Physical Sciences and Mathematics Commons^™

Concentrations, Distributions And Chemical Speciation Of Zinc And Cadmium In The Equatorial And South Atlantic Ocean, Gonzalo G. Carrasco

OES Theses and Dissertations

Certain trace metals are important cofactors in enzymatic systems and are thus, essential for life in the world's oceans. Two of these metals, Zn and Cd, are required by phytoplankton for enzymes that facilitate carbon uptake (Morel and Price, 2003). In seawater the total dissolved concentration of a metal (MTD) is distributed among different chemical species and this chemical speciation dictates a metal's bioavailability. Strong organic metal-binding ligands greatly affect the metal's chemical speciation in the ocean, potentially limiting phytoplankton growth by reducing the concentrations of Zn²⁺ and Cd²⁺, the bioavailable forms of these two metals to …

Trace Metal Biogeochemistry In The Western North Pacific, Peter Lynn Morton

OES Theses and Dissertations

Dissolved and suspended particulate samples collected during the Intergovernmental Oceanographic Commission 2002 Contaminant Baseline Survey were analyzed to determine the surface and vertical distributions of Cd, Co, Cu, Mn, Ni Zn and Pb across the western and central North Pacific.

Dissolved trace metal concentrations were measured using a novel isotope dilution-ICP-MS method after extraction over an 8-hydroxyquinoline resin column and validated through the use of the SAFe consensus reference materials. Filtered suspended particulate matter was digested using an HCl/HNO3/HF mixture and analyzed by HR-ICP-MS to obtain total particulate concentrations for the trace metals and other tracer elements such as Al, …

Modeling Decision Making Related To Incident Delays During Hurricane Evacuations, Robert Michael Robinson

Computational Modeling & Simulation Engineering Theses & Dissertations

Successful evacuations from metropolitan areas require optimizing the transportation network, monitoring conditions, and adapting to changes. Evacuation plans seek to maximize the city's ability to evacuate traffic to flee the endangered region, but once an evacuation begins, real time events degrade even the best plans.

To better understand behavioral responses made during a hurricane evacuation, a survey of potential evacuees obtained data on demographics, driving characteristics, and the traffic information considered prior to and during an evacuation. Analysis showed significant levels of correlation between demographic factors (e.g., gender, age, social class, etc.) and self-assessed driver characteristics, but limited correlation with …

Canonical Correlation Analysis For Longitudinal Data, Raymond Mccollum

Mathematics & Statistics Theses & Dissertations

Data (multivariate data) on two sets of vectors commonly occur in applications. Statistical analysis of these data is usually done using a canonical correlation analysis (CCA). Occurrence of these data at multiple occasions or conditions leads to longitudinal multivariate data for a CCA. We address the problem of canonical correlation analysis on longitudinal data when the data have a Kronecker product covariance structure. Using structured correlation matrices we model the dependency of repeatedly observed data. Recent work of Srivastava, Nahtman, and von Rosen (2008) developed an iterative algorithm to determine the maximum likelihood estimate of the Kronecker product covariance structure …

Mathematical Models And Stability Analysis Of Cholera Dynamics, Shu Liao

Mathematics & Statistics Theses & Dissertations

In this dissertation, we present a careful mathematical study of several epidemic cholera models, including the model of Codeco [11] in 2001, that of Hartley, Morris and Smith [22] in 2006, and that of Mukandavire, Liao, Wang and Gaff et al. [60] in 2010. We formally derive the basic reproduction number R0 for each model by computing the spectral radius of the next generation matrix. We focus our attention on the stability analysis at the disease-free equilibrium which determines the short-term epidemic behavior, and the endemic equilibrium which determines the long-term disease dynamics. Particularly, we incorporate the Volterra-Lyapunov matrix …

Analysis Of Models For Longitudinal And Clustered Binary Data, Weiming Yang

Mathematics & Statistics Theses & Dissertations

This dissertation deals with modeling and statistical analysis of longitudinal and clustered binary data. Such data consists of observations on a dichotomous response variable generated from multiple time or cluster points, that exhibit either decaying correlation or equi-correlated dependence. The current literature addresses modeling the dependence using an appropriate correlation structure, but ignores the feasible bounds on the correlation parameter imposed by the marginal means.

The first part of this dissertation deals with two multivariate probability models, the first order Markov chain model and the multivariate probit model, that adhere to the feasible bounds on the correlation. For both the …

Interannual Differences In Nutrient Dynamics During A Brown Tide Bloom (Aureococcus Anophagefferens) And The Interaction Of A. Anophagefferens With Heterotrophic Bacteria, George Eric Boneillo

OES Theses and Dissertations

Blooms of Aureococcus anophagefferens (Brown Tides) in Chincoteague Bay were observed over a six-year period (2002–2007) during which interannual differences in nitrogen and carbon uptake and concentrations of dissolved constituents were compared at two sites, one in Maryland and the other in Virginia. Overall, I observed an increase in bloom intensity and duration over time. No single nitrogen compound was responsible for fueling blooms. Instead, A. anophagefferens demonstrated the ability to use a wide range of nitrogen compounds to meet its nutritional demands. Results show that NO₃-, NH₄+, urea, and DFAA were taken up simultaneously during …

Impacts Of The Spotted Spiny Lobster (Panulirus Guttatus) On The Long-Spined Sea Urchin (Diadema Antillarum) And Patch Reef Communities In The Florida Keys, Meredith D. Kintzing

Biological Sciences Theses & Dissertations

Caribbean coral reefs have undergone a phase shift from a system dominated by corals to one where algae are pervasive. This shift was precipitated by the loss of herbivores, including the mass mortality of the long spined sea urchin (Diadema antillarum), coupled with disease and the recruitment failure of hermatypic corals. Diadema populations have recovered in some areas of the Caribbean, but are still below historical levels in the Florida Keys, likely due to low larval supply coupled with predation on juveniles. Lobsters are sea urchin predators in other systems and the spotted spiny lobster (Panulirus guttatus …

Design Of Organic Tandem Solar Cells Using Pcpdtbt: Pc61 Bm And P3ht: Pc71bm, Gon Namkoong, Patrick Boland, Keejoo Lee, James Dean

Electrical & Computer Engineering Faculty Publications

We conducted optical and electrical simulations with the goal of determining the optimal design for conjugated polymer-fullerene tandem solar cells using poly[2,6-(4,4-bis-(2-ethylhexyl)- 4H-cyclopenta[2,1- b;3,4- b′] dithiophene)-alt-4,7-(2,1,3-benzothiadiazole)] (PCPDTBT): [6,6]-phenyl C₆₁ butyric acid methyl ester (PC₆₁ BM) as a bottom cell and poly(3-hexylthiophene) (P3HT): [6,6]-phenyl C₇₁ butyric acid methyl ester (PC₇₁BM) as a top cell. The effects of photon density, absorption, balanced and unbalanced charge carrier transport, and bimolecular recombination in the two subcells were incorporated into the simulations. We found that the maximum energy conversion efficiency (η) is 9% when charge carrier mobilities in …

Excitation-Induced Germanium Quantum Dot Formation On Si (100)-(2×1), Ali Oguz Er, Hani E. Elsayed-Ali

Physics Faculty Publications

The effect of nanosecond pulsed laser excitation on the self-assembly of Ge quantum dots grown by pulsed laser deposition on Si (100)-(2×1) was studied. In situ reflection high-energy electron diffraction and ex situ atomic force microscopy were used to probe the quantum dot structure and morphology. At room temperature, applying the excitation laser decreased the surface roughness of the grown Ge film. With surface electronic excitation, crystalline Ge quantum dots were formed at 250 °C, a temperature too low for their formation without excitation. At a substrate temperature of 390 °C, electronic excitation during growth was found to improve the …

Measurement Of Single- And Double-Spin Asymmetries In Deep Inelastic Pion Electroproduction With A Longitudinally Polarized Target, H. Avakian, P. Bosted, V. D. Burkert, L. Elouadrhiri, K. P. Adhikari, M. Aghasyan, M. Amaryan, M. Anghinolfi, H. Baghdasaryan, J. Ball, G. Dodge, G. Gavalian, N. Guler, A. Klein, S E. Kuhn, D. Martinez, M. R. Niroula, F. Sabatié, H. Seraydaryan, S. Tkachenko, L. B. Weinstein

Physics Faculty Publications

We report the first measurement of the transverse momentum dependence of double-spin asymmetries in semi-inclusive production of pions in deep-inelastic scattering off the longitudinally polarized proton. Data have been obtained using a polarized electron beam of 5.7 GeV with the CLAS detector at the Jefferson Lab (JLab). Modulations of single spin asymmetries over the azimuthal angle between lepton scattering and hadron production planes ϕ have been measured over a wide kinematic range in Bjorken x and virtual photon squared four-momentum Q². A significant nonzero sin2ϕ single spin asymmetry was observed for the first time indicating strong spin-orbit correlations …

Parton Energy Loss In Heavy-Ion Collisions Via Direct-Photon And Charged-Particle Azimuthal Correlations, B. I. Abelev, M. M. Aggarwal, Z. Ahammed, A. V. Alakhverdyants, B. D. Anderson, D. Arkhipkin, G. S. Averichev, S. Bueltmann, I. Koralt, Star Collaboration

Physics Faculty Publications

Charged-particle spectra associated with direct photon Ydir) and π⁰ are measured in p+p and Au+Au collisions at center-of-mass energy √sNN=200 GeV with the STAR detector at the Relativistic Heavy Ion Collider. A shower-shape analysis is used to partially discriminate between Ydirand π⁰. Assuming no associated charged particles in the γdir direction (near side) and small contribution from fragmentation photons (Yfrag), the associated charged-particle yields opposite to Ydir(away side) are extracted. In central Au+Au collisions, the charged-particle yields at midrapidity (|η|<1) and high transverse momentum (3 < P_T^assoc < 16 GeV/c) associated with γdir and π⁰ (|η|<0.9, 8 < P_T^trig <16 GeV/c) are suppressed by a factor of 3–5 compared with p+p collisions. The observed suppression of the associated charged particles is similar for Ydir and π⁰ and …

Applications Of Spoke Cavities, Jean R. Delayen

Physics Faculty Publications

The superconducting spoke cavity was introduced in the late 1980s in response to the need for superconducting structures in the mid-velocity range. Since then it has found application in many projects. Prototypes have been developed for a wide range of beam velocities. The characteristics and features of the spoke cavity are reviewed and some of their applications are presented.

Security In Ad Hoc Networks And Pervasive Computing, Isaac Z. Wu, X.-Y. Li, M. Song, C.-M. Liu

Electrical & Computer Engineering Faculty Publications

Pervasive computing is an exciting and blooming research field, in which innovative techniques and applications are continuously emerging and aim to provide ambient and personalized services to users with high quality. Ad hoc networks are wireless, self-organizing systems formed by cooperating nodes within communication range of each other that form temporary networks. Their topology is dynamic, decentralized, ever changing and the nodes may move around arbitrarily. The last few years have witnessed a wealth of research ideas on ad hoc networking that are moving rapidly into implemented standards. Technology under development for ad hoc networks and pervasive computing is making …

Temporal Controls On Dissolved Organic Matter And Lignin Biogeochemistry In A Pristine Tropical River, Democratic Republic Of Congo, Robert G. M. Spencer, Peter J. Hernes, Rosmarie Ruf, Andy Baker, Rachael Y. Dyda, Aron Stubbins, Johan Six

Chemistry & Biochemistry Faculty Publications

Dissolved organic carbon (DOC), lignin biomarkers, and the optical properties of dissolved organic matter (DOM) were measured in the Epulu River (northeast Democratic Republic of Congo) with the aim of investigating temporal controls on the quantity and chemical composition of DOM in a tropical rainforest river. Three different periods defined by stages of the hydrologic regime of the region, (1) post dry flushing period, (2) intermediary period, and (3) start of the dry period/post flush, were sampled. Temporal variability in DOM quantity and quality was observed with highest DOC, lignin concentration (Σ₈) and carbon‐normalized (Λ₈) values …

Effluent Organic Nitrogen (Eon): Bioavailability And Photochemical And Salinity-Mediated Release, Deborah A. Bronk, Quinn N. Roberts, Marta P. Sanderson, Elizabeth A. Canuel, Patrick G. Hatcher, Rajaa Mesfioui, Katherine C. Filippino, Margaret R. Mulholland, Nancy G. Love

Chemistry & Biochemistry Faculty Publications

The goal of this study was to investigate three potential ways that the soluble organic nitrogen (N) fraction of wastewater treatment plant (WWTP) effluents, termed effluent organic N (EON), could contribute to coastal eutrophication - direct biological removal, photochemical release of labile compounds, and salinity-mediated release of ammonium (NH₄+). Effluents from two WWTPs were used in the experiments. For the bioassays, EON was added to water from four salinities (∼0 to 30) collected from the James River (VA) in August 2008, and then concentrations of N and phosphorus compounds were measured periodically over 48 h. Bioassay results, based …

An Examination Of The Association Of Selected Toxic Metals With Total And Central Obesity Indices: Nhanes 99-02, Miguel A. Padilla, Mai Elobeid, Douglas M. Ruden, David B. Allison

Psychology Faculty Publications

It is conceivable that toxic metals contribute to obesity by influencing various aspects of metabolism, such as by substituting for essential micronutrients and vital metals, or by inducing oxidative stress. Deficiency of the essential metal zinc decreases adiposity in humans and rodent models, whereas deficiencies of chromium, copper, iron, and magnesium increases adiposity. This study utilized the NHANES 99-02 data to explore the association between waist circumference and body mass index with the body burdens of selected toxic metals (barium, cadmium, cobalt, cesium, molybdenum, lead, antimony, thallium, and tungsten). Some of the associations were significant direct relationships (barium and thallium), …

Longitudinal Scaling Property Of The Charge Balance Function In Au + Au Collisions At √Snn= 200 Gev, B. I. Abelev, M. M. Aggarwal, Z. Ahammed, A. V. Alakhverdyants, I. Alekseev, B. D. Anderson, D. Arkhipkin, G. S. Averichev, J. Balewski, L. S. Barnby, S. Bültmann, I. Koralt, D. Plyku

Physics Faculty Publications

We present measurements of the charge balance function, from the charged particles, for diverse pseudorapidity and transverse momentum ranges in Au + Au collisions at √^sNN = 200 GeV using the STAR detector at RHIC. We observe that the balance function is boost-invariant within the pseudorapidity coverage [ − 1.3 , 1.3 ] . The balance function properly scaled by the width of the observed pseudorapidity window does not depend on the position or size of the pseudorapidity window. This scaling property also holds for particles in different transverse momentum ranges. In addition, we find that the width …

Mesoscopic Methods In Engineering And Science, Alfons Hoekstra, Li-Shi Luo, Manfred Krafczyk

Mathematics & Statistics Faculty Publications

(First paragraph) Matter, conceptually classified into fluids and solids, can be completely described by the microscopic physics of its constituent atoms or molecules. However, for most engineering applications a macroscopic or continuum description has usually been sufficient, because of the large disparity between the spatial and temporal scales relevant to these applications and the scales of the underlying molecular dynamics. In this case, the microscopic physics merely determines material properties such as the viscosity of a fluid or the elastic constants of a solid. These material properties cannot be derived within the macroscopic framework, but the qualitative nature of the …

Spawning-Related Movements Of Barred Sand Bass Paralabrax Nebulifer, In Southern California: Interpretations From Two Decades Of Historical Tag And Recapture Data, E. T. Jarvis, Christi Linardich, C. F. Valle

Biological Sciences Faculty Publications

During the 1960s and 1990s, the California Department of Fish and Game tagged 8,634 barred sand bass in southern California, and 972 fish (11%) were recaptured. Tag returns suggest barred sand bass are transient aggregate spawners that form spawning aggregations consisting of both resident and migrant individuals. Spawning residency at a historic spawning location was estimated by the frequency of returns over time; most same-year returns (82%, n  =  141) were recaptured within a 7 to 35-day period. The maximum recapture distance was 92 km. The average (± SD) non-spawning season recapture distance from peak spawning season tagging locations was …

Modeling The Vertical Distributions Of Downwelling Plane Irradiance And Diffuse Attenuation Coefficient In Optically Deep Waters, X. J. Pan, Richard C. Zimmerman

OES Faculty Publications

The diffuse attenuation coefficient Kᵈ is critical to understand the vertical distribution of underwater downwelling irradiance (Eᵈ). Theoretically Eᵈ is composed of the direct solar beam and the diffuse sky irradiance. Applying the statistical results from Hydrolight radiative transfer simulations, Kᵈ is expressed into a mathematical equation (named as PZ06) integrated from the contribution of direct solar beam and diffuse sky irradiance with the knowledge of sky and water conditions. The percent root mean square errors (RMSE) for the vertical distribution of Eᵈ(z) under various sky and water conditions between PZ06 and Hydrolight results are typically less than 4%. Field …

Operation And Application Of A Regional High-Frequency Radar Network In The Mid-Atlantic Bight, Hugh Roarty, Scott Glenn, Josh Kohut, Donglai Gong, Ethan Handel, Erick Rivera, Teresa Garner, Larry Atkinson, Wendell Brown, Chris Jakubiak, Mike Muglia, Sara Haines, Harvey Seim

CCPO Publications

The Mid-Atlantic Regional Coastal Ocean Observing System (MARCOOS) High- Frequency Radar Network, which comprises 13 long-range sites, 2 medium-range sites, and 12 standard-range sites, is operated as part of the Integrated Ocean Observing System. This regional implementation of the network has been operational for 2 years and has matured to the point where the radars provide consistent coverage from Cape Cod to Cape Hatteras. A concerted effort was made in the MARCOOS project to increase the resiliency of the radar stations from the elements, power issues, and other issues that can disable the hardware of the system. The quality control …

Endocrine Disruptors And Obesity: An Examination Of Selected Persistent Organic Pollutants In The Nhanes 1999-2002 Data, Mai A. Elobeid, Miguel A. Padilla, David W. Brock, Douglas M. Ruden, David B. Allison

Psychology Faculty Publications

Recent evidence suggests that endocrine disrupting chemicals (EDCs) may cause perturbations in endogenous hormonal regulation that predispose to weight gain. Using data from NHANES (1999-2002), we investigated the association between body mass index (BMI), waist circumference (WC) and selected persistent organic pollutants (POPs) via multiple linear regressions. Consistent interaction was found between gender, ln oxychlordane and ln p,p' DDT. Also, we found an association between WC and ln oxychlordane and ln hpcdd in subjects with detectable levels of POPs, whereas an association between WC and ln p,p' DDT was observed in all subjects. Furthermore, ln Ocdd showed an increase with …

Hard Photodisintegration Of A Proton Pair, I. Pomerantz, N. Bubis, K. Allada, A. Beck, B. L. Berman, W. Boeglin, A. Camsonne, M. Canan, K. Chirapatpimol, E. Cisbani

Physics Faculty Publications

We present a study of high energy photodisintegration of proton-pairs through the γ + ³He → p + p + n channel. Photon energies, Eγ , from 0.8 to 4.7 GeV were used in kinematics corresponding to a proton pair with high relative momentum and a neutron nearly at rest. The s⁻¹¹ scaling of the cross section, as predicted by the constituent counting rule for two nucleon photodisintegration, was observed for the first time. The onset of the scaling is at a higher energy and the cross section is significantly lower than for deuteron (pn pair) photodisintegration. …

Dielectrophoretic Choking Phenomenon In A Converging-Diverging Microchannel, Ye Ai, Shizhi Qian, Sheng Liu, Sang W. Joo

Mechanical & Aerospace Engineering Faculty Publications

Experiments show that particles smaller than the throat size of converging-diverging microchannels can sometimes be trapped near the throat. This critical phenomenon is associated with the negative dc dielectrophoresis arising from nonuniform electric fields in the microchannels. A finite-element model, accounting for the particle-fluid-electric field interactions, is employed to investigate the conditions for this dielectrophoretic (DEP) choking in a converging-diverging microchannel for the first time. It is shown quantitatively that the DEP choking occurs for high nonuniformity of electric fields, high ratio of particle size to throat size, and high ratio of particle's zeta potential to that of microchannel. © …

Comment On "Superfluid Turbulence From Quantum Kelvin Wave To Classical Kolmogorov Cascades", Jeffrey Yepez, George Vahala, Linda L. Vahala, Min Soe

Electrical & Computer Engineering Faculty Publications

No abstract provided.

On The Fractional Solubillity Of Copper In Marine Aerosols: Toxicity Of Aeolian Copper Revisited, Edward R. Sholkovitz, Peter N. Sedwick, Thomas M. Church

OES Faculty Publications

Paytan et al. (2009) argue that the atmospheric deposition of aerosols lead to copper concentrations that are potentially toxic to marine phytoplankton in a large area of tropical and subtropical North Atlantic Ocean. A key assumption in their model is that all marine aerosols (mineral dust and anthropogenic particles) have a high (40%) fractional solubility of copper. Our data show that the fractional solubility of copper for Saharan dust over the Sargasso Sea and Bermuda is significantly lower (1-7%). In contrast, anthropogenic aerosols with non-Saharan sources have significantly higher values (10-100%). Hence, the potential Cu toxicity in the tropical and …

The Widespread Occurrence Of Coupled Carbonate Dissolution/Reprecipitation In Surface Sediments On The Bahamas Bank, David J. Burdige, Xinping Hu, Richard C. Zimmerman

OES Faculty Publications

Using two complimentary approaches (pore water advection/diffusion/reaction modeling and stable isotope mass balance calculations) we show that carbonate dissolution/reprecipitation occurs on early diagenetic time scales across a broad range of sediments on the Great Bahamas Bank. The input of oxygen into the sediments, which strongly controls sediment carbonate dissolution, has two major sources belowground input by seagrasses (that is, seagrass O₂ pumping), and permeability-driven advective pore water exchange. The relative importance of these O₂ delivery mechanisms depends on both seagrass density, and on how bottom water flow interacts with the seagrass canopy and leads to this advective exchange. …

Effect Of The Heterotrophic Dinoflagellate Oxyrrhis Marina And The Copepod Acartia Tonsa On Vertical Carbon Flux In And Around Thin Layers Of The Phytoflagellate Isochrysis Galbana, A. B. Bochdansky, S. M. Bollens, G. C. Rollwagen-Bollens, A. H. Gibson

OES Faculty Publications

Dynamics of material and energy flow through food webs differ when resources are allocated in patches in comparison to situations in which the same resources are distributed evenly throughout the water column. Thin layers of plankton are special cases of such resource patches. While previous studies have predominantly focused on the response of organisms to these layers, we investigated how 2 types of grazers in turn affect thin layers. In an experimental study with tightly controlled environmental conditions, we monitored the redistribution of particulate organic (POC), dissolved organic (DOC) and inorganic (DIC) carbon from thin layers of Isochrysis galbana. …

Causes Of Tropical Atlantic Paleo-Salinity Variation During Periods Of Reduced Amoc, Xiuquan Wan, Ping Chang, Matthew W. Schmidt

OES Faculty Publications

During periods of reduced Atlantic meridional overturning circulation (AMOC) associated with a freshening of northern North Atlantic surface water, paleo proxy records indicate a corresponding surface salinity increase over the entire tropical Atlantic. Although latitudinal-shifts in the mean position of the Atlantic Intertropical Convergence Zone (ITCZ) can explain certain features of the paleo salinity reconstructions, this mechanism does not offer an explanation for the reconstructed basin-wide paleo-salinity response to AMOC change. Here, we present new results from general circulation model simulations that suggest the sea surface salinity (SSS) increase in the tropical north Atlantic during periods of weakened AMOC is …