Physical Sciences and Mathematics Commons^™

Growth Potential Of Young Black Sea Bass, Centropristis Striata, In Artificial Environments, Joung Won Kim

OES Theses and Dissertations

The growth potential of the commercially important marine finfish, black sea bass (Centropristis striata), was examined for aquaculture under controlled conditions. The effect of food and body weight on growth was evaluated using juveniles and young black sea bass cultured with a natural diet and a commercial diet at various feeding levels.

Growth was affected by type of food, food consumption rate, and fish body weight. For fish having positive weight gain, absolute growth rate (gram/day) increased exponentially as food consumption rate (percent of body weight per day) and/or body weight increased. Instantaneous growth rate (percent of body weight per …

Synthesis Of Potential Long Acting Calcium Channel Antagonists: A Study Of 1,4-Dihydropyridine Analogs, Thomas E. Christos

Chemistry & Biochemistry Theses & Dissertations

An investigation was undertaken to synthesize and evaluate longer acting analogs to the antihypertensive agent nifedipine. Analogs that are capable of covalent bonding to the nifedipine receptor were considered. These compounds may show increased activity as they will remain at the receptor for a longer period of time.

During the course of this study, previously unreported and unexpected products were encountered and lead to a more intense examination of the Hantzsch synthesis. Of particular interest was the oxazolidine 25 which was a major component of the Hantzsch synthesis when ethanolamine was used instead of ammonium hydroxide. Also isolated during this …

Reactions Of Organic N-Chloramines In The Gastric Fluid Of The Rat, Kathryn E. Mazina

Chemistry & Biochemistry Theses & Dissertations

Using chlorine as a drinking water disinfectant may have potential health effects due to its reactivity with organic amino nitrogen compounds found in the stomach. Organic N-chloramines have been shown to form in the stomachs of laboratory rats. The possible reactions of N-chloramines in the stomach fluid were examined in this study using a model radiolabeled N-chloramine. ³⁶Cl-N-Chloropiperidine, was synthesized and purified to remove ³⁶Cl-chloride. Stomach fluid was obtained from Sprague-Dawley rats which had been first fasted for 24 or 48 hours and then administered 3 mL of deionized water. Different concentrations of radiolabeled chloramine were reacted with …

A Comparison Of Potential Fishing Methods Associated With Fish Aggregating Devices Off The Northeast Coast Of Puerto Rico, Alan M. Friedlander

OES Theses and Dissertations

Six fish aggregating devices (FADs) were deployed in June and monitored through December 1986. Emphasis was placed on trolling, live-bait handlining and longlining.

There was a significant difference (x2 = 7.815, pCoryphaena hippurus) which made up 64.2% of the catch.

Handlining at night around inshore buoys for one boat yielded 82.7 kg per trip. Pelagic fish comprised 83.9% of the catch, with the majority (81.4%) being kingfish (Scomberomorous cavalla). Catch rates were 50% higher and the species diversity much greater on the FADs versus control during experimental nightfishing, but the difference was not significant.

Longlining resulted in 3.4 …

Laminar Viscous Effects On Longitudinal Dispersion In Tidal Froude Models, Larry H. White

OES Theses and Dissertations

A laboratory investigation was designed to test the ability of a tidal Froude model operated according to the minimum Reynolds number criterion of 1400 to simulate the longitudinal dispersion of its turbulent, laboratory prototype in the absence of depth distortion and density stratification. To examine the model's performance, comparative tracer-dye dispersion tests were conducted in the model and in the prototype to determine spatial and temporal longitudinal dye distributions. Froude similitude of cross-sectional mean tide heights and current velocities was achieved. The minimum Reynolds number criterion did not guarantee turbulent flow throughout all tidal stages, prolonged periods of laminar flow …

The Geochemistry Of Selenium And Sulfur In A Coastal Salt Marsh, David Jay Velinsky

OES Theses and Dissertations

Investigation of the various chemical forms of selenium and sulfur in sediments and pore waters can provide information about various oxidation/reduction processes. Five cores were obtained from the Great Marsh, from April 1985 to June 1986. Sampling times coincided with the seasonal redox cycle known to occur within the marsh system. Sediments were analyzed for various selenium and sulfur phases.

Iron monosulfides and elemental sulfur both display large seasonal changes in concentration and distribution with depth, indicating a coupling with redox conditions. In contrast, the depth distribution of greigite did not show appreciable changes with season. Pyrite underwent large concentration …

Processes Which Create And Destroy Stratification In The South Atlantic Bight During Gabex Ii, Rebecca Lynn Lovingood

OES Theses and Dissertations

The stratification present on the South Atlantic Bight (SAB) during the summertime is influenced by creative forces, namely surface heating, precipitation, fresh water runoff and advection of Gulf Stream water, and destructive forces, these being wind, bottom currents, tides, evaporation and cooling. During the summer of 1981 the Georgia Bight Experiment II (GABEX II) was conducted to evaluate the Gulf Stream intrusions on the shelf dynamics. Calculations using potential energy as an indicator of stratification showed that the mixing forces were strong enough to destroy the stratification if the advection of buoyancy is ignored. During this period, however, the potential …

Analysis Of Phytoplankton And Particle Variability At A Warm Core Ring/Shelf Break Front Using Flow Cytometry, Kimberly G. Davis

OES Theses and Dissertations

Particle variability at a Gulf Stream warm core ring/ shelf break front on 09 Nay 1985 was analyzed. Single particle measurements of fluorescence, perpendicular light scatter, and volume were made using a FACS Analyzer flow cytometer. Advantages and disadvantages of at-sea use of the instrument are described. To evaluate the flow cytometry data, individual particle data were compared with bulk phytoplankton and particle measurements. Abundance and size distributions of fluorescent and non-fluorescent particles indicated a convergence zone at the front while upwelling was likely within the ring perimeter. Variability in fluorescence (approximating chlorophyll A) and cell biovolume exposed regions of …

Determination Of Amino Acids And Chloramino Acids In Municipal Wastewater, Jeffrey Taylor Jewell

Chemistry & Biochemistry Theses & Dissertations

It is well known that unchlorinated municipal wastewater contains high levels of organic and inorganic amino nitrogen compounds, the single most abundant amino-N species being ammonia. Upon chlorination, these compounds are transformed almost instantaneously and quantitatively into N-chloramino derivatives. The organic chloramines have been shown to

interfere with disinfection and have lower disinfection capacities than their inorganic counterpart monochloramine. The environmental effects imposed by the discharge of these compounds into natural receiving waters is unknown. This study has shown that amino acid precursors for N-chloramino acids range in concentration from 1.4 X 10^-7 M to 9.0 X 10^{-7 …}

Cross-Shore Sediment Transport In Relation To Waves And Currents In A Groin Compartment, Hyo Jin Kang

OES Theses and Dissertations

In nearshore areas waves are generally irregular, and the irregular wave-induced currents have different peak velocities (magnitude asymmetry) and durations (duration asymmetry) between forward and backward motions. These asymmetries may produce a net cross-shore sediment transport in one direction. The sediment transport mostly occurs as bedload where the waves are non-breaking.

Sediment transport on a sloping bed is also affected by gravity, and accordingly the Shields parameter should be re-evaluated for a grain on a sloping bed. It was also found that the affect of a steady current that interacts nonlinearly with the waves was important for the cross-shore sediment …

Large Deviation Local Limit Theorems For Ratio Statistics, Sanjeev V. Sabnis

Mathematics & Statistics Theses & Dissertations

Let {T„, n > 1} be an arbitrary sequence of non-lattice random variables and {S_n, n > 1} be another sequence of positive non-lattice random variables. Let the two sequences be independent. Let Ø_1n and Ø_2n be the moment genereating functions of {Tn, n > 1} and { S_n,n > 1} respectively. Let {a_n} be a sequence of real numbers such that a_n —»• oo.

An Annual Study Of Phytoplankton Composition And Associated Environmental Conditions Of Lake Trashmore, Virginia Beach, Virginia, Seba B. Sheavly

Biological Sciences Theses & Dissertations

A 12 month study of Lake Trashmore was conducted on phytoplankton composition, inorganic nutrients and their seasonal associations. The dominant phytoplankton groups observed were diatoms, chlorophyceans and cyanobacteria. Phytoplankton assemblage patterns were coupled with pH, temperature, dissolved oxygen, nitrites and silicates. Diatoms dominated during periods of high nutrient concentrations, cooler temperatures and an unstable water column. Cyanobacteria forms dominated during periods of warmer temperatures, higher pH and decreased nitrogen and dissolved oxygen concentrations. A seasonal community shift occurred from cyanobacterial dominance to chlorophycean dominance when pH levels decreased. The lake is eutrophic based on indices of chlorophyll a concentrations, transparency …

Provenance Of Sands Within The Lower Chesapeake Bay Based On Ilmenite Composition, Edward Augustus Council Iii

OES Theses and Dissertations

Surficial sands deposited in the Chesapeake Bay are a mixture of sands derived from the bay's shorelines, from offshore, and from relict deposits. Direct fluvial input is probably minor except from the James River, which may serve as a local source of sands in the Thimble Shoals area. Sands in the western half of the bay are primarily derived from the erosion of the adjacent shoreline. In contrast, the eastern half of the bay has two major sources of sand. Shoreline erosion is the dominant source north of the town of Eastville, Virginia, while the offshore is the major source …

On A Moving Boundary Problem Of Transitional Ballistics, Jen-Ing G. Hwang

Mathematics & Statistics Theses & Dissertations

A major problem which arises in computer simulation of the firing of a gun weapon is the development of numerical schemes which effectively account for the physics of projectile motion. The chief difficulty is that away from the projectile the calculation is ordinarily accomplished on a fixed numerical grid, whereas due to projectile movement some cells of the grid near the projectile undergo volume changes as the calculation proceeds. A local finite volume scheme is developed which accounts for the expansion or compression of cells fore-and-aft of the projectile. Through the process of numerical experiment, the effectiveness of the scheme …

A Numerical Study Of Three-Dimensional Vortex Breakdown, Robert Edward Spall

Mechanical & Aerospace Engineering Theses & Dissertations

A numerical simulation of vortex breakdown using the time-dependent Navier-Stokes equations was performed. Unlike previous studies, the numerical algorithm, formulated in terms of the velocity and vorticity, was not restricted to axisymmetric flows. Prototype vortices were parameterized in terms of their Reynolds number and Rossby number. Two cases were studied extensively. In one case, a vortex was imbedded in a uniform free stream. In the other case, the axial velocity of the free stream was decelerated in the streamwise direction. For both cases breakdown occurred when the Rossby number was below a critical value. Vortex lines, particle traces and velocity …

Groin-Associated Rip Currents Measured Using A New Digital Current Meter, Dennis L. Lundberg

OES Theses and Dissertations

Rip currents have often been noted in physical model studies of groins and their effectiveness. Nevertheless, detailed field investigations of rip currents along a groin wall have not been heretofore conducted. A new digital current meter system was designed and built to study the groin-associated rip currents in a test groin compartment at Willoughby Spit, Norfolk, VA. Six ducted impeller current meters are controlled by a data acquisition system that utilizes an onboard microprocessor and solid state memory. The new system provides high quality data on horizontal water velocities associated with wave action. The velocities stored are time mean velocities …

The Stratigraphy Of Late Quaternary Deposits In The Payan Mining District, Narino, Colombia, South America, Richard Alan Barringer

OES Theses and Dissertations

Late Quaternary terrace deposits along the Rio Magui consist of cobble or pebble gravels with thick volcanic ash caps. These gravel terrace deposits unconformably overlie a cemented volcanic tuff (Ananias Formation), and are subdivided into two formations (Antigua and Panambi formations) based on the cobble lithology and size, depth of weathering, geomorphic relationships, and heavy mineral assemblages. Carbon-14 dates from wood suggest that the Antigua fan deposits are older (greater than 40,000 YBP) than the lower Panambi alluvium (less tahn 25,000 YBP) which is restricted to lower terraces within the modern river valleys.

Two separate ash units identified by differences …

A Simple Numerical Model For The Study Of Baroclinic Estuarine Shelf Interactions, Thomas J. Berger

OES Theses and Dissertations

A one and a half layer nonlinear f-plane numerical model was used to study estuarine-shelf interactions. The single active layer covered a domain consisting of a 100 km long by 20 km wide channel discharging onto a 100 km wide by 300 km long shelf. Channel and "western” shelf boundaries were no-slip, "eastern" or oceanic boundary was free-slip and "northern" and "southern" shelf boundaries were open. The channel was forced with a constant inflow velocity spun up from 2 cm s^-1 to 27 cm s^-1over five days. The model initial conditions were a flat interface at …

Studies Of Radiation Effects In Three High Polymers, Heidi Rene-Mitchell Ries

Physics Theses & Dissertations

Three high polymers, Mylar®, Ultem®, and Kapton®, were irradiated to total doses of 1, 5, and 9.5 gigarad using 1-MeV electrons. The glass transition temperatures (T_g) of the materials before and after irradiation were measured using an AC electrical dissipation factor technique. From the T_g data, it was found that the electron radiation at these total doses results in net chain scissioning in Mylar and net crosslinking in Ultem, while self-mending is predominant in Kapton. The dielectric constant was measured before and after irradiation, but no significant changes due to irradiation were observed. Electron paramagnetic resonance (EPR) …

Ignition Of A Combustible Solid With Reactant Consumption, D. Glenn Lasseigne, W. E. Olmstead

Mathematics & Statistics Faculty Publications

The effects of excessive reactant consumption on the ignition of a combustible solid are introduced through a revised scaling of the heat release constant. Large activation energy asymptotics then yields a new one-parameter integral equation governing the temperature evolution near ignition. Analysis of the integral equation reveals a critical value of the parameter which distinguishes between the cases of ignition and nonignition. © 1987 Society for Industrial and Applied Mathematics

The Relationship Of Upwelling To Mussel Production In The Rias On The Western Coast Of Spain, Jack O. Blanton, Kenneth R. Tenore, F. Castillejo, Larry P. Atkinson, Franklin B. Schwing, Amy Lavin

CCPO Publications

We have calculated an upwelling index for each month over a 17-year period (1969-1985) for a point off the western coast of Spain. We interpret April through September values of the index to indicate the flux of nitrate-rich water in the Spanish Rias. The index representing the 6-month upwelling series has been correlated with an index representing the conditions of mussels grown during that season on rafts in Ria de Arosa. Two seasons represent extreme upwelling conditions over the 17-year sampling period: 1977 when the upwelling index was the highest, and 1983 when it was the lowest. A comparison of …

Shoreward Intrusion Of Upper Gulf Stream Water Onto The United States Southeastern Continental Shelf, Lie-Yauw Oey, Larry P. Atkinson, Jackson O. Blanton

CCPO Publications

In winter, cooling of the South Atlantic Bight continental shelf water results in higher density in the middle shelf region relative to the shelf-break region where the western flank of the Gulf Stream flows. Shoreward, estuarine-like intrusion of the upper Gulf Stream water in the presence of such a positive onshore density gradient is then possible through advective processes triggered either by the meander of the Stream or onshore Ekman transports by southward wind stresses. Repeated cross-shelf hydrographic transects were conducted from 10 January through 30 January 1986 to more closely study this intrusion process. These observations show many features …

Acceleration Of Nutrient Uptake By Phytoplankton In A Coastal Upwelling Ecosystem: A Modeling Analysis, Richard C. Zimmerman, James N. Kremer, Richard C. Dugdale

OES Faculty Publications

Studies of upwelling centers in the eastern Pacific suggest that maximum rates of nitrate uptake (light and nutrient saturated) increase, or shift-up, as newly upwelled water moves downstream. The rate of shift-up appears to be related to irradiance and the ambient concentration of limiting nutrient at the time of upwelling. A mathematical model was developed to evaluate effects of irradiance and initial nitrate concentration on temporal patterns of shift-up and subsequent time scales of nutrient utilization over a range of simulated upwelling conditions. When rates consistent with field studies were used, complete shift-up was possible only under certain conditions, and …

Comment On "Orientation, Alignment, And Hyperfine Effects On Dissociation Of Diatomic Molecules To Open Shell Atoms", Mark D. Havey, Linda L. Vahala

Electrical & Computer Engineering Faculty Publications

A recent paper in this journal [Y. B. Band e t a l., J. Chem. Phys. 8 4, 3762 (1986)] reported parameters describing orientation and alignment produced, in an axial recoil limit, by one photondissociation of diatomic molecules. Reported also were values, applicable to the resonance transitions of the alkali atoms, for orientation and alignment depolarization coefficients. Most of the numerical values reported for the coefficients were incorrect, in some cases by as much as a factor of 2. We report a tabulation of correct depolarization coefficients applicable to the resonance transitions of common alkali isotopes. Further, the coefficients …

Limit Theorems In The Area Of Large Deviations For Some Dependent Random Variables, Narasinga Rao Chaganty, Jayaram Sethuraman

Mathematics & Statistics Faculty Publications

A magnetic body can be considered to consist of n sites, where n is large. The magnetic spins at these n sites, whose sum is the total magnetization present in the body, can be modelled by a triangular array of random variables (X(n) 1,..., X(n) n). Standard theory of physics would dictate that the joint distribution of the spins can be modelled by dQ_n(x) = z_n^-1 exp[ -H_n(x)]Π dP(x_j), where x = (x₁,..., x_n) ∈ Rⁿ, where H_n is the Hamiltonian, z_n is …

The Hydrogeology Of Nags Head Woods, Dare County, North Carolina, Janet Salyer Emry

OES Theses and Dissertations

Nags Head Woods, a coastal maritime forest located on a barrier island in eastern North Carolina, stabilizes a back-barrier dune system bordering a tidal marsh. The purpose of this study is to provide basic information about the groundwater geology in Nags Head Woods and to predict the effects upon water levels due to municipal pumping of Fresh Pond, a large lake near the center of the island.

Clean, fine-to-medium sands dominate the top of the surficial (water table) aquifer, underlain by silty fine-to-coarse sands at -4 m elevation. A silty clay bed of very low permeability is present at -12 …

Validation Of The Otolith Increment Aging Technique For Striped Bass, Morone Saxatilis, Larvae Reared Under Suboptimal Feeding Conditions, Cynthia Jones, Edward B. Brothers

OES Faculty Publications

Striped bass, Morone saxatilis, larvae were reared in the laboratory for 97 days to validate the otolith increment aging technique for this species. Otolith-increment deposition rates were determined under optimal laboratory conditions for growth and under three conditions of restricted feeding and using both light and scanning electron microscopy (SEM). Under optimal laboratory conditions. increments were deposited daily from the fourth day after hatching through the first 2 months of life and were discernible with the light microscope. For larvae reared under restricted feeding regimes and readings done with the light microscope, counts did not reflect true age. Counts …

Is Growth Of Eelgrass Nitrogen Limited? A Numerical Simulation Of The Effects Of Light And Nitrogen On The Growth Dynamics Of Zostera Marina, Richard C. Zimmerman, Robert D. Smith, Randall S. Alberte

OES Faculty Publications

A numerical model of nitrogen uptake and growth was developed for the temperate seagrass Zostera marina L. Goals were to evaluate the relative effects of light and nitrogen availability on nitrogen uptake and partitioning between leaf and root tissue, and to estimate nitrogen concentrations in the sedment and water column required to saturate growth. Steady-state predictions are quite robust with respect to a range of parameter values justified by available data The calculations indicated that roots are probably more important in overall nitrogen acquisition in most light and nitrogen environments encountered in situ, but may contribute less than 50 …

On The Thermal Stresses Due To A Uniform Heat Flow Past A Circular Hole With A Radial Edge Crack, George F. Edmonds

Mathematics & Statistics Theses & Dissertations

The problem solved in this dissertation is that of finding the stresses in an isotropic, linear, thermoelastic solid when a uniform heat flow is disturbed by the presence of an insulated circular hole with a radial edge crack. By superimposing a Mellin transform solution of the equations of thermoelasticity on a Michell series solution the author reduces the problem to a pair of singular integral equations which are then solved numerically. The stress intensity factors and crack formation energies, quantities of interest to workers in fracture mechanics, are then calculated.

Depositional And Diagenetic History Of The Middle Ordovician Carbonates Of The Shenandoah Valley, Northern Virginia, Lynn Ellen Weyenberg

OES Theses and Dissertations

An examination of the Middle Ordovician carbonates in northwest Virginia has revealed a particularly sensitive record of deposition and subsidence. Two-hundred acetate peels from six measured stratigraphic sections in Shenandoah County, Virginia were examined to interpret the depositional and diagenetic history. Two major lithofacies have been recognized within the New Market Limestone and three have been recognized in the Lincolnshire Formation. These five lithofacies represent an overall transgressive sequence. This transgression was not uniform but paused several times to allow carbonate deposition to reach sea-level. These shoaling events suggest a slowly subsiding basin in this region. The carbonate rocks within …