Physical Sciences and Mathematics Commons^™

Excitation Power Dependence Of Blinking In Copper-Indium-Sulfide Quantum Dots, Nicholas Chambers

Physics Undergraduate Honors Theses

Under continuous excitation, quantum dots exhibit random transitions between fluorescent ON states and non-fluorescent OFF states --- a phenomenon known as blinking. A physical description of the mechanism responsible for blinking that applies broadly to many types of quantum dots remains under debate. We study the blinking behavior of the non-toxic CuInS2 quantum dot, a system that has seen little investigation at the single-particle level. In particular, the optical properties of CuInS2 quantum are often improved by adding ZnS to the nanoparticles, but this addition leads to complex structural-optical property relationships that are even less understood. To probe the relationship …

Fabrication Of Black Phosphorus Terahertz Photoconductive Antennas, Nathan Tanner Sawyers

Physics Undergraduate Honors Theses

Terahertz (THz) photoconductive antennas (PCAs) using 40nm thin-film flakes of black phosphorus (BP) and hexagonal boron nitride (hBN) have been shown computationally to be capable of THz emission comparable to those based on GaAs [2]. In this paper, I briefly describe the scientific and practical interest in THz emissions and explain what warrants research into black phosphorus as a photoconductive semiconductor in THz devices. Furthermore, I outline the basic principle of how these antennas work and mention alternative designs produced by other researchers in the past. Finally, I summarize the fabrication process of these antennas, as well as the measurements …

Photon Correlation Measurements And Second Harmonic Generation Using Pulsed Lasers, Apoorva Bisht

Physics Undergraduate Honors Theses

Correlation measurements are one of the fundamental ways to understand the photon statistics/distribution for a source of light. It is also an important method to confirm single photon sources by confirming the anitbunching nature. This project developed a correlation measurement system, utilized field programmable gate arrays, and non-linear crystals for processes like second harmonic generation and down conversion.

Subterraneans: A Regional Earth Dwelling For Comfort And Beauty, Isaak Benchoff

Architecture Undergraduate Honors Theses

Subterraneans is a study of an affordable, self-sufficient, sustainable, and dignified housing prototype for the region of Northwest Arkansas. It is a design process investigation based on the ideas of turning a local, sustainable material into affordable homes that can be built within a community of people sharing land and resources. The homes would utilize as many natural materials as possible to minimize the impact on the Earth and the cost to the owners.

Research looked at many different vernacular building precedents as well as the work done by contemporary design firms in the area of economical, low-impact, and passively …

Open Source Intelligence For Cybersecurity Events Via Twitter Data, Dakota Dale

Graduate Theses and Dissertations

Open-Source Intelligence (OSINT) is largely regarded as a necessary component for cybersecurity intelligence gathering to secure network systems. With the advancement of artificial intelligence (AI) and increasing usage of social media, like Twitter, we have a unique opportunity to obtain and aggregate information from social media. In this study, we propose an AI-based scheme capable of automatically pulling information from Twitter, filtering out security-irrelevant tweets, performing natural language analysis to correlate the tweets about each cybersecurity event (e.g., a malware campaign), and validating the information. This scheme has many applications, such as providing a means for security operators to gain …

First-Principal Investigations Of The Electronic, Magnetic, And Thermoelectric Properties Of Crtirhal Quaternary Heusler Alloy, Shuruq Alsayegh

Graduate Theses and Dissertations

Density functional theory calculations are performed to investigate the electrical electronic, magnetic, and thermoelectric properties of CrTiRhAl quaternary Heusler alloy (QHA). The type-I atomic configuration is found to be the most stable structure of this alloy. The CrTiRhAl QHA exhibits a half-metallic ferromagnetic structure with a narrow band gap at one spin channel (semiconductor), and a metallic behavior at the other spin channel. This corresponds to a 100% spin-polarization, making it ideal for potential spintronic applications. Applying the semi-classical Boltzmann theory, the Seebeck coefficient, electrical conductivity, and electronic thermal conductivity of CrTiRhAl alloy were calculated. The predicted figure of merit …

An Experimental Study Into Tholin's Solubility With Liquid Hydrocarbons On Titan, Katherine Dzurilla

Graduate Theses and Dissertations

Titan’s production of organics in its atmosphere and the liquid hydrocarbon lakes present on its surface make it a prime target for astrobiologists. Many previous studies on laboratory analogs of these organics, called "tholins", have found amino acids, nitriles, and other building blocks necessary for life. The potential solubility of tholins in the lakes of Titan presents an opportunity to create physical and chemical changes within the organics. While the lakes of Titan are primarily comprised of nonpolar compounds (methane and ethane), many predict that very small amounts of polar hydrocarbons are also present. To better understand these processes, researchers …

An Age, Size, And Climate Response Study Of Old Growth Shortleaf Pine In The Mccurtain County Wilderness Area, Oklahoma, Nicholas Cancalosi-Dean

Graduate Theses and Dissertations

Increment cores were extracted from 483 trees distributed over 21 semi-randomly sampled 0.1-hectare plots on three distinct landscape positions in the McCurtain County Wilderness Area (MCWA), a 57 square kilometer tract of uncut shortleaf pine in southeastern Oklahoma. Forty additional cores were taken off plot from older-appearing trees. All sampled trees were shortleaf pine (Pinus echinata) with a diameter at breast height (DBH) of at least 10 cm. Hardwoods were not included in the size and age analyses. The study site chosen for the sampling was made up of four parallel east-west trending ridges near North Linson Creek, making up …

Effects Of Land Use On Soil Microbial Communities In Tropical Montane Forests Of Malaysian Borneo, Yang Kai Tang

Graduate Theses and Dissertations

Land use, such as logging and forest conversion to agriculture, can modify soil physicochemical and biological properties, and affect soil health. To understand how land use change can impact soil properties and canopy structure, we used a land use gradient in Malaysian Borneo consisting of six sites, including old growth forests, mixed forests, and agriculture fields. Specifically, we aimed to answer the following questions: (1) How do soil physicochemical properties vary across land use types? (2) Does bacterial diversity and composition vary across different land use types? (3) Does fungal diversity and composition vary across different land use types? We …

Biochar As A Lake Management Option For Harmful Algal Blooms: Lab Experiments And Bioassays, Brittany Mc Intyre

Graduate Theses and Dissertations

Harmful Algal Blooms (HABs) are an increasing global concern for water management due to their increased frequency, distribution, and toxin production. In freshwaters the growth of cyanobacteria (commonly known as blue-green algae), due to anthropogenic nutrient enrichment is the primary driver of HABS; these are often referred to as cyanoHABs. The management of cyanoHABs should be focused on in the watershed through best management and conservation practices or the physical, chemical and biomanipulation of the lake or reservoir that is experiencing these blooms. In this study, we examine the use of biochar as an option for the management or treatment …

Dpd Guided Insight On The Formation Process Of Polyethersulfone Membranes By Nonsolvent Induced Phase Separation And The Effects Of Additives, Eric Ledieu

Graduate Theses and Dissertations

Dissipative particle dynamics (DPD), a coarse grain simulation method, was applied to the membrane formation process of non-solvent induced phase separation (NIPS) to gain further insight on the mechanism of certain variables and how they affect the final morphology. NIPS involves two solutions, an organic polymer dissolved in an organic solvent colloquially called the dope and an aqueous coagulation bath, brought into contact with one another. The solvents then mix, causing the polymer to fall out of solution as an asymmetric membrane with a dense surface layer and a more open subsurface layer in response to the decreasing solubility. Polyethersulfone …

The Terroir Of Swiss Cheese: A Temporal And Geomorphological Investigation Of The Martian Co2 Sublimation Pits, Racine D. Cleveland

Graduate Theses and Dissertations

Observations by NASA Mars Global Surveyor showed evidence of rough topography on the South Pole of Mars. The topography is the result of CO2 sublimation processes that occur through the changing seasons on the red planet. These sublimation areas are known to scientists as Swiss Cheese Features (SCF). SCF are erosional degradation pits that have been studied for over two decades. Studies show that these SCF increase in area over time, but these values are collected by hand on a per feature basis. Models for the pit evolution have also played a part in understanding these SCF. This work is …

Achieving Causal Fairness In Recommendation, Wen Huang

Graduate Theses and Dissertations

Recommender systems provide personalized services for users seeking information and play an increasingly important role in online applications. While most research papers focus on inventing machine learning algorithms to fit user behavior data and maximizing predictive performance in recommendation, it is also very important to develop fairness-aware machine learning algorithms such that the decisions made by them are not only accurate but also meet desired fairness requirements. In personalized recommendation, although there are many works focusing on fairness and discrimination, how to achieve user-side fairness in bandit recommendation from a causal perspective still remains a challenging task. Besides, the deployed …

Consumer Valuation And Preferences For Sustainably Produced Rice In Ghana, Vera Adabrah-Danquah

Graduate Theses and Dissertations

Sustainable agricultural production is a systematic concept that integrates environmental health, economic profitability, and social/economic equity goals. Improving the sustainability of food production is of utmost importance to the human race, given the growing population and the increased depletion of natural resources. Improving sustainability is particularly important for rice, a global food staple with a significant environmental footprint. Rice accounts for 10% of global methane emissions. The Sustainable Rice Platform (SRP) standard is the first globally recognized certified sustainable production standard for rice. This study focuses on consumers' preferences for sustainable rice in Ghana, including consumers’ perceptions of different SRP's …

Exploring Ferroelectric Phenomena In Batio3, Linbo3, And Liznsb: From Extended Oxygen Vacancies To Tri-Stable Polarization And Giant Hyperferroelectricity, Shaohui Qiu

Graduate Theses and Dissertations

This dissertation presents three projects that investigate the complex phenomena of ferroelectricity under different conditions in BaTiO3, LiNbO3, and LiZnSb using first-principles density functional calculations. Extended defects in ferroelectric solids play a crucial role in reducing the lifetime and performance of ferroelectric devices by causing fatigue, domain pinning, and aging. Thus, understanding their impact is of critical importance for the development of reliable and high-performance ferroelectric devices. In addition, hyperferroelectricity is an intriguing phenomenon that has attracted much attention in recent years. Despite the existence of depolarization field, spontaneous polarization persists under an open-circuit boundary condition (OCBC), making hyperferroelectric materials …

Asymptotic Properties And Separation Rates For Navier-Stokes Flows, Patrick Michael Phelps

Graduate Theses and Dissertations

In this dissertation, we investigate asymptotic properties of local energy solutions to the Navier-Stokes equations and develop an application which controls the separation of non-unique solutions in this class. Specifically, we quantify the rate at which two, possibly unique solutions evolving from the same data may separate pointwise away from a singularity. This is motivated by recent results on non-uniqueness for forced and unforced Navier-Stokes and analytical and numerical evidence suggesting non-uniqueness in the Leray class. Our investigation begins with discretely self-similar solutions known to exist globally in time and to be regular outside a space-time paraboloid. We prove decay …

Insights Into Star Formation And Agn Activity In Protocluster Environments From Morphological Studies And Sed Fitting, Erik B. Monson

Graduate Theses and Dissertations

In this dissertation I present work done from 2018-2023 to investigate the growth of galaxies and supermassive black holes (SMBH) in high redshift overdensities (protoclusters) by studying the star-forming galaxy and active galactic nucleus (AGN) population in the SSA22 protocluster. I examined possible environmental sources of the enhanced star formation and AGN activity in the z = 3.09 SSA22 protocluster using Hubble WFC3 ∼ 1.6 μm observations of the SSA22 field, including new observations centered on eight X-ray selected protocluster AGN. To investigate the role of mergers in the observed AGN and star formation enhancement, quantitative and visual morphological classifications …

Understanding And Tuning Magnetism In Van Der Waals Magnetic Compounds, Rabindra Basnet

Graduate Theses and Dissertations

The recently discovered two-dimensional (2D) magnetism has attracted intensive attention due to possible magnetic phenomenon arising from 2D magnetism and their promising potential for spintronics applications. The advances in 2D magnetism have motivated the study of layered magnetic materials, and further enhanced our ability to tune their magnetic properties. Among various layered magnets, tunable magnetism has been widely investigated in metal thiophosphates MPX3. It is a class of magnetic van der Waals (vdW) materials with antiferromagnetic ordering persisting down to atomically thin limit. Their magnetism originates from the localized moments due to 3d electrons in transition metal ions. So, their …

On The Impact Of Inclination-Dependent Attenuation On The Derived Star Formation Histories Of Disk Galaxies, Keith Doore

Graduate Theses and Dissertations

The physical properties of a galaxy (e.g., its star-formation history and dust content) regulate the distribution of light that is emitted by stars and attenuated by the interstellar gas and dust. This attenuation by dust can have a significant impact on the observed spectral energy distribution (SED) of a disk galaxy, especially when taking into account its viewing angle (i.e., inclination). For example, as the inclination angle of a galactic disk changes from face-on to edge-on (i.e., i = 0 deg to i = 90 deg), the proportion of light that is attenuated along the line of sight increases, due …

Potential Control Of Invasive Mesquite Through Improving The Consumer’S Understanding Of Liquid Smoke Applications., Seth W. Ellsworth

Graduate Theses and Dissertations

Mesquite trees continue to invade forests and range lands in many countries across the world. The cost to remove these trees is staggering. In Texas, landowners spent $25 million over a 10- year period to clear 300,000 ha of mesquite trees, a fraction of the 22 million ha of Texas land affected by this invasion. Estimates are that the mesquite continues to negatively impact one to two percent of additional land in selected counties each year in Texas. However, the problem is not unique to Texas, but rather to the 44 species of mesquite trees, belonging to the genus Prosopis …

Effects Of Landscape And Yard Features On Mammals In Residential Yards In Northwest Arkansas, Emily Johansson

Graduate Theses and Dissertations

The human footprint is rapidly expanding, and wildlife habitat is continuously being converted to human residential properties. Most wildlife residing in developing areas are displaced to nearby undeveloped areas. However, some animals can coexist with humans and acquire the necessary resources (food, water, shelter) within the human environment. This may be particularly true when development is low intensity, as in suburban yards. Due to the wide variety in how homeowners utilize their yards, they can be considered individually managed “greenspaces.” These yards can provide a range of food (e.g., bird feeders, compost, gardens), water (bird baths and garden ponds), and …

Improving Classification In Single And Multi-View Images, Hadi Kanaan Hadi Salman

Graduate Theses and Dissertations

Image classification is a sub-field of computer vision that focuses on identifying objects within digital images. In order to improve image classification we must address the following areas of improvement: 1) Single and Multi-View data quality using data pre-processing techniques. 2) Enhancing deep feature learning to extract alternative representation of the data. 3) Improving decision or prediction of labels. This dissertation presents a series of four published papers that explore different improvements of image classification. In our first paper, we explore the Siamese network architecture to create a Convolution Neural Network based similarity metric. We learn the priority features that …

Evaluation Of Hydrogeochemical Characteristics Of San Joaquin, Tulare, And Mojave Aquifers, Southern California, Maedeh Hassanvand

Graduate Theses and Dissertations

Before making attempts to enhance and manage the quality of water, a thorough understanding of these processes is necessary since the chemical quality of groundwater is impacted by a number of linked processes. This would be more important in arid and semiarid regions like the southern part of California where more rely on groundwater for agriculture and drinking water uses than the other states. As a result, fundamental knowledge of the governing processes of groundwater chemistry is required for effective water resource management. Thus, this study is primarily concerned with three aspects in Mojave, Tulare, and San Joaquin aquifers: The …

Evaluating Snow And Ice Cover In Tierra Del Fuego, Argentina, Zoe Pitman

Geosciences Undergraduate Honors Theses

Evaluating changes in snow and ice cover is an important field for studying climate change and its impacts. This evaluation is commonly done using remote sensing because of its ability to evaluate large areas. The purpose of this study is to determine the reliability of one remote sensing technology, the Moderate Resolution Imaging Spectroradiometer (MODIS), by comparing it to in-situ snow and climate data from the weather station at the Austral Center for Scientific Research (CADIC). Data was converted from daily to monthly averages and was sorted into a series of graphs to compare the two data sets. Correlations were …

Geochemical Analysis And Numerical Modeling Of Central And East Tennessee Mississippi Valley-Type Ore Districts: Constraints On Ore Genesis, Jackson Price Copeland

Geosciences Undergraduate Honors Theses

A simple two-way stochastic mixing model is presented for analysis of the lead (Pb) isotope compositions of the North American Mississippi Valley-Type (MVT) districts of East Tennessee, Central Tennessee, and Central Kentucky. Four distinct mixing scenarios were run to critically evaluate the stochastic model and examine different hypotheses regarding the genesis of Central Tennessee and Central Kentucky MVT deposits. Additionally, Pb isotope analysis was conducted on sphalerite samples from the Central and East Tennessee MVT districts. Model and sampling results suggest that Central Tennessee and Central Kentucky ores likely formed by mixing of three fluids. In contrast to conclusions from …

Gradient Estimates And The Fundamental Solution For Higher-Order Elliptic Systems With Lower-Order Terms, Ariel E. Barton, Michael J. Duffy Jr.

Mathematical Sciences Faculty Publications and Presentations

We establish the Caccioppoli inequality, a reverse Hölder inequality in the spirit of the classic estimate of Meyers, and construct the fundamental solution for linear elliptic differential equations of order 2m with certain lower order terms.

Quantifying The Effect Of Socio-Economic Predictors And The Built Environment On Mental Health Events In Little Rock, Ar, Alfieri Ek, Grant Drawve, Samantha Robinson, Jyotishka Datta

Sociology and Criminology Faculty Publications and Presentations

Law enforcement agencies continue to grow in the use of spatial analysis to assist in identifying patterns of outcomes. Despite the critical nature of proper resource allocation for mental health incidents, there has been little progress in statistical modeling of the geo-spatial nature of mental health events in Little Rock, Arkansas. In this article, we provide insights into the spatial nature of mental health data from Little Rock, Arkansas between 2015 and 2018, under a supervised spatial modeling framework. We provide evidence of spatial clustering and identify the important features influencing such heterogeneity via a spatially informed hierarchy of generalized …

Evaluating Species-Specific Replenishment Solution Effects On Plant Growth And Root Zone Nutrients With Hydroponic Arugula (Eruca Sativa L.) And Basil (Ocimum Basilicum L.), Lauren L. Houston, Ryan W. Dickson, Matthew B. Bertucci, Trenton L. Roberts

Horticulture Faculty Publications and Presentations

Managing nutrients in recirculating solutions can be challenging in hydroponic production, and poor management practices can rapidly result in root zone nutrient imbalances in reduced yield. Using mass balance principles to formulate hydroponic replenishment solutions is a proposed strategy to reduce nutrient imbalances and the need to periodically replace the hydroponic solution. Objectives were to (1) formulate species-specific nutrient replenishment solutions for arugula (Eruca sativa L.) and basil (Ocimum basilicum L.) using mass balance principles and (2) evaluate the effects of using these replenishment solutions on plant growth and root zone nutrients over time. In the first experiment, …

Dipole Cooperativity And Polarization Frustration Determine The Secondary Structure Distribution Of Short Alanine Peptides In Water, Ying Yuan, Feng Wang

Chemistry & Biochemistry Faculty Publications and Presentations

The physical driving forces for secondary structure preferences of hydrated alanine peptide are investigated with B3LYP-D3(BJ) and the adaptive force matching (AFM) method. The AFM fit to the DFT surface, ALA2022, provides excellent agreement with the nuclear magnetic resonance scalar coupling constants from experiments. In turn, the model is used to gain insight into the physical driving forces behind secondary structure preferences of hydrated peptides. DFT calculations with and without the Conductor-like Screening Model (COSMO) show that the α helix is stabilized by solvent polarization due to dipole cooperativity. The two adjacent amide groups in β strand form a near-planar …

Simulating A Flexible Water Model As Rigid: Best Practices And Lessons Learned, Raymond Weldon, Feng Wang

Chemistry & Biochemistry Faculty Publications and Presentations

Two ways to create rigid versions of flexible models are explored. The rigid model can assume the Model’s Geometry (MG) as if the molecule is not interacting with any other molecules or the ensemble averaged geometry (EG) under a particular thermodynamic condition. Although the MG model is more straightforward to create, it leads to relatively poor performance. The EG model behaves similarly to the corresponding flexible model (the FL model) and, in some cases, agrees even better with experiments. While the difference between the EG and the FL models is mostly a result of flexibility, the MG and EG models …