodes in alkaline electrolyte. Data are presented comparing the results of three different methods of surface area estimation. Model pore electrodes were also prepared and oxidized to study the reactions in a pore. Data for constant current oxidations of these electrodes is given. The second section deals with the potentiostatic oxidations of silver in alkaline electrolyte. Data are presented on the total charge acceptance versus applied potential for a potential …

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A Study Of Folic Acid Dependent Reactions In Bovine Brain, Dillard Spencer Broderick Aug 1969

A Study Of Folic Acid Dependent Reactions In Bovine Brain, Dillard Spencer Broderick

Theses and Dissertations

The enzymatic interconversion of serine to glycine and N5, N10-methylene tetrahydrofolate to N5 -methyl tetrahydrofolate have been studied in a cell-free system derived from bovine brain. A partial purification of serine transhydroxymethylase and N5, N10 -methylene tetrahydrofolate reductase has been achieved by ammonium sulfate fractionation, protamine sulfate fraction, and by various column chromatography procedures. The two enzymes studied catalyze sequentially the reductive transfer of the hydroxymethyl group of serine to the N5 position of tetrahydrofolate forming N5 -methyl tetrahydrofolate. The products of these reactions were assayed by the incorporation of C14 from a one-carbon precursor i.e., L-beta-(C14)-serine, or N5 -methyl …

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Thermodynamics Of Proton Dissociation And Metal Ion Complexation In Aqueous Solution. I, Cation Binding With Cyclic Polyethers: Significance In Ion Transport Processes. Ii, Proton Dissociation From Adenosine, Several Monosaccharides And Related Compounds. Iii, Proton Dissociation From Several Pyrimidines And Their Nucleosides At 10, 25 And 40°, Joseph Howard Ryttling Aug 1969

Thermodynamics Of Proton Dissociation And Metal Ion Complexation In Aqueous Solution. I, Cation Binding With Cyclic Polyethers: Significance In Ion Transport Processes. Ii, Proton Dissociation From Adenosine, Several Monosaccharides And Related Compounds. Iii, Proton Dissociation From Several Pyrimidines And Their Nucleosides At 10, 25 And 40°, Joseph Howard Ryttling

Theses and Dissertations

The log K, ΔH° and ΔS° values for the interaction of several metal ions with the two isomers of the cyclic polyether, 2,5,8,15,-18,21 hexaoxatricyclo[20.4.0.0^9,14]hexacosane are reported. The stability order found for alkali metal ion interaction with either isomer is identical to the order of ion permeability through reconstituted biological membranes for structurally related antibiotics. The size of the metal ion is critical in determining the extent of interaction. A calorimetric titration study of proton ionization from several monosaccharides and derivatives, pyrimidine bases and their nucleosides, adenosine and its derivatives, and cycloheptaamylose is described. The heats of reaction obtained in this …

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Mechanism Of Water Transport Through Reverse Osmotic Membranes, Cheryl Kay Murphy Jul 1969

Mechanism Of Water Transport Through Reverse Osmotic Membranes, Cheryl Kay Murphy

Theses and Dissertations

Cellulose acetate membranes show a higher permeability to water than to salt and are being used for desalination of salt water by reverse osmosis. Use of highly acetylated cellulose membranes give a higher salt rejection but also decrease flow rate of the water. The addition of very-short-chain substances or alkyl groups larger than one carbon atom to the cellulose membrane also decreases water flux. A proposed mechanism of transport through the membrane is that the water molecule is passed along the chain by hydrogen bonding with the acetyl groups, The NMR shows a change in the chemical shift of water …

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Syntheses Via Modifications Of The Knorr-Paal Procedure :|Ba. Derivatives Of 2,6-Dioxa-10-Azatricyclo[5.2.1.0[Superscript 4,10]]Decane ; B. Highly Sterically Crowded 1,2,5-Trialkylpyrroles And Pyrrolidines, Weldron Severin Burnham Jun 1969

Syntheses Via Modifications Of The Knorr-Paal Procedure :|Ba. Derivatives Of 2,6-Dioxa-10-Azatricyclo[5.2.1.0[Superscript 4,10]]Decane ; B. Highly Sterically Crowded 1,2,5-Trialkylpyrroles And Pyrrolidines, Weldron Severin Burnham

Theses and Dissertations

Earlier work in these laboratories on the heterotricyclic system 2,6-dioxa-10-azatricyclo[5.2.1.04,10]-decane, formed from 1,4-diketones and 2-amino-1,3-propanediols by a product-water-azeotroping procedure, was extended with the synthesis of analogous compounds, e.g., the 1,4,7-triethyl-, 1,7-dimethyl-4-isopropyl-1,7-diethyl-4-isopropyl-, 1,7-dimethyl-3- and 4-phenyl- compounds. The 1,7-dimethyl heterotricycle, the kinetically-controlled product, was accompanied by the thermodynamically-controlled product, 2-(2,5-dimethyl-1-pyrryl)-1,3-propanediol. The 1,7-diethyl heterotricycle was also accompanied by the isomeric pyrrole as were the 1,7-dimethyl-3- and 4-phenyl compounds. A scheme postulating a common intermediate is presented. The interesting analogous compounds, 1,7-dimethyl-2-oxa-6-thia-10-azatricyclo[5.2.1.04,10]decane, 1,4,7-trimethyl-2,6-dioxa-11-azatricyclo[5.3.1.04,11]undecane and 11-hydroxymethyl- and 11-methyl-9,13-dioxa-14- azatetracyclo[6.5.1.02,7 011,14]tetradeca-2,4,6-triene were also prepared. The syntheses in good yields of a considerable number of moderately to …

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High Pressure, High Temperature Syntheses Of Selected Lanthanide-Tellurium Compounds, John Francis Cannon Jun 1969

High Pressure, High Temperature Syntheses Of Selected Lanthanide-Tellurium Compounds, John Francis Cannon

Theses and Dissertations

High pressure, high temperature technics were employed to successfully synthesize HoTe1.7, ErTe1.7, TmTe1.7, LuTe1.7, YTe1.7, and LuTe3. The pressure-temperature regions in which synthesis of each compound is successful were determined. Pressures to 100 kbars concurrently with temperatures to 1200 °C were used in an attempt to prepare ScTe1.7 and ScTe3, but these efforts met with failure. X-ray studies of these new compounds confirmed that they are extensions of the LTe2-X (0≤x

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The Thermodynamics Of Transition Metal Chelation In Dilute Aqueous Solution.|Ni.|Pthe Thermodynamics Of Interaction Of Serinate Ion With Divalent Co, Ni, Cu, Zn, And Cd Ions In Aqueous Solution.|Nii.|Pthe Calorimetric Standardization Of Dilute Ferrous Ion Solutions For Use In Determining 2,2'-Bipyridine, Joseph Willard Richards May 1969

The Thermodynamics Of Transition Metal Chelation In Dilute Aqueous Solution.|Ni.|Pthe Thermodynamics Of Interaction Of Serinate Ion With Divalent Co, Ni, Cu, Zn, And Cd Ions In Aqueous Solution.|Nii.|Pthe Calorimetric Standardization Of Dilute Ferrous Ion Solutions For Use In Determining 2,2'-Bipyridine, Joseph Willard Richards

Theses and Dissertations

Calorimetrically determined ΔH° values are given for the stepwise formation of chelate species between serinate ion and the divalent metal ions of Co, Ni, Cu, Zn, and Cd. These values of ΔH° are compared with those reported in the literature and were combined with values of ΔG° (log K) found in the literature to calculate values of ΔS°. These values of ΔG° and ΔS° are listed also. A new method of standardizing dilute ferrous ion solutions is reported. This procedure makes use of the thermometric titration technique to detect the equivalence point for the reaction of K_2Cr_2O_7 with ferrous ion. …

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A Study Of Factors Which May Influence Attitudes Of Lds Teen-Agers Toward Family Home Evening, Don Leroy Miller Jan 1969

A Study Of Factors Which May Influence Attitudes Of Lds Teen-Agers Toward Family Home Evening, Don Leroy Miller

Theses and Dissertations

The purpose of this study was to identify factors related to attitudes of teenagers toward the Family Home Evening Program of the Church of Jesus Christ of Latter-day Saints. Hypotheses involving the relationships of certain factors to attitudes toward home evening were tested.

A cluster sample of twenty-three ninth grade classes was selected and data were gathered through use of a questionnaire. Statistics used in analysis of data included the Pearsonian product moment correlation coefficient, and analysis of variance. Responses to open-end questions were content analyzed by three independent judges.

Findings suggest that perceived participation by teenagers in planning and …

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Expectation Values Of Simple Correlated Helium-Atom Wavefunctions, Thomas P. Tsien, Russell T. Pack Nov 1968

Expectation Values Of Simple Correlated Helium-Atom Wavefunctions, Thomas P. Tsien, Russell T. Pack

Faculty Publications

In this Note we present the results of a calculation of the expectation values of a number of one- and two electron properties of the ground-state helium atom using two very simple correlated wavefunctions.

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New Solutions Of The Einstein-Maxwell Equations From Old, B. Kent Harrison Nov 1968

New Solutions Of The Einstein-Maxwell Equations From Old, B. Kent Harrison

Faculty Publications

Methods are discussed with which one may derive theorems which allow one to generate new solutions of the Einstein-Maxwell equations from old ones. The old solutions used to generate new ones must admit at least one nonnull Killing vector and may be required to satisfy other conditions, depending on the theorem derived. Examples of derivable theorems are shown; these theorems are used in turn to show how generation of new solutions is accomplished. Examples of the latter are shown, such as generation of Brill or electrified NUT space from the Schwarzschild solution, generation of a new twisted Melvin universe from …

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The Effect Of Thiamine And Its Antagonists On Plasma And Tissue Lactic Dehydrogenase In Rats, Dong Hwa Park Aug 1968

The Effect Of Thiamine And Its Antagonists On Plasma And Tissue Lactic Dehydrogenase In Rats, Dong Hwa Park

Theses and Dissertations

The lactic dehydrogenase activity in plasma and tissues was measured in the thiamine-deprived, the oxythiamine-treated and the pyrithiamine-treated rats as well as the control rats. The lactic dehydrogenase levels of brain and kidney were significantly increased by oxythiamine treatment. The enzyme activity in heart was markedly decreased only in the thiamine-deprived rats. Unlike the above tissues, the enzyme levels in liver were decreased by 29-44 per cent in all three types of thiamine deficiency, However, the enzyme activity in plasma was significantly increased only by pyrithiamine administration. The distribution patterns of lactic dehydrogenase isozymes were electrophoretically examined in these deficiencies. …

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Determination Of Stability Constants At 25c For The Interaction In Aqueous Solution Of Serine With Co (Ii), Ni (Ii), Cd (Ii), Zn (Ii), And Cu (Ii) Ions, Liak Hwe Ma Aug 1968

Determination Of Stability Constants At 25c For The Interaction In Aqueous Solution Of Serine With Co (Ii), Ni (Ii), Cd (Ii), Zn (Ii), And Cu (Ii) Ions, Liak Hwe Ma

Theses and Dissertations

Values of thermodynamic stability constants at 25°C for the complexes of serine with the metal ions. Co^2+, Ni^2+, Cd^2+, Zn^2+, and Cu^2+ were obtained from pH titration data. All measurements were made in aqueous solution, and data were obtained at three different ionic strengths for each metal ion studied. It was assumed that the activity of the zwitterion is unity. The effect of metal ion hydrolysis upon the log K values was taken into account for the calculations. For all the metal ions studied, stability constants for MA^+, MA_2, and MA_3^- were reported with the exception of copper (II) which …

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A Study Of Reaction Parameters In The Hydrogenation Of Acetic Acid By Rhenium Heptoxide Catalyst, Victor L. Mylroie Aug 1968

A Study Of Reaction Parameters In The Hydrogenation Of Acetic Acid By Rhenium Heptoxide Catalyst, Victor L. Mylroie

Theses and Dissertations

Rhenium oxides as well as other rhenium compounds are known to display a broad spectrum of catalytic activity,^25 being resistant to attack by acids under nonoxidizing conditions, and showing a remarkable ability to resist poisoning which is a serious limiting factor in many commonly used catalysts. Rhenium catalysts are cheaper than the platinum metals with the exception of palladium. One of the most remarkable properties of the rhenium catalyst is the ability to catalyze the hydrogenation of carboxylic acids and amides to the corresponding alcohols and amines respectively. The carboxyl group (-COOH) is notoriously difficult to reduce catalytically and most …

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High Pressure, High Temperature Syntheses Of Rare Earth Diantimonides And Th₃P₄ Type Polymorphs Of Rare Earth Sesquisulfides, Normal L. Eatough Aug 1968

High Pressure, High Temperature Syntheses Of Rare Earth Diantimonides And Th₃P₄ Type Polymorphs Of Rare Earth Sesquisulfides, Normal L. Eatough

Theses and Dissertations

The rare earths form series of compounds which are known for several elements but end abruptly or undergo a change of structure at some member of the series. The diantimonides are one such series. Sb-Sb repulsion becomes stronger as the rare earth size decreases and the previously known series ended at Sm. It was felt that high pressure would overcome the Sb-Sb repulsion and allow bonding to form stable or metastable compounds not possible by ordinary techniques. Synthesis studies were carried out on mixtures of antimony with all the rare earths except Pm and with Sc and Y. The known …

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The Thermodynamics (Log K, [Delta]H°, [Delta]S°, [Delta]Cp°) Of Metal Ligand Interaction In Aqueous Solution.|Ni.|P Design And Construction Of An Isothermal Titration Calorimeter.|Nii.|Pthe Interaction Of Cyanide Ion With Bivalent Nickel, Zinc, Cadmium And Mercury.|Niii.|Pthe Interaction Of Glycinate Ion With Bivalent Manganese, Iron, Cobalt, Nickel, Copper, Zinc And Cadmium, Harlin Dee Johnston Aug 1968

The Thermodynamics (Log K, [Delta]H°, [Delta]S°, [Delta]Cp°) Of Metal Ligand Interaction In Aqueous Solution.|Ni.|P Design And Construction Of An Isothermal Titration Calorimeter.|Nii.|Pthe Interaction Of Cyanide Ion With Bivalent Nickel, Zinc, Cadmium And Mercury.|Niii.|Pthe Interaction Of Glycinate Ion With Bivalent Manganese, Iron, Cobalt, Nickel, Copper, Zinc And Cadmium, Harlin Dee Johnston

Theses and Dissertations

A new isothermal titration calorimeter has been designed to facilitate the study of heats of reaction and heats of solution at constant temperature. With this calorimeter, endothermic or exothermic processes can be studied at temperatures constant to ±0.0002°C. Heat effects are compensated by balancing the heat effect of the process taking place in the calorimeter against a variable heat and a constant cooling Peltier device. The calorimeter was tested by measuring the heat of ionization of water and the heat of dilution of aqueous HClO_4 solutions. For these systems heats were measured to an accuracy of ±0.02 calorie. Log K, …

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An Investigation Of Column Efficiency And The Relationship To Liquid Phase Distribution On Ultra-Low Loaded Glass Bead Gas Chromatographic Columns, Donald G. Nyberg May 1968

An Investigation Of Column Efficiency And The Relationship To Liquid Phase Distribution On Ultra-Low Loaded Glass Bead Gas Chromatographic Columns, Donald G. Nyberg

Theses and Dissertations

Studies have been made of column efficiencies, extra-column effects, the liquid phase mass transfer term (C_l), and liquid phase distribution at ultra-low liquid loadings on glass bead gas-liquid chromatographic columns. The advantages of using lightly loaded columns are described in detail along with a critical evaluation of the limitations of this liquid phase reduction ad infinitum. Theories have been presented by Giddings^22,23,25,30,32 which predict the mass transfer term (C_l) as a function of two extreme liquid phase distributions. The first equation assumes 100% "capillary" liquid held at the glass bead contact points and represents a very inefficient column. This prediction …

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A Method For Measuring Magnetization To High Pressures, C. R. Johansen, Mark H. Nelson, J. H. Gardner Mar 1968

A Method For Measuring Magnetization To High Pressures, C. R. Johansen, Mark H. Nelson, J. H. Gardner

Faculty Publications

A partially successful attempt has been made to measure the magnetic moment per unit volume of ferromagnetic materials as a function of pressure to the 100-kbar region. The apparatus, an early version of which has been described previously, consists basically of two opposed Bridgman flat anvils of alumina. One anvil also acts as a dielectric-filled microwave resonant cavity for an x-band spectrometer, allowing electron spin resonance studies to be made to high pressure. The sample to be studied is placed in contact with the anvil-cavity and covered with a pressure-transmitting medium which in turn is encircled by a flat pyrophyllite …

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The Relationship Of Church Activity Of Parents Of Lds Seminary Students To The Attendance Of Seminary Students At Church, Ronald D. Firth Jan 1968

The Relationship Of Church Activity Of Parents Of Lds Seminary Students To The Attendance Of Seminary Students At Church, Ronald D. Firth

Theses and Dissertations

It has been observed that not all L.D.S. Seminary students are active in church attendance. There is little doubt in the minds of educators that parents affect a great deal the activities of their children.

The purpose of the study was to learn what relationship, if any, existed between a seminary student's church attendance and the church activities of his parents, and to find out which, if any, of five specific areas of parental church activity had the most positive effect on a student's church attendance.

Based on his experience in the church, the writer chose the following areas of …

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Very High Pressure Effects Upon The Epr Spectrum Of Ruby, H. Mark Nelson, D. B. Larson, J. H. Gardner Sep 1967

Very High Pressure Effects Upon The Epr Spectrum Of Ruby, H. Mark Nelson, D. B. Larson, J. H. Gardner

Faculty Publications

The variation in the electron paramagnetic resonance (EPR) spectrum of ruby as a function of pressure has been observed to beyond 70 kbar for a magnetic field orientation parallel to the crystalline c axis. The data can be interpreted in terms of the usual spin Hamiltonian, where the spectroscopic splitting factor g|| has the same value as at ambient pressures, but where the zero-field splitting deltaincreases in a linear fashion from 0.38 to 0.43 cm. The experimental apparatus has been described previously, although important improvements in the pressure seal and in the pressure calibration have been made and are described …

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Thermodynamics Of Metal-Ligand Interactions In Solution I. The Thermodynamics Of Metal-Cyanide Interaction ; Ii. Application Of The Entropy Titration Technique To Metal-Ligand Systems ; Iii. Log K, [Delta]H And [Delta]S Values For The Interaction Of Sulfate Ion With Metal Ions ; Iv. Interaction Of Mercuric Cyanide With Thiourea In Water-Ethanol Solvent Mixtures, Delbert J. Eatough Aug 1967

Thermodynamics Of Metal-Ligand Interactions In Solution I. The Thermodynamics Of Metal-Cyanide Interaction ; Ii. Application Of The Entropy Titration Technique To Metal-Ligand Systems ; Iii. Log K, [Delta]H And [Delta]S Values For The Interaction Of Sulfate Ion With Metal Ions ; Iv. Interaction Of Mercuric Cyanide With Thiourea In Water-Ethanol Solvent Mixtures, Delbert J. Eatough

Theses and Dissertations

Log K values, valid at zero ionic strength are reported for the interaction in aqueous solution of CN- with Ni2+ and Hg2+ at 10°, 25° and 40°C, and with Pd2+ at 25°C. ∆H° and ∆S° values valid at zero ionic strength and 25°C are also reported for the interaction of CN- with Hg2+ and for the reaction Pd(CN)42- + CN- = Pd(CN)53-. In connection with the study of Pd2+ - CN- interaction, log K values for the hydrolysis of Pd2+ to give PqOH+ and Pd(OH)2 and an E° value for the reaction Pd(s) = Pd2+ + 2e- are reported. A …

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Secondary Reactions And Partial Rate Factors In The Sulfonation Of Chlorobenzene And Toluene, Ernest Arthur Brown Aug 1967

Secondary Reactions And Partial Rate Factors In The Sulfonation Of Chlorobenzene And Toluene, Ernest Arthur Brown

Theses and Dissertations

The sulfonation of chlorobenzene, chlorobenzene-benzene, and toluene-benzene mixtures by sulfur trioxide in liquid sulfur dioxide at -12.5° C. was studied to obtain isomer distribution and relative rate data. The isomer distribution for the reaction on chlorobenzene was determined by an isotope dillution technique. Relative rate experiments were conducted by sulfonating C14 labeled benzene in competition with nonradioactive chlorobenzene and toluene and the count rate of the products was used to determine product composition. Ultraviolet spectrophotometry was also used to investigate variations in isomer distributions as a function of sulfur trioxide concentration. The apparent relative rates of sulfonation (kX/kB) as calculated …

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Equation Of State Of Sodium Chloride, Daniel L. Decker Dec 1966

Equation Of State Of Sodium Chloride, Daniel L. Decker

Faculty Publications

Because of many requests, I wish to publish the following numerical table of results for the equation of state of NaCl as calculated in an earlier paper1 along with a few comments on various proposed equations for NaCl. Table I gives the pressure in kilobars at the corresponding values of t.a/ao and temperature in the appropriate row and column. The parameter t.a/ao is the fractional compression of the lattice parameter where the standard value ao is the appropriate lattice parameter at zero pressure and 25°C. The increments between the values given in the table were chosen such that one can …

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Model Of Electron Correlation In Solids, Everett G. Larson, Walter R. Thorson Sep 1966

Model Of Electron Correlation In Solids, Everett G. Larson, Walter R. Thorson

Faculty Publications

The usual Hartree-Fock model (energy-band theory) does not always give an adequate description of electronic structure in a solid, because it ignores the effects of electron correlation. It was shown first by Wigner that such a situation always develops in an electron ''gas'' at sufficiently low density; a solid structure described by ''resonance'' of Heitler-London pair bonds between electrons localized on neighboring atoms is then a good model of the system.The transition from a Bloch-type state to such a highly correlated state as a function of electron density (lattice parameter) is a problem of considerable interest for the theory of …

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Pressure Calibration To 100 Kbar Based On The Compression Of Nacl, R. N. Jeffrey, J. Dean Barnett, H. B. Vanfleet, H. Tracy Hall Jul 1966

Pressure Calibration To 100 Kbar Based On The Compression Of Nacl, R. N. Jeffrey, J. Dean Barnett, H. B. Vanfleet, H. Tracy Hall

Faculty Publications

An independent determination has been made of the transformation pressures assigned to the high-pressure transformations in Ba and Bi which are generally used for calibration points. The metals were imbedded in NaCl, and the transitions were detected by the resistance change of the metal while the NaCl lattice parameter was simultaneously measured by x-ray diffraction. The NaCl compression values determined at the fixed points were related to pressure by reference to the semiempirical compression curve of Decker. The Ba I-II and Bi III-V transformations at room temperature were assigned thermodynamic equilibrium values of 53.3 ±1.2 kbar and 73.8 ±1.3 kbar, …

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