Physical Sciences and Mathematics Commons^™

Characterization Of Cellulase Enzyme Inhibitors Formed During The Chemical Pretreatments Of Rice Straw, Kalavathy Rajan

Graduate Theses and Dissertations

Production of fuels and chemicals from a renewable and inexpensive resource such as lignocellulosic biomass is a lucrative and sustainable option for the advanced biofuel and bio-based chemical platform. Agricultural residues constitute the bulk of potential feedstock available for cellulosic fuel production. On a global scale, rice straw is the largest source of agricultural residues and is therefore an ideal crop model for biomass deconstruction studies. Lignocellulosic biofuel production involves the processes of biomass conditioning, enzymatic saccharification, microbial fermentation and ethanol distillation, and one of the major factors affecting its techno-economic feasibility is the biomass recalcitrance to enzymatic saccharification. Preconditioning …

Analytical Comparison Of Contrasting Approaches To Estimating Competing Risks Models, Brian Stephen Rickard

Graduate Theses and Dissertations

Survival analysis is a commonly used tool in many fields but has seen little use in education research despite a common number of research questions for which it is well suited. Researchers often use logistic regression instead; however, this omits useful information. In research on retention and graduation for example, the timing of the event is an important piece of information omitted when using logistic regression. A simulation study was conducted to evaluate four methods of analyzing competing risks survival data, Cox proportional hazards regression, Weibull regression, Fine and Gray's Method, and Cox proportional hazards regression with frailty. College student …

Interpretation Of Late Cretaceous Volcanic Mounds And Surrounding Gulfian Series Formations Using 3d Seismic Data In Zavala County, Texas, Laura Claire Bennett

Graduate Theses and Dissertations

The Late Cretaceous Gulfian series is a prominent and important series across the State of Texas that has been extensively studied since the nineteenth century. It is composed of series of southeast-dipping shelf carbonates and clastics deposited on the northwest margin of the Gulf of Mexico Basin. In south Texas, the Gulfian series was deposited in the Rio Grande Embayment and Maverick Basin and is comprised of the Eagle Ford Group, Austin Group, Anacacho Limestone, San Miguel Formation, Olmos Formation, and Escondido Formation that crop out and continue basinward in the subsurface. Late Cretaceous volcanism formed volcanic mounds composed of …

Terrestrial Impacts Of The Central Atlantic Magmatic Province On Western Pangea, Todd Kenneth Knobbe

Graduate Theses and Dissertations

Earth's climate is predominantly controlled by the fluctuation of greenhouse gases, specifically CO2 and CH4, over geologic time. The late Triassic is a period of abrupt climate change that has been associated with a disruption to the global carbon cycle due the emplacement of the Central Atlantic Magmatic Province (CAMP). Evidence has shown that this global carbon cycle perturbation may be the culprit for the end-Triassic extinction. The Whitmore Point Member of the Moenave Formation is a lacustrine deposit with a disputed age of either late Triassic or early Jurassic and currently no absolute dating techniques can be applied to …

Mirror Buckling Transitions In Freestanding Graphene Membranes Induced Through Scanning Tunneling Microscopy, James Kevin Schoelz

Graduate Theses and Dissertations

Graphene has the ability to provide for a technological revolution. First isolated and characterized in 2004, this material shows promise in the field of flexible electronics. The electronic properties of graphene can be tuned by controlling the shape of the membrane. Of particular interest in this endeavor are the thermal ripples in graphene membranes. Years of theoretical work by such luminaries as Lev Landau, Rudolf Peierls, David Mermin and Herbert Wagner have established that 2D crystals should not be thermodynamically stable. Experimental research on thin films has supported this finding. Yet graphene exists, and freestanding graphene films have been grown …

Mapping Ancient Baldcypress Forests For Conservation At Black River, North Carolina, Jordan Nichole Burns

Graduate Theses and Dissertations

A few ancient baldcypress-bottomland hardwood forests survive across the southeastern United States in a mosaic of remnant old-growth stands left untouched by extensive logging during the early 20th century. Uncut stands in the Southeast that survived centuries of disturbance following European settlement tended to be too senescent and non-commercial to justify logging. Remnant ancient baldcypress forests at Black River, North Carolina, appear to contain the oldest living trees in eastern North America and The Nature Conservancy has protected several of these stands. However, the full extent of ancient bottomland forests along Black River is not known and many valuable tracts …

Toolstone Use In Ozark Prehistory: Assessing Adaptations To A Lithic Dichotomy In The Boston Mountains And Springfield Plateau, Luke Allen Morris

Graduate Theses and Dissertations

Toolstone use in the Ozark Mountains is a reactionary process reliant on how the landscape provides or constrains chipped stone for prehistoric populations. These technological adaptations are recognized at sites throughout the area, but no regional assessment of lithic assemblages provides answers as to why certain stones are used at a particular location. This thesis employs a five step mass analysis of lithic assemblages, and GIS visualizations to observe how the organization of stone technologies vary based on location within contrasting geologic contexts. The chert-bearing Springfield Plateau, and the Boston Mountains with siltstone, are two neighboring dichotomous landscapes that illustrate …

Inertial Force-Driven Synthesis Of Near-Infrared Plasmonic Nanosphere Composites: Physicochemical Characterizations, Joseph Noel Batta-Mpouma

Graduate Theses and Dissertations

Near-infrared (NIR) responsive nanoparticles (NPs) like gold nanorods (GNRs) are important in biomedical fields because of their transparency for biological tissues. Although GNRs are sought after as contrast agents for theranostics in cancer studies, capping ligands like cetyltrimethylammonium bromide (CTAB) for the GNR synthesis are toxic for biological tissues. The need for an alternative to toxic GNRs is of interest to alleviate the problem.

This work aimed to optimize the synthesis of NIR responsive nanosphere composites (NSCs) by inertial force (g-force) using colloidal gold NPs as model, elucidate the mechanism for the NSC formation, and study their detailed physicochemical characteristics. …

Geologic Controls On Oil And Gas Accumulation And Production From Missourian Stage Granite Wash Reservoirs In The Western Anadarko Basin, Wheeler County, Texas, Derrell Mathis

Graduate Theses and Dissertations

Up-to-date regional and local Granite Wash data of any form is either too scarce to reference or highly privatized by exploration and production companies operating in the region. The objective of this research is to correlate horizontal production data with mapped depositional trends from Upper Pennsylvanian (Missourian Stage) Granite Wash reservoirs in the Western Anadarko Basin in northeastern Wheeler County, Texas. The correlation of raster logs to define various trap type and geometries in Missourian Granite Wash reservoirs of Wheeler County, Texas is used to understand the geologic controls on oil and gas accumulation and production. The analysis includes detailed …

Epitaxial Growth Of Silicon On Poly-Crystalline Si Seed Layer At Low Temperature By Using Hot Wire Chemical Vapor Deposition, Manal Abdullah Aldawsari

Graduate Theses and Dissertations

There has been a growing interest in using low cost material as a substrate for the large grained polycrystalline silicon photovoltaic devices. The main property of those devices is the potential of obtaining high efficiency similar to crystalline Si devices efficiency yet at much lower cost because of the thin film techniques. Epitaxial growth of Si at low temperatures on low cost large grained seed layers, prepared by aluminum induced crystallization method (AIC), using hot wire chemical vapor deposition (HWCVD) system is investigated in this thesis. In this work, different parameters have been studied in order to optimize the growth …

The Power Behind The Controversy: Understanding Local Policy Elites' Perceptions On The Benefits And Risks Associated With High Voltage Power Line Installation In The State Of Arkansas, Rachael Marie Moyer

Graduate Theses and Dissertations

Following a proposal for the installation of high voltage power lines in northwest Arkansas, a controversial policy debate emerged. Proponents of the transmission line argue that such an installation is inevitable and necessary to efficiently and reliably support the identified electric load in the region. Opponents claim that the lines will degrade the natural environment and hamper the tourism-based local economy in affected regions, notably in Ozark Mountain areas. This study seeks to understand how local policy elites perceive the benefits and risks associated with proposed transmission lines, which is a critical step in comprehending the formation and changes of …

Novel [3,3]- And [1,3]- Rearrangements Of Azole-Derived N,X-Ketene Acetals, Sefat A. Alwarsh

Graduate Theses and Dissertations

The formation of carbon-carbon bonds in organic chemistry is fundamentally important. One of the major reactions that chemists have widely investigated is the Claisen rearrangement. Based on the fundamental features of this rearrangement, chemists exploited the capability of the transformation and invented their own variations of Claisen-type rearrangements. Our goal in this project is to develop a novel variation of the Claisen rearrangement using azole compounds, which are common heteroaromatic ring systems that are present extensively in the biomedically important natural products. We propose here novel methodologies of preparing 2-substitution azole derivatives using aza-based Claisen rearrangement, N,X-ketene acetals that requires …

A Pump Monitoring Approach To Irrigation Pumping Plant Performance Testing, William Merritt Mcdougall

Graduate Theses and Dissertations

Traditionally, irrigation pumping plants have been tested using an instantaneous appraoch, which tests performance parameters over a very short time interval. Using this method, the tester measures the necessary work and energy use parameters to calculate the desired pumping plant performance values. The primary limitation of this approach is its inability to determine the season long efficiency of an irrigation pumping plant.

A new approach to evaluating irrigation pumping plant performance is the use of pump monitoring systems which use high frequency, real-time data collection and telemetry to relay information directly from the pump to the user. This method of …

Stratigraphic Analysis With Respect To Aggregate Potential In The Duffield Quarry In Gum Log, Arkansas, Brock Evan Langford

Graduate Theses and Dissertations

The crushed stone mining industry is valued at nearly one billion dollars in Arkansas alone. Physical properties of the rock dictate whether or not an area may be suited for the establishment of an aggregate quarry. The Gum Log quarry located 10 miles northeast of Russellville, Arkansas is geographically well situated near areas in need of aggregate material, as well as physically competent rock. The rock mined in Gum Log is located in the Upper Atoka Formation, a Middle Pennsylvanian aged member of the Arkoma Basin. There are five different lithologic facies identifiable in the quarry (Facies 1-5 respectively): A …

Wip, Armon Nayeraini

Computer Science and Computer Engineering Undergraduate Honors Theses

Games have been shown to be capable tools in teaching. Additionally, programming can be a hard skill to learn. The objective of this research was to create a game that helps student learn coding concepts by playing a video game. The result of our work is a fully functional game that introduces the beginning concepts of programming: sequential, conditional, iterative operations.

Constituent Load Estimation In The Lower Ouachita-Smackover Watershed, Zach P. Simpson, Erin E. Scott, Brian E. Haggard

Technical Reports

Water quality was monitored at 21 sites in the Lower Ouachita‐Smackover Watershed from 2013 November through 2014 September. The U.S. Geological Survey maintains discharge monitoring stations at two of these sites, Moro Creek (USGS 07362500) and Smackover Creek (USGS 07362100), which were sampled during base flow and storm event conditions, whereas the other sites were only sampled during baseflow. The Arkansas Water Resources Center (AWRC) estimated constituent loads for nitrate‐N (NO₃‐–N), total nitrogen (TN), soluble reactive phosphorus (SRP), total phosphorus (TP) and total suspended solids (TSS) using the U.S. Geological Survey LOADEST software. LOADEST creates regression models between constituent concentrations …

Tweetement: Pseudo-Relevance Feedback For Twitter Search, Kanatbay Bektemirov

Computer Science and Computer Engineering Undergraduate Honors Theses

Microblogging platforms such as Twitter let users communicate with short messages. Due to the messages’ short content and the users’ tendency to type short queries while searching, it is particularly challenging to locate useful tweets that match user queries. The fundamental problems of word mismatch due to ambiguity are especially acute. To solve this problem, this thesis explores and compares multiple automatic query expansion methods that involve the most frequent hashtags and keywords. We built a Web service that provides real-time Twitter Search results incorporating automatic query expansion. Six pseudo-relevance feedback methods were studied and the numbers indicate that results …

Controls On Dissolution Rate Variation At A Pair Of Underflow-Overflow Springs At The Savoy Experimental Watershed, Kiefer Allen Vaughn

Graduate Theses and Dissertations

Physical dissolution experiments and numerical modeling have been used in the past to study limestone dissolution rates. Numerical models have typically used constant dissolution rates, whereas rates in nature vary in time. Limestone tablets allow natural estimation of rates over month time scales, but these rates cannot necessarily be extrapolated to geologic timescales and also do not aid our understanding of short term variability. This study characterizes natural variability in these rates and examines potential causes of that variability from first principles. This may enable more accurate projections of dissolution rates within models. This study combines measurement of physical and …

Wayne E. Sabbe Arkansas Soil Fertility Studies 2014, Nathan A. Slaton

Arkansas Agricultural Experiment Station Research Series

Rapid technological changes in crop management and production require that the research efforts be presented in an expeditious manner. The contributions of soil fertility and fertilizers are major production factors in all Arkansas crops. The studies described within will allow producers to compare their practices with the university’s research efforts. Additionally, soil-test data and fertilizer sales are presented to allow comparisons among years, crops, and other areas within Arkansas.

Evaluating The Assessment Methodology For The Chlorophyll-A And Secchi Transparency Criteria At Beaver Lake, Arkansas, J. Thad Scott, Brian E. Haggard

Technical Reports

No abstract provided.

Habitat Assessment And Ecological Restoration Design For An Unnamed Tributary Of Stone Dam Creek, Conway, Arkansas, Paige E. Boyle, Mary C. Savin, James A. Mccarty, Marty D. Matlock

Discovery, The Student Journal of Dale Bumpers College of Agricultural, Food and Life Sciences

Urbanization can lead to increased sedimentation, erosion, pollution, and runoff into streams. The United States Environmental Protection Agency’s (USEPA) Rapid Bioassessment Protocols (RBPs) are sets of guidelines that can be used to assess a habitat’s sedimentology, hydrology, vegetation, and geomorphology to determine impairment. An unnamed tributary of Stone Dam Creek on the University of Central Arkansas (UCA) campus in Conway, Arkansas runs partially underground and through the urbanized UCA campus watershed. The stream was assessed using the USEPA’s RBPs to determine impairment of the stream, and received a RBP score of 71.2 out of 200 compared to 153.5 in a …

A New Design Method For Vanadium Redox Batteries In Renewable Energy Systems, Casey Gibson, Karla G. Morrissey Unversity Of Arkansas, Fayetteville

Inquiry: The University of Arkansas Undergraduate Research Journal

This study investigated the behavior of vanadium redox flow batteries (VRFBs), which are batteries capable of easily switching between charging and discharging modes, making them a suitable option for storing intermittent sources of alternative energies (solar, wind, etc). Since different sizes of the battery provide varying voltages, optimal parameters for a particular home are key for implementation. These parameters, specifically the cell and tank volumes of the battery that are capable of providing consistent on-load voltage, were determined using data from a 13 kW solar array and a medium-sized house. Charge/discharge current values were used to run a mathematical model …

Impact Of Environmentally Friendly Packaging On Consumers’ Attitudes And Patronage Intentions Toward Apparel Retail Brands, Madalyn M. Smith, Eunjoo Cho

Discovery, The Student Journal of Dale Bumpers College of Agricultural, Food and Life Sciences

Consumer interest in social responsibility (SR) has greatly increased in recent years. Providing environmentally friendly packaging (recycled and reusable bags) is one example of how apparel retail brands can engage in SR. The objective of this research was to explore the impact of using environmentally friendly packaging on consumers’ attitudes and patronage intentions toward apparel retail brands. To conduct this research, undergraduate and graduate students from a major mid-Southern university completed an online survey testing consumers’ perceptions, environmental consciousness, attitudes, and patronage intentions. Results from this study revealed that young consumers’ perceptions of environmentally friendly packaging has a positive impact …

Bond Length - Bond Valence Relationships For Carbon - Carbon And Carbon - Oxygen Bonds, C. Harris, F. D. Hardcastle

Journal of the Arkansas Academy of Science

In the present study, relationships are developed for determining bond orders (also referred to as bond valences or bond numbers) from published bond lengths for carbon-carbon (C-C) and carbon-oxygen (C-O) bonds. The relationships are based on Pauling’s empirical formula s = exp((Ro-R)/b)), where s is the bond order, R is the corresponding bond length, Ro is the unit valence bond length, and b is a fitting parameter. We use a recently derived relationship for the b parameter in terms of the bonding atoms’ published atomic orbital exponents. The resulting equations were checked against published x-ray diffraction (XRD) data for 176 …

Wave Profile For Anti-Force Waves With Maximum Possible Currents, M. Hemmati, R. Horn, W. P. Childs, A. K. Meredith

Journal of the Arkansas Academy of Science

In the theoretical investigation of the electrical breakdown of a gas, we apply a one-dimensional, steady state, constant velocity, three component fluid model and consider the electrons to be the main element in propagation of the wave. The electron gas temperature, and therefore the electron gas partial pressure, is considered to be large enough to provide the driving force. The wave is considered to have a shock front, followed by a thin dynamical transition region. Our set of electron fluid-dynamical equations consists of the equations of conservation of mass, momentum, and energy, plus the Poisson's equation. The set of equations …

Aquatic Effects Of A Localized Oil Spill On Lake Conway, Ar And Its Tributaries, M. E. Kennon, J. L. Bouldin

Journal of the Arkansas Academy of Science

Oil spills, no matter where they occur, elicit environmental concern and avoiding these disasters should be a priority. Old pipelines that are not regularly maintained and carry large amounts of crude oil long distances are of particular concern. One such pipeline is the 65 year-old Pegasus pipeline owned by ExxonMobil. On March 29, 2013, 795,000 L of Wabasca Heavy Canadian crude oil spilled into a neighborhood of Mayflower, Arkansas, when the Pegasus pipeline ruptured. This spill led to the evacuation of many homes in the surrounding neighborhood. Drainage ditches in the affected neighborhood drained oil into a nearby cove of …

Natural Nutrient Sources In The Cache River Watershed, Arkansas, M. K. Kilmer, N. Poe, S. Chappell, J. L. Bouldin

Journal of the Arkansas Academy of Science

The growth of the hypoxic ‘dead zone’ in the Gulf of Mexico in recent years has placed increased focus on potential sources of nutrient pollution, with most of the focus being placed on watersheds where practices, including fertilizer application and land alterations combine to increase non-point source runoff. In this study, nutrient concentrations in surface waters of altered and unaltered areas of the Cache River Watershed, Arkansas, were compared to determine if agricultural land usage was responsible for the majority of nutrient inputs. Results suggest that for dissolved nitrites and orthophosphates, agricultural (altered) sites contribute significantly more than relatively unaltered …

Low-Level Mercury Causes Inappropriate Activation In T And B Lymphocytes In The Absence Of Antigen Stimulation, K. L. Weigand, J. L. Reno, B. M. Rowley

Journal of the Arkansas Academy of Science

The immune system primarily utilizes two cell types for adaptive immunity: T lymphocytes and B lymphocytes. T lymphocytes are activated when antigen presenting cells (APCs) present antigen to membrane-bound T cell receptors. B lymphocytes are activated when an antigen binds to receptors embedded in the plasma membrane. In both T and B cells this antigen binding crosslinks the receptor complexes and initiates the signal transduction cascade. These cascades frequently consist of a series of intracellular molecules becoming phosphorylated in a step-wise fashion. Once activated, these cells differentiate into effector cells that clear out the stimulating antigen. Mercury, which is a …

The Effect Of Turning Frequency On In-Vessel Compost Processing And Quality, Paige E. Boyle, Mary C. Savin, Lisa S. Wood

Discovery, The Student Journal of Dale Bumpers College of Agricultural, Food and Life Sciences

Composting can contribute to the zero waste initiative on the University of Arkansas (UA) campus. In-vessel systems like Earth Tubs™ are purported to provide better control of temperature and moisture during the composting process. Turning materials helps facilitate microbial activity and thermophilic composting. The goal of this research was to determine if turning frequency affects processing or final quality of compost made with pre- and post-consumer food waste feedstock and a wood chip bulking agent. Turning frequencies (treatment) of 3 days/week and 7 days/ week were evaluated simultaneously throughout three sequential runs. Temperature, pH, electrical conductivity (EC), and moisture content …

Earthworm Populations In A Wheat-Soybean Double-Crop System Under Seven Years Of Established Residue Management Practices, Jill Thomason, Mary Savin, Kristopher Brye, Donn T. Johnson

Discovery, The Student Journal of Dale Bumpers College of Agricultural, Food and Life Sciences

Earthworms improve soil structure, distribute litter and microbes, stimulate microbial activity, facilitate decomposition, and increase nitrogen (N) availability for plant growth. Earthworm density is often reduced in low organic matter soils that are intensively managed to grow row crops. This study was designed to relate earthworm density and community composition to residue management after seven years of established management practices in a wheat (Triticum aestivum L.)-soybean (Glycine max (L.) Merr.) double-crop system maintained in Marianna, Ark. Residue management practices included conventional tillage (CT) and no-tillage (NT), N fertilization to produce high and low wheat residue amounts left in the field, …