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Full-Text Articles in Physical Sciences and Mathematics

Benzimidazol-2-Ylidene Ruthenium Complexes For C-N Bond Formation Through Alcohol Dehydrogenation, Zahid Nawaz, Nevi̇n Gürbüz, Muhammed Naveed Zafar, Namik Özdemi̇r, Beki̇r Çeti̇nkaya, İsmai̇l Özdemi̇r Oct 2023

Benzimidazol-2-Ylidene Ruthenium Complexes For C-N Bond Formation Through Alcohol Dehydrogenation, Zahid Nawaz, Nevi̇n Gürbüz, Muhammed Naveed Zafar, Namik Özdemi̇r, Beki̇r Çeti̇nkaya, İsmai̇l Özdemi̇r

Turkish Journal of Chemistry

A low temperature hydrogen borrowing approach to generate secondary amines using benzimidazole-based N-heterocyclic carbene (BNHC) ruthenium complexes is reported. A series of the piano-stool complexes of the type [(η6 -p-cymene)(BNHC)RuCl2 ] (1a-g) were synthesized via one-pot reaction of the NHC salt precursor, Ag2 O, and [RuCl2 (p-cymene)]2 and characterized using conventional spectroscopic techniques. The geometry of two precursors, [(η6 -p-cymene)(Me4BnMe2 BNHCCH2OxMe)RuCl2 ] (1f) and [(η6 -p-cymene)(Me5BnMe2 BNHCCH2OxMe)RuCl2 ] (1g), was studied by single crystal X-ray diffraction. These catalysts were found to dehydrogenate alcohols efficiently at temperatures as low as 50 °C to allow Schiff-base condensation and subsequent …


Recommendations For Improving The Experimental Protocol For The Determination Of Photocatalytic Activity By Nitric Oxide Oxidation Measurements, Seli̇n Ernam, Zeynep Ece Akgül, Deni̇z Üner Oct 2023

Recommendations For Improving The Experimental Protocol For The Determination Of Photocatalytic Activity By Nitric Oxide Oxidation Measurements, Seli̇n Ernam, Zeynep Ece Akgül, Deni̇z Üner

Turkish Journal of Chemistry

The photocatalytic nitric oxide (NO) oxidation reaction is used as a standard diagnostic tool for photocatalytic activity according to the well-defined protocol described by ISO Standard 22197-1-2007. This protocol identifies the negative peak showing a NOx concentration drop during a gas flow switch from the calibration bypass to the reactor as adsorption of NOx on the surface. Evidence is provided for this first transient to be due to a dilution effect in the gas phase within the reactor. With proper models of residence time distribution analysis, this transient revealed the internal hydrodynamics and it can be used to determine the …


Synthesis Of Alnustone-Like Diarylpentanoids Via A 4 + 1 Strategy And Assessment Of Their Potential Anticancer Activity, Nesli̇han Çelebi̇oğlu, Özlem Özdemi̇r Tozlu, Hasan Türkez, Hasan Seçen Oct 2023

Synthesis Of Alnustone-Like Diarylpentanoids Via A 4 + 1 Strategy And Assessment Of Their Potential Anticancer Activity, Nesli̇han Çelebi̇oğlu, Özlem Özdemi̇r Tozlu, Hasan Türkez, Hasan Seçen

Turkish Journal of Chemistry

Twelve compounds with a 1,5-diaryl-1-penten-3-one structure were synthesized and their cytotoxic activities were evaluated. The 1,5-diaryl-1-penten-3-one compounds were obtained via in situ enaminations of 4-phenyl-2-butanone and 4-(4-hydroxyphenyl)-2- butanone in the presence of pyrrolidine-AcOH, followed by condensation with six different benzaldehydes. The synthesized compounds were tested for their cytotoxic activity against human glioblastoma (U87-MG), breast (MCF-7), and prostate (PC-3) cancer cell lines. Some of the novel compounds exhibited remarkable cytotoxic action, especially against MCF-7 cancer cells.


Synthesis, Characterization, And Photophysical And Fluorescence Sensor Behaviors Of A New Water-Soluble Double-Bridged Naphthalene Diimide Appended Cyclotriphosphazene, Süreyya Oğuz Tümay, Serkan Yeşi̇lot Oct 2023

Synthesis, Characterization, And Photophysical And Fluorescence Sensor Behaviors Of A New Water-Soluble Double-Bridged Naphthalene Diimide Appended Cyclotriphosphazene, Süreyya Oğuz Tümay, Serkan Yeşi̇lot

Turkish Journal of Chemistry

A new water-soluble template of double-bridged naphthalene diimide appended cyclotriphosphazene was prepared, and its photophysical and sensor behaviors were evaluated. The characterization of novel double-bridged naphthalene diimide appended cyclotriphosphazene (6) was carried out by NMR (1 H, 13C, 31P) and mass spectroscopies. The photophysical behaviors of compound 6 were evaluated by UV-Vis absorption and fluorescence spectroscopies in various solvent systems and different concentrations. As an application for usability of the obtained water-soluble template in different applications, the fluorescence sensor property of compound 6 was investigated in the presence of many different competing species (organic acids, saccharides, nitroaromatic compounds, anions, and …


Phthalocyanines Prepared From 4,5-Dihexylthiophthalonitrile, A Popular Building Block, Derya Topkaya Taşkiran, Zeynel Şahi̇n, Ümi̇t İşci̇, Fabi̇enne Dumouli̇n Oct 2023

Phthalocyanines Prepared From 4,5-Dihexylthiophthalonitrile, A Popular Building Block, Derya Topkaya Taşkiran, Zeynel Şahi̇n, Ümi̇t İşci̇, Fabi̇enne Dumouli̇n

Turkish Journal of Chemistry

Phthalocyanines are tetrapyrrolic artificial porphyrinoids that play major roles in advanced biological and technological applications. Research on this family of dyes is particularly active in Türkiye, with many derivatives being prepared from 4,5-dihexyl-thiophthalonitrile DiSHexPN, which is one of the most popular noncommercially available building blocks for phthalocyanines. This review summarizes the phthalocyanines and their versatile properties and applications that have been published since 1994, when the synthesis of DiSHexPN was first described, to emphasize the importance of this building block in plentiful applications, all with bio-medical or technological impact.


Enhancing Exploration-Exploitation In Harmony Search For Airborne Hyperspectral Imaging Band Selection (E3hs), Mohammed Abdulmajeed Moharram, Divya Meena Sundaram Oct 2023

Enhancing Exploration-Exploitation In Harmony Search For Airborne Hyperspectral Imaging Band Selection (E3hs), Mohammed Abdulmajeed Moharram, Divya Meena Sundaram

Turkish Journal of Electrical Engineering and Computer Sciences

Hyperspectral imaging has emerged as a prominent area of research in the field of remote sensing science. However, hyperspectral images (HSIs) pose a notable challenge due to the presence of numerous irrelevant and redundant spectral bands exhibiting high correlation. Therefore, it is necessary to enhance the classification performance for HSI processing by selecting the most relevant discriminative spectral bands. To this end, this paper introduces a metaheuristic search method called enhancing exploration-exploitation in harmony search (E3HS). The standard harmony search suffers from many weaknesses, such as premature convergence and falling easily into the local optimum. Consequently, E3HS was proposed to …


Infrared Imaging Segmentation Employing An Explainable Deep Neural Network, Xinfei Liao, Dan Wang, Zairan Li, Nilanjan Dey, Rs Simon, Fuqian Shi Oct 2023

Infrared Imaging Segmentation Employing An Explainable Deep Neural Network, Xinfei Liao, Dan Wang, Zairan Li, Nilanjan Dey, Rs Simon, Fuqian Shi

Turkish Journal of Electrical Engineering and Computer Sciences

Explainable AI (XAI) improved by a deep neural network (DNN) of a residual neural network (ResNet) and long short-term memory networks (LSTMs), termed XAIRL, is proposed for segmenting foot infrared imaging datasets. First, an infrared sensor imaging dataset is acquired by a foot infrared sensor imaging device and preprocessed. The infrared sensor image features are then defined and extracted with XAIRL being applied to segment the dataset. This paper compares and discusses our results with XAIRL. Evaluation indices are applied to perform various measurements for foot infrared image segmentation including accuracy, precision, recall, F1 score, intersection over union (IoU), Dice …


Classification Of Chronic Pain Using Fmri Data: Unveiling Brain Activity Patterns For Diagnosis, Rejula V, Anitha J, Belfin Robinson Oct 2023

Classification Of Chronic Pain Using Fmri Data: Unveiling Brain Activity Patterns For Diagnosis, Rejula V, Anitha J, Belfin Robinson

Turkish Journal of Electrical Engineering and Computer Sciences

Millions of people throughout the world suffer from the complicated and crippling condition of chronic pain. It can be brought on by several underlying disorders or injuries and is defined by chronic pain that lasts for a period exceeding three months. To better understand the brain processes behind pain and create prediction models for pain-related outcomes, machine learning is a potent technology that may be applied in Functional magnetic resonance imaging (fMRI) chronic pain research. Data (fMRI and T1-weighted images) from 76 participants has been included (30 chronic pain and 46 healthy controls). The raw data were preprocessed using fMRIprep …


Yolo And Lsh-Based Video Stream Analytics Landscape For Short-Term Traffic Density Surveillance At Road Networks, Lavanya K, Stuti Tiwari, Rahul Anand, Jude Hemanth Oct 2023

Yolo And Lsh-Based Video Stream Analytics Landscape For Short-Term Traffic Density Surveillance At Road Networks, Lavanya K, Stuti Tiwari, Rahul Anand, Jude Hemanth

Turkish Journal of Electrical Engineering and Computer Sciences

The duty of monitoring traffic during rush hour is difficult due to the fact that modern roadways are getting more crowded every day. The automated solutions that have already been created in this area are ineffective at processing enormous amounts of data in a short amount of time, leading to ineffectiveness and inconsistent results. The YOLO (you only look once) and LSH (locality sensitive hashing) algorithms are combined with the Kafka architecture in this study to create a method for assessing traffic density in real-time scenarios. Our concept, which is specifically designed for vehicular networks, predicts the traffic density in …


Hybrid Machine Learning Model To Predict Chronic Kidney Diseases Using Handcrafted Features For Early Health Rehabilitation, Amjad Rehman, Tanzila Saba, Haider Ali, Narmine Elhakim, Noor Ayesha Oct 2023

Hybrid Machine Learning Model To Predict Chronic Kidney Diseases Using Handcrafted Features For Early Health Rehabilitation, Amjad Rehman, Tanzila Saba, Haider Ali, Narmine Elhakim, Noor Ayesha

Turkish Journal of Electrical Engineering and Computer Sciences

Chronic kidney diseases proliferate due to hypertension, diabetes, anemia, obesity, smoking etc. Patients with such conditions are sometimes unaware of first symptoms, complicating disease diagnosis. This paper presents chronic kidney disease (CKD) prediction model to classify CKD patients from NCKD (Non-CKD). The proposed study has two main stages. First, we found the odds ratio through logistic regression and comparison test to identify early risk factors from kidneys? MRI and differentiate CKD from NCKD subjects. In stage 2, LR, LDA, MLP classifiers were applied to predict CKD and NCKD by extracting features from MRI. The odds ratio of blood glucose random …


Deep Feature Extraction, Dimensionality Reduction, And Classification Of Medical Images Using Combined Deep Learning Architectures, Autoencoder, And Multiple Machine Learning Models, Ahmet Hi̇dayet Ki̇raz, Fatime Oumar Djibrillah, Mehmet Emi̇n Yüksel Oct 2023

Deep Feature Extraction, Dimensionality Reduction, And Classification Of Medical Images Using Combined Deep Learning Architectures, Autoencoder, And Multiple Machine Learning Models, Ahmet Hi̇dayet Ki̇raz, Fatime Oumar Djibrillah, Mehmet Emi̇n Yüksel

Turkish Journal of Electrical Engineering and Computer Sciences

Accurate analysis and classification of medical images are essential factors in clinical decision-making and patient care. A novel comparative approach for medical image classification is proposed in this study. This new approach involves several steps: deep feature extraction, which extracts the informative features from medical images; concatenation, which concatenates the extracted deep features to form a robust feature vector; dimensionality reduction with autoencoder, which reduces the dimensionality of the feature vector by transforming it into a different feature space with a lower dimension; and finally, these features obtained from all these steps were fed into multiple machine learning classifiers (SVM, …


Multi-View Brain Tumor Segmentation (Mvbts): An Ensemble Of Planar And Triplanar Attention Unets, Snehal Rajput, Rupal Kapdi, Mehul Raval, Mohendra Roy Oct 2023

Multi-View Brain Tumor Segmentation (Mvbts): An Ensemble Of Planar And Triplanar Attention Unets, Snehal Rajput, Rupal Kapdi, Mehul Raval, Mohendra Roy

Turkish Journal of Electrical Engineering and Computer Sciences

3D UNet has achieved high brain tumor segmentation performance but requires high computation, large memory, abundant training data, and has limited interpretability. As an alternative, the paper explores using 2D triplanar (2.5D) processing, which allows images to be examined individually along axial, sagittal, and coronal planes or together. The individual plane captures spatial relationships, and combined planes capture contextual (depth) information. The paper proposes and analyzes an ensemble of uniplanar and triplanar UNets combined with channel and spatial attention for brain tumor segmentation. It investigates the significance of each plane and analyzes the impact of uniplanar and triplanar ensembles with …


Cccd: Corner Detection And Curve Reconstruction For Improved 3d Surface Reconstruction From 2d Medical Images, Mriganka Sarmah, Arambam Neelima Oct 2023

Cccd: Corner Detection And Curve Reconstruction For Improved 3d Surface Reconstruction From 2d Medical Images, Mriganka Sarmah, Arambam Neelima

Turkish Journal of Electrical Engineering and Computer Sciences

The conventional approach to creating 3D surfaces from 2D medical images is the marching cube algorithm, but it often results in rough surfaces. On the other hand, B-spline curves and nonuniform rational B-splines (NURBSs) offer a smoother alternative for 3D surface reconstruction. However, NURBSs use control points (CTPs) to define the object shape and corners play an important role in defining the boundary shape as well. Thus, in order to fill the research gap in applying corner detection (CD) methods to generate the most favorable CTPs, in this paper corner points are identified to predict organ shape. However, CTPs must …


A Unique Hybrid Domain Hand-Crafted Feature To Classify Colorectal Tissue Histopathological Images Using Multiheaded Cnn, Anurodh Kumar, Amit Vishwakarma, Varun Bajaj Oct 2023

A Unique Hybrid Domain Hand-Crafted Feature To Classify Colorectal Tissue Histopathological Images Using Multiheaded Cnn, Anurodh Kumar, Amit Vishwakarma, Varun Bajaj

Turkish Journal of Electrical Engineering and Computer Sciences

Early diagnosis of colorectal cancer lengthens human life and is helpful in efforts to cure the illness. Histopathological inspection is a routinely utilized technique to diagnose it. Visual assessment of histopathological images takes more investigation time, and the decision is based on the individual perceptions of clinicians. The existing methods for colorectal cancer classification use only spatial information. However, studies on the spectral domains of information are lacking in the literature. Therefore, the performance of the existing techniques is moderate. To improve the performance of colorectal cancer classification, this work proposes a unique hybrid domain hand-crafted feature formulated using scale-invariant …


Focal Modulation Network For Lung Segmentation In Chest X-Ray Images, Şaban Öztürk, Tolga Çukur Oct 2023

Focal Modulation Network For Lung Segmentation In Chest X-Ray Images, Şaban Öztürk, Tolga Çukur

Turkish Journal of Electrical Engineering and Computer Sciences

Segmentation of lung regions is of key importance for the automatic analysis of Chest X-Ray (CXR) images, which have a vital role in the detection of various pulmonary diseases. Precise identification of lung regions is the basic prerequisite for disease diagnosis and treatment planning. However, achieving precise lung segmentation poses significant challenges due to factors such as variations in anatomical shape and size, the presence of strong edges at the rib cage and clavicle, and overlapping anatomical structures resulting from diverse diseases. Although commonly considered as the de-facto standard in medical image segmentation, the convolutional UNet architecture and its variants …


Cognitive Digital Modelling For Hyperspectral Image Classification Using Transfer Learning Model, Mohammad Shabaz, Mukesh Soni Oct 2023

Cognitive Digital Modelling For Hyperspectral Image Classification Using Transfer Learning Model, Mohammad Shabaz, Mukesh Soni

Turkish Journal of Electrical Engineering and Computer Sciences

Deep convolutional neural networks can fully use the intrinsic relationship between features and improve the separability of hyperspectral images, which has received extensive in recent years. However, the need for a large number of labelled samples to train deep network models limits the application of such methods. The idea of transfer learning is introduced into remote sensing image classification to reduce the need for the number of labelled samples. In particular, the situation in which each class in the target picture only has one labelled sample is investigated. In the target domain, the number of training samples is enlarged by …


Trcaptionnet: A Novel And Accurate Deep Turkish Image Captioning Model With Vision Transformer Based Image Encoders And Deep Linguistic Text Decoders, Serdar Yildiz, Abbas Memi̇ş, Songül Varli Oct 2023

Trcaptionnet: A Novel And Accurate Deep Turkish Image Captioning Model With Vision Transformer Based Image Encoders And Deep Linguistic Text Decoders, Serdar Yildiz, Abbas Memi̇ş, Songül Varli

Turkish Journal of Electrical Engineering and Computer Sciences

Image captioning is known as a fundamental computer vision task aiming to figure out and describe what is happening in an image or image region. Through an image captioning process, it is ensured to describe and define the actions and the relations of the objects within the images. In this manner, the contents of the images can be understood and interpreted automatically by visual computing systems. In this paper, we proposed the TRCaptionNet a novel deep learning-based Turkish image captioning (TIC) model for the automatic generation of Turkish captions. The model we propose essentially consists of a basic image encoder, …


Feature Distillation From Vision-Language Model For Semisupervised Action Classification, Asli Çeli̇k, Ayhan Küçükmani̇sa, Oğuzhan Urhan Oct 2023

Feature Distillation From Vision-Language Model For Semisupervised Action Classification, Asli Çeli̇k, Ayhan Küçükmani̇sa, Oğuzhan Urhan

Turkish Journal of Electrical Engineering and Computer Sciences

The training of supervised machine learning approaches is critically dependent on annotating large-scale datasets. Semisupervised learning approaches aim to achieve compatible performance with supervised methods using relatively less annotation without sacrificing good generalization capacity. In line with this objective, ways of leveraging unlabeled data have been the subject of intense research. However, semisupervised video action recognition has received relatively less attention compared to image domain implementations. Existing semisupervised video action recognition methods trained from scratch rely heavily on augmentation techniques, complex architectures, and/or the use of other modalities while distillation-based methods use models that have only been trained for 2D …


A Comprehensive Review Of Geometrical Thermodynamics: From Fluctuations To Black Holes, S. Mahmoudi, Kh. Jafarzade, Seyed Hossein Hendi Oct 2023

A Comprehensive Review Of Geometrical Thermodynamics: From Fluctuations To Black Holes, S. Mahmoudi, Kh. Jafarzade, Seyed Hossein Hendi

Turkish Journal of Physics

This paper presents a comprehensive review of geometrical thermodynamics, which employs geometric concepts to study the thermodynamic properties of physical systems. The review covers key topics such as thermodynamic fluctuation theory, proposed thermodynamic metrics in various coordinate systems, and thermodynamic curvature.Additionally, the paper discusses the geometrical approach to black hole thermodynamics and provides an overview of recent research in this field.


A Portable And Low-Cost Incubator System Enabling Real-Time Cell Imaging Based On A Smartphone, Ari̇f Engi̇n Çeti̇n Oct 2023

A Portable And Low-Cost Incubator System Enabling Real-Time Cell Imaging Based On A Smartphone, Ari̇f Engi̇n Çeti̇n

Turkish Journal of Physics

Incubators serve as essential tools for maintaining optimal temperature, humidity, and atmospheric gas composition for cell cultures. Their applications span across various fields like cell biology, microbiology, and molecular biology. However, in many cell-based studies, observing cellular changes often necessitates moving cells out of the incubator for microscope examination. Unfortunately, exposing cells to an environment that does not support healthy growth can undermine the reliability of test outcomes. In this article, we present a groundbreaking solution: a cost-effective, portable incubator system seamlessly integrated with a smartphone for real-time characterization tests. This innovation offers comparable imaging capabilities and maintains an environment …


Isotope And Hydrochemical Characteristics Of Thermal Waters Along The Active Fault Zone (Erzin-Hatay/Turkey) And Their Geothermal Potential, Di̇dem Yasi̇n, Gali̇p Yüce Sep 2023

Isotope And Hydrochemical Characteristics Of Thermal Waters Along The Active Fault Zone (Erzin-Hatay/Turkey) And Their Geothermal Potential, Di̇dem Yasi̇n, Gali̇p Yüce

Turkish Journal of Earth Sciences

Geochemical investigations carried out on thermal waters over the Erzin-Hatay area allowed the collection of a suite of 9 samples from natural springs and one well characterized by outlet temperatures in the range from 19.6 to 31.5 °C. All of the springs have slightly acidic pH (in the range of 6) but one sample was marked by a pH value >11 as a consequence of serpentinization processes. The water chemistry denotes water/rock interactions with either magmatic or carbonatic rocks in a water reservoir equilibrated at temperatures estimated to be in the range of 58-162 °C. The stable isotope composition of …


A Review Of The Geothermal System Evolution And Distribution In The Central Anatolian Crystalline Complex (Türkiye), Mehmet Furkan Şener, Muhammed Zeynel Öztürk, Alper Baba Sep 2023

A Review Of The Geothermal System Evolution And Distribution In The Central Anatolian Crystalline Complex (Türkiye), Mehmet Furkan Şener, Muhammed Zeynel Öztürk, Alper Baba

Turkish Journal of Earth Sciences

Türkiye is located in the Mediterranean sector of the Alpine-Himalayan tectonic belt and is among the foremost seven countries in the world having an abundance of geothermal resources. The Central Anatolian Crystalline Complex (CACC) is one of the most important geothermal regions in Türkiye. This study aims to evaluate the geothermal system of CACC using the geological, structural, and hydrogeochemical properties that were obtained from previous studies. The present study investigated and evaluated the hydrogeochemical and isotopic properties of 762 water samples belonging to 45 different localities from 41 scientific studies. The result shows that CACC has different heat sources …


Cognitive Load Detection Using Ci-Ssa For Eeg Signal Decomposition And Nature-Inspired Feature Selection, Jammisetty Yedukondalu, Lakhan Dev Sharma Sep 2023

Cognitive Load Detection Using Ci-Ssa For Eeg Signal Decomposition And Nature-Inspired Feature Selection, Jammisetty Yedukondalu, Lakhan Dev Sharma

Turkish Journal of Electrical Engineering and Computer Sciences

Cognitive load detection is eminent during the mental assignment of neural activity because it indicates how the brain reacts to stimuli. The level of cognitive load experienced during mental arithmetic tasks can be determined using an electroencephalogram (EEG). The EEG data were collected from publicly available datasets, namely, mental arithmetic task (MAT) and simultaneous task workload (STEW). The first phase comprises decomposing the electroencephalogram (EEG) signal into intrinsic mode functions (IMFs) using circulant singular spectrum analysis (Ci-SSA). In the second phase, entropy-based features were evaluated using IMFs. After that, the extracted features were fed to nature-inspired feature selection algorithms: genetic …


A Machine Learning Approach For Dyslexia Detection Using Turkish Audio Records, Tuğberk Taş, Muhammed Abdullah Bülbül, Abas Haşi̇moğlu, Yavuz Meral, Yasi̇n Çalişkan, Gunay Budagova, Mücahi̇d Kutlu Sep 2023

A Machine Learning Approach For Dyslexia Detection Using Turkish Audio Records, Tuğberk Taş, Muhammed Abdullah Bülbül, Abas Haşi̇moğlu, Yavuz Meral, Yasi̇n Çalişkan, Gunay Budagova, Mücahi̇d Kutlu

Turkish Journal of Electrical Engineering and Computer Sciences

Dyslexia is a learning disorder, characterized by impairment in the ability to read, spell, and decode letters. It is vital to detect dyslexia in earlier stages to reduce its effects. However, diagnosing dyslexia is a time-consuming and costly process. In this paper, we propose a machine-learning model that predicts whether a Turkish-speaking child has dyslexia using his/her audio records. Therefore, our model can be easily used by smart phones and work as a warning system such that children who are likely to be dyslexic according to our model can seek an examination by experts. In order to train and evaluate, …


Density Functional Theory Calculations Of Equilibrium Oxygen Isotope Fractionation Between Borate Minerals And Aqueous Fluids, Hai-Zhen Wei, Martin Palmer, Jun-Lin Wang, Shao-Yong Jiang, Simon V. Hohl, Yuan-Feng Zhu, Chun Huan, Miao-Miao Zhang, Yeşi̇m Yücel Öztürk Sep 2023

Density Functional Theory Calculations Of Equilibrium Oxygen Isotope Fractionation Between Borate Minerals And Aqueous Fluids, Hai-Zhen Wei, Martin Palmer, Jun-Lin Wang, Shao-Yong Jiang, Simon V. Hohl, Yuan-Feng Zhu, Chun Huan, Miao-Miao Zhang, Yeşi̇m Yücel Öztürk

Turkish Journal of Earth Sciences

Borax, ulexite, and colemanite minerals are by far the most important economic source of boron and occur almost exclusively in nonmarine evaporite deposits. While much is known about the geological setting in which they are found, surprisingly little is known about the chemical and physical properties of the brines from which they are formed. Oxygen isotope studies have the potential to reveal important new information regarding borate formation, but unlike most other common oxygen-bearing salts precipitated from brines, there are no experimental data regarding the oxygen isotope fractionation factors between borates and brines. As a first attempt to address this …


Zircon Grain Shape Parameters From Ignimbrites Of The Central Anatolian Volcanic Province (Cavp) With Implications For Petrogenetic Processes, Lütfi̇ye Akin Sep 2023

Zircon Grain Shape Parameters From Ignimbrites Of The Central Anatolian Volcanic Province (Cavp) With Implications For Petrogenetic Processes, Lütfi̇ye Akin

Turkish Journal of Earth Sciences

Zircon morphology parameters reflect the physicochemical conditions during crystallization and can be modified by different processes. Zircon populations from Miocene-Pliocene ignimbrites of the Central Anatolian Volcanic Province (CAVP) were studied to reveal relations between the external morphology of zircons and petrogenetic processes. Descriptive grain shape parameters (e.g., minor and major axes, area, perimeter, aspect ratio, roundness, and circularity) were automatically measured from transmitted light images of zircons by a graphical application called AnalyZr. Principal component and cluster analysis were used to determine potential shape descriptors (perimeter, major and minor axis length, and maximum and minimum Feret) for characterizing grains from …


Rank Of Kozlu Formation Coals In The Zonguldak Basin: Implications For Coalbed Gas, Mehmet Namik Yalçin, Cemi̇l Seyi̇s, Sedat İnan Sep 2023

Rank Of Kozlu Formation Coals In The Zonguldak Basin: Implications For Coalbed Gas, Mehmet Namik Yalçin, Cemi̇l Seyi̇s, Sedat İnan

Turkish Journal of Earth Sciences

Carboniferous bituminous coals of the Zonguldak Basin have been mined for over a century. Due to underground mining activity, there have been several fatal incidents related to gas explosions. The gas content of the coals varies greatly in the basin mainly based on coal maturity (rank), increasing with increasing coal depth. In this study, we report a map for coal depth and coal rank in the Kozlu-Üzülmez-Karadon districts of Zonguldak Basin with hope the that it would aid coal gas exploration/exploitation and also coal gas degassing efforts for safer underground mining production in the Zonguldak Basin.


Dynamics Of A Giant Slow Landslide Complex Along The Coast Of The Aral Sea, Central Asia, Gökhan Aslan, Marcello De Michele, Daniel Raucoules, François Renard, John Dehls, Ivanna Penna, Reginald Hermanns, Zi̇yadi̇n Çakir Sep 2023

Dynamics Of A Giant Slow Landslide Complex Along The Coast Of The Aral Sea, Central Asia, Gökhan Aslan, Marcello De Michele, Daniel Raucoules, François Renard, John Dehls, Ivanna Penna, Reginald Hermanns, Zi̇yadi̇n Çakir

Turkish Journal of Earth Sciences

We report here a slow-moving landslide complex of the lateral spreading type revealed by Sentinel-1 interferometric timeseries analysis. Located along the western coast of the Aral Sea, with a >150-km length and 3-km width, a giant active landslide complex, slides with a constant velocity of up to 60 mm/year. Systematic subsidence up to 5 mm/year is also observed along narrow strips of terraces that appear to result from rotations of fault-bounded blocks. The landslide deformation velocity does not correlate with the annual variations of the water level in the southwestern lake of the Aral Sea during the observation period of …


Mineralogical-Petrographical Features, Geochemical Characteristics, And S Isotope Variability Of Pb-Zn Deposits In The Sakarya Fragment Of The Biga Peninsula (Nw Türkiye), Gökhan Demi̇rela, Si̇nan Akiska, Eli̇f Akiska Sep 2023

Mineralogical-Petrographical Features, Geochemical Characteristics, And S Isotope Variability Of Pb-Zn Deposits In The Sakarya Fragment Of The Biga Peninsula (Nw Türkiye), Gökhan Demi̇rela, Si̇nan Akiska, Eli̇f Akiska

Turkish Journal of Earth Sciences

The Biga Peninsula in northwestern Anatolia, a part of the Alpine-Himalayan orogenic belt, has a complex geology that was formed following the closure of the northern branch of the Neotethys. Intense volcanism and plutonism in the area from the Eocene to the Middle Miocene period caused several Pb-Zn-Cu±Ag±Au deposits to form. The geometry of the mineralizations is largely made up of polymetallic veins, manto-chimneys, and irregular replacement bodies. Ore-bearing and host rocks in the mineralization zones and the wall rocks outside the mineralization zones were compiled in this study. The most common minerals in the skarn zones are garnet, pyroxene, …


Stepwise Dynamic Nearest Neighbor (Sdnn): A New Algorithm For Classification, Deni̇z Karabaş, Derya Bi̇rant, Peli̇n Yildirim Taşer Sep 2023

Stepwise Dynamic Nearest Neighbor (Sdnn): A New Algorithm For Classification, Deni̇z Karabaş, Derya Bi̇rant, Peli̇n Yildirim Taşer

Turkish Journal of Electrical Engineering and Computer Sciences

Although the standard k-nearest neighbor (KNN) algorithm has been used widely for classification in many different fields, it suffers from various limitations that abate its classification ability, such as being influenced by the distribution of instances, ignoring distances between the test instance and its neighbors during classification, and building a single/weak learner. This paper proposes a novel algorithm, called stepwise dynamic nearest neighbor (SDNN), which can effectively handle these problems. Instead of using a fixed parameter k like KNN, it uses a dynamic neighborhood strategy according to the data distribution and implements a new voting mechanism, called stepwise voting. Experimental …