Physical Sciences and Mathematics Commons^™

Pyrene Pyrimidine Derivatives: Synthesis, Characterization And Applications, John Kihara Mathaga

LSU Master's Theses

In this thesis, development of new materials to the field of optoelectronics were studied. Optoelectronic devices based on organic semiconductors in order to replace their inorganic counterparts have been an increasing focus of research in recent decades. Organic light-emitting diodes (OLEDs) have gained commercial acceptance for their potential use in high-resolution displays and solid-state lighting. This general acceptance is despite the fact that organic electronic concepts (solar cells, transistors and detectors) are still in an early stage of development. OLEDs materials intrinsic advantages, like low power consumption as compared to LED counterparts, a tunable color range, ease of manufacturing, and …

Evolution Of Computational Thinking Contextualized In A Teacher-Student Collaborative Learning Environment., John Arthur Underwood

LSU Doctoral Dissertations

The discussion of Computational Thinking as a pedagogical concept is now essential as it has found itself integrated into the core science disciplines with its inclusion in all of the Next Generation Science Standards (NGSS, 2018). The need for a practical and functional definition for teacher practitioners is a driving point for many recent research endeavors. Across the United States school systems are currently seeking new methods for expanding their students’ ability to analytically think and to employee real-world problem-solving strategies (Hopson, Simms, and Knezek, 2001). The need for STEM trained individuals crosses both the vocational certified and college degreed …

Synthesis, Characterization, And Investigation Of Metal Ion Quenching In Fluorescent Carbon Dot Surrogates For Particulate Matter Black Carbon And Evaluation Of Cellular Health Effects Due To The Surrogate Materials, Christopher Lee Sumner Jr

LSU Doctoral Dissertations

Black carbon (BC) is an environmental pollutant of particular concern to many international organizations for both its health effects and environmental effects. Probing health effects of BC as produced in the environment is difficult due to the complex nature of environmental pollutants found in their naturally occurring state. Fluorescent carbon dots (FCDs) were chosen to be used as a surrogate for BC. In the process of examining FCDs and their behavior as surrogates, information was gained on the health effects and behavior of FCDs as a class of nanomaterials for cell and tissue studies, which is outlined in this dissertation. …

Predictive Modeling Of Asynchronous Event Sequence Data, Jin Shang

LSU Doctoral Dissertations

Large volumes of temporal event data, such as online check-ins and electronic records of hospital admissions, are becoming increasingly available in a wide variety of applications including healthcare analytics, smart cities, and social network analysis. Those temporal events are often asynchronous, interdependent, and exhibiting self-exciting properties. For example, in the patient's diagnosis events, the elevated risk exists for a patient that has been recently at risk. Machine learning that leverages event sequence data can improve the prediction accuracy of future events and provide valuable services. For example, in e-commerce and network traffic diagnosis, the analysis of user activities can be …

Combinatorial And Asymptotic Statistical Properties Of Partitions And Unimodal Sequences, Walter Mcfarland Bridges

LSU Doctoral Dissertations

Our main results are asymptotic zero-one laws satisfied by the diagrams of unimodal sequences of positive integers. These diagrams consist of columns of squares in the plane; the upper boundary is called the shape. For various types of unimodal sequences, we show that, as the number of squares tends to infinity, 100% of shapes are near a certain curve---that is, there is a single limit shape. Similar phenomena have been well-studied for integer partitions, but several technical difficulties arise in the extension of such asymptotic statistical laws to unimodal sequences. We develop a widely applicable method for obtaining these limit …

New Synthetic Transformations Utilizing Silyloxyallyl Cations And Epoxonium Ions As Reactive Intermediates, Alexander Houston Cleveland

LSU Doctoral Dissertations

The development of new chemical transformations is of paramount importance in organic chemistry. In fact the study and creation of new reactions often uncovers new chemical reactivities and creates a new area of chemistry. The purpose of this dissertation is to present the development of new synthetic reactions that were uncovered through previous discoveries. Additionally the underlying theme of this work relies on the intermediacy of cationic reactive intermediates such as silyloxyallyl cations and epoxonium ions. Chapters 1 and 2 present the reactivity of novel silyloxyallyl cations. These cationic species are generated via the mild ionization of a-hydroxy silylenol ethers …

Behavior Of Iron Species And Free Radicals In Ambient Pm2.5 And Pm Surrogates, Cholena Russo Ren

LSU Doctoral Dissertations

Air pollution, consisting of ambient particulate matter (PM), has been a rising health concern to the public. PM contains free radicals and have been known to damage human cells; however, their free radical chemistry is not well understood. This study utilized various vacuum and/or heat treatments to study free radical behavior in PM_2.5 (particulate matter with an aerodynamic diameter of 2.5 mm or less) and PM surrogates and simulated sunlight effects on PM_2.5. To mimic PM, iron-silica catalysts (i.e. PM surrogates) were synthesized and real-world ambient PM_2.5 was selected. The free radicals in PM_{2.5 …}

Legendrian Dga Representations And The Colored Kauffman Polynomial, Justin Murray, Dan Rutherford

Faculty Publications

For any Legendrian knot K in standard contact R-3 we relate counts of ungraded (1-graded) representations of the Legendrian contact homology DG-algebra (A(K), partial derivative) with the n-colored Kauffman polynomial. To do this, we introduce an ungraded n-colored ru-ling polynomial, R-n,K(1)(q), as a linear combination of reduced ruling polynomials of positive permutation braids and show that (i) R-n,K(1)(q) arises as a specialization F-n,F-K(a, q)vertical bar(a-1) = 0 of the n-colored Kauffman polynomial and (ii) when q is a power of two R-n,K(1)(q) agrees with the total ungraded representation number, Rep(1) (K, F-q(n)), which is a normalized count of n-dimensional representations …

3d-Printed Structured-Illumination Neutron Optics For Phase Contrast Imaging With A Triga Neutron Source, Bridget Cadigan

Honors Theses

No abstract provided.

Information Retrieval-Based Optimization Approaches For Requirement Traceability Recovery, Danissa Victoria Rodriguez Caraballo

LSU Doctoral Dissertations

Requirements traceability provides support for important software engineering activities. Requirements traceability recovery (RTR) is becoming increasingly important due to the numerous benefits to the overall quality of software. Improving the RTR problem has become an active topic of research for software engineers; researchers have proposed a number of approaches for improving and automating RTR across the requirements and the source code of the system. Textual analysis and Information Retrieval (IR) techniques have been applied to the RTR problem for many years; however, most of the existing IR-based methodologies applied to the RTR problem are semiautomatic or time-consuming, even though many …

Accurate Tracking Of Position And Dose During Vmat Based On Vmat-Ct, Xiaodong Zhao

LSU Doctoral Dissertations

Purpose: Local tomography reconstruction is achievable with EPID images acquired during VMAT and was named as VMAT-CT. However, it did not gain popularity due to multiple limitations and technical challenges. The goal of this study was to extend VMAT-CT concept, generate complete 3D or 4D CT images and dose, track and adapt VMAT plan based on updated images and dose.

Methods: We considered collimator angle and removed blurred areas in EPID images for VMAT-CT reconstruction to reduce artifacts and improve image quality. VMAT-CT+ images were generated by fusing VMAT-CT and planning CT using rigid or deformable registration. For 4D SBRT …

On Characterizing Quantum Processes And Detectors, Kevin Valson Jacob

LSU Doctoral Dissertations

In 2009, physicists at the National Institute of Standards and Technology in Colorado, Boulder developed what could arguable be called the first rudimentary quantum computer [1]. The past decade has seen unprecedented improvements in quantum information science culminating in the demonstration of quantum supremacy --- that quantum computers can solve problems that are impractical to be solved on the best supercomputers [2]. This remarkable progress necessitates the development of techniques to characterize the quantum devices that are being developed. In my thesis, I will focus on such devices that manipulate and detect light.

In Chapter 1, I will introduce the …

The Siltcatcher: A Sediment-Capture System For Wetland Creation And Coastal Protection In Western Lake Pontchartrain, Andrew M. Wright

LSU Master's Theses

The West Lake Pontchartrain region faces a number of long-term environmental challenges due to anthropogenic climate disturbance and landscape modification, including sea level rise, increased storm surge risk, shoreline erosion, and wetland degradation. In response, this thesis applies recent research in the fields of landscape architecture and civil engineering to propose a dynamic, natural-systems solution for wetland creation and shoreline protection. The project envisions a series of breakwater-like structures in western Lake Pontchartrain positioned to slow water released from the nearby Bonnet Carré Spillway, causing suspended sediment to settle and create self-building and self-sustaining wetlands capable of keeping pace with …

Physical And Biological Factors Controlling The Fate Of Nitrate In A Louisiana Coastal Deltaic Floodplain, Alexandra Christensen

LSU Doctoral Dissertations

The Mississippi River Delta is threatened by a growing pressure to support large human populations in the United States both with food production, navigation systems, and urban development in the Mississippi River Basin. Nitrate-nitrogen load in the Mississippi River, up to 100 Tg N yr^-1 from agricultural and urban runoff, leads to phytoplankton blooms and hypoxia across the Louisiana continental shelf, creating dead zones of low dissolved oxygen threatening a significant commercial fishery. Along the coast and river corridors, floodplain ecosystems have the capacity to retain and remove nitrate. This dissertation explores the role of productive, actively growing coastal …

An Atmospheric And Spatiotemporal Examination Of Lightning-Initiated Terrestrial Gamma-Ray Flashes Detected By The Fermi Satellite And Tetra Ii, Deirdre Colleen Smith

LSU Doctoral Dissertations

Terrestrial Gamma-ray Flashes (TGFs) are sub-millisecond bursts of the highest naturally occurring light-energy found within Earth’s atmosphere. TGFs are associated with the electric fields produced in thunderstorms and are geolocated by coincident sferics from lightning strokes. Though billions of lightning strokes occur globally each year, fewer than 1,000 TGFs are detected via satellite and ground-based sensors and only a small fraction are geolocated via sferics.

To date, few studies have focused on individual thunderstorms and climates that produce TGFs. This dissertation examines TGFs from two differing data samples: 1) NASA's Fermi Gamma-Ray Burst Monitor (2013-2018) and 2) The TGF and …

The Long-Term Outlook Of The Mississippi-Atchafalaya Bifurcation: A Convergence Of Engineering, Economics, And Deltaic Evolution, Thomas Mitchell Andrus

LSU Doctoral Dissertations

The most recent and currently active delta lobe of the Mississippi River (MR) is the Atchafalaya-Wax Lake lobe, which was initiated approximately 400 years ago as a result of MR stream capture by the Atchafalaya River (AR). This capture process accelerated in the early to mid-1900s but further progress was prevented by construction and operation of the Old River Control Structure (ORCS) Complex. Many recent studies indicate that MR system below the ORCS is on a retreating geologic trajectory due to contributing factors such as sea level rise, subsidence, faulting, and declining hydraulic stream power. Diversions along the Lower MR …

An Ecopath With Ecosim Analysis On Offshore Petroleum Platform Influences On Gulf Of Mexico Red Snapper, Valentin Gomez

LSU Master's Theses

Offshore oil and gas platforms have had a significant presence in the Gulf of Mexico since the 1950s. An important secondary function of these structures is that they provide artificial habitat to fisheries, most notably Red snapper. Policy changes intended to reduce the risk associated with aging infrastructure have reduced the number of standing platforms from 4044 to 1867 from 2001 to 2018. The effect this loss of habitat has on Red snapper was tested by creating three scenarios of platform changes and modeling the perturbation from 2005 to 2050. The simulation was accomplished using the ecological model Ecopath with …

Limitations On Protecting Information Against Quantum Adversaries, Eneet Kaur

LSU Doctoral Dissertations

The aim of this thesis is to understand the fundamental limitations on secret key distillation in various settings of quantum key distribution. We first consider quantum steering, which is a resource for one-sided device-independent quantum key distribution. We introduce a conditional mutual information based quantifier for quantum steering, which we call intrinsic steerability. Next, we consider quantum non-locality, which is a resource for device-independent quantum key distribution. In this context, we introduce a quantifier, intrinsic non-locality, which is a monotone in the resource theory of Bell non-locality. Both these quantities are inspired by intrinsic information and squashed entanglement and are …

X-Ray Interferometry Without Analyzer For Breast Ct Application, A Simulation Study, Jingzhu Xu

LSU Doctoral Dissertations

We investigated a novel analyzer-less X-ray interferometer with a spatially modulated phase-grating (MPG) which produces three types of images (attenuation image, phase image and scatter image) for Breast computed tomography (CT). The system provides the three complimentary X-ray images with the goals of limiting the dose to the object and achieving similar attenuation image sensitivity as a standard absorption-only Breast CT. The MPG system features an X-ray source, a source-grating, a single phase-grating, and a detector. No analyzer grating is necessary, compared to other geometries such as Talbot-Lau X-ray interferometry (TLXI). Thus, there is a ~2 times improvement in X-ray …

Biogeography Of Biological Control: Spatial Variation In Agent-Host Interactions, Nathan Harms

LSU Doctoral Dissertations

Management of plant invasions using biological control has the potential to generate spatial patterns which reflect geographic or genetic variation in invader or control agents. Despite its rarity in practice, investigations into the biogeography of interacting species (i.e., plant invader and control agent) in the context of biological control can lend insights into species distribution-abundance patterns and provide predictions for spatial variation in control success. I explored spatial variability in biological control agent-plant interactions using two wetland weed study systems with large geographic distributions: flowering rush (Butomus umbellatus L.) and alligatorweed (Alternanthera philoxeroides (Mart.) Griseb). Through literature and …

Evaluation Of Neutron Skyshine Contributions During Injection At An Electron Synchrotron Facility Using Fluka, Andrew D. Hastings

LSU Master's Theses

The Center for Advanced Microstructures and Devices (CAMD) is a 1.5 giga-electron volt (GeV) electron synchrotron research facility under the jurisdiction of Louisiana State University (LSU). When originally constructed in 1992, CAMD was surrounded by pasture and woodland. Over the past several years, urban development of the area has found CAMD bracketed by a shopping center, apartment complex, and business offices. These developments raised concerns amongst the CAMD radiation safety personnel regarding an increased potential for public exposure to radiation. To ensure compliance with the annual public effective dose equivalent limit of 1 milli-sievert (mSv), the radiation monitoring program was …

Applications And Implementation Of A Satellite-Based Quantum Internet, Renèe Desporte

Honors Theses

No abstract provided.

Noise Resilience Of Variational Quantum Compiling, Kunal Sharma, Sumeet Khatri2, M. Cerezo, Patrick J. Coles

Faculty Publications

Variational hybrid quantum-classical algorithms (VHQCAs) are near-term algorithms that leverage classical optimization to minimize a cost function, which is efficiently evaluated on a quantum computer. Recently VHQCAs have been proposed for quantum compiling, where a target unitary U is compiled into a short-depth gate sequence V. In this work, we report on a surprising form of noise resilience for these algorithms. Namely, we find one often learns the correct gate sequence V (i.e. the correct variational parameters) despite various sources of incoherent noise acting during the cost-evaluation circuit. Our main results are rigorous theorems stating that the optimal variational parameters …

Comprehensive Investigation Of Radiation Techniques For Whole Breast And Post-Mastectomy Irradiations, Yibo Xie

LSU Doctoral Dissertations

Purpose: The purpose of this dissertation is to compare treatment outcomes and cost-effectiveness of various radiotherapy techniques for post-mastectomy radiotherapy (PMRT) and whole breast radiotherapy (WBRT) patients.

Methods: Treatment planning comparison of standard volumetric modulated arc therapy (STD-VMAT), multiple arc VMAT (MA-VMAT), non-coplanar VMAT (NC-VMAT), intensity modulated radiotherapy (IMRT), helical tomotherapy (HT), mixed beam therapy and proton therapy was performed for 9 PMRT patients, and cost-effectiveness of those PMRT techniques compared to standard of care (SOC) were evaluated using a Markov model. Treatment planning comparison of SOC, field-in-field (FIF), hybrid IMRT, full IMRT, STD-VMAT, MA-VMAT and NC-VMAT was performed …

Vegetation Prior To And During Onset Of East Antarctic Glaciation: High Resolution Palynological Insights From Sabrina Coast, East Antarctica, Meghan L. Duffy

LSU Master's Theses

The Aurora Subglacial Basin (ASB) contains an estimated 3.5 m of global sea-level equivalent ice volume and is primarily drained by the Totten Glacier system, which terminates at the Sabrina Coast, East Antarctica. Thinning and retreating of the Totten Glacier indicate that this region is highly susceptible to oceanographic and atmospheric warming. The paleoclimate reconstruction of these changes, conducted in the context of this MS thesis, will improve understanding of East Antarctic Ice Sheet (EAIS) dynamics in this sensitive system. A recent study used seismic and sediment core data to document a dynamic early evolution of the EAIS in the …

Dissipation Of Benzobicyclon And Benzobicyclon Hydrolysate In A Louisiana Rice Field, Xavier Poole

LSU Master's Theses

Pesticide resistance in rice fields is an ongoing issue that has resulted in the development and use of pesticides with new modes of action. Benzobicyclon is the first registered hydroxyphenylpyruvate(HPPD)-inhibiting pesticide in the United States and has gained attention as a resistance management strategy to control weed pests in rice fields. Understanding the environmental fate and dissipation mechanisms of benzobicyclon is important due to the unique rotation of rice and crayfish in Louisiana on the same fields. Benzobicyclon persistence into the crayfish growing seasons may lead to unintended consequences for crayfish growth and production, assuming there is toxicity to crawfish. …

Novel Photon-Detector Models For Enhanced Quantum Information Processing, Elisha Siddiqui

LSU Doctoral Dissertations

This work is devoted to the development of novel photon-detector models at room temperature using quantum optics elements. This work comprises of two photon-number-resolving detector (PNRD) models, and the application of PNRD in LIDAR. The first model is based on using a two-mode squeezing device to resolve photon number at room temperature. In this model we study the average intensity-intensity correlations signal at the output of a two-mode squeezing device with |N> and |α> as the two input modes. We show that the input photon-number can be resolved from the average intensity-intensity correlations. In particular, we show jumps in the …

Investigation Of Complex Magnetic Phenomena In Spinel Femn2o4, Mnfe2o4, And Nife2o4, Roshan Kumar Nepal

LSU Doctoral Dissertations

Frustrated magnetic systems, where all spin interactions cannot be simultaneously satisfied, have continued to attract interest due to a plethora of novel magnetic states that emerge in them due to frustration and their potential technological applications. Spinel oxides AB₂O₄, where A and B are metal ions) are an excellent testing ground for the exploration of frustrated magnetism. This dissertation presents the experimental investigation of complex magnetic phenomena in the spinel oxides FeMn₂O₄, MnFe₂O₄, and NiFe₂O₄.

FeMn₂O₄ and MnFe₂O_{4 …}

On Selected Subclasses Of Matroids, Tara Elizabeth Fife

LSU Doctoral Dissertations

Matroids were introduced by Whitney to provide an abstract notion of independence.

In this work, after giving a brief survey of matroid theory, we describe structural results for various classes of matroids. A connected matroid $M$ is unbreakable if, for each of its flats $F$, the matroid $M/F$ is connected%or, equivalently, if $M^*$ has no two skew circuits. . Pfeil showed that a simple graphic matroid $M(G)$ is unbreakable exactly when $G$ is either a cycle or a complete graph. We extend this result to describe which graphs are the underlying graphs of unbreakable frame matroids. A laminar family is …

Phytoplankton And Carbon Dynamics In The Estuarine-Coastal Waters Of The Northern Gulf Of Mexico From Field Data And Ocean Color Remote Sensing, Bingqing Liu

LSU Doctoral Dissertations

In this study, phytoplankton community and carbon dynamics were examined in the optically complex estuarine-coastal regions of the northern Gulf of Mexico (nGOM) from field and satellite ocean color observations. As part of this study, bio-optical ocean color algorithms for i) dissolved organic carbon (DOC), ii) phytoplankton pigment composition, iii) adaptive estimation of Chl a and iv) phytoplankton size fractions were developed to facilitate the study of biogeochemical cycling in the nGOM.

The phytoplankton based algorithms were applied to Sentinel 3A/B-OLCI oean color data to assess phytoplankton community dynamics to extreme river discharge conditions as well as hurricanes in the …