Physical Sciences and Mathematics Commons^™

Nuclear Structure Of 26si And 32cl For Astrophysics, Liudmyla Afanasieva

LSU Doctoral Dissertations

We studied the nuclear structure of two isotopes, 26Si and 32Cl, important for understanding stellar explosions like novae and Type I X-ray bursts. The 31S(p,γ)32Cl reaction rate influences the enrichment of sulfur observed in some nova ejecta, but the uncertainty in the rate spans as much as an order of magnitude and arises from uncertainties in the properties of resonances corresponding to excited states in 32Cl. We populated states in 32Cl via the 10B(24Mg,2n)32Cl reaction using the Argonne Tandem-Linac Accelerator System (ATLAS), with a 75 MeV beam of 24Mg bombarding a 200 μg/cm2 10B target. Gamma rays emitted from recoiling …

Seavipers - Computer Vision And Inertial Position Reference Sensor System (Cviprss), Justin Lee Erdman

LSU Doctoral Dissertations

This work describes the design and development of an optical, Computer Vision (CV) based sensor for use as a Position Reference System (PRS) in Dynamic Positioning (DP). Using a combination of robotics and CV techniques, the sensor provides range and heading information to a selected reference object. The proposed optical system is superior to existing ones because it does not depend upon special reflectors nor does it require a lengthy set-up time. This system, the Computer Vision and Inertial Position Reference Sensor System (CVIPRSS, pronounced \nickname), combines a laser rangefinder, infrared camera, and a pan--tilt unit with the robust TLD …

Nanoscale Gumbos: Size-Control, Characterization, And Applications As Enantioselective Molecularly Imprinted Polymers And Fluorescent Materials, Suzana Hamdan

LSU Doctoral Dissertations

Nanomaterials derived from a group of uniform materials based on organic salts (GUMBOS) have been introduced into the scientific literature through many analytical, biological, and technological applications. These nanomaterials, referred to as nanoGUMBOS, have been shown to display a number of interesting properties including fluorescence, magnetism, tumor targeting, and optoelectronic properties. Herein, we present major studies on nanoGUMBOS including synthesis and size-control, chiral molecular imprinting in polymers, as well as investigation of optical properties and quantum yield of fluorescent semiconductor-based nanoGUMBOS. Various strategies were introduced for production of well-defined nanoGUMBOS. Specifically, several methods based on sonochemistry, microwave, cyclodextrin, and surfactant-assisted …

Polycyclic Aromatic Hydrocarbons Dynamics In The Northern Gulf Of Mexico, Puspa Lal Adhikari

LSU Doctoral Dissertations

Polycyclic aromatic hydrocarbons (PAHs) are introduced into the marine environment via oil seeps/spills, riverine discharges, continental runoff, coastal erosion, and atmospheric deposition. An estimated 2.1 x 1010g of PAHs entered into the northern Gulf of Mexico (GOM) during the Deepwater Horizon (DWH) oil spill in 2010. It became evident following the oil spill that accurate quantification of ultimate fate of these potentially carcinogenic and/or mutagenic organic pollutants is extremely challenging. In general, very little is known about PAHs fate, distribution and accumulation in the open ocean ecosystems. This study determines the upper ocean vertical fluxes and sedimentary PAHs accumulation rates …

Computational Studies On Bimetallic Catalysis And X-Ray Absorption Spectroscopy, Sayakkarage R. G. Fernando

LSU Doctoral Dissertations

Computational studies are very important to gain an insight into reaction mechanisms and in interpreting and understanding complicated experimental observations. This report contains a discussion on computational studies performed on bimetallic catalysis and on X-ray absorption spectroscopy of insulators. The viability of a bimetallic rhodium and cobalt catalysts for industrially important hydroformylation and aldehyde-water shift catalysis (AWS) is discussed. Density functional theory (DFT) studies were used for bimetallic catalysis and time-dependent DFT studies were used for excited state dynamics. These studies were performed using Gaussian 09 package and NWChem. Hydroformylation is experimentally performed in acetone and 30% water/acetone systems and …

Wavelets, Coorbit Theory, And Projective Representations, Amer Hasan Darweesh

LSU Doctoral Dissertations

Banach spaces of functions, or more generally, of distributions are one of the main topics in analysis. In this thesis, we present an abstract framework for construction of invariant Banach function spaces from projective group representations. Coorbit theory gives a unified method to construct invariant Banach function spaces via representations of Lie groups. This theory was introduced by \Fch\, and \Gro\, in \cite{FG,FG1, FG2,FG3} and then extended in \cite{CO2}. We generalize this concept by constructing coorbit spaces using projective representation which is first studied by O. Christensen in \cite{O1}. This allows us to describe wider classes of function spaces as …

The Electronic Structure Of Environmentally Persistent Free Radicals Formed On Metal Oxide Surfaces, Chad Allen Thibodeaux

LSU Doctoral Dissertations

We have investigated the electronic structure of environmentally persistent free radicals (EPFRs) formed on two different metal oxides: Cu(II)O and ZnO. Cu(II)O is known to be one of the most active metal oxides to form EPFRs. ZnO, however, forms the longest-lived EPFRs. First, we examined the adsorption of phenol on different crystal faces of ZnO. Ultraviolet photoelectron spectroscopy (UPS) shows direct evidence of charge transfer away from the ZnO to the phenol. This differs from the hypothesized mechanism of EPFR formation that says that an electron is transferred to the metal oxide. UPS difference spectra also shows that the phenol …

Towards The Realization Of Systematic, Self-Consistent Typical Medium Theory For Interacting Disordered Systems, Chinedu Ekuma Ekuma

LSU Doctoral Dissertations

This work is devoted to the development of a systematic method for studying electron localization. The developed method is Typical Medium Dynamical Cluster Approximation (TMDCA) using the Anderson-Hubbard model. The TMDCA incorporates non-local correlations beyond the local typical environment in a self-consistent way utilizing the momentum resolved typical-density-of-states and the non-local hybridization function to characterize the localization transition. For the (non-interacting) Anderson model, I show that the TMDCA provides a proper description of the Anderson localization transition in one, two, and three dimensions. In three-dimensions, as a function of cluster size, the TMDCA systematically recovers the re-entrance behavior of the …

On The Development Of Analytical Methodologies To Interrogate The Lipid Dynamics And Phase Transition Resulting From The Reduction Of Stimuli-Responsive Vesicles, James Edward Winter

LSU Doctoral Dissertations

The potential is great for liposome drug delivery systems that provide specific contents release at diseased tissue sites upon activation by upregulated enzymes; however, this potential will only come to fruition with mechanistic knowledge of the contents release process. NAD(P)H:quinone oxidoreductase type 1 (NQO1) is a target for reductively-responsive liposomes, as it is an enzyme upregulated in numerous cancer tissues and is capable of reducing quinone propionic acid (QPA) trigger groups to hydroquinones that self-cleave from dioleolylphosphatidylethanolamine (DOPE) liposome surfaces, thereby initiating contents release. This research targets the development of analytical methodologies to observe and characterize the dynamics and resulting …

Rényi Quantum Conditional Mutual Information And Parity Quantum Optical Metrology, Kaushik Parasuram Seshadreesan

LSU Doctoral Dissertations

This is a two-part thesis strung together by a common underlying theme—quantum correlations. We present some new characterizations and quantifications of quantum correlations and an application of one such correlation—entanglement—for quantum technology.

In Part I of the thesis, we use a Rényi generalization of the quantum conditional mutual information (QCMI) to define and study new measures of quantum entanglement and quantum discord. In particular, using a quantity derived from a Rényi QCMI, we introduce: a) the geometric squashed entanglement, a faithful entanglement measure, which is a lower bound on the squashed entanglement and which reduces to the geometric measure of …

Synthesis With Hypergraphs, Christopher Thomas Alvin

LSU Doctoral Dissertations

Many problems related to synthesis with intelligent tutoring may be phrased as program synthesis problems using AI-style search and formal reasoning techniques. The _x000C_first two results in this dissertation focus on problem synthesis as an aspect of intelligent tutoring systems applied to STEM-based education frameworks, specifically high school geometry. Given a geometric _x000C_figure as input, our technique constructs a hypergraph representing logical deduction of facts, and then traverses the hypergraph to synthesize problems and their corresponding solutions. Using similar techniques, our third result is focused on exhaustive synthesis of molecules. This synthesis process involves bonding sets of basic, molecular `fragments' …

Site-Specific Habitat And Landscape Associations Of Rusty Blackbirds Wintering In Louisiana, Sinead Mary Borchert

LSU Master's Theses

The Rusty Blackbird (Euphagus carolinus) has gained notoriety in recent years as one of the fastest declining North American bird species, with a global population loss of as much as 95%. Causes of the decline are not completely understood, but the high rate of forested wetland change in the southeastern United States suggests that wintering habitat degradation may be a primary driver. To better inform management on critical wintering grounds, I surveyed 68 sites in Louisiana where Rusty Blackbirds had been known to occur to address how occupancy changes with habitat type and colonization and extinction rates vary with ground …

Forest Stakeholders, Policies And Trade In India's Forest Sector, Joy Das

LSU Master's Theses

The thesis examines a panel of trade flows during 2009-2013, exploring the influence of regulatory quality on the pattern of forest products imports by India from 143 partner countries. The study applies a pooled regression model followed by Generalized Least Squared (GLS) technique and a more robust Feasible Generalized Least Squared (FGLS) method of estimation with regulatory quality, distance between the partner country and India, total forest area of partner country, GDP and population indicators to assess the impact of partner country’s regulatory quality and other trade-related factors on imports of forest products by India. The results support the notion …

Pattern Mining And Events Discovery In Molecular Dynamics Simulations Data, Shobhit Sandesh Shakya

LSU Doctoral Dissertations

Molecular dynamics simulation method is widely used to calculate and understand a wide range of properties of materials. A lot of research efforts have been focused on simulation techniques but relatively fewer works are done on methods for analyzing the simulation results. Large-scale simulations usually generate massive amounts of data, which make manual analysis infeasible, particularly when it is necessary to look into the details of the simulation results. In this dissertation, we propose a system that uses computational method to automatically perform analysis of simulation data, which represent atomic position-time series. The system identifies, in an automated fashion, the …

Classification In The Presence Of Ordered Classes And Weighted Evaluative Attributes, Forrest Justin Osterman

LSU Doctoral Dissertations

We are interested in an important family of problems in the interface of the Multi-Attribute Decision-Making and Data Mining fields. This is a special case of the general classification problem, in which records describing entities of interest have been expressed in terms of a number of evaluative attributes. These attributes are associated with weights of importance, and both the data and the classes are ordinal. Our goal is to use historical records and the corresponding decisions to best estimate the class values of new data points in a way consistent with prior classification decisions, without knowledge of the weights of …

Effects Of Inbreeding On Endangered Red Wolves (Canis Rufus), Kristin E. Brzeski

LSU Doctoral Dissertations

Inbreeding depression, the reduction in offspring fitness caused by mating among close relatives, is widespread in small populations and a major concern in conservation biology because it can affect population persistence. The negative effects of inbreeding results in the evolution of inbreeding avoidance behaviors; within small populations, such behaviors may encourage individuals to select mates outside of their respective species. Mate choice may also be facilitated by variation at major histocompatibility complex (MHC) genes, a gene group critical for immune response and disease resistance. Given broad impacts of inbreeding and MHC variation on fitness and behavior, evaluating their effects is …

A Trust-Based Relay Selection Approach To The Multi-Hop Network Formation Problem In Cognitive Radio Networks, Brandy Michelle Tyson

LSU Doctoral Dissertations

One of the major challenges for today’s wireless communications is to meet the growing demand for supporting an increasing diversity of wireless applications with limited spectrum resource. In cooperative communications and networking, users share resources and collaborate in a distributed approach, similar to entities of active social groups in self organizational communities. Users’ information may be shared by the user and also by the cooperative users, in distributed transmission. Cooperative communications and networking is a fairly new communication paradigm that promises significant capacity and multiplexing gain increase in wireless networks. This research will provide a cooperative relay selection framework that …

Development Of Transition Metal-Catalyzed Polymerization Reactions And Their Applications For The Preparation Of Well-Defined Conjugated Polymer Architectures, Carlos Anthony Chavez

LSU Doctoral Dissertations

The synthesis of conjugated polymers and design of complex materials based on them have become increasingly popular as the demand for low-cost efficient and processible optoelectronic and semiconducting devices escalates. While advanced applications of polymeric materials require some degree of sophistication, success can be achieved through careful consideration of polymerization techniques and methodologies. Controlling critical aspects of the polymerization process allows for synthesis of complex macromolecular architectures possessing unique and novel properties that may be worth of further comprehensive investigation. This dissertation primarily focuses on the development and preparation of well-defined hierarchical macromolecular architectures. The foundation of this work encompasses …

Exploring Superconductivity In Chiral Structured Aube, Drew Jared Rebar

LSU Doctoral Dissertations

AuBe is a noncentrosymmetric superconductor with the B20 FeSi-type structure. Noncentrosymmetric superconductors are expected to give rise to unconventional superconductivity due to spin orbit coupling and a mixed spin-singlet, spin-triplet state. The B20 structure of AuBe is particularly interesting since this is one of the only known crystal structures for bulk magnetic skyrmions in materials such as MnSi and Cu2OSeO3. The superconducting state was characterized by specific heat, dc magnetization, ac susceptibility, and resistivity. Specific heat revealed AuBe to host an isotropic gap characteristic of predominantly s-wave spin-singlet pairing in the weak coupling limit. Magnetization and susceptibility measurements revealed a …

Optimized Aperiodic Multilayer Structures For Absorbers And Thermal Emitters, Christopher H. Granier

LSU Doctoral Dissertations

In this dissertation, we begin with a brief introduction to nanophotonics. In particular, we will focus on the theory of computational electricity and magnetism, specifically, the method used for this research, the transfer-matrix method. We will also provide discussions of the principles which motivate the analysis of the multilayer structures: Planck's blackbody distribution, Kirchoff's law, and thermodynamics. Finally, we will provide a brief discussion of computer-based optimization algorithms, specifically NLOPT (a library which provides computational packages for nonlinear optimization) and genetic algorithms. This background information is necessary to understand discussions which occur in later chapters.

Chapter 2 will discuss multilayer …

Single Molecule Electrophoresis And Optical Detection Using Thermoplastic Nanofluidic Devices: An Experimental And Simulation Study, Kumuditha Madushanka Weerakoon Ratnayake

LSU Doctoral Dissertations

Nanofludic devices provide a great platform for single molecular analysis. The unique phenomena in nanoscale gained such interest in investigating the single molecular behavior in nanochannels. Sizes less than 200 nm in one or two-dimensional structures have lead to fascinating observations not accessible in microscale. When a single molecule translocates through a nanotube it interacts with channel walls by adsorption/ desorption, van der Waals interactions and hydrophilic interactions providing a mechanism for separation without any extra additives. Moreover, double layer thickness governed by the background electrolyte plays a vital role. We report single molecular electrophoresis phenomena in nanochannels and nanoslits …

The Stratal Architecture Of The False River Point Bar (Lower Mississippi River, La), Alexandra Lechnowskyj

LSU Master's Theses

The False River point bar system is located roughly thirty miles north of Baton Rouge, LA. It is an oxbow lake cut off from the Mississippi River, and represents a large-scale modern analogue to the ancient systems of northeastern Alberta, Canada, specifically those of the Athabasca Oils Sands. While previous work has been done regarding the general architecture of a point bar, there is still omplexity associated with larger scale systems, as studies have been mostly based on small and medium-scale examples. Examination of the point bar was done through a combination of coring and geophysical logging, followed by software …

Shape Optimization For Drag Minimization Using The Navier-Stokes Equation, Chukwudi Paul Chukwudozie

LSU Master's Theses

Fluid drag is a force that opposes relative motion between fluid layers or between solids and surrounding fluids. For a stationary solid in a moving fluid, it is the amount of force necessary to keep the object stationary in the moving fluid. In addition to fluid and flow conditions, pressure drag on a solid object is dependent on the size and shape of the object. The aim of this project is to compute the shape of a stationary 2D object of size 3.5 m2 that minimizes drag for different Reynolds numbers. We solve the problem in the context of shape …

Using Fault Kinematics To Evaluate The Relationship Between Cenozoic Fault Activity, Sedimentation Rates And Salt Movement In The Gulf Of Mexico - A Comparison Between Southwest Louisiana And Southeast Louisiana, Abah Philip Omale

LSU Master's Theses

ABSTRACT Fault initiation and reactivation across south Louisiana during the Cenozoic was driven by either clastic sediment progradation mobilizing underlying salt or by sediment progradation inducing tensional bending stresses during lithospheric flexure. Climate and tectonics within the North American continent during the Cenozoic created differences in the source location, amount of sediments transported, as well as the spatial and temporal distribution of sediments transported into the Gulf of Mexico. This study analyzes 140 fault intercepts along 11 regional cross sections containing well log data in south Louisiana. Cumulative throw, incremental throw, and fault slip rates indicate fault activity punctuated by …

Dosimetric Advantages Of Personalized Phantoms For Quality Assurance And Research In Radiation Dose Measurements, Andrew Michael Halloran

LSU Master's Theses

Background: Phantoms have been in use in medical and health physics for decades, serving as a surrogate for human tissue in several different applications. In radiation dose measurements, anthropomorphic phantoms are designed with tissue substitute materials to mimic both the elemental compositions and anatomical structures of the human body. In some cases the performance of anthropomorphic phantoms for personalized measurements is severely limited by the use of reference anatomy in the geometric design. 3D printing could potentially be used to overcome some of these shortcomings by enabling rapid fabrication of personalized phantoms for individual patients based on radiographic imaging data. …

Comparison Of 3d And 4d Cbct For The Localization Of Moving Targets, Runyon Colie Woods

LSU Master's Theses

Purpose: Compare the localization accuracy of 3D cone beam computed tomography (CBCT) and 4D CBCT for a dynamic respiratory phantom, considering cases with and without respiratory variations between planning and treatment. Methods and Materials: A respiratory phantom was imaged using 3D CBCT and 4D CBCT. Measurements of the amplitude of motion in 3D CBCT and 4D CBCT and size of the sphere at its exhale position in 4D CBCT were acquired. The phantom was then misaligned by known distances relative to a reference position. 3D CBCT and 4D CBCT were used to re-align the phantom by comparing localization images to …

Neodymium Isotope Ratios And A Positive Δ13c Excursion: Connecting Oceanographic And Climate Changes Near The M4-M5 Sequence Boundary Of The Late Ordovician, Zachary Wright

LSU Master's Theses

A significant positive carbon isotope excursion first described from the Guttenberg Member of the Decorah Formation in Iowa called the GICE is a defining feature of Late Ordovician chemostratigraphy. It occurs near the M4-M5 sequence boundary of the Late Ordovician and has been correlated across the globe using prominent K-bentonite ash beds and conodont biomarkers. The cause of the GICE has been debated, with some arguing that it represents the initiation of a glacial period in a greenhouse climate 10 Ma before the end Ordovician glaciation and extinction. A variety of cooling signals have been identified across the M4-M5 sequence …

The Influence Of Marine Topography On The Antarctic Ice Sheet, Daniel Michael Mullally Jr

LSU Master's Theses

The primary controls on Antarctic Ice Sheet (AIS) volume and extent include changes in water temperature, precipitation, atmospheric temperature, and sea level. Here we evaluate the influence of a 5th control, the depth of the continental shelf. Shelf depth affects ice sheet mass balance in the marine environment by controlling the flux of ice that can be exported to the marine environment. This is significant because heat exchange between ocean and ice sheet have been demonstrated to be a dominant control on marine ice volume (Pollard and DeConto, 2009). We used the Parallel Ice Sheet Model (PISM) to simulate AIS …

Potential For Geothermal Energy In Northern Louisiana: Analysis Of The Subsurface Environment In Union And Morehouse Parishes, Tessa Shizuko Hermes

LSU Master's Theses

Efforts to mitigate greenhouse gas emissions and reduce dependence on fossil fuels have led to renewed focus on the exploration and development of alternative energy production. One such option is hydrothermal binary geothermal energy production from geothermal reservoirs with temperatures of at least 100 °C at depths no greater than 5 km. In the U.S., such systems have the potential to provide 5,400 % of 2013 total U.S. energy consumption. This study evaluates the potential for geothermal energy systems implementation in Morehouse and Union Parishes, Louisiana, by using publicly available bottom hole temperature (BHT), mud weight (MW), logged formation top …

Effect Of The Herbicide Atrazine On Phytoplankton, Water Quality, And Ecosystem Functions In Louisiana Estuaries, Alexis Victoria Starr

LSU Master's Theses

Pesticides are used primarily for agricultural purposes in the US and while these chemicals provide many benefits, the inherent toxicity of the compounds pose a substantial risk to the environment. These chemicals may enter water bodies in areas with a high proportion of agricultural land use through surface run off, ground water discharge, and erosion, and negatively impact non-target aquatic organisms. As a result, Louisiana’s estuaries may be vulnerable to a variety of compounds, including the herbicide atrazine. Atrazine is used extensively throughout the Midwest and has been known to enter the Mississippi River through surface runoff and ground water …