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Articles 1411 - 1440 of 2433

Full-Text Articles in Physical Sciences and Mathematics

A Secure And Fair Resource Sharing Model For Community Clouds, Santhosh S. Anand May 2013

A Secure And Fair Resource Sharing Model For Community Clouds, Santhosh S. Anand

Graduate Theses and Dissertations

Cloud computing has gained a lot of importance and has been one of the most discussed segment of today's IT industry. As enterprises explore the idea of using clouds, concerns have emerged related to cloud security and standardization. This thesis explores whether the Community Cloud Deployment Model can provide solutions to some of the concerns associated with cloud computing. A secure framework based on trust negotiations for resource sharing within the community is developed as a means to provide standardization and security while building trust during resource sharing within the community. Additionally, a model for fair sharing of resources is …


Variability In The Hydraulic Conductivity Of A Test Pad Liner System Using Different Testing Techniques, Matthew Jonathan Nanak May 2013

Variability In The Hydraulic Conductivity Of A Test Pad Liner System Using Different Testing Techniques, Matthew Jonathan Nanak

Graduate Theses and Dissertations

Historic methods (the time lag approach, the velocity approach, and the Z-t approach), utilized to reduce two stage borehole test data, were evaluated. Two of the historic methods provided viable results and were used for this research project. Additionally, these two methods are recommended for reducing two stage borehole test data in the future.

Flexible wall permeameter and soil index laboratory testing were conducted on the soil used to construct three environmentally controlled compacted clay liners (test pads) to develop a zone of acceptance (placement window). Using the results from the laboratory testing, two acceptance criterions were evaluated, while one …


An Investigation Of The Electronic Coupling In Some Dimeric Ruthenium (Ii) Polypyridine Complexes, Roland Ngebichie Njabon May 2013

An Investigation Of The Electronic Coupling In Some Dimeric Ruthenium (Ii) Polypyridine Complexes, Roland Ngebichie Njabon

Graduate Theses and Dissertations

A detailed understanding of respiration at the molecular level requires an understanding of the many electron transfer steps involved in the process. These electron transfer processes are extremely fast and are impossible to measure by simple rapid mixing techniques. In order to get around this problem, scientists have used laser flash photolysis. This technique relies on the fact that under proper conditions, a reactant can be generated by a very short laser pulse. Once generated, the course of the reaction can be monitored by various techniques capable of very rapid time response. Many applications of this methodology rely on the …


Modeling Greenhouse Gas Emissions And Net Return Implications For Cow-Calf Producers In The Ozark Highlands, Stephen Aaron Smith May 2013

Modeling Greenhouse Gas Emissions And Net Return Implications For Cow-Calf Producers In The Ozark Highlands, Stephen Aaron Smith

Graduate Theses and Dissertations

Cow-calf producers in the Ozark Highlands region are under continuous pressure to improve economic efficiency. Additionally, estimating greenhouse gas (GHG) emissions from cow-calf and forage production processes may become increasingly important as policy makers seek to mitigate or reduce agriculture's role in climate change. As such, this analysis had three objectives. Objective 1: Provide a model that could be used by cow-calf producers, extension agents, and researchers to evaluate GHG and net return (NR) repercussions when modifying site characteristics, production methods, and inputs. Objective 2: Develop a user guide such that the methodology for estimating cow-calf GHG emissions and NR …


Biodiesel Transesterification Byproducts As Soil Amendments, Solomon Parker May 2013

Biodiesel Transesterification Byproducts As Soil Amendments, Solomon Parker

Graduate Theses and Dissertations

For every ten kilograms of biodiesel that is produced from the transesterification of vegetable oil, approximately 1 kg of glycerol is produced as a byproduct. Also known as glycerin, it is a chemical used in many products including cosmetics, foods, and desiccants. However, the crude glycerol created during biodiesel production is tainted with potassium hydroxide and methanol making it unsuitable for commercial use without costly refinement. With increase in production of biodiesel driven by rising fuel prices, the market has become glutted with glycerol and it is on the threshold of becoming a waste product. Common methods for disposing glycerol …


Active Galactic Nuclei Mergers And Outflows: Observations From Optical And Ultraviolet Emission Lines, Robert Scott Barrows May 2013

Active Galactic Nuclei Mergers And Outflows: Observations From Optical And Ultraviolet Emission Lines, Robert Scott Barrows

Graduate Theses and Dissertations

I have investigated the nature of a subset of active galactic nuclei (AGN) which show double peaks in their characteristic optical and ultraviolet emission lines. I have performed this investigation through studies of the broad emission line regions (BLRs), which are produced less than 1 pc from the central supermassive black hole (SMBH), and the narrow emission line regions (NLRs), which originate at larger (kpc) distances. The BLR studies consist of detailed line modeling of two individual quasars with double-peaked broad emission line profiles. The modeling suggests there are two primary interpretations of the complex broad line profiles. The first …


On Chlorine Salts: Their Detection, Stability And Implications For Water On Mars And Europa, Jennifer Hanley May 2013

On Chlorine Salts: Their Detection, Stability And Implications For Water On Mars And Europa, Jennifer Hanley

Graduate Theses and Dissertations

Chlorine salts (e.g. chlorides, chlorates and perchlorates) are an important factor in the stability of water on the surfaces of planetary bodies. Here we have shown that perchlorate and chlorate salts will lower the freezing point of water, allowing it to be liquid down to ~204 K. These salts will also slow down the evaporation rate, extending the lifetime of the liquid water solution. Chlorine salts have been detected on Mars, which has significant implications for the stability of water and hence its habitability. To study their effects on the stability of water on planetary surfaces, we need to first …


Further Studies On The Allylic Diazene Rearrangement, Maha Laxmi Shrestha May 2013

Further Studies On The Allylic Diazene Rearrangement, Maha Laxmi Shrestha

Graduate Theses and Dissertations

Former graduate student Wei Qi and Professor Matt McIntosh have reported diastereoselective reductive 1,3-transpositions of acyclic alpha, beta-unsaturated tosyl hydrazones to afford substrates with a 1,4-syn or 1,4-anti relationship between alkoxy and methyl groups that proceed via an ADR (Qi, W.; McIntosh, M. C. Org. Lett. 2008, 10, 357; Qi, W.; McIntosh, M. C. Tetrahedron 2008, 64, 7021). In these reports, silica gel was employed to accelerate the reduction. We have found that acetic acid gives the same results with high diastereoselectivity in the reaction. We further optimized the reaction by lowering the amount of catecholborane to 3 eq. Effects …


Student Motivation For Pursuing A Minor In Environmental Sustainability, Luanne Woods Lewis May 2013

Student Motivation For Pursuing A Minor In Environmental Sustainability, Luanne Woods Lewis

Graduate Theses and Dissertations

Environmental sustainability dominates the global conversation seeking to increase awareness and change the culture of thinking concerning the relationship between humans and the Earth. Because many universities offer programs relative to environmental sustainability, a need exists to understand why students pursue these programs. This study examined student motivation for pursuing an environmental sustainability minor in one institution of higher education. Career, learning, monetary, and Social responsibility were the motivational factors considered in this study. The results of this study indicated significant differences among the motivational factors for pursuing a minor in sustainability among those students surveyed. Significant differences existed for …


Breckenridge Shelter Geoarchaeology, Trevor John Seekamp May 2013

Breckenridge Shelter Geoarchaeology, Trevor John Seekamp

Graduate Theses and Dissertations

My graduate research mainly focuses on Breckenridge Shelter (3CR002), Carroll County, Arkansas. As a geoarchaeologist, my concerns are geomorphological and geological processes affecting the shelter and surrounding hill slope. Breckenridge is one of several similar, Pine Hollow bluff shelters, about Beaver Lake, an impoundment of the White River, in northwest Arkansas.


The Effect Of Symmetry On The Riemann Map, Jeanine Louise Myers May 2013

The Effect Of Symmetry On The Riemann Map, Jeanine Louise Myers

Graduate Theses and Dissertations

The Riemann mapping theorem guarantees the existence of a conformal mapping or Riemann map in the complex plane from the open unit disk onto an open simply-connected domain, which is not all of the complex plane. Although its existence is guaranteed, the Riemann map is rarely known except for special domains like half-planes, strips, etc. Therefore, any information we can determine about the Riemann map for any class of domains is interesting and useful.

This research investigates how symmetry affects the Riemann map. In particular, we define domains with symmetries called Rectangular Domains or RDs. The Riemann map of an …


Gesture Based Home Automation For The Physically Disabled, Alexander Hugh Nelson May 2013

Gesture Based Home Automation For The Physically Disabled, Alexander Hugh Nelson

Graduate Theses and Dissertations

Paralysis and motor-impairments can greatly reduce the autonomy and quality of life of a patient while presenting a major recurring cost in home-healthcare. Augmented with a non-invasive wearable sensor system and home-automation equipment, the patient can regain a level of autonomy at a fraction of the cost of home nurses. A system which utilizes sensor fusion, low-power digital components, and smartphone cellular capabilities can extend the usefulness of such a system to allow greater adaptivity for patients with various needs. This thesis develops such a system as a Bluetooth enabled glove device which communicates with a remote web server to …


Agricultural Production And Stability Of Settlement Systems In Upper Mesopotamia During The Early Bronze Age (Third Millennium Bce), Tuna Kalayci May 2013

Agricultural Production And Stability Of Settlement Systems In Upper Mesopotamia During The Early Bronze Age (Third Millennium Bce), Tuna Kalayci

Graduate Theses and Dissertations

This study investigates the relationship between rainfall variation and rain-fed agricultural production in Upper Mesopotamia with a specific focus on Early Bronze Age urban settlements. In return, the variation in production is used to explore stability of urban settlement systems. The organization of the flow of agricultural goods is the key to sustaining the total settlement system.

The vulnerability of a settlement system increases due to the increased demand for more output from agricultural lands. This demand is the key for the success of urbanization project. However, without estimating how many foodstuffs were available at the end of a production …


Design And Fabrication Of Nanofluidic Systems With Integrated Sensing Electrodes For Rapid Biomolecule Characterization, Taylor Bradley Busch May 2013

Design And Fabrication Of Nanofluidic Systems With Integrated Sensing Electrodes For Rapid Biomolecule Characterization, Taylor Bradley Busch

Graduate Theses and Dissertations

A transparent nanofluidic system with embedded sensing electrodes was designed and fabricated by integrating Atomic Force Microscopy (AFM) nanolithography, Focused Ion Beam (FIB) milling and metal deposition, and standard microfabrication processing. The fabrication process started with the evaporation of chrome/gold (Cr/Au) onto a Pyrex 7740 wafer followed by photolithography and wet etching of the microchannels. The wafer was patterned a second time to form Au microelectrodes with 15-45 micrometer separation gaps in the nanochannel region. Sensing electrodes (up to one micron wide) were then deposited using FIB to bridge the gaps. The nanochannels were realized through both AFM nanolithography and …


The Geometry And Sensitivity Of Ion-Beam Sculpted Nanopores For Single Molecule Dna Analysis, Ryan Connor Rollings May 2013

The Geometry And Sensitivity Of Ion-Beam Sculpted Nanopores For Single Molecule Dna Analysis, Ryan Connor Rollings

Graduate Theses and Dissertations

In this dissertation, the relationship between the geometry of ion-beam sculpted solid-state nanopores and their ability to analyze single DNA molecules using resistive pulse sensing is investigated. To accomplish this, the three dimensional shape of the nanopore is determined using energy filtered and tomographic transmission electron microscopy. It is shown that this information enables the prediction of the ionic current passing through a voltage biased nanopore and improves the prediction of the magnitude of current drop signals when the nanopore interacts with single DNA molecules. The dimensional stability of nanopores in solution is monitored using this information and is improved …


Subsurface Stratigraphy And Characterization Of Mississippian (Osagean To Meramecian) Carbonate Reservoirs Of The Northern Anadarko Shelf, North-Central Oklahoma, Brett Robert Wittman May 2013

Subsurface Stratigraphy And Characterization Of Mississippian (Osagean To Meramecian) Carbonate Reservoirs Of The Northern Anadarko Shelf, North-Central Oklahoma, Brett Robert Wittman

Graduate Theses and Dissertations

Mississippian carbonate strata of the midcontinent contain prolific oil and gas reservoirs. Production from these carbonates has been primarily from two reservoir types, the Mississippi "chat" and recently denser chert-rich mudstone intervals. The"chat" interval is a high porosity chert residuum associated with the both the Osagean and basal Pennsylvanian unconformity. The distribution of the "chat" reservoir is discontinuous and heterogeneous. Recent horizontal drilling successes have reinvigorated academic and industry interest in the Lower Mississippian. Much of the activity is now targeting lower porosity, cherty, mudstone intervals of the Reeds Spring and Cowley Formations, which were previously considered to be non-economic. …


Litter Conditioning Is Differentially Affected By Leaf Species, Phosphorus Enrichment, And Light Availability, Erin E. Scott May 2013

Litter Conditioning Is Differentially Affected By Leaf Species, Phosphorus Enrichment, And Light Availability, Erin E. Scott

Graduate Theses and Dissertations

Anthropogenic enrichment of nitrogen and phosphorus is one of the most pervasive and detrimental threats to aquatic ecosystems worldwide. In streams that rely on allochthonous basal food resources, such as leaves, nutrient pollution can result in altered food quality and decreased carbon (C) standing stocks. However, the magnitude and mechanisms of this change in quality are poorly understood. Laboratory microcosm studies were conducted to 1) quantify the response of litter C:P to a gradient of phosphorus (P) enrichment (0, 0.05, and 0.5 mg SRP/L) across leaf species with variable levels of degradability (sugar maple and oak), and 2) quantify the …


Geophysical Surveys And Archaeological Insights At Fort Pierre Chouteau A Frontier Trading Post On The Middle Missouri, Margaret Maurine Patton May 2013

Geophysical Surveys And Archaeological Insights At Fort Pierre Chouteau A Frontier Trading Post On The Middle Missouri, Margaret Maurine Patton

Graduate Theses and Dissertations

Fort Pierre Chouteau in present day South Dakota was the most important fur trading post of the American Fur Company in the 1830s, serving as a regional hub for the fur trade. The Fort was sold to the U.S. Military in 1855 for use as a base in the Sioux Wars but was abandoned in 1856. Geophysical surveys and previous excavations indicate evidence of both occupations. Geophysics is an important tool for determining the extent of archaeological sites, yet the relationships between geophysical anomalies and excavation features may not be readily evident. Initial geophysical surveys (Kvamme 2007) were completed to …


New Effects Of Aging And Lattice Intercalation On Surface Properties Of Titanate Nanobelts, Roger Williams May 2013

New Effects Of Aging And Lattice Intercalation On Surface Properties Of Titanate Nanobelts, Roger Williams

Graduate Theses and Dissertations

Titanate nanobelts (NBs) have structural characteristics beyond that of clays. Due to a negatively charged lattice matrix of edge-shared TiO6-octahedra, the location of intercalated cations within the interlayer space may dictate the charge-conductions. This environment may in turn govern the lattice-framework's stability and surface properties, based upon our preliminary

data.

On that basis, these nanomaterials have been found in our lab to possess superb biological compatibility that is closely related to the types of the intercalated cations. In addition, a prolonged agitation was proven to enable us to manipulate the titanate NBs' length. In a parallel study, a ripening was …


Magnesium Isotopic Compositions Of The Moon And Achondrites: Implications For Their Origin And Evolution, Fatemeh Sedaghatpour May 2013

Magnesium Isotopic Compositions Of The Moon And Achondrites: Implications For Their Origin And Evolution, Fatemeh Sedaghatpour

Graduate Theses and Dissertations

The main objectives of this thesis are to estimate Mg isotopic compositions of the Moon and achondrites, to understand the behavior of Mg isotopes during magmatic differentiation processes in different planetary bodies, and to evaluate the extent of Mg isotopic heterogeneity in the solar system. In order to achieve these goals, Mg isotopes have been measured for 47 well-characterized lunar samples and 22 differentiated meteorites by MC-ICPMS. The limited Mg isotopic variations among mare and highland regolith, mare breccias, and highland impact-melt rocks reflect negligible Mg isotope fractionation during lunar surface processes (e.g. solar wind, cosmic rays, micrometeorite bombardments, meteorite …


Hardy Space Properties Of The Cauchy Kernel Function For A Strictly Convex Planar Domain, Belen Espinosa Lucio May 2013

Hardy Space Properties Of The Cauchy Kernel Function For A Strictly Convex Planar Domain, Belen Espinosa Lucio

Graduate Theses and Dissertations

This work is based on a paper by Edgar Lee Stout, where it is shown that for every strictly pseudoconvex domain $D$ of class $C^2$ in $\mathbb{C}^N$, the Henkin-Ram\'irez Kernel Function belongs to the Smirnov class, $E^q(D)$, for every $q\in(0,N)$.

The main objective of this dissertation is to show an analogous result for the Cauchy Kernel Function and for any strictly convex bounded domain in the complex plane. Namely, we show that for any strictly convex bounded $D\subset\mathbb{C}$ of class $C^2$ if we fix $\zeta$ in the boundary of $D$ and consider the Cauchy Kernel Function

\mathcal{K}(\zeta,z)=\frac{1}{2\pi i}\frac{1}{\zeta-z}

as a …


Groundcover Management System And Nutrient Source Impact Physical Soil Quality Indicators In An Organically Managed Apple Orchard, Neal Mays May 2013

Groundcover Management System And Nutrient Source Impact Physical Soil Quality Indicators In An Organically Managed Apple Orchard, Neal Mays

Graduate Theses and Dissertations

In March 2006, four groundcover management systems (GMS) and two nutrient sources (NS) were implemented for their ability to alter the soil physical condition of a newly established, organically managed apple (Malus x domestica Borkh.) orchard. Annual applications of municipal green compost (GC), shredded office paper (SP), wood chips (WC), and mow-blow (MB) grass mulch were utilized as GMS, and NS supplied to trees were from composted poultry litter (PL), a commercial organic fertilizer (CF), or an untreated control (NF) in a 4x3 factorial study. An established, conventionally-managed orchard was located adjacent to the organic research orchard on the same …


Directed Percolation And The Abstract Tile Assembly Model, Tyler Garrett Moore May 2013

Directed Percolation And The Abstract Tile Assembly Model, Tyler Garrett Moore

Graduate Theses and Dissertations

Self-assembly is a process by which simple components build complex structures through local interactions. Directed percolation is a statistical physical model for describing competitive spreading processes on lattices. The author describes an algorithm which can transform a tile assembly system in the abstract Tile Assembly Model into a directed percolation problem, and then shows simulations of the aTAM which support this algorithm. The author also investigates two new constructs designed for Erik Winfree's abstract Tile Assembly Model called the NULL tile and temperature 1.5. These constructs aid the translation between self-assembly and directed percolation and may assist self-assembly researchers in …


Interactions Between Ions And Lysenin Nanochannels And Their Potential Applications As Biosensors, Radwan Awwad Al Faouri May 2013

Interactions Between Ions And Lysenin Nanochannels And Their Potential Applications As Biosensors, Radwan Awwad Al Faouri

Graduate Theses and Dissertations

Lysenin is classified as a pore-forming toxin protein that is isolated from the earthworm Eisenia fetida and consists of 297 amino acids [1]. Lysenin inserts large conducting pores (3.0-4.7 nm in diameter) into artificial membranes (BLM) which include sphingomyelin. These pores (channels) are open and oriented upon insertion into the bilayer lipid membrane. Lysenin channels gate at positive voltages (voltage-induced gating), but not at negative voltages. Lysenin pores also exhibit activity modulation in response to changes in ionic strength and pH, indicating that electrostatic interaction is responsible for Lysenin conductance activities. In this line of inquiries, and by modulating Lysenin …


Personalized News Recommender Using Twitter, Satya Srinivasa Nirmal Jonnalagedda May 2013

Personalized News Recommender Using Twitter, Satya Srinivasa Nirmal Jonnalagedda

Graduate Theses and Dissertations

Online news reading has become a widely popular way to read news articles from news sources around the globe. With the enormous amount of news articles available, users are easily swamped by information of little interest to them. News recommender systems are one approach to help users find interesting articles to read. News recommender systems present the articles to individual users based on their interests rather than presenting articles in order of their occurrence. In this thesis, we present our research on developing personalized news recommendation system with the help of a popular micro-blogging service "Twitter". The news articles are …


Plasmonic Nanostructures For The Absorption Enhancement Of Silicon Solar Cells, Nathan Matthias Burford May 2013

Plasmonic Nanostructures For The Absorption Enhancement Of Silicon Solar Cells, Nathan Matthias Burford

Graduate Theses and Dissertations

In this work, computational investigation of plasmonic nanostructures was conducted using the commercial finite element electromagnetics solver Ansys® HFSS. Arrays of silver toroid nanoparticles located on the surface of an amorphous silicon thin-film absorbing layer were studied for particle sizes ranging from 20 nm to 200 nm in outer diameter. Parametric optimization by calculating an approximation of the photocurrent enhancement due to the nanoparticles was performed to determine optimal surface coverage of the nanoparticles. A comparison was made between these optimized nanotoroid arrays and optimized nanosphere arrays based on spectral absorption enhancement and potential photocurrent enhancement in an amorphous silicon …


The Consciousness Of Water: Narrative Flows, Environmental Change, And The Voice Of Yemen, Tricia Nellessen May 2013

The Consciousness Of Water: Narrative Flows, Environmental Change, And The Voice Of Yemen, Tricia Nellessen

Graduate Theses and Dissertations

Icebergs are melting in the Arctic. The Gulf of Mexico is warming and producing hurricanes such as Katrina. The delta of the southern United States is drying. And, Yemen will be the first country in modern history to experience a lack of accessible ground water, as soon as 2017 possibly. Yemen's situation has been tracked by scholars and governments since the 1960s. Despite this fact, cities have expanded in Yemen and the population has increased its use of water while little has been invested in desalination or infrastructure to offset growth. Climate change has affected humans for thousands of years; …


Quantum Resonant Beats And Revivals In The Morse Oscillators And Rotors, Zhenhua Li May 2013

Quantum Resonant Beats And Revivals In The Morse Oscillators And Rotors, Zhenhua Li

Graduate Theses and Dissertations

Analytical eigenfunctions and eigenvalues for the Morse oscillator were applied to investigate the quantum resonant beats and revivals of wave packet propagation. A concise way for exact prediction of the complete revival period of the Morse oscillator was given for the first time. It was suggested that any complete period was made of integer numbers of the minimum or fundamental period. Within the fundamental period, the anharmonicity of this oscillator appeared to cause interesting space-time phenomena that include relatively simple Farey-sum revival structures. In addition, a simple sum of two Morse oscillators led to a double-Morse well whose geometric symmetry …


Comparing The Impact Of Traditional And Modeling College Algebra Courses On Student Performance In Survey Of Calculus, Jerry West May 2013

Comparing The Impact Of Traditional And Modeling College Algebra Courses On Student Performance In Survey Of Calculus, Jerry West

Graduate Theses and Dissertations

Students in higher education deserve opportunities to succeed and learning environments which maximize success. Mathematics courses can create a barrier for success for some students. College algebra is a course that serves as a gateway to required courses in many bachelor's degree programs. The content in college algebra should serve to maximize students' potential in utilizing mathematics and gaining skills required in subsequent math-based courses when necessary. The Committee for Undergraduate Programs in Mathematics has gone through extensive work to help mathematics departments reform their college algebra courses in order to help students gain interest in the utilization of mathematics …


Ecological Design In The Ozarks - Workshop And Lake Frances Charrette, Steven D. Patterson, Brian E. Haggard, Mark E. Boyer May 2013

Ecological Design In The Ozarks - Workshop And Lake Frances Charrette, Steven D. Patterson, Brian E. Haggard, Mark E. Boyer

Technical Reports

No abstract provided.