Physical Sciences and Mathematics Commons^™

Synthesis Of Diaryl And Alkyl-Aryl Ethers Via Diaryl Iodonium Reagents, Rory Tennessee Gallagher

Dissertations and Theses

Substituted benzenoid rings are a prevalent motif in many industries including high tech, agrochemicals, and pharmaceuticals. As a result, the arylation of chemical compounds is a highly sought-after chemical transformation. There are many literature methods to achieve this chemical transformation, nucleophilic aromatic substitution and transition metal catalysis are both widely used and studied. Diaryliodonium salt mediated chemistry is an attractive alternative to these methods as it does not require the expensive toxic metals and designer ligands of transition metal catalysis and is not restricted to electron deficient aryl rings with specific substitution patterns like nucleophilic aromatic substitution.

Many diaryliodonium salt …

Advancing Our Understanding Of Green Roofs With Samantha Hartzell, Samantha Hartzell

PDXPLORES Podcast

Green roofs provide a variety of benefits including increasing stormwater retention, lowering cooling costs and mitigating the urban heat island effect. However, the ecosystem services provided by green roofs vary by vegetation choice and environmental conditions.

Assistant Professor Samantha Hartzell is an ecohydrologist whose research focuses on developing technologies to improve green roof designs, inform vegetation selection, and better understand the value of green roofs.

Click on the "Download" button to access the audio transcript.

Citizen Science Across Two Centuries Reveals Phenological Change Among Plant Species And Functional Groups In The Northeastern Us, Kerissa Battle, Anna Duhon, Conrad R. Vispo, Theresa M. Crimmins, Todd Rosenstiel, Lilas L. Armstrong-Davies, Catherine De Rivera

Environmental Science and Management Faculty Publications and Presentations

1. Understanding the breadth and complexity of changes in phenology is limited by the availability of long-term historical data sets with broad geographic range.
2. We compare a recently discovered historical data set of plant phenology observations collected across the state of New York (1826–1872) to contemporary volunteer-contributed observations (2009–2017) to evaluate changes in plant phenology between time periods. These multi-site, multi-taxa phenology data matched with temperature data uniquely extend historical observations back in time prior to the major atmospheric effects of the Industrial Revolution.
3. The majority of the 36 trees, shrubs and forbs that comprised our analysable data set flowered and …

Equidistant Sets In Spaces Of Bounded Curvature, Logan Scott Fox

Dissertations and Theses

Given a metric space (X,d), and two nonempty subsets A,B ⊆ X, we study the properties of the set of points of equal distance to A and B, which we call the equidistant set E(A,B). In general, the structure of the equidistant set is quite unpredictable, so we look for conditions on the ambient space, as well as the given subsets, which lead to some regularity of the properties of the equidistant set. At a minimum, we will always require that X is path connected (so that E( …

Geodesic Bicombings On Some Hyperspaces, Logan S. Fox

Mathematics and Statistics Faculty Publications and Presentations

We show that if (X,d)" role="presentation" style="box-sizing: inherit; display: inline; line-height: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; position: relative;">(X,d)(X,d) is a metric space which admits a consistent convex geodesic bicombing, then we can construct a conical bicombing on CB(X)" role="presentation" style="box-sizing: inherit; display: inline; line-height: normal; word-spacing: normal; overflow-wrap: normal; white-space: nowrap; float: none; direction: ltr; max-width: none; max-height: none; min-width: 0px; min-height: 0px; border: 0px; padding: 0px; margin: 0px; position: relative;">CB(X)CB(X), the hyperspace of nonempty, closed, bounded, and …

Orbital Analysis Of Bonding In Diarylhalonium Salts And Relevance To Periodic Trends In Structure And Reactivity, Shubhendu S. Karandikar, Avik Bhattacharjee, Bryan Metze, Nicole Javaly, Edward J. Valente, Theresa M. Mccormick, David R. Stuart

Chemistry Faculty Publications and Presentations

Diarylhalonium compounds provide new opportunities as reagents and catalysts in the field of organic synthesis. The three center, four electron (3c–4e) bond is a center piece of their reactivity, but structural variation among the diarylhaloniums, and in comparison with other λ3-iodanes, indicates that the model needs refinement for broader applicability. We use a combination of Density Functional Theory (DFT), Natural Bond Orbital (NBO) Theory, and X-ray structure data to correlate bonding and structure for a λ3-iodane and a series of diarylchloronium, bromonium, and iodonium salts, and their isoelectronic diarylchalcogen counterparts. This analysis reveals that the s-orbital on the central halogen …

Understanding The Transport And Chemistry Of Indoor Air During Wildfire Smoke Events With Elliott Gall, Elliott T. Gall

PDXPLORES Podcast

Dr. Elliott Gall, Associate Professor in the Mechanical and Materials Engineering Department at Portland State University, studies indoor air quality in order to better understand how to improve building designs to promote health.

Wildfires are increasing in frequency and intensity. So, too, are wildfire smoke events. Smoke from wildfires pose serious health risks. That is why the Environmental Protection Agency recommends individuals remain indoors during smoke events.

In this episode, Professor Gall discusses the importance of understanding the chemistry of wildfire smoke indoors and how smoke is transported into buildings.

Click on the "Download" button to access the audio transcript.

Pre-Eruptive Magma Configurations And Petrogenetic Relationships Of The Rattlesnake Tuff, Oregon–Insights From Spectacularly Banded High-Silica Rhyolite Pumices, Vanessa M. Swenton, Martin J. Streck

Geology Faculty Publications and Presentations

The 7.1Ma Rattlesnake Tuff (RST) of eastern Oregon is a widespread and voluminous (>300 km3) ignimbrite composed of 99% crystal poor (≤1%) high-silica rhyolite (HSR) and

Houseless Water Insecurity During Covid-19 Pandemic, Alicia N. Gamble

Student Research Symposium

Water security is of the utmost importance for the houseless population. However, little is known about how the houseless population has been resilient to water barriers related to the COVID-19 pandemic. The purpose of this study is to understand houseless individuals' perceptions of public versus grassroots water sources, and the barriers and impacts of these sources. In order to understand these perceptions, individuals experiencing houselessness (e.g. living in tents, vehicles, emergency shelters, couch-surfing, or no roof) that utilize water sources in Portland, Oregon will be interviewed while walking in public areas to gain rich qualitative data, along with GPS data …

Comparison Of Heavy Metals In Spinach Grown On The Roof Ground Location At Portland State University, Tyler A. Robin

Student Research Symposium

As a result of urbanization, fresh, healthy food can be expensive and easily contaminated but space for local farming is limited. Roofs can be underutilized in densely populated cities and can offer a space for local fresh farming. The purpose of this study is to continue a previous study done in 2021, to find if growing leafy vegetables on the roof can limit heavy metal exposure from air pollutants. This study compares spinach grown on the roof in 2021, 2019 and spinach bought from stores around the Portland State University campus and the heavy metals found in these greens. The …

Research Proposal For An Assessment Of The Potential For The Arbuscular Fungi “Rhizophagus Irregularis” To Aid In Corn Uptake And Availability Of Iron, Caitlin Costello

Student Research Symposium

Global iron deficiency is one factor contributing to malnutrition and varied health conditions. This deficiency accounts for 841,000 deaths and approximately 35,057,000 “disability-adjusted life years lost” (Stoltzfus, R. J. 2003). One way to combat this is to maintain or increase the iron uptake of the globe’s major crops. Research has shown that certain types of mycorrhizal fungi can increase the nutrient uptake of plants. To further this research, we will look at the arbuscular fungi Rhizophagus irregularis and its potential relationship with a short harvest corn variety. This type of mycorrhizal fungi improves plant nutrition including the plant’s ability to …

Surface Plasmon Characterization In Ag Nanotriangles For Evaluation Of Fano Resonance Conditions, Nabila Islam

Student Research Symposium

Surface plasmon polariton (SPP) is a collective oscillation of electrons and light at the metal -dielectric interface excited by the incident radiation on metal surface through the momentum matching conditions. The properties of SPPs and the resonance conditions are highly dependent on the confining materials and geometry of the confining nanostructure. The sensitivity of the surface plasmon resonance to the property of the confining materials made Surface plasmon resonance (SPR) sensors a central tool for biosensing. However, the frequency resolution of SPR sensors is typically limited by the broad resonance of the SPR mode. The resolution can be enhanced through …

Mapping Ecosystem Service Flows Of Estuary Restoration Projects On The Oregon Coast To Identify Impacted Stakeholders, Shersten Finley

Student Research Symposium

Restoration of largely depleted estuarine systems is increasingly recognized as key to solving a variety of problems coastal communities face currently. Many of these issues will become more acute with climate change and sea level rise. Historic losses of estuary area, and recognition of the ecosystem services provided by functioning estuary ecosystems have resulted in current impetus to pursue estuary restoration. By mapping the flows of ecosystem services using three ecosystem service ‘scorecard’ categories pertaining to coastal resource management: recreation, aesthetics, and cultural/historical/spiritual, we gain a better understanding of the populations impacted by the changes in flows of ecosystem service …

Simple Arenes As Aryne Synthetic Equivalents Via Sulfonium Salt Intermediates, Riley A. Roberts

Student Research Symposium

Arynes are ephemeral molecules that are yet to be fully exploited in synthetic strategy because they are often challenging to access. These reactive intermediates participate in a myriad of reactions that conventional chemistry is incapable of, making them extremely useful for the synthesis of important molecules like pharmaceuticals and agrochemicals. While classical approaches for synthesizing arynes employ cheap starting material, extremely harsh reagents are necessary to generate the aryne. In contrast, methods that do not require harsh reaction conditions do require starting material that is exceedingly difficult to synthesize. To access arynes quickly and efficiently, the work described herein aims …

The Power Of The Collective: A Multi Agent-Based Modeling Approach To Nuclear Radiation Localization, Benjamin Totten, Christof Teuscher

Student Research Symposium

Gamma radiation is a very high frequency, very dangerous electromagnetic wave that has a chance of being emitted after radioactive decay. Radiation source localization, or locating the previously unknown source of nuclear radiation, in a rapid and efficient manner is critically important, but challenging. We aim to create an architecture for multiple, fully independent agents that cooperate to localize sources faster than existing single-agent architectures, without compromising accuracy. Using Agent-Based Modeling and Deep Reinforcement Learning, agents are enabled to make decisions based on other agents' behaviors while maintaining programmatic autonomy. We hypothesize that radiation sources can be localized faster using …

Using Digital Holographic Microscopy To Characterize Vibrio's Chemotaxis, Jacqueline Acres, Eric Valentino

Student Research Symposium

Vibrio alginolyticus is a marine bacterium that displays distinctive chemotactic behavior. Chemotaxis is the ability to move in response to a concentration gradient, either in the direction of nutrients or away from repellants. Vibrio's single, polar flagellum allows it to form a tight cloud in the presence of a chemoattractant. In this work, we experimentally characterize cloud sizes after both normal culture conditions and simulated microgravity using digital holographic microscopy or DHM. DHM allows visualization of volumetric samples by recording x,y,z and t information in holograms. Plane-by-plane reconstruction retrieves the z-plane information which can then by stitched together into hyperstacks …

Social Capital And Cross-Boundary Collaboration In Wyoming Wildfire Management Networks, Hannah L. Spencer, Christian Heisler

Student Research Symposium

Wildfire hotspots often intersect jurisdictional boundaries, so protecting human communities and restoring healthy fire regimes will require collaborative, cross-boundary action from fire managers. However, collaboration between fire management groups can have varied outcomes depending on the actors involved, all with different missions, financial obligations, and cultures. One way to conceptualize the interactions between actors is with the idea of social capital. We will investigate the following research question: how does social capital impact cross-boundary collaboration in wildfire management networks? We will survey wildfire managers in northwestern Wyoming about their collaborative actions using a snowball sampling method. Using Social Network Analysis …

Growing Reservoir Networks Using The Genetic Algorithm Deep Hyperneat, Nancy L. Mackenzie

Student Research Symposium

Typical Artificial Neural Networks (ANNs) have static architectures. The number of nodes and their organization must be chosen and tuned for each task. Choosing these values, or hyperparameters, is a bit of a guessing game, and optimizing must be repeated for each task. If the model is larger than necessary, this leads to more training time and computational cost. The goal of this project is to evolve networks that grow according to the task at hand. By gradually increasing the size and complexity of the network to the extent that the task requires, we will build networks that are more …

Computational Investigation Of The Mechanism Of An Octahedral Ni(Ii) Proton Reduction Catalyst And Importance Of Intramolecular Hydrogen Bonding, Avik Bhattacharjee, Dayalis S.V. Brown, Carolyn N. Virca, Trent E. Ethridge, Oreana Mendez Galue, Uyen T. Pham, Theresa M. Mccormick

Student Research Symposium

Water-splitting to make hydrogen gas is of extreme importance in the field of alternative energy research. Transition-metal complexes are capable of catalyzing the conversion of water to hydrogen at higher pH, with low overpotential. Our research focuses on the importance of intramolecular hydrogen bonding (H-bonding) on the pKa and thermodynamic stability of the catalytic intermediates of a well-known proton-reduction catalyst, nickel (II) tris-pyridinethiolate. Density Functional Theory (DFT) calculations on the parent catalyst and eleven derivatives demonstrate geometric isomer formation after the protonation step of catalysis. These isomers differ in the relative thermodynamic stabilities and pKa values, which can be attributed …

Analysis Of Aftershock Parameters For The Alaskan Subduction Zone Tectonic Region, Gabrielle M. Paris (They/Them), Richard C. Hugo, Andrew J. Michael

Student Research Symposium

On 29 July 2021, a magnitude 8.2 earthquake was felt by over 200 people near Perryville, Alaska. The early aftershock forecasts issued by the USGS use default parameters based on expected productivity within a given tectonic region. These forecasts predicted a slower decrease in aftershock activity than what was observed. Even after the USGS adjusted the aftershock forecast parameters, the forecasts did not improve in the long term. Accurate aftershock predictions are important for maintaining public confidence in disaster alert systems. The question I want to explore is: are the generic parameters used in aftershock forecasting accurately describing the observed …

Stakeholder Perceptions Of Microplastics Management In Oregon, Maya A. Hurst-Mayr

Student Research Symposium

There is currently no federal policy in the United States that specifically addresses microplastics (MPs) pollution. However, states are beginning to act on this issue; California’s SB 1422 initiates measurement of MPs in drinking water resources and Senate Bill 1263 requires the state to adopt a strategy to reduce the ecological impact of MPs in marine ecosystems. Other West Coast states like Oregon and Washington are expected to follow California’s example. It is important to know what the actors who are a part of shaping MPs policy in Oregon would see as barriers and opportunities to doing so. We conducted …

Discussion Of “Guiding Principles For Hydrologists Conducting Interdisciplinary Research And Fieldwork With Participants”, Melissa Haeffner

Environmental Science and Management Faculty Publications and Presentations

Rangecroft et al. (2021) offer a set of principles for conducting interdisciplinary research and fieldwork with participants from a hydrologist perspective. In this invited paper, I present some thoughts from a social scientist’s perspective, not to disagree with their points but to add to them. Specifically, I use my sociology background and interdisciplinary experiences to reflect on qualitative evaluative criteria, power dynamics in the scientific community, barriers to interdisciplinary research, and approaches to overcome obstacles. Individual researchers can educate themselves about other disciplines, and there are also opportunities for institutional change on the part of universities, funders, and …

Extending Tensor Virtual Machine To Support Deep-Learning Accelerators With Convolution Cores, Yanzhao Wang, Fei Xie

Computer Science Faculty Publications and Presentations

Deep-learning accelerators are increasingly popular. There are two prevalent accelerator architectures: one based on general matrix multiplication units and the other on convolution cores. However, Tensor Virtual Machine (TVM), a widely used deep-learning compiler stack, does not support the latter. This paper proposes a general framework for extending TVM to support deep-learning accelerators with convolution cores. We have applied it to two well-known accelerators: Nvidia's NVDLA and Bitmain's BM1880 successfully. Deep-learning workloads can now be readily deployed to these accelerators through TVM and executed efficiently. This framework can extend TVM to other accelerators with minimum effort.

Objective Crystallographic Symmetry Classifications Of A Noisy Crystal Pattern With Strong Fedorov-Type Pseudo­Symmetries And Its Optimal Image-Quality Enhancement, Peter Moeck

Physics Faculty Publications and Presentations

Statistically sound crystallographic symmetry classifications are obtained with information-theory-based methods in the presence of approximately Gaussian distributed noise. A set of three synthetic patterns with strong Fedorov-type pseudo­symmetries and varying amounts of noise serve as examples. Contrary to traditional crystallographic symmetry classifications with an image processing program such as CRISP, the classification process does not need to be supervised by a human being and is free of any subjectively set thresholds in the geometric model selection process. This enables crystallographic symmetry classification of digital images that are more or less periodic in two dimensions (2D), also known as crystal …

Black Carbon Dominated Dust In Recent Radiative Forcing On Rocky Mountain Snowpacks, Kelly E. Gleason, Joseph R. Mcconnell, Monica M. Arienzo, Graham Sexstone, Stefan Rahimi

Environmental Science and Management Faculty Publications and Presentations

The vast majority of surface water resources in the semi-arid western United States start as winter snowpack. Solar radiation is a primary driver of snowmelt, making snowpack water resources especially sensitive to even small increases in concentrations of light absorbing particles such as mineral dust and combustion-related black carbon (BC). Here we show, using fresh snow measurements and snowpack modeling at 51 widely distributed sites in the Rocky Mountain region, that BC dominated impurity-driven radiative forcing in 2018. BC contributed three times more radiative forcing on average than dust, and up to 17 times more at individual locations. Evaluation of …

Sl-Cyclegan: Blind Motion Deblurring In Cycles Using Sparse Learning, Ali Syed Saqlain, Li-Yun Wang, Zhiyong Liu

Computer Science Faculty Publications and Presentations

In this paper, we introduce an end-to-end generative adversarial network (GAN) based on sparse learning for single image motion deblurring, which we called SL-CycleGAN. For the first time in image motion deblurring, we propose a sparse ResNet-block as a combination of sparse convolution layers and a trainable spatial pooler k-winner based on HTM (Hierarchical Temporal Memory) to replace non-linearity such as ReLU in the ResNet-block of SL-CycleGAN generators. Furthermore, we take our inspiration from the domain-to-domain translation ability of the CycleGAN, and we show that image deblurring can be cycle-consistent while achieving the best qualitative results. Finally, we perform extensive …

Unveiling The Nature Of A Miniature World: A Horizon Scan Of Fundamental Questions In Bryology, Jairo Patiño, Irene Bisang, Bernard Goffinet, Lars Hedenäs, Stuart Mcdaniel, Silvia Pressel, Michael Stech, Claudine Ah-Peng, Sarah Eppley, Multiple Additional Authors

Center for Life in Extreme Environments Publications

Introduction: Half a century since the creation of the International Association of Bryologists, we carried out a review to identify outstanding challenges and future perspectives in bryology. Specifically, we have identified 50 fundamental questions that are critical in advancing the discipline.

Methods: We have adapted a deep-rooted methodology of horizon scanning to identify key research foci. An initial pool of 258 questions was prepared by a multidisciplinary and international working group of 32 bryologists. A series of online surveys completed by a broader community of researchers in bryology, followed by quality-control steps implemented by the working group, were …

The Connections Between Innovation, Culture, And Expertise In Water Infrastructure Organizations, Alice Brawley-Chesworth

Dissertations and Theses

Infrastructure organizations are notoriously conservative and resistant to change, even when faced with wicked problems that cannot be solved with the same thinking used in the past. In the water sector, this resistance to change has been linked to an industry culture that is based in a single, engineering-oriented knowledge system. Scholars have suggested that diversification of knowledge systems is necessary for implementation of innovations that will move the sector forward to solve wicked problems.

This research used a qualitative case study approach comparing two water sector organizations in Portland, Oregon. One organization included members who shared an engineering knowledge …

The Plant Water Management Experiments, Marc Benjamin Wasserman

Dissertations and Theses

A simple means of watering plants in the low-g environment aboard orbiting spacecraft is not obvious. Since the beginning of spaceflight, numerous approaches have been pursued to water plants that seek to maximize plant viability and system reliability, while minimizing crew time and system complexity. The Plant Water Management experiments (PWM) seek to apply recent advances in low-gravity capillary fluidics to the challenges faced during plant growth operations aboard spacecraft. One primary challenge encountered in such applications is to establish Earth-like flows, minimizing the low-g specific adaptations required by the plants. This is difficult due to the fluid physics challenges …

Quantification Of Motility In Bacillus Subtilis At Temperatures Up To 84°C Using A Submersible Volumetric Microscope And Automated Tracking, Megan M. Dubay, Nikki Johnston, Mark Wronkiewicz, Jake Lee, Chris Lindensmith, Jay Nadeau

Physics Faculty Publications and Presentations

We describe a system for high-temperature investigations of bacterial motility using a digital holographic microscope completely submerged in heated water. Temperatures above 90°C could be achieved, with a constant 5°C offset between the sample temperature and the surrounding water bath. Using this system, we observed active motility in Bacillus subtilis up to 66°C. As temperatures rose, most cells became immobilized on the surface, but a fraction of cells remained highly motile at distances of >100 μm above the surface. Suspended non-motile cells showed Brownian motion that scaled consistently with temperature and viscosity. A novel open-source automated tracking package was used …