Physical Sciences and Mathematics Commons^™

Leachate Monitoring In Naturally Saline Groundwater Chesapeake Landfill Chesapeake Virginia, T. Britt Mcmillan

OES Theses and Dissertations

Groundwater chemistry around the Chesapeake municipal landfill was monitored over a one year period. Ten sample sites as well as two surface water sites were used to monitor water quality. Two wells, one at 3 m and the other at 10 m were located at each site. Surface water samples were taken from the Elizabeth River, north of the landfill, and a tidal channel, west of the landfill. Seven groundwater sites were downgradient of the landfill and three sites were upgradient (control sites).

The landfill overlies a tidal marsh, approximately 100 m south of the intracoastal waterway (Elizabeth River). Dredge …

Depositional Environments Of Late Precambrian Sediments From Liberia, Sierra Leone, And Senegal, West Africa, Alfred W. Magee Iii

OES Theses and Dissertations

Field and hand sample descriptions were supplemented with petrographic and textural analyses derived from thin sections, and scanning electron microscopy (SEM) to determine environments of deposition for the late Precambrian Gibi Mountain Formation, Liberia, Tabe

Formation, Sierra Leone, and the basal Mali Group, Senegal, West Africa.

The Gibi Mountain Formation consists of a glaciomarine tillite, marine laminites with dropgrains, and shallow water arkoses. A shale facies remains unresolved in origin.

The Tabe Formation is composed of three members: Tibai, Dodo, and Taban. The Tibai Member contains a glaciomarine tillite deposited in a shallow shelf marine environment, marine laminites, and shallow …

Lineament Analysis And Tectonic Interpretation For The Central Tharsis Region, Mars, Robert C. Anderson

OES Theses and Dissertations

Lineament studies conducted for the Central Tharsis Region of Mars (JOON and JOOS latitude; 450w to 157.50W longitude) indicate two major events controlled the formation of the Tharsis Dome: 1) a pre-Tharsis fracture system consisting of North-West (3150) trending fractures; and 2) a Tharsian fracture system containing North-South (355°) and East-West (275°) trending fractures. The North-West (3150) trending fractures represent a crustal weakness zone which controlled the early formation of the Tharsis Dome. Analytical studies suggest four centers of uplift: 1) 6°N, 124°W; 2) 0.5°N, 114°W; 3) 5°S, 105°W; and 4) 7°S, 104°W. Each of these uplifting centers is associated …

Depositional Model For The Auriferous Gravels In The Payan Mining District Department Of Narino, Columbia, South America, Jim R. Garrett

OES Theses and Dissertations

Unlike placer deposits in arid and semi-arid environments where gold concentration is closely tied to the position of the bedrock, Payan placer deposits have no association with bedrock. Gold concentration values show highest gold concentrations occur at the contact of a coarse sand unit and its underlying gravel unit. Comparisons of the size and shape distributions of gold grain populations with their associated black sand populations indicate the gold and black sand were not deposited in hydraulic equilibrium. The mean size of each gold population is consistently coarser than the mean size of its associated black sand population despite the …

Design Of Multivariable Feedback Control Systems Via Spectral Assignment, Mohsen Marefat

Electrical & Computer Engineering Theses & Dissertations

During the past 15 year s significant advances have been made towards developing viable synthesis- techniques for multivariable feedback control systems. The entire aggregate of this theoretical work has been reviewed and consolidated. Diverse notations have been standardized into a single system. A two-step design philosophy for spectral assignment has been developed which first meets stability and time response requirements by assigning eigenvalues and eigenvector s and then provides for attainment of secondary objectives without significant deviation from the initial assignment. Finally, a computer-aided design package has been created to streamline the process of mathematical calculation and to allow users …

Investigation Of Eddy Population And Motion In The Southern International Ice Patrol Operations Area (40°-47°N By 40°-55°W), Frank J. Williams

OES Theses and Dissertations

A study of the eddy population in the Newfoundland Basin region over the period from November 1981 to December 1984 was conducted. The study was undertaken to demonstrate the importance and basic character of eddy motion in the area patrolled by the International Ice Patrol. This is a descriptive study and no rigorous mathematical solutions are attempted. Data was collected on the number of eddies in the area, their average duration and size, formation, migration and deterioration patterns and rotational velocity. Satellite infrared imagery maintained by National Weather Service and Naval Eastern Oceanographic Center, Canadian Forces METOC Center sea surface …

Conodont Biostratigraphy Of The Cambrian-Ordovician Boundary Interval In The Northern Shenandoah Valley Of Virginia, U.S.A., Randall C. Orndorff

OES Theses and Dissertations

Conodonts collected from two measured sections in the northern Shenandoah Valley of Virginia indicate that locally the Cambrian-Ordovician boundary is within the upper part of the Conococheague Formation and that the Conococheague-Stonehenge formational contact as defined in this study, is diachronous in relation to the boundary. Using the generally accepted definition of the CambrianOrdovician boundary as at the base of the trilobite Missisguoia Zone or within the conodont Hirsutodontus hirsutus Subzone of the Cordylodus proavus Zone, it is found here that the boundary is 230 ft (70 m) below the formational contact at the Narrow Passage Creek section. Several North …

Comparison Of An Improved Plankton Sampler To The Standard Conical Plankton Net, Ronald S. Schmidt

OES Theses and Dissertations

A comparison of field and tank tests between the standard conical plankton net and an improved version of a plankton sampler is presented. The improved sampler was shown to filter larger quantities of water than the standard net without having the filtration efficiency reduced below 85%. The improved sampler was also shown to capture an increased number of plankton per volume sampled, as a result of eliminating increased avoidance activity by zooplankton. It was not shown that. the improved sampler capture either larger maximum sizes of zooplankton or additional species.

High Performance Switching Circuits For Vlsi, Ali Reza Feizi

Electrical & Computer Engineering Theses & Dissertations

Interconnection topology and device performance are of major concern in the design of LSI/VLSI systems, Pass networks are very suitable in this regard because of low power consumption, high density, and simple interconnection topology. A special type of pass networks called Binary Tree Structured (BTS) pass networks uses almost minimum number of transistors for the design of switching circuits. An algorithmic procedure is developed here for BTS pass networks which is very efficient in terms of both execution time and memory space. Based on these networks, the necessary and sufficient conditions are derived for the design of multiple-output pass networks. …

Algebraic Grid Generation Using Tensor Product B-Splines, Bonita Valerie Saunders

Mathematics & Statistics Theses & Dissertations

In general, finite difference methods are more successful if the accompanying grid has lines which are smooth and nearly orthogonal. This thesis discusses the development of an algorithm which produces such a grid when given the boundary description.

Topological considerations in structuring the grid generation mapping are discussed. In particular, this thesis examines the concept of the degree of a mapping and how it can be used to determine what requirements are necessary if a mapping is to produce a suitable grid.

The grid generation algorithm uses a mapping composed of bicubic B-splines. Boundary coefficients are chosen so that the …

The Apparent Dissociation Constants Of Carbonic Acid In Low Salinity Waters, Ching-Hui Hsu

OES Theses and Dissertations

The first and second apparent dissociation constants of carbonic acid in artificial seawater and diluted artificial seawater, K₁ ' and K₂ 1 were determined at selected combinations of temperatures and salinities between 2 to 30° C and 0 to 35 o/oo with special attentions to waters with salinities below 20 o/oo at atmospheric pressure by measuring K₁ ' and the product of K₁ ' and K₂.

The results can be expressed as functions of temperature and salinity by the following equations, pK₁ '=3360.206T^-1 +0. 033331 T-14.8303-0.09633x (Cl^1/2) pK₂ '=14911.671 …

Minimal Norm Constrained Interpolation, Larry Dean Irvine

Mathematics & Statistics Theses & Dissertations

In computational fluid dynamics and in CAD/CAM a physical boundary, usually known only discreetly (say, from a set of measurements), must often be approximated. An acceptable approximation must, of course, preserve the salient features of the data (convexity, concavity, etc.) In this dissertation we compute a smooth interpolant which is locally convex where the data are locally convex and is locally concave where the data are locally concave.

Such an interpolant is found by posing and solving a minimization problem. The solution is a piecewise cubic polynomial. We actually solve this problem indirectly by using the Peano kernel theorem to …

Development Of An On-Line Computer System For Cyclic Voltammetry Studies, Tai-Lee Leo Huo

Chemistry & Biochemistry Theses & Dissertations

An Apple II Plus microcomputer was interfaced to a PAR 174A Polarographic Analyser, an HP 7O4OA X-Y recorder and a three-electrode system. This on-line computer system was applied to Cyclic Voltammetry (CV) studies. The interfacing involved both hardware and software development. Various hardware components were used to amplify and transmit the analog signal both going into the computer and coming from the computer. Software programs were written for staircase waveform generation, data acquisition, and plotting the voltammograms obtained.

A package was designed for CV experiments to be used by the students in the instrumental analysis laboratory. This package contains several …

Mossbauer Study Of Gadolinium Iron Garnet, Jun Li

Physics Theses & Dissertations

The Mossbauer spectroscopic study of Gadolinium Iron Garnet R₃Fe5^O12 (GdIG) has been performed over the temperature range of 7K to 715K. Both high temperature and low temperature properties of GdIG have been studied. The magnetization is along (111) direction over this temperature range. The internal magnetic fields at Fe⁵⁷ sites in GdIG gave two values for the octahedral(a), site which differ by 4-6 KOe and one value for the tetrahedral (d), site at each temperature. Measurements of the total isomer shift in the spectra show that the shift of the center of the spectra consists …

Color Display Of Vowel Spectra As A Training Aid For The Deaf, Amir Jalali Jagharghi

Electrical & Computer Engineering Theses & Dissertations

The objective of this research was to develop a transformation for mapping speech parameters to color parameter. This transformation is done in real-time, and the resulting color parameter are continuously displayed on a color monitor. This visual speech display is to be used as a speech articulation training aid for the deaf. The conversion of speech acoustic signals into speech parameter was accomplished using special -purpose electronics. The real-time conversion of speech parameter to display parameter was controlled by an 8086/8088 microprocessor operating in an S-100 bus structure. The coefficients of the Karhunen-Loeve series expansion of speech power spectra were …

Analog Computer Simulation With Automatic Scaling By Digital Computer, Mark Anthony Motter

Electrical & Computer Engineering Theses & Dissertations

A computer-aided design approach for the simplification of analog computer simulation is presented. The simulation configuration consists of an EAI 2000 analog computer with serial communications link to a PDP — 11/24 digital computer. Under control of the PDP-11, the analog simulations are realized with appropriate time and magnitude scaling which adjusts the range of the simulation coefficients and prevents overloads of the analog components. The analog computer hardware configuration accommodates both stable plants up to eighth order and closed-loop systems up to tenth order. Cascade compensation is provided for the closed-loop systems.

The plant may be described by either …

Feasibility Studies Of Conversion Electron Mossbauer Spectroscopy (Cems) Of Iron-Doped Inp, Edward Agyekum

Physics Theses & Dissertations

An electron detector for conversion electron Mossbauer spectroscopy (CEMS) has been designed and built. Tests have been performed to study the effects on the electron detector resolution with respect to high anode voltage, He/CH₄ gas flow rate, and counting rate. These parameters have been optimized to detect the 7.3 keV conversion electrons emitted following resonant absorption of the 14.4 keV source gamma-rays associated with the Mossbauer effect using ⁵⁷Fe nuclei. CEMS spectra have been obtained using standard ⁵⁷Fe enriched and natural iron samples. CEMS spectra and Mossbauer transmission spectra have also been obtained for iron-compensated InP (InP:Fe) …

Foraminiferal Paleoenvironments Of The Eastover Formation (Upper Miocene Virginia), Joann H. Goshorn

OES Theses and Dissertations

Sixty-two taxa representing 29 genera from 39 foraminiferal sample pairs have been documented and analyzed in a paleoenvironmental study of the Eastover Formation in southeastern Virginia. The Eastover Formation consists of a lower Claremont Manor Member, a silt fine-grained sand and an upper Cobham Bay Member, a shelly fine grained sand. Planktonic specimens were rare and indicated a late Miocene to early Pliocene age for the Eastover Formation. Benthics were used to interpret paleoenvironments by comparison with data from the distribution of Recent foraminifera, species diversity, planktonic to benthic ratios, and sediment analyses. The foraminifera indicate that the Eastover Formation …

Statistical Calibration Theory, James John Mckeon

Mathematics & Statistics Theses & Dissertations

A calibration method substitutes for measurements, X(,i), that are accurate but impractical or costly, a set of measurements, Y(,i), that are less accurate but simpler or less costly. There are two general types of calibration methods. The classical approach in which once the calibration sample is drawn, the estimates of the X values for a given unit is found without any consideration of the distribution of X values for the other units to be measured. This corresponds best to the literal meaning of the word "calibration". Maximum likelihood estimation is the statistical formulation of the classical approach.

The second approach …

The Synthesis And Evaluation Of A New Analog Of Phencyclidine (Pcp), William H. Johnson Jr.

Chemistry & Biochemistry Theses & Dissertations

Based on an interpretation of the literature of phencyclidine (PCP) together with an examination of the relevant models or prototype structures, this research has attempted to design and synthesize a rigid analog of the phencyclidine structure. The parent ring systems suggested for this study were the 1-arnino and 2-arninornethyltetralins, 10 and, 12.

Several organic compounds, based on this design, have been prepared by classical examples of reductive alkylation reactions of the corresponding 2-hydroxyciethylene-1-tetralones, 11, and by the condensation and subsequent reductive alkylation of the 1-arninotetralin, 9. These arninomethyltetralones, 28, 29 and 30, together with an example of a substituted 1-arninotetralin, …

A Geophysical Model Of The Gravity-Magnetic High, Virginia Coastal Plan, Gordon Everett Davison

OES Theses and Dissertations

The coastal plain province of Virginia is characterized by a coincidental gravity and magnetic high separating Appalachian-trend geophysical signatures to the west from non-Appalachian signatures to the east. Two cross-trend gravity and magnetic profiles, one on the Northern Neck of Virginia and one along Interstate Highway 64, were used to interpret the anomalous high. The profile models suggests that the anomaly is characterized by high-density, variably magnetic, east-dipping (60°) crustal blocks. Further information from well-logs indicate that the anomaly is due to meta-mafic rocks of oceanic origin, flanked by low-density, lower susceptibility, granitic units. This suggests that the anomalous gravity-magnetic …

Fluvial Depositional Processes Of A Tropical River, Colombia, South America, Michael L. Babuin

OES Theses and Dissertations

Fluvial depositional processes along the Rio Magui in south-western Columbia are primarily controlled by localized uplift downstream of the mouth of the river, sediment sources that produce both coarse-and-fine-grained load, and numerous over-bank flows caused by torrential rainfall.

Test Derivation For Cmos Iterative Logic Arrays, Ravi Sharma

Electrical & Computer Engineering Theses & Dissertations

Testability criteria for stuck-open (s-op) faults in one-dimensional unilateral iterative logic arrays (ILA) of CMOS combinational cells are considered in this thesis. A functional fault model to represents-op faults i~ an ILA cell is given. The procedure to detect as-op fault needs a pair of test vectors. The first is used to set up the initial conditions required to test the fault and the second is the test which distinguishes between the good and the bad circuit. Based on this approach necessary and sufficient conditions are given for the testability of as-op fault in a CMOS ILA cell. These conditions …

Effects Of El Nino On Local Hydrography And Growth Of The Giant Kelp, Macrocystis Pyrifera, At Santa Catalina Island, California, Richard C. Zimmerman, Deborah L. Robertson

OES Faculty Publications

Deepened isotherms associated with El Niño resulted in severe nutrient limitation and very low kelp productivity during the last half of 1983. Frond growth rates were so low that terminal blades formed before reaching the surface, eliminating the canopy. Frond initiation rates were also extremely low, resulting in significant reductions in mean plant size. Plants growing above 10m were more severely affected than plants at 20m. Nutrient pulses associated with internal waves are thus critical for survival of Macrocystis pyrifera in nutritionally marginal habitats in Southern California.

Community Ecology, Robert K. Rose, Elmer C. Birney

Biological Sciences Faculty Publications

COMMUNITIES with Microtus tend to be structurally simple, usually grasslands or tundra, and to have no more than two species of Microtus and rarely more than six species of small mammals. Microtus often dominates both numerically and in total small mammal biomass, especially at higher latitudes. The small mammal community is most influenced by Microtus through its fluctuations in density, and thus also in biomass, by its relatively high level of diurnal activity, and by its year-round activity. Other species of small mammals may be adversely affected because Microtus usually is larger and behaviorally dominant and also because the mere …

Microbial Manganese Reduction By Enrichment Cultures From Coastal Marine Sediments, David J. Burdige, Kenneth H. Nealson

OES Faculty Publications

Manganese reduction was catalyzed by enrichment cultures of anaerobic bacteria obtained from coastal marine sediments. In the absence of oxygen, these enrichment cultures reduced manganates when grown on either lactate, succinate, or acetate in both sulfate-free and sulfate-containing artificial seawaters. Sodium azide as well as oxygen completely inhibited microbial manganese reduction by these enrichment cultures, whereas molybdate had no effect on them. The addition of nitrate to the medium slightly decreased the rate of Mn²⁺ production by these enrichment cultures. These findings are consistent with the hypothesis that the manganese-reducing organisms in these enrichment cultures use manganates as terminal …

Fault Movements And Tectonics Of Eastern Iran: Boundaries Of The Lut Plate, Ali A. Nowroozi, A. Mohajer-Ashjai

OES Faculty Publications

Summary. From 1977 March 21 to 1981 July 28, about 15 earthquakes with M_s ≥6.0 and many earthquakes with M_s≥4.5 have occurred in Iran. The upsurge of seismic activity started following the Khorqu earthquake of 1977 March 21, M,=7.0, south-east of the Fars folded series of Zagros. This shock had a thrust focal mechanism solution indicating the general northward movement of the Arabian plate with respect to the Iranian landmass. It was followed by six major damaging earthquakes in eastern Iran. The earthquakes are associated with extensive faulting which surrounds the Lut plate. (1) The Zarand earthquake …

Large Deviation Local Limit Theorems For Arbitrary Sequences Of Random Varibles, Narasinga Rao Chaganty, J Sethuraman

Mathematics & Statistics Faculty Publications

The results of W. Richter (Theory Prob. Appl. (1957) 2 206-219) on sums of independent, identically distributed random variables are generalized to arbitrary sequences of random variables T_n. Under simple conditions on the cumulant generating function of T_n, which imply that T_n/n converges to zero, it is shown, for arbitrary sequences {m_n}, that k_n (m_n), the probability density function of T_n/n at m_n, is asymptotic to an expression involving the large deviation rate of T_n/n. Analogous results for lattice …

The Use Of Ilmenite Element Composition For The Determination Of Provenance, Yu W. Tsang

OES Theses and Dissertations

Fifty three samples were taken from three major rivers and their tributaries in Virginia: the James, Roanoke. and Potomac-Shenandoah Rivers. Samples were obtained from the Valley and Ridge. Blue Ridge and Piedmont provinces. The possible source rock types for these samples were determined by comparison of tributary ilmenite composition with drainage basin rock types. Ilmenite element concentration varied with different rock types. Ti was usually high for the ilmenite derived from non-mafic igneous rocks. Mg and Cr were high for the ilmenite from mafic igneous rocks. Zn was low for metamorphic ilmenite. The ilmenite from sedimentary rocks tended to have …

Sedimentologic And Stratigraphic Significance Of Boulder Layers In The Outer Coastal Plain Of Southeastern Virginia, Robert C. Mcdaniel

OES Theses and Dissertations

In southeastern Virginia one to two discontinuous boulder layers occur at the base of the Pleistocene Norfolk Formation. The sediments, heavy minerals and microfossils within the boulder layers in addition to boulder lithologies, dimensions and orientations were studied to determine the origin of these layers. These data indicate the boulder layers were separated into two similar yet distinct layers.

The ancestral James River with sea-level 100 meters lower than today probably had the capacity to entrain 70-80 percent of the clasts in the boulder layers, but probably not the capacity to entrain the larger cobbles and boulders in the boulder …