Physical Sciences and Mathematics Commons^™

Interfacing A Computer To A Scanning Tunneling Microscope, Markus Jarasch

Dissertations and Theses

A program was written in 'C' to control the functions of an already existing Scanning Tunneling Microscope (STM). A DAS-1601 data acquisition card (from Keithley Data Acquisition) was installed together with its drivers for 'C' on a computer with a 486-DX motherboard. The computer was interfaced to the electronics of the STM. Images taken of HOPG (highly oriented pyrolitic graphite) were of a reasonable quality and showed atomic resolution.

Electrophoretic Studies Of Ion Adsorption To Sarcoplasmic Reticulum And Phosphatidylcholine Membranes, Andreas Schilling

Dissertations and Theses

In this study, electrophoretic mobilities of native and two types of trypsin digested sarcoplasmic reticulum vesicles have been determined by microelectrophoresis using a Doppler Electrophoretic Light Scattering Analyzer to investigate the influence of hydrodynamic drag, caused by the Ca2⁺, Mg2⁺ -ATPase protruding from the surface of native sarcoplasmic reticulum vesicles. After the prolonged digestion (protein:trypsin ratio of 20 for 3 hours at 25°C), the ATPase was cleaved and removed from the sarcoplasmic reticulum membrane as shown with SDS gel electrophoresis and an ATPase activity assay. Ionic strength and pH dependence of mobility showed a nearly pH independent …

Interactions Of Ruthenium Red With Phospholipid Vesicles, Dirk Voelker

Dissertations and Theses

We have studied the electrostatic and other interactions of the inorganic, hexavalent dye Ruthenium Red (RR) with phospholipid vesicles composed of phosphatidylcholine (PC) and phosphatidylserine (PS) or phosphatidylinositol (Pl) in various mixtures and concentrations. Experiments were based on spectrophotometric absorption measurements which compared RR concentrations in the presence and in the absence of liposomes at different dye concentrations. Multilamellar liposomes were obtained by handshaken preparations. Five freeze-and-thaw cycles of the lipid-RR suspension produced an ion equilibrium distribution at the membrane-water interface. Results are given in terms of the Gouy-Chapman-Stem adsorption theory with the linear partition coefficient and a newly introduced …

Smectic-A —Smectic-C* —Smectic-C Multicritical Point In Ferroelectric Liquid Crystals, Shankar B. Rananavare, V. G. K. M. Pisipati, E. W. Wong

Chemistry Faculty Publications and Presentations

We report a smectic-A–smectic-C–smectic-C* (ACC*) multicritical point in mixtures of chiral DOBAMBC [p-(n-decyloxybenzylidene)-p-amino-(2-methyl-butyl)] cinnamate and achiral 10O.8 (4-decyloxybenzylidene-4-octylaniline). Studies of the phase diagram, tilt angle (θ), polarization (P), and helix pitch (p) indicate an ACC* Lifshitz point that can be described in terms of the extended Landau theory. Specifically, the T*_AC and the maximum polarization (P_m) exhibit quadratic composition dependence while the helical pitch length (p=2π/q) varies linearly. Both q and P_m vanish discontinuously at the C-C* …

Magmatic Evolution And Eruptive History Of The Granitic Bumping Lake Pluton, Washington: Source Of The Bumping River And Cash Prairie Tuffs, John Frederick King

Dissertations and Theses

The 25 Ma Bumping Lake pluton ranges in composition from quartz diorite to granite with the granitic facies comprising approximately 90% of the pluton's surface area. The granite may be classified as calcalkaline, peraluminous and I-type with some Stype characteristics. A late-stage, mafic-poor facies fills cooling related extensional fractures. The pluton was passively emplaced into the Ohanapecosh Formation at a shallow level in the crust. Contact relationships vary from sharp where the contact is vertical to gradational at the roof of the pluton. Where gradational, stoped xenoliths from the roof of the pluton increase in size, angularity and retain more …

Structure And Phase Transition Of The 6,5-Annulene Isomer Of C_{61}H_{2}, Andrea N. Lommen, Paul A. Heiney, Gavin B. M. Vaughan, Peter W. Stephens, Dengfa Liu, Dayin Li, Allan L. Smith, Andrew R. Mcghie, Robert M. Strongin, Laurent Brard, Amos B. Smith Iii

Chemistry Faculty Publications and Presentations

We have used differential scanning calorimetry and x-ray diffraction to study the crystalline phases of the 6,5-annulene isomer of C₆₁H₂. At 308 K the methylenated fullerenes are orientationally disordered in a face-centered cubic lattice with lattice parameter 14.19±0.02 Å. Below Tc=290 K the symmetry is lowered to Pa3¯, a simple-cubic structure. At 20 K the lattice parameter is 14.06±0.02 Å, with substantial statistical disorder remaining. The transition temperature in C₆₁H₂ is slightly higher than in C₆₀O and higher still than in C₆₀, but the three compounds exhibit orientationally …

A User-Level Process Package For Concurrent Computing, Ravi Konuru, Steve Otto, Jonathan Walpole, Robert Prouty, Jeremy Casas

Computer Science Faculty Publications and Presentations

A lightweight user-level process(ULP) package for parallel computing is described. Each ULP has its own register context, stack, data and heap space and communication with other ULPs is performed using locally synchronous, location transparent, message passing primitives. The aim of the package is to provide support for lightweight over-decomposition, optimized local communication and transparent dynamic migration. The package supports a subset of the Parallel Virtual Machine(PVM) interface[Sun90).

Genetic Algorithms And Artificial Life, Melanie Mitchell, Stephanie Forrest

Computer Science Faculty Publications and Presentations

Genetic algorithms are computational models of evolution that play a central role in many artificial-life models. We review the history and current scope of research on genetic algorithms in artificial life, giving illustrative examples in which the genetic algorithm is used to study how learning and evolution interact, and to model ecosystems, immune system, cognitive systems, and social systems. We also outline a number of open questions and future directions for genetic algorithms in artificial-life research

Synthesis And Characterization Of Some Flourine-Containing Lithium Alkyl Sulfonates: Flourinated Sulfonates And Sf5-Containing Sulfonates, Steven A. Ullrich

Dissertations and Theses

Lithium salts of pentafluorothio alkyl sulfonic acids and perfluoroalkyl disulfonic acids were prepared for testing for possible use as polymer electrolytes. Most of these lithium salts were made from the corresponding sodium, potassium or calcium salts. Aqueous solutions of these salts were passed through polystyrene sulfonate ion exchange resin in the acid form to obtain aqueous solutions of the corresponding acids. The acids were then neutralized with lithium hydroxide using a pH meter. One salt was made by reacting the barium salt of the corresponding acid with lithium sulfate. A sulfonyl fluoride polymer (-0-CH2-C (CH20CF2CF2S02F) H-) n was reacted with …

Adaptive Execution Of Data Parallel Computations On Networks Of Heterogeneous Workstations, Robert Prouty, Steve Otto, Jonathan Walpole

Computer Science Faculty Publications and Presentations

Parallel environments consisting of a network of heterogeneous workstations introduce an inherently dynamic environment that differs from multicomputers. Workstations are usually considered “shared” resources while multicomputers provide dedicated processing power. The number of workstations available for use is continually changing; the parallel machine presented by the network is in effect continually reconfiguring itself. Application programs must effectively adapt to the changing number of processing nodes while maintaining computational efficiency. This paper examines methods for adapting to this dynamic environment within the framework of explicit message passing under the data parallel programming model. We present four requirements which we feel a …

Solubility Studies Of Iron(Iii) Oxides And Hydroxides, Victor L. Menting

Dissertations and Theses

The hydrolysis of iron(III) ions in aqueous solution forms a series of soluble hydroxide complexes with associated equilibrium constants. The solubility of iron(III) is controlled by the various soluble hydroxide complexes, and can, in theory, be calculated from the pH and equilibrium constants. Experimental verification of the calculated solubility has proven difficult due to the lack of sensitive analytical techniques and the presence of colloidal ferric hydroxide interferences. Recently, electrochemical methods for the determination of low levels of iron(III) have been developed using adsorptive cathodic stripping voltammetry which relies on the interfacial accumulation of the chelate of iron with Solochrome …

Comet: A Synthetic Benchmark For Message-Passing Architectures, Nalini Ganapati, Steve Otto, Jonathan Walpole

Computer Science Faculty Publications and Presentations

Rapid advances in hardware technology have led to wide diversity in parallel computer architectures. This diversity makes it difficult to evaluate or compare the performance of different parallel computers. Existing benchmarks tend either to be too architecture-specific, or too high-level. Both problems can result in benchmarks that not only provide insufficient information on the performance characteristics of the computer being tested, but are also difficult to port. New benchmarking approaches are needed for new architectural classes, particularly distributed-memory, message-passing computers. This paper focuses on benchmarking distributed-memory message-passing computers. A synthetic benchmark called CoMet (COmmunication METrics), is presented. CoMet is based …

A Method For Determining Ice-Thickness Change At Remote Locations Using Gps, Christina L. Hulbe, I. M. Whillans

Geology Faculty Publications and Presentations

Ice-thickness changes at remote locations on ice sheets can be determined by means of precise Global Positioning System (GPS) surveys with interferometric solutions. Remote sites are precisely surveyed relative to GPS receivers on rock. Repeat observations of the position of a remote site provide its vertical velocity. The difference between this velocity and accumulation rate is an indicator of change in ice-sheet thickness. Allowance must be made for the movement of survey markers due to firn compaction and down-slope ice motion, To allow for firn compaction, very long- poles arc placed to a sufficient depth in the firn that the …

Numerical Simulation Of Nonequilibrium Effects In An Argon Plasma Jet, C. H. Chang, John D. Ramshaw

Physics Faculty Publications and Presentations

Departures from thermal (translational), ionization, and excitation equilibrium in an axisymmetric argon plasma jet have been studied by two?dimensional numerical simulations. Electrons, ions, and excited and ground states of neutral atoms are represented as separate chemical species in the mixture. Transitions between excited states, as well as ionization/recombination reactions due to both collisional and radiative processes, are treated as separate chemical reactions. Resonance radiation transport is represented using Holstein escape factors to simulate both the optically thin and optically thick limits. The optically thin calculation showed significant underpopulation of excited species in the upstream part of the jet core, whereas …

Carbon Monoxide In The Antarctic Atmosphere: Observations Of Decreasing Concentrations, M. A. K. Khalil, R. A. Rasmussen

Environmental Science and Management Faculty Publications and Presentations

Hydroxyl radicals remove hundreds, perhaps thousands, of organic gases from the atmosphere and are often regarded as am index of the oxidizing capacity of the Earth's atmosphere (Thompson 1992). In recent years, there have been growing concerns that, over the past century and now, human activities may be depleting hydroxyl concentrations by adding huge amounts of carbon monoxide and methane to the atmosphere. Reduction in the hydroxyl concentrations can then indirectly lead to more global warming, stratospheric ozone depletion, and other disturbances in atmospheric chemistry. Carbon monoxide (CO) is a key component in the determination of hydroxyl radical (OH) concentrations: …

Neutron-Scattering Study Of Librations And Intramolecular Phonons In Rb_{2.6}K_{0.4}C_{60}, D. Reznik, W. A. Kamitakahara, D. A. Neumann, J. R. D. Copley, J. E. Fischer, Robert M. Strongin, M. A. Cichy, Amos B. Smith Iii

Chemistry Faculty Publications and Presentations

We report the results of inelastic neutron-scattering measurements on Rb_2.6K_0.4C₆₀. Librational modes were observed as broad peaks with maxima between 4.1 and 4.7 meV, as the temperature is lowered from 300 to 12 K. As in K₃C₆₀, no change in the width or position of the librational peak was observed when the sample was cooled through the superconducting transition. Thus any coupling of the librations to electronic states is small. The magnitude of the orientational potential barrier was estimated from the librational peak frequency. A flat background observed in the …

Evaluation Of Strain Rates On Ice Stream B, Antarctica, Obtained Using Differential Gps, Christina L. Hulbe, I. M. Whillans

Geology Faculty Publications and Presentations

The "stop-and-go" kinematic Global Positioning System (CPS) technique was used to survey 270 stations twice within a 25 km by 10 km strain grid on the surface of Ice Stream B. One or two geodetic quality receivers operated as reference pivots, while two similar receivers traveled to grid stations. Each station was occupied for 25 s. The method is rapid and reliable. Each survey was completed within 2 weeks. Calculated horizontal strain rates are accurate to 1%. Relative vertical velocities are accurate to 20 mm kmI a-1. Maps of the four horizontal velocity gradients, relative vertical velocity and surface elevation …

Source Rock Geochemistry Of The Southern Tyee Basin, Southwest Oregon, David E. Long

Dissertations and Theses

This study examined source rock geochemistry of the southern Tyee Basin. Total organic carbon, rock-eval pyrolysis, vitrinite reflectance, thermal alteration index and visual assessments were performed on splits from cutting samples from five wells and on outcrop samples from four measured sections. Organic matter was found to be dispersed, averaging about 0.5 weight percent. The organic matter is primarily terrestrial in origin, or type I l l , with low potential for gas production and no oil potential. Three coal samples are clearly the richest sources of organic matter examined in this study.

Atmospheric Hydrocarbon Analysis, Dawei Han

Dissertations and Theses

This treatise studied two correlated important issues in atmospheric chemistry: real-time monitoring of ambient air and removal mechanisms of atmospheric hydrocarbons. An analytical system was designed for the purpose of identification and measurement of sub-ppb level hydrocarbons of different reactivities in air samples. This analytical system was then applied to a series of smog-chamber studies which simulated the removal of reactive hydrocarbons from the atmosphere by reaction with hydroxyl radicals. Six representative atmospheric hydrocarbons (hexane, octane, toluene, m-xylene, a-xylene and mesitylene) were selected for these experiments. The experimental data indicated that the decay of atmospheric hydrocarbons under laboratory conditions is …

Script-Based Qos Specifications For Multimedia Presentations, Richard Staehli, Jonathan Walpole

Computer Science Faculty Publications and Presentations

Multimedia presentations can convey information not only by the sequence of events but by their timing. The correctness of such presentations thus depends on the timing of events as well as their sequence and content. This paper introduces a formal specification language for playback of real-time presentations. The main contribution of this language is a quality of service (QOS) specification that relaxes resolution and synchronization requirements for playback. Our definitions give a precise meaning to the correctness of a presentation. This specification language will form the basis for a QOS interface for reservation of operating system resources.

Modeling Of The Surface Plasmon Resonance (Spr) Effect For A Metal-Semiconductor (M-S) Junction At Elevated Temperatures, Erik De Jesus Sanchez

Dissertations and Theses

The effect of temperature increase on the optical excitation of Surface Plasmon Resonance (SPR) at an Ag-Si metal-semiconductor (M-S) junction at a wavelength of 1 . 1 52 pm is investigated theoretically using computer modeling in Fortran. In order to accurately quantify the SPR, the temperature dependent optical constants for Ag and Si are obtained theoretically or semiempirically , using a Drude model for Ag and previous experimentally determined equations for Si (the behavior of the optical constants for crystalline Si and doped Si are found to have very little deviation between each other for our case). An improvement in …

Mapping The Distribution Of Vesicular Textures On Silicic Lavas Using The Thermal Infrared Multispectral Scanner, Jaime Ondrusek, Philip R. Christensen, Jonathan Fink

Geology Faculty Publications and Presentations

The Thermal Infrared Multispectral Scanner (TlMS) is a potentially powerful tool for mapping detailed chemical variations in silicic lava flows which in turn could expand knowledge of pre-eruption compositional gradients and mixing processes in silicic magma bodies. However, thermal infrared image data may be greatly influenced by the range of vesicular textures which occur on silicic flows . To investigate the effect of vesicularity on TIMS imagery independent of chemical variations, we studied Little Glass Mountain at the Medicine Lake Volcano of northern California, a large rhyolitic flow of uniform composition but textural heterogeneity. The imagery was recalibrated so that …

Modeling Complex Ecological Economic Systems: Toward An Evolutionary, Dynamic Understanding Of People And Nature, Robert Costanza, Lisa Wainger, Carl Folke, Karl-Göran Mäler

Institute for Sustainable Solutions Publications and Presentations

Recent understanding about system dynamics and predictability that has emerged from the study of complex systems is creating new tools for modeling interactions between anthropogenic and natural systems. A range of techniques has become available through advances in computer speed and accessibility and by implementing a broad, interdisciplinary systems view.

Data Dependence In Programs Involving Indexed Variables, Borislav Nikolik

Dissertations and Theses

Symbolic execution is a powerful technique used to perform various activities such as program testing, formal verification of programs, etc. However, symbolic execution does not deal with indexed variables in an adequate manner. Integration of indexed variables such as arrays into symbolic execution would increase the generality of this technique. We present an original substitution technique that produces array-term-free constraints as a counterargument to the commonly accepted belief that symbolic execution cannot handle arrays. The substitution technique deals with constraints involving array terms with a single aggregate name, array terms with multiple aggregate names, and nested array terms. Our approach …

Evaluating The Effectiveness Of Certain Metrics In Measuring The Quality Of End User Documentation, Ronald Morrison

Dissertations and Theses

Traditional methods of evaluating quality in computer end user documentation have been subjective in nature, and have not been widely used in practice. Attempts to quantify quality and more narrowly define the essential features of quality have been limited -- leaving the issue of quality largely up to the writer of the user manual.

Quantifiable measures from the literature, especially Velotta (1992) and Brockman (1990), have been assembled into a set of uniformly weighted metrics for the measurement of document quality. This measure has been applied to the end user documentation of eighty-two personal computer packages. End user documentation is …

Orientational Phase Transition In Na_{X}C_{60} (1, T. Yildirim, J. E. Fischer, A. B. Harris, Peter W. Stephens, Dengfa Liu, Laurent Brard, Robert M. Strongin, Amos B. Smith Iii

Chemistry Faculty Publications and Presentations

X-ray diffraction and calorimetry data on cubic Na_xC₆₀(1<x60, e.g., T_m(x=1.3)=325 K. The ordered phases are the same as in pure C₆₀: simple cubic, space group Pa3¯, but the orientations in the disordered phase are more restricted. We explain how Na stabilizes the ordered phase to rather high T, while K and Rb do not, in terms of Coulomb interactions between C₆₀ molecules and and Na ions which we calculate from the local charge density of C₆₀.

Comparison Of Ion Adsorption To Phophatidylcholine/Phosphatidylserine And Sarcoplasmic Reticulum Membranes, Martin Mense

Dissertations and Theses

Artificial lipid membranes have been used in biophysical studies as well defined models of biological membranes. In the present work we studied adsorption of ions to artificial lipid membranes, composed of phosphatidylcholine (PC) and phosphatidylserine (PS), and to biological membrane from sarcoplasmic reticulum (SR). The studies of ion adsorption and electrokinetic characterization of membranes were done by means of microelectrophoresis of PC/PS liposomes and SR vesicles. The ions of interest were positively charged potassium (K), calcium (Ca), tetraphenylarsonium (TPAs), tetraphenylphosphonium (TPP) and negatively charged pentachlorophenol (PCP).

Electrophoretic mobility of PC/PS liposomes and SR vesicles has been measured as a function …

A Cognitively Motivated System For Software Component Reuse, Michael Joseph Mateas

Dissertations and Theses

Software reuse via component libraries suffers from the twin problems of code location and comprehension. The Intelligent Code Object Planner (ICOP) is a cognitively motivated system that facilitates code reuse by answering queries about how to produce an effect with the library. It can plan for effects which are not primitive with respect to the library by building a plan that incorporates multiple components. The primary subsystems of ICOP are a knowledge base which describes the ontology of the library, a natural language interface which translates user queries into a formal effect language (predicates), a planner which accepts the effect …

A Retarding-Potential Analyzer For Measuring Energy Distributions In Electron Beams, Li Zhou

Dissertations and Theses

An energy analyzer for electron beams, based on a retarding-potential method, has been studied both experimentally and theoretically. In this method a potential energy barrier at right-angles to the beam acts as a high-pass energy filter allowing electrons having energies greater than the barrier height to pass through while turning back electrons of lower energy. The potential barrier in the present study was created by applying a negative potential to an electrode consisting of a 600/inch hexagonal copper mesh or an electrode having a pair of single apertures in series (compound aperture). Two different compound apertures, of diameters 0.4 mm …

Hydrogeochemical Characterization Of The Alvord Valley Known Geothermal Resources Area, Harney County, Oregon, Anna Maria St. John

Dissertations and Theses

The Alvord Valley Known Geothermal Resources Area (KGRA) , located east of the Steens Mountain-Pueblo Mountains fault block in southeastern Oregon, is within the northern Basin and Range province. This investigation focuses on three thermal areas in the Alvord Basin: Borax Lake and the hot springs north of Borax Lake, Alvord Hot Springs and Mickey Springs.

Mickey Springs and the springs north of Borax Lake are boiling at the surface (94 and 95° C, respectively). Inflow temperatures to Borax Lake, measured at a depth of 30 m, are greater than 100° C. Surface temperatures for Alvord Hot Springs and a …