Physical Sciences and Mathematics Commons^™

Application Of Nearly Linear Solvers To Electric Power System Computation, Lisa L. Grant

Doctoral Dissertations

"To meet the future needs of the electric power system, improvements need to be made in the areas of power system algorithms, simulation, and modeling, specifically to achieve a time frame that is useful to industry. If power system time-domain simulations could run in real-time, then system operators would have situational awareness to implement and avoid cascading failures, significantly improving power system reliability. Several power system applications rely on the solution of a very large linear system. As the demands on power systems continue to grow, there is a greater computational complexity involved in solving these large linear systems within …

Environmental Hazard Identification, Assessment And Control For A Sustainable Maritime Transportation System, Lizzette Marie Pérez Lespier

Doctoral Dissertations

"A demand exists to contribute towards the widening awareness of the need for sustainable maritime development and for coordinated maritime policies worldwide. Maritime shipping is considered the most eco-efficient mean of transportation and yet, is responsible for negative environmental impacts.

This dissertation focuses on developing data-driven decision support tools to evaluate the sustainable performance of MTS by focusing on the elements of the MTS that place stress on the environment. The first research contribution is a System Dynamics simulation model that examines the MTS resiliency after an extreme event and determines the sequence needed to restore the ocean-going port to …

Programming Problems On Time Scales: Theory And Computation, Rasheed Basheer Al-Salih

Doctoral Dissertations

"In this dissertation, novel formulations for several classes of programming problems are derived and proved using the time scales technique. The new formulations unify the discrete and continuous programming models and extend them to other cases "in between." Moreover, the new formulations yield the exact optimal solution for the programming problems on arbitrary isolated time scales, which solve an important open problem. Throughout this dissertation, six distinct classes of programming problems are presented as follows. First, the primal as well as the dual time scales linear programming models on arbitrary time scales are formulated. Second, separated linear programming primal and …

Designing High Performance Overall Water Splitting Electrocatalysts From Non-Precious Metal Selenides, Abdurazag T. Swesi

Doctoral Dissertations

“The energy production has been depending mostly on fossil fuel which will be depleted someday in the near future. Aspects such as the loss of energy resources and destruction of the environment have motivated researchers for pursuing transition away from fossil fuels to renewable solar-fuels. Therefore, in order to meet the continuous increasing demand for energy, the hydrogen, with the largest energy density stored in it, can then efficiently be used in fuel cells without concern of contaminants. Water splitting reaction to generate H₂ and O₂ is one promising method of converting solar energy into fuels. The major …

A Harmonic M-Factorial Function And Applications, Reginald Alfred Brigham Ii

Doctoral Dissertations

"We offer analogs to the falling factorial and rising factorial functions for the set of harmonic numbers, as well as a mixed factorial function called the M-factorial. From these concepts, we develop a harmonic analog of the binomial coefficient and an alternate expression of the harmonic exponential function and establish several identities. We generalize from the harmonic numbers to a general time scale and demonstrate how solutions to some second order eigenvalue problems and partial dynamic equations can be constructed using power series built from the M-factorial function"--Abstract, page iii.

Geophysical Interpretation And Static Reservoir Modeling Of Structurally Complex Reservoir, Rg Oil Field Area, Sirte Basin, Libya, Abdalla A. Abdelnabi

Doctoral Dissertations

"Cambrian-Ordovician and Upper Cretaceous reservoir formations are found in the central western Sirte Basin, the main oil producing region in the Sirte Basin, Libya. As a result of changes in sedimentary environments and structural activities, a number of irregularities in reservoir continuity have developed, which negatively affected the overall performance of the reservoir. Effective simulation of such complex reservoirs can be achieved by integrating geophysical, geological, and petrophysical data to construct a reliable full-field static model, which has the potential to simulate the vertical and lateral variations in the reservoir formations. In this study, 2D and 3D seismic data acquired …

Long-Range Interatomic Interactions: Oscillatory Tails And Hyperfine Perturbations, Chandra Mani Adhikari

Doctoral Dissertations

"We study the long-range interaction between two hydrogen atoms, in both the van der Waals and Casimir-Polder regimes. The retardation regime is reached when the finiteness of the speed of light becomes relevant. Provided that both atoms are in the ground states, the retardation regime is achieved when the interatomic distance, R, is larger than 137 a₀, where a₀ is the Bohr radius.

To study the interaction between two hydrogen atoms in 1S and 2S states, we differentiate three different ranges for the interatomic distance: van der Waals range (a₀ « R « a₀/α, where α is the fine structure …

Balanced Truncation Model Reduction Of Nonlinear Cable-Mass Pde System, Madhuka Hareena Lochana Weerasinghe

Doctoral Dissertations

We consider model order reduction of a cable-mass system modeled by a one dimensional wave equation with interior damping and dynamic boundary conditions. The system is driven by a time dependent forcing input to a linear mass-spring system at the left boundary of the cable. A mass-spring model at the right end of the cable includes a nonlinear stiffening force. The goal of the model reduction is to produce a low order model that produces an accurate approximation to the displacement and velocity of the mass in the nonlinear mass-spring system at the right boundary. We believe the nonlinear cable-mass …

St. Louis Area Earthquake Hazards Mapping Project: Seismic And Liquefaction Hazard Maps, Chris H. Cramer, Robert A. Bauer, Jaewon Chung, J. David Rogers, Larry Pierce, Vicki Voigt, Brad Mitchell, David Gaunt, Robert A. Williams, David J. Hoffman, Gregory L. Hempen, Phyllis J. Steckel, Oliver Salz Boyd, Connor M. Watkins, Kathleen B. Tucker, Natasha S. Mccallister

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

We present probabilistic and deterministic seismic and liquefaction hazard maps for the densely populated St. Louis metropolitan area that account for the expected effects of surficial geology on earthquake ground shaking. Hazard calculations were based on a map grid of 0.005°, or about every 500 m, and are thus higher in resolution than any earlier studies. To estimate ground motions at the surface of the model (e.g., site amplification), we used a new detailed near-surface shear-wave velocity model in a 1D equivalent- linear response analysis. When compared with the 2014 U.S. Geological Survey (USGS) National Seismic Hazard Model, which uses …

Biomarker Discovery Using Urinary Metabolomics For Noninvasive Early Cancer Detection, Casey Franklin Burton

Doctoral Dissertations

"The development of new screening methods for the early detection of cancer remains one of the foremost challenges facing modern cancer research. The emergence of new analytical technologies and their application to 'omics'-based approaches has provided researchers with powerful new tools for molecular biomarker discovery that may benefit early screening of cancer. This dissertation outlines several key advances made toward the application of urinary metabolomics to cancer biomarker discovery. The term urinary metabolomics here refers to the investigation of small metabolites in urine as potential disease biomarkers. The advantage of using this approach lies in its noninvasive sampling characteristics and …

Fusion Of Non-Visual And Visual Sensors For Human Tracking, Wenchao Jiang

Doctoral Dissertations

"Human tracking is an extensively researched yet still challenging area in the Computer Vision field, with a wide range of applications such as surveillance and healthcare. People may not be successfully tracked with merely the visual information in challenging cases such as long-term occlusion. Thus, we propose to combine information from other sensors with the surveillance cameras to persistently localize and track humans, which is becoming more promising with the pervasiveness of mobile devices such as cellphones, smart watches and smart glasses embedded with all kinds of sensors including accelerometers, gyroscopes, magnetometers, GPS, WiFi modules and so on. In this …

Dirac Surface States Of Magnetic Topological Insulators, Seng Huat Lee

Doctoral Dissertations

"Magnetic topological insulator (TI) has been theoretically proposed to be a platform for inducing magnetic monopole and exhibit fascinating quantum phenomena, whereas topological superconductor can host Majorana fermions, particles that are their own antiparticles, which can be manipulated for topological quantum computing. In this dissertation, we experimentally demonstrated that by intercalation of different transition metals in the van der Waals gaps of Bi₂Se₃ TI, magnetism and even superconductivity can be induced. In Fe_xBi₂Se₃, antiferromagnetism is induced with a transition temperature at ~ 100 K. Coexistence of the Dirac surface state with …

Data Analytics Methods For Attack Detection And Localization In Wireless Networks, Yi Ling

Doctoral Dissertations

"Wireless ad hoc network operates without any fixed infrastructure and centralized administration. It is a group of wirelessly connected nodes having the capability to work as host and router. Due to its features of open communication medium, dynamic changing topology, and cooperative algorithm, security is the primary concern when designing wireless networks. Compared to the traditional wired network, a clean division of layers may be sacrificed for performance in wireless ad hoc networks. As a result, they are vulnerable to various types of attacks at different layers of the protocol stack. In this paper, I present real-time series data analysis …

Depositional Systems, Sequence Architecture, And Controlling Factors Of An Eocene Stratigraphic Sequence At Minfeng Steep Margin Of Dongying Depression, Eastern China, Zhixin Li

Doctoral Dissertations

“This study is carried out in Minfeng area, the steep margin of Dongying half graben, eastern China, by integrating 3-D seismic, wireline log, and core data, and aims to interpret the depositional systems, reconstruct sequence stratigraphic architecture, and understand the controlling processes and factors at the steep margin of a rift basin. In the first part of this work, an Eocene stratigraphic sequence is divided into three systems tracts, corresponding to different stages of lake evolution, as early expansion (EEST), late expansion-early contraction (LEECST), and late contraction (LCST). EEST is the thickest and diagnostic by the best-developed marginal and basinal …

Overview Of Co₂ Leakage Problems And Sealants For Co₂ Leakage Remediation, Shudai Peng

Masters Theses

"Excessive Carbon Dioxide (CO₂) emission has become a serious issue and caused lots of environmental problems. Carbon Capture and Storage (CCS) program has been developed to reduce the CO₂ content in the atmosphere. CO₂ storage has been targeted mainly on depleted oil or gas reservoirs and deep saline aquifers. However, leakage could occur through wellbores, cap rocks, formation faults, and fractures during and after CO₂ injection. To minimize the risk, different types of sealants have been investigated to prevent CO₂ leaks. The aim of this thesis is to provide a comprehensive review of the materials which could be used as …

Optimization Of Solvent Suppression Sequences For Nmr Analysis Of Aqueous Solutions, Annalise Rose Pfaff

Doctoral Dissertations

"When the use of deuterated solvents is precluded in the NMR analysis of biomolecules in their natural environment, pre-saturation solvent suppression pulse sequences are frequently employed to avoid interference from the overbearing solvent signal. However, these sequences generally require extensive re-adjustment of NMR parameters between samples. For this reason, the EXCEPT (EXponentially Converging Eradication Pulse Train) solvent suppression sequence was developed, which exhibits a tolerance of over an order of magnitude in sample T₁ variation. EXCEPT uses an innovative version of "inversion-recovery nulling" with frequency-selective, low-power adiabatic pulses and exponentially decreasing interpulse delays that effectively reduce solvent net magnetization by …

Cyber-Physical Security Of A Chemical Plant, Prakash Rao Dunaka

Masters Theses

"The increasing number of cyber attacks on industries demands immediate attention for providing more secure mechanisms to safeguard industries and minimize risks. A supervisory control and data acquisition (SCADA) system employing the distributed networks of sensors and actuators that interact with the physical environment is vulnerable to attacks that target the interface between the cyber and physical subsystems. These cyber attacks are typically malicious actions that cause undesired results in the cyber physical world, for example, the Stuxnet attack that targeted Iran's nuclear centrifuges. An attack that hijacks the sensors in an attempt to provide false readings to the controller …

Imaging In Karst Terrain Using The Electrical Resistivity And Multichannel Analyses Of Surface Wave Methods, Ragab W. Jaafar

Masters Theses

"Electrical resistivity tomography and multi-channel analyses of surface waves data were acquired at a study area in Phelps County in the south-central part of Missouri. The objectives of the investigation were fourfold: 1) to image the subsurface in the study area to a depth of 70 feet; 2) to compare the ERT images generated using both the dipole-dipole and Wenner-Schlumberger arrays; and 3) to assess how variations in the MASW array configuration affected MASW data quality; and 4) to compare the ERT-estimated depth to top-of-rock and the MASW-generated depth to top-of-rock.

The subsurface in the study area was imaged to …

Mining Asteroids For Volatile Resources: An Experimental Demonstration Of Extraction And Recovery, Egboche Christopher Unobe

Masters Theses

"Gaseous compounds trapped within carbonaceous asteroids may prove to be important targets for prospective space miners in the near-term. Volatile release is from hydrated, hydroxylated and carbonated phases present, making such bodies attractive as feedstock for the production of H₂O, CO₂ and simple organic compounds. A source of these species in orbit provides an opportunity to locally produce space-craft propellant and other life-support gases through the application of In-situ Resource Utilization (ISRU).

For this study, an experimental vacuum system was modified and used to test the technical validity of radiatively heating asteroid simulants to extract contained gaseous …

Study Of Surface Complexation And Mineral Dissolution During Water-Rock Interaction In High Salinity Waterflooding At Elevated Temperatures, Sameer Salasakar

Masters Theses

"High salinity waterflooding for carbonate reservoirs is efficient and cheap method used for improved oil recovery. Various mechanisms have been proposed including adsorption/desorption on rock surface, mineral dissolution and precipitation, multicomponent ion exchange, interfacial tension reduction, fine migration and double layer expansion. These all process alter the wettability which leads to improved oil recovery.

Objective of this study was to understand processes that occur during water-rock interaction when high salinity water is flooded into the reservoir. In this work, effect of temperature on water-rock interaction is studied along with effect of pH and specific surface areas of calcite at normal …

A Bounded Actor-Critic Algorithm For Reinforcement Learning, Ryan Jacob Lawhead

Masters Theses

"This thesis presents a new actor-critic algorithm from the domain of reinforcement learning to solve Markov and semi-Markov decision processes (or problems) in the field of airline revenue management (ARM). The ARM problem is one of control optimization in which a decision-maker must accept or reject a customer based on a requested fare. This thesis focuses on the so-called single-leg version of the ARM problem, which can be cast as a semi-Markov decision process (SMDP). Large-scale Markov decision processes (MDPs) and SMDPs suffer from the curses of dimensionality and modeling, making it difficult to create the transition probability matrices (TPMs) …

The Use Of Geophysical Methods For Dam Seepage Investigations And Dredged Oyster Deposit Characterization, Stanley Chinedu Nwokebuihe

Doctoral Dissertations

"The dissertation is made up of three papers, which discuss the utility of geophysical tools in earthfill dam investigations and dredged oyster bed characterization.

In the first paper, an earthfill dam in Warren County, Missouri was effectively investigated for seepage through the dam and its outlet works using an integration of the electrical resistivity tomography, induced polarization and spontaneous potential geophysical tools. Recommendations were subsequently made based on the results of the study on grout locations to prevent further seepage. In the second paper, a similar study of earthfill dam seepage was conducted on a different dam in Southern Missouri. …

Dissolution-Enlarged Fractures Imaging Using Electrical Resistivity Tomography (Ert), Elnaz Siami-Irdemoosa

Doctoral Dissertations

"In recent years the electrical imaging techniques have been largely applied to geotechnical and environmental investigations. These techniques have proven to be the best geophysical methods for site investigations in karst terrain, particularly when the overburden soil is clay-dominated. Karst is terrain with a special landscape and distinctive hydrological system developed by dissolution of rocks, particularly carbonate rocks such as limestone and dolomite, made by enlarging fractures into underground conduits that can enlarge into caverns, and in some cases collapse to form sinkholes.

Bedding planes, joints, and faults are the principal structural guides for underground flow and dissolution in almost …

Application Of Quantum Monte Carlo Methods To Molecular Potential Energy Surfaces, Andrew Douglas Powell

Doctoral Dissertations

"Various computational methods have been used to generate potential energy surfaces, which can help us simulate and interpret how atoms or molecules behave during a chemical reaction. For accurate work, ab initio wavefunction methods have traditionally been used, which have some disadvantages. For example, highly accurate methods scale poorly with system size (n⁷ or higher) and are mostly not well parallelized for calculations with multiple processors. One alternative method that has more favorable scaling with system size and is well parallelized is a computational technique called quantum Monte Carlo (QMC). QMC methods scale with the number of electrons as …

Bootstrap-Based Confidence Intervals In Partially Accelerated Life Testing, Ahmed Mohamed Eshebli

Doctoral Dissertations

"Accelerated life testing (ALT) is utilized to estimate the underlying failure distribution and related parameters of interest in situations where the components under study are designed for long life and therefore will not yield failure data within a reasonable test period. In ALT, life testing is carried out under two or more higher than normal stress levels, with the resulting acceleration of the failure process yielding a sufficient amount of un-censored life-span data within a practical test duration. Usually one (or more) parameters of the life distribution is linked to the stress level through a suitably selected model based on …

Efficient Algorithms For Analyzing Large Scale Network Dynamics: Centrality, Community And Predictability, Sima Das

Doctoral Dissertations

"Large scale networks are an indispensable part of our daily life; be it biological network, smart grids, academic collaboration networks, social networks, vehicular networks, or the networks as part of various smart environments, they are fast becoming ubiquitous. The successful realization of applications and services over them depend on efficient solution to their computational challenges that are compounded with network dynamics. The core challenges underlying large scale networks, for example: determining central (influential) nodes (and edges), interactions and contacts among nodes, are the basis behind the success of applications and services. Though at first glance these challenges seem to be …

Phytoforensics: Applications In Vapor Intrusion Assessment, Jordan Lee Wilson

Doctoral Dissertations

"Vapor intrusion (VI) occurs when contaminants in the vapor phase migrate in the shallow subsurface and enter buildings through cracks, seams, and gaps and has been recognized as a serious human-health threat as occupants are exposed to potentially harmful concentrations over long periods of time. The VI pathway has recently (2017) been identified as a primary exposure pathway and implemented into the Hazard Ranking System for inclusion on the Nation Priorities List. However, assessing VI and human exposure is not simple and current methods are time-, cost-, and labor-intensive; intrusive; and temporally and spatially variability. Trees are ideal candidates for …

The Maculoprotective Effect Of A Thiol Antioxidant In Retinal Degeneration Models, Hsiu-Jen Wang

Doctoral Dissertations

"Age-related macular degeneration (AMD) is a leading cause of irreversible blindness among adults, age 60 and older, in developed countries. While oxidative stress is implicated in the pathogenesis of AMD, clinical studies have shown that dietary antioxidants can delay progression of AMD. Currently, there is no FDA-approved treatment for AMD. Therefore, we hypothesized that N-acetylcysteine amide (NACA), a thiol antioxidant, would protect retinal pigment epithelium and impede the progression of retinal degeneration. The goal of this work was to evaluate the efficacy of NACA in preventing retinal pigment epithelial cell and photoreceptor death in AMD models. To achieve this, we …

Local Holomorphic Extension Of Cauchy Riemann Functions, Brijitta Antony

Doctoral Dissertations

"The purpose of this dissertation is to give an analytic disc approach to the CR extension problem. Analytic discs give a very convenient tool for holomorphic extension of CR functions. The type function is introduced and showed how these type functions have direct application to important questions about CR extension. In this dissertation the CR extension theorem is proved for a rigid hypersurface M in C² given by y = (Re ω)^m(Im ω)ⁿ where m and n are non-negative integers. If the type function is identically zero at the origin, then there is no CR extension. …

Drinking Water Disinfection By-Products Detection, Formation And The Precursors Removal Study, Runmiao Xue

Doctoral Dissertations

"Haloacetic acids (HAAs) and trihalomethanes (THMs) are two groups of commonly found disinfection by-products (DBPs). Iodinated THMs and HAAs were observed after disinfection of water containing high level of iodide and are proved to be more toxic than their corresponding chlorinated and brominated species. In the presented dissertation, a novel rapid and sensitive high performance ion chromatography-tandem mass spectrometry (HPIC-MS/MS) method has been developed for simultaneous analysis of all these HAAs, bromate, bromide, iodide, and iodate, seventeen compounds in total, without any tedious sample preparation. Besides an efficient analytical method for the detection of DBPs, seeking for a green disinfectant …