Physical Sciences and Mathematics Commons^™

Hobby Grade Lithium-Ion Batteries For Spacecraft Applications: Establishing An Automated Electrical Characteristics Testing Procedure For Flight Acceptance Of Non-Space-Grade Small Secondary Batteries, Braidon Hughes

Graduate Theses and Dissertations

Li-ion batteries are widely used due to the large amount of rechargeable energy they pack into a small, light package. This higher energy density makes Li-ion batteries ideal for small satellite applications, specifically CubeSats. CubeSats have grown in popularity in higher level education due to the National Aeronautics and Space Administration’s implementation of the Cube Satellite Launch Initiative, making it easier and cheaper to conduct small, low orbit missions. Because these CubeSats are occupying the same space as a crewed spacecraft, it is imperative that they are safe. There are numerous reports of Li-ion batteries creating fires that result in …

Synthesis Of Polyethylene Glycol-Based Hydrogels And Silver/Gold Nanostructures For Biomedical Applications, Isabelle Ishimwe Niyonshuti

Graduate Theses and Dissertations

This work focuses on the synthesis of biocompatible polyethylene glycol (PEG)-based hydrogels, silver nanoparticles (AgNPs), and silver-gold nanocages (Ag-AuNCs) for biomedical applications. The dissertation includes two parts with Part I on the work of PEG-based hydrogel for wound healing applications and Part II on the work of Ag/Au nanostructures for antimicrobial applications. Part I studies PEG-based hydrogel for the delivery of fibroblast growth factors (FGFs) for wound healing applications, aiming to overcome the challenge of designing hydrogels capable of the sustained release of bioactive FGFs. This research develops new biocompatible anionic injectable hydrogel formulations based on Poly (Oligo Ethylene Glycol …

Interplay Between The Lattice And Spin Degrees Of Freedom In Magnetoelectric And Magnetic Materials, Temuujin Bayaraa

Graduate Theses and Dissertations

This dissertation contains several investigations on the cross-coupling between structural and spin degrees of freedom in multiferroic and ferrimagnetic compounds by means of first-principles calculations and ab-initio-based Monte-Carlo simulations. We start with the reviews of magnetoelectricity, ferrimagnetism, strain engineering, followed by a brief introduction to first-principles computational methods, magnetic effective Hamiltonians, and other techniques that are utilized here. The results section of the dissertation can be divided into two parts. The first half focuses on magnetoelectric effects arising from different sources, while the second half is about the ferrimagnetic nature of materials. In the first part, we examine the epitaxial …

A 60- Year Record Of The Demotechnic Index Of States, 1960-2019, Gavin James Kellough

Graduate Theses and Dissertations

A country’s dependency on energy resources can be interpreted through the calculation of energy indices. The Demotechnic Index (DI) was used to determine the trajectory of energy efficiency of each state in the United States over the period 1960-2019. The DI serves as a measure of the energy intensity of states and a proxy for energy sustainability of each state.The DI is the ratio of total energy use to total metabolic energy demand of a population. Mathematically, DI = (E_T-E_M)/E_M E_T represents the total energy used (metabolic energy + technological energy in kilojoules annually, kJ/y), while EM represents the basic …

Cover Crop Effects On Infiltration, Aggregate Stability, And Water Retention On Loessial And Alluvial Soils Of The Lower Mississippi River Valley, Shelby G. Lebeau

Graduate Theses and Dissertations

Cover crops are a widely considered practice to improve soil health in the form of erosion control, organic matter additions, and improving water-holding capacity. Despite the well-documented benefits, little is known about the effect of cover crops on soils in the Lower Mississippi River Valley (LMRV), an area historically dominated by intensive cultivated agriculture, with soils prone to erosion, and unsustainable aquifer withdrawals for irrigation. The main objective of this study was to evaluate the effects of cover crops [with cover crops (CC) and without cover crops (NCC)] on near-surface soil physical/chemical- and infiltration-related properties, aggregate stability, and water retention. …

Forced And Unforced Permafrost Changes In The Northern Hemisphere During 1901-2100, Hong Guo

Graduate Theses and Dissertations

Permafrost regions are very sensitive to rapid changes in climate and environment. In recent decades, there has been growing interest to better understand the permafrost degradation over the Northern Hemisphere in the context of human-induced climate change. Understanding permafrost dynamics is not only important for infrastructure but also for environmental protection in cold regions. In-situ permafrost measurements are important for assessing permafrost conditions. However, direct permafrost observations are sparse and asymmetrical in both spatial and temporal coverage. Active layer thickness (ALT) modeling is another approach that can overcome many of these limitations, but the models have large uncertainty in predicting …

The Effects Of Commercial Harvest On The Density And Demography Of Aquatic Turtles In Arkansas, Andrhea Darleen Massey

Graduate Theses and Dissertations

The United States is home to the second highest concentration of turtle species in the world, after Asia. As of 2018, there are 57 turtle species recognized within the US, 40% of which are listed as threatened or endangered, with the primary threats to population persistence identified as over-consumption and/or habitat loss. Within the US, the Mississippi Alluvial Valley (MAV) region represents the second highest turtle species richness, after the Mobile River Basin. The MAV region of Arkansas is one of the least regulated in terms of commercial aquatic turtle harvest and has undergone large-scale habitat conversion from bottomland hardwood …

Hybrid Two Dimensional Quantum Devices, Joshua Patrick Thompson

Graduate Theses and Dissertations

This thesis describes measurements on hybrid material systems involving two dimensional (2D) materials and phenomena along with the development of a small, hermetically sealed cell. The hermetic cell is designed to assist with analyzing sensitive 2D materials outside of an inert environment. When working with van der Waals materials that are especially sensitive to oxygen or water, it can be difficult to identify usable thin flakes without exposing them to air. To help preserve materials for analysis in air, a capsule was designed that isolates the material in an inert environment. Although the capsule is hermetically sealed, the encapsulated material …

Formation Of Reactive Nitrogen Species During Dichloramine Decay And Their Impact On N Nitrosodimethylamine Formation Under Drinking Water Conditions, Huong Thu Pham

Graduate Theses and Dissertations

NDMA occurrence and formation pathways in drinking water systems are reviewed and NDMA yields are compared on the basis of disinfectant type, water chemistry, and precursor category. In chloramination, despite monochloramine being the predominant species between pH 7-9, evidence suggests that dichloramine is the primary species involved in NDMA formation. This is somewhat confounding as NDMA yields are maximal at pH 9, yet at pH 9 dichloramine decays faster than it forms and hence is present at trace levels; additionally, the proposed mechanism involves a spin-forbidden incorporation of dissolved oxygen as a triplet, which is presumably kinetically slow. This review …

Detrital Zircon U-Pb Geochronology Of Upper Mississippian Siltstone, Oklahoma And Arkansas, Linnea Johnson

Graduate Theses and Dissertations

Although Upper Mississippian strata have been characterized extensively using lithostratigraphy, sequence stratigraphy, and biostratigraphy across the North American midcontinent, the origin of the silt comprising the Meramec STACK (Sooner Trend Anadarko Basin, Canadian and Kingfisher counties) reservoirs of the Anadarko Basin in west-central Oklahoma and age equivalent units is not well understood, despite its economic importance as an unconventional petroleum reservoir. Previously published models have variously invoked fluvial, marine, and aeolian sediment transport for Upper Mississippian siltstone present along the paleo-shelf edge of the Laurentian craton. This study uses detrital zircon U-Pb geochronology and grain morphology, handheld x-ray fluorescence (hXRF) …

Field Evaluation Of Struvite As A Phosphorus Source, Niyi Sunday Omidire

Graduate Theses and Dissertations

Phosphorus (P) is an element that is crucial in many biological processes in all forms of life and is not substitutable. Excess P in wastewaters leading to the degradation of receiving waters or eutrophication once released is a major environmental concern. Removal of excess P from wastewater as the mineral struvite (MgNH4PO4·6H2O) could be a promising solution to reduce P discharge into receiving waters and can potentially provide a valuable fertilizer-P source for agricultural production. The objectives of this project were to evaluate the effects of: 1) chemically precipitated struvite (CPST), compared to triple superphosphate (TSP) and an unamended control …

Machine Learning Applied To A Modern-Pleistocene Petrographic Dataset: The Global Prediction Of Sand Mineralogy (Gloprsm) Model, Isaac Johnson

Graduate Theses and Dissertations

Petrography has long been used as a tool to decipher the sedimentary provenance of sand and sandstone from the relative proportions of framework grain types. Petrographers have also related the proportions of quartz (Q), feldspar (F), and lithic (L) grains to the processes that form and modify sediments within sediment routing systems. This past work has shown that factors including source lithology, climate, transport history, and tectonism work in concert to modify the framework mineralogy of sand. However, there is a lack of a quantitative understanding of the interactions and feedbacks between these factors and how they modify sand mineralogy. …

Design, Synthesis, And Catalytic Application Of Crystalline Porous Nanomaterials, Zainab Abdullah Almansaf

Graduate Theses and Dissertations

Chapter 1: COFs (covalent organic frameworks) are a new type of microporous crystalline polymer connected by organic units via strong covalent bonds. Due to their well-defined crystalline structures and excellent chemical and thermal stabilities, COF materials are considered promising candidates in applications such as gas adsorption, catalysis, and energy storage.Chapter 2: A new covalent organic framework (COF) based on imine bonds was assembled from 2-(4-formylphenyl)-5-formylpyridine and 1,3,6,8-tetrakis(4-aminophenyl)pyrene, which showed an interesting dual-pore structure with high crystallinity. Postmetallation of the COF with Pt occurred selectively at the N donor (imine and pyridyl) in the larger pores. The metalated COF served as …

Evapotranspiration In Mid-South Rice Production, Colby Wade Reavis

Graduate Theses and Dissertations

Rice provides much needed sustenance to a large portion of the global population, particularly in the developing world. With stress placed on food production systems under the reality of climate change and an increasing global population, rice production systems require solutions to a number of issues, including a limited water supply. As producers explore new strategies for conserving local water resources to continue to maintain yields, new irrigation strategies and technologies are being developed and validated for use at commercial production scales. Alternate wetting and drying (AWD) is an irrigation practice that provides water savings through the capture of rainfall …

Data-Driven Statin Initiation Evaluation And Optimization For Prediabetes Population, Muhenned A. Abdulsahib

Graduate Theses and Dissertations

This dissertation develops quantitative models to support medical decision making of statininitiation considering the uncertainty in disease progression for prediabetes patients. A mathematical model is built to help medical decision-makers take action of statin initiation under uncertainty in future prediabetes progressions. The association between cholesterol drug use, such as statin, and elevating glucose level attracted considerable amounts of attention in the literature. Statin effects on glucose vary with respect to different levels of glucose. The first chapter of this dissertation introduces the problem and an overview of the tools that will be used to solve it. In the second chapter …

Body Mass And Body Condition Variation Of Mallards (Anas Platyrhynchos) Within And Among Winters Within The Lower Mississippi Alluvial Valley, John Thompson Veon

Graduate Theses and Dissertations

Most North American waterfowl overwinter in southern North America before migrating back to breeding grounds in the northern US and Canada. These species face the challenge of needing to maintain or increase their body mass during an environmentally difficult winter period. Successful body mass maintenance during the winter period has major ramifications not only for their winter survival but for their fitness across the entire year. Recent research in Europe and the western United States suggests that the body mass of mallards (Anas platyrhynchos) has increased from the late 1960s to early 2000s. However, the factors responsible for increases in …

Investigating Depth Estimation To Archaeological Magnetic Source Bodies, Jeremy G. Menzer

Graduate Theses and Dissertations

Magnetometry is the most widely applied archaeo-geophysical technique. Current practice standards employ the technique to map only in a two-dimensional plan view fashion, but in deep geologic studies depth estimators are routinely applied to magnetic datasets. These estimators provide three-dimensional information to magnetic source-bodies. There are many different depth estimators employed in geologic study that all require various degrees of processing complexity. This study investigates two mathematically simple techniques, half-width rules and multi-height methods. Half-width rules are likely the oldest depth estimators within the field while multi-height techniques are but a minor footnote in the literature. The applicability of these …

Gaas Growth On Sapphire Substrates (C And R Plane) For Integrated Microwave Photonics (Imwp), Samir Kumar Saha

Graduate Theses and Dissertations

The microwave signal processing in the optical domain creates new opportunities for information and communication technology (ICT) and networks by increasing speed, bandwidth, and processing capability. IMWP incorporates the functions of microwave photonics components/subsystems in monolithic or hybrid photonic circuits to meet future needs. Sapphire platforms have the potential to integrate all-in-one, for instance, light source, analog signal processing, light detection, CMOS control circuit, silicon on sapphire to achieve high-performance, low-cost mixed-signal optical links etc. Molecular beam epitaxy (MBE) has been used to grow GaAs on sapphire substrates to integrate optoelectronic devices in the same platform.

The initial stage of …

Two-Dimensional Black Phosphorus For Terahertz Emission And Near-Field Radiative Heat Transfer, Mahmudul Hasan Doha

Graduate Theses and Dissertations

The main focus of this work is to investigate two potential optical and optoelectronic applications of black phosphorus (BP): the near-field radiative heat transfer in plasmonic heterostructures with graphene and terahertz emission from multi-layer BP photoconductive antennas. When the separation distance between graphene-black phosphorene is much smaller than or comparable to the thermal wavelength at different temperatures, a near-field radiation heat transfer breaks the Planck blackbody limit. The magnitude of the near-field radiation enhancement acutely depends on the gate voltage, doping, and vacuum gap of the graphene and BP pair. The strong near-field radiation heat transfer enhancement of the specific …

Parity-Time Symmetry In A Coherent Atomic Medium, Jingliang Feng

Graduate Theses and Dissertations

Parity-time (PT) symmetry has attracted considerable attention since optics was realized with the ability to provide a fertile platform for the exploration of PT symmetry. Although many of the previous researches on PT symmetry have been conducted in solid-state system and the network of fiber loops, coherent atomic medium offers another platform for the exploration of PT symmetry due to its easy reconfigurability and flexible tunability in parameters.

This dissertation mainly focuses on the investigations of the phenomena related to PT-symmetric optical lattice in a coherent atomic medium. First, a controllable photonic crystal with periodic Raman gain was constructed in …

Community Perceptions And Aesthetic Valuation Of Remediation Gardens, Rachel Bechtold

Graduate Theses and Dissertations

Creating successfully remediated landscapes may rely on both natural resources and human perception in landscape design. Urban areas present a dynamic environment wherein communities and nature compete for resources and space. This dissertation study was designed to better understand aesthetic perceptions of native plants capable of land remediation in midwestern communities. Findings from this study show the importance of aesthetic perceptions of stakeholders towards rehabilitated landscapes and the importance of organizing indicators for future design decisions in an interdisciplinary fashion. Recommendations include continued evaluation of aesthetic perceptions for plant species in urban landscapes and modeling a more consistent framework for …

Experimental And Computational Studies Of Electron Rich Alkenes, Alexa May

Graduate Theses and Dissertations

Thermal homolysis is one of the most fundamental reactions in organic chemistry. Free radical reactions are generally initiated by light or a radical initiator to generate the first radical, which can then propagate or terminate the reaction. Direct thermal homolysis requires no chemical initiators, just an increase in temperature depending on the homolysis energy.There are few studies of direct radical homolysis in complex systems or under mild conditions. The reactions involving C-N homolysis under mild conditions are reported in Chapter 1. Though the authors do not all propose a radical mechanism, we believe they can all be explained by a …

Optimization Of Nitrogen Removal Rate In One-Stage Reactor Through Partial Nitrification Anammox Process During Direct Treatment Of Poultry Litter Wastewater, Yiting Xiao

Graduate Theses and Dissertations

Anammox is an increasingly common process used for the treatment of reject water and even mainstream wastewater due to its low oxygen demand. However, anammox is not commonly utilized in the direct treatment of poultry litter because of the high organic content, which would inhibit the anammox process. Thus, this project is aimed at optimizing the nitrogen removal rate through partial nitrification anammox process (PN/A) to treat synthetic poultry litter wastewater. Nitrogen removal efficiencies will therefore be improved through optimizing the combination of three operating parameters including hydraulic retention time (HRT), dissolved oxygen (DO) concentration, and carbon to nitrogen (C/N) …

Analysis Of Bacteriorhodopsin Suspended In A Bilayer Lipid Membrane, Moath Alhejji

Graduate Theses and Dissertations

The bacteriorhodopsin protein’s unique characteristic of proton pumping can convert light energy to electric energy. The aim of this research was to generate photocurrent using bacteriorhodopsin in a bi-layer lipid membrane. Lipid monolayer and bilayer were formed using painting and folding methods, respectively. Capacitance and resistance of the lipid membranes were measured and used to validate the best methodology. My results show that the folding method is more efficient in incorporating Bacteriorhodopsin. The photocurrent was generated by illuminating a green laser (532 nm) on the bilayer lipid membranes. The patch clamp electrophysiology technique was used to apply voltage across the …

Deep Learning Strategies For Pool Boiling Heat Flux Prediction Using Image Sequences, Connor Heo

Graduate Theses and Dissertations

The understanding of bubble dynamics during boiling is critical to the design of advanced heater surfaces to improve the boiling heat transfer. The stochastic bubble nucleation, growth, and coalescence processes have made it challenging to obtain mechanistic models that can predict boiling heat flux based on the bubble dynamics. Traditional boiling image analysis relies on the extraction of the dominant physical quantities from the images and is thus limited to the existing knowledge of these quantities. Recently, machine-learning-aided analysis has shown success in boiling crisis detection, heat flux prediction, real-time image analysis, etc., whereas most of the existing studies are …

Fair And Diverse Group Formation Based On Multidimensional Features, Mohammed Saad A Alqahtani

Graduate Theses and Dissertations

The goal of group formation is to build a team to accomplish a specific task. Algorithms are being developed to improve the team's effectiveness so formed and the efficiency of the group selection process. However, there is concern that team formation algorithms could be biased against minorities due to the algorithms themselves or the data on which they are trained. Hence, it is essential to build fair team formation systems that incorporate demographic information into the process of building the group. Although there has been extensive work on modeling individuals’ expertise for expert recommendation and/or team formation, there has been …

Catalytic Activity Of Molybdenum-Dioxo Complexes, Randy Tran

Graduate Theses and Dissertations

This dissertation details the development of rationally designed dioxomolybdenum catalyst active for deoxydehydration (DODH), the net reduction of diols and polyols into alkenes and dienes. Catalyst design involved variations on dioxomolybdenum(VI) supported by a dianionic meridional pincer ligand. Rational substrate scope was explored using aliphatic diols, aromatic diols, and biomass derived diols. Various reductants were tested for ability to catalyze the reaction. The substrate specific mechanism of DODH was explored utilizing NMR and in-situ infrared spectroscopy and important rate constants and rate determining steps were found to aid in the optimization of ideal reaction conditions. Catalytic activity was observed to …

The Morphodynamic Interaction Of River Deltas And Their Marshes, Kelly M. Sanks

Graduate Theses and Dissertations

Globally, many of the largest river deltas contain vast marsh platforms that are currently threatened due to a combination of anthropogenic alterations to rivers and increasing relative sea level rise. Restoration and management plans for river deltas depend on optimizing riverine sediment accumulation in marsh platforms. However, the accumulation of organic material in marsh platforms is often neglected in predictive models and the interaction of ecogeomorphic processes governing marsh accumulation with the physical processes governing river delta growth is poorly understood.

Herein, I investigate this complex relationship through a combination of field and experimental studies. I show that in coastal …

Thin Safety Margin: The Sefor Super-Prompt-Critical Transient Experiments, Ozark Mountains, Arkansas 1970–1971, Jerry Havens, Collis Geren

Arkansas Scholarly Editions

Thin Safety Margin charts the history of SEFOR, a twenty-megawatt reactor that operated for three years in the rural Ozark Mountains of Arkansas as part of an internationally sponsored program designed to demonstrate the Doppler effect in plutonium-oxide-fueled fast reactors. Authors Jerry Havens and Collis Geren draw upon this history to assess the accidental explosion risk inherent in using fast reactors to reduce the energy industry’s carbon dioxide emissions.

If a sufficiently powerful fast-neutron explosion were to cause the containment of a reactor such as SEFOR’s to fail, the reactor’s radiotoxic plutonium fuel could vaporize and escape into the surrounding …

The Pandemic, Climate Change And Farm Subsidies, Allen H. Olson, Edward J. Peterson

Journal of Food Law & Policy

Many people believe that once the COVID-19 pandemic has passed, life will return to the way it was. This belief is both unrealistic and dangerous. It is unrealistic because the virus will be around for years if not indefinitely. The timeframe for the worst of the pandemic will depend on our ability to administer effective vaccines worldwide and the public’s willingness to accept continued social distancing in the meantime. The damage done to public health, the economy and individuals is already substantial and will get worse. Recovery will be slow and incomplete. The belief that life will return to the …