Physical Sciences and Mathematics Commons^™

Probing Of Carbohydrate-Protein Interactions Using Galactonoamidine Inhibitors, Jessica B. Pickens

Graduate Theses and Dissertations

Glycoside hydrolases are ubiquitous and one of the most catalytically proficient enzymes known, and thus understanding their mechanisms are crucial. Most research has focused on the interaction of the glycon of substrates and their inhibitors within the active site of glycoside hydrolases. The inhibitors employed to probe these interactions generally had small aglycons (i.e. a hydrogen atom, amidines, small aliphatic groups, or benzyl groups). Here, the interactions of the aglycon with glycoside hydrolases are examined by probing the active sites with a library of 25 galactonoamidines. The studies described in this dissertation aim to increase the understanding of stabilization of …

Nematode Populations As Affected By Residue And Water Management In A Long-Term Wheat-Soybean Double Crop In Eastern Arkansas, Lucia Emperatriz Escalante Ortiz

Graduate Theses and Dissertations

Soybeans (Glycine max) are one of the major row crops in the United States, particularly in Arkansas. Soybean cyst nematode (SCN, Heterodera glycines) and southern root-knot nematode (RKN, Meloidogyne incognita) are two of the most damaging pests that cause major economic losses in soybeans. Little is known concerning the effects of common and alternative agronomic practices on nematodes in fields with nematode population densities below threshold levels. Therefore, the objective of this study was to evaluate the effects of the combination of tillage (conventional tillage and no-tillage), irrigation (irrigated and non-irrigated), wheat (Triticum aestivum) residue burning (burned and no burned), …

Detecting Differentially Co-Expressed Gene Modules Via The Edge-Count Test, Anne Gratius Lin

Graduate Theses and Dissertations

Background

Gene expression profiling by microarray has been used to uncover molecular variations in many different diseases. Complementary to conventional differential expression analysis, differential co-expression analysis can identify gene markers from the systematic and granular level. There are three aspects for differential co-expression network analysis, including the network global topological comparison, differential co-expression cluster identification, and differential co-expressed genes and gene pair identification. To date, most of the methods available still rely on Pearson’s correlation coefficient despite its nonlinear insensitivity.

Results

Here we present an approach that is robust to nonlinearity by using the edge-count test for differential co-expression analysis. …

An Investigation Of Metal Sulfides As The Source Of The Low Emissivity Anomaly On The Highlands Of Venus, Sara Taeko Port

Graduate Theses and Dissertations

Since its detection in the 1960s the source of the unusual radar emissivity signal seen on several highlands on Venus has long eluded researchers. Researchers have determined that a mineral with a high dielectric constant could explain the signal. Using a Venus simulation chamber, we experimentally investigated this enigma to build upon the candidate mineral list that has been compiled over the last several decades. We tested the stability of 8 different minerals and elements at two to three different temperature/pressure regimes in three different gas mixtures meant to simulate the conditions found on Venus for a period of no …

Studies Of Initial Growth Of Gan On Inn, Alaa Alnami

Graduate Theses and Dissertations

III-nitride materials have recently attracted much attention for applications in both the microelectronics and optoelectronics. For optoelectronic devices, III-nitride materials with tunable energy band gaps can be used as the active region of devices to enhance the absorption or emission. A such material is indium nitride (InN), which along with gallium nitride (GaN) and aluminum nitride (AlN) embody the very real promise of forming the basis of a broad spectrum, a high efficiency solar cell. One of the remaining complications in incorporating InN into a solar cell design is the effects of the high temperature growth of the GaN crystal …

Reactivity Of Photogenerated Amine Radical Cations, Qile Wang

Graduate Theses and Dissertations

Recently photoredox catalysis has emerged as a powerful tool in organic synthesis led by Professor McMillan, Stephenson, Yoon. Upon absorption of visible light, photocatalyst can be excited to its singlet state followed by intersystem crossing to form a long lived excited triplet state. While amine serves as electron donor, single electron transfer (SET) can happen between excited triplet photocatalyst and nitrogen atom on amine to give a reduced photocatalyst and amine radical cation.

Cyclopropylamines or cyclobutylamines can be oxidized by excited photocatalyst to generate amine radical cations and due to the ring strain, subsequent C-C bond cleavages can lead to …

Suitability Assessment For Integrated Urban Development In Makkah City Of Saudi Arabia, Mislat Alotaibi

Graduate Theses and Dissertations

Makkah – the third most populated city in Saudi Arabia with a population of 1,684,408 according to the 2010 demographic survey conducted by the Saudi General Authority for Statistics – is experiencing urban sprawl, which can be defined as an unplanned urban expansion that might degrade the environment and diminish the aesthetic view. This is a persisting problem in Makkah driven by multitude of processes involving the random expansion in its undeveloped land and the removal of its historic mountains surrounding Al-Masjid Al-Haram (the Holy Mosque) in an attempt to push the city limit of urban capacity within its administrative …

Incorporating Geophysical Data In Slope Stability Modeling For Two Slopes In Arkansas, Vanessa Lebow

Graduate Theses and Dissertations

Slope failures in the United States alone cause millions of dollars in damage to infrastructure, threaten national monuments, create environmental hazards, and take an average of 25-50 lives a year. With the inevitable construction that occurs on slopes, it is imperative that the slopes be properly designed which requires a thorough understanding of slope grade, subsurface soil conditions, soil strength parameters, water table locations, and depth to bedrock across the entire site. The preferred method of data collection would be to use borings and other in-situ methods; however, sometimes due to cost constraints or site accessibility only a very limited …

Cost Effectiveness Of Greenhouse Gas Reductions Through Afforestation Of Agricultural Land In The Arkansas Delta, Karli A. Moore

Graduate Theses and Dissertations

Sequestration of atmospheric carbon in forested lands offsets carbon emissions from other industries. Conversion of private lands, particularly agricultural tracts in marginal areas, to forests can bolster carbon abatement. The United States government agencies administer some voluntary, incentive-based programs to encourage landowners to adopt production practices with positive environmental outcomes. This policy stream can be used to increase transition of marginal agricultural land to forests, thereby creating new carbon sinks. We analyze an eleven-county study area in the Arkansas Delta to determine feasibility for a subsidy focused on carbon abatement through afforestation. This study area is significant for two reasons: …

Development Of A Comsol Microdialysis Model, Towards Creation Of Microdialysis On A Chip With Improved Geometries And Recovery, Patrick Pysz

Graduate Theses and Dissertations

Microdialysis (µD) sampling is a diffusion-limited sampling method that has been widely used in different biomedical fields for greater than 35 years. Device calibration for in vivo studies is difficult for current non-steady state analytes of interest correlated with both inflammatory response and microbial signaling molecules (QS); which exist in low ng/mL to pg/mL with molecular weights over a wide range of 170 Da to 70 kDa. The primary performance metric, relative recovery (RR), relating the collected sample to the extracellular space concentration varies from 10% to 60% per analyte even under controlled bench-top conditions. Innovations in microdialysis device design …

Turbidity And Ion Concentrations Vary With Land Use And Underlying Geology At The West Fork Of The White River, Erin E. Scott, Brian E. Haggard

Technical Reports

The West Fork of the White River (WFWR) watershed in northwest Arkansas is a trans-ecoregion watershed and is experiencing land-use changes, especially in the downstream portion of the watershed. The entire 54-km long river has been on the State’s 303(d) list of impaired waterbodies for turbidity, total dissolved solids (TDS), and sulfate for many years. The purpose of this study was to identify which part(s) of the river fail to meet applicable water quality standards (WQS) and to investigate possible sources of pollutants, whether human-caused or naturally occurring. Water samples were collected once or twice a month at 9 sites …

Stream Water Quality To Support Huc 12 Prioritization In The Lake Wister Watershed, Oklahoma: August 2017 Through May 2019, Bradley J. Austin, Brina A. Smith, Brian E. Haggard

Technical Reports

Nonpoint source pollution associated with human land use (agriculture and urbanization) is one of the leading causes of impairment to waterways in the United States (EPA 2000). The primary pollutants associated with agricultural and urban land use are sediment and nutrients which enter nearby streams during rain events and are then carried downstream. These sediments and nutrients may result in water quality issues in the downstream water bodies like increased algal growth or decreased water clarity (e.g. Smith et al., 1999). Best management practices (BMPs) are often used to mitigate the effects of nonpoint source pollution in the watershed. Practices …

Development Of A Ground-Based Aerial-Tracking Instrument For Open-Path Spectroscopy To Monitor Atmospheric Constituents, Haden Hodges

Civil Engineering Undergraduate Honors Theses

A ground-based aerial-tracking instrument, known as the Ground Tracker, designed to provide spectral data to quantify greenhouse gases is under development. The Ground Tracker includes an Optical System including a high power rifle scope, video camera, and spectrometer used to locate an active light source from the Emitter, and collect spectral data by utilizing an actuating mirror. The implementation of this instrument could be made low cost by utilizing existing weather balloon infrastructure to allow the Emitter to be placed into the lower stratosphere. The recovery of the emitter will be possible by tracking the GPS coordinates. Weather balloon instrument …

Modification And Optimization Of Conducting Polymer-Modified, Redox-Magnetohydrodynamics (R-Mhd) Pumping For Enhanced And Sustained Microfluidics Applications, Md Foysal Zahid Khan

Graduate Theses and Dissertations

In this work, a novel microfluidic pumping approach, redox-magnetohydrodynamics (R-MHD) has improved by materials and device optimization to use in lab-on-a-chip applications. In R-MHD, magnetic flux (B) and ionic current density (j) interacts to generate body force (FB) in between active electrodes, according to the equation FB = j×B. This unique fluid pumping approach is scalable, tunable, generates flat flow profile, and does not require any channels or valves. Pumping performance, such as speed scales with the ionic current density (j) and duration depends on the total charge (Q). The ionic current density (j) results from the conversion of electronic …

Impact Of Excitation-Inhibition Balance/Imbalance On Dynamics Of Cortical Neural Networks, Vidit Agrawal

Graduate Theses and Dissertations

The purpose of this research is to study the implications of Excitation/Inhibition balance and imbalance on the dynamics of ongoing (spontaneous) neural activity in the cerebral cortex region of the brain.

The first research work addresses the question that why among the continuum of Excitation-Inhibition balance configurations, particular configuration should be favored? We calculate the entropy of neural network dynamics by studying an analytically tractable network of binary neurons. Our main result from this work is that the entropy maximizes at regime which is neither excitation-dominant nor inhibition-dominant but at the boundary of both. Along this boundary we see there …

Smoothness Of Defining Functions And The Diederich-Fornæss Index, Felita Nadia Humes

Graduate Theses and Dissertations

Let Ω ⊂ Cn be a smooth, bounded, pseudoconvex domain, and let M ⊂ ∂Ω be a complex submanifold with rectifiable boundary. In 2017, Harrington studied the equation dM A = α ̃ on M, where α ̃ is D’Angelo’s 1-form and A is real. In this thesis, we will study a non-pseudoconvex example in which M has a non-rectifiable boundary. In spite of the lack of topological obstructions on the boundary, there are no continuous solutions to dM A = α ̃.

Effect Of Cross-Validation On The Output Of Multiple Testing Procedures, Josh Dallas Price

Graduate Theses and Dissertations

High dimensional data with sparsity is routinely observed in many scientific disciplines. Filtering out the signals embedded in noise is a canonical problem in such situations requiring multiple testing. The Benjamini--Hochberg procedure using False Discovery Rate control is the gold standard in large scale multiple testing. In Majumder et al. (2009) an internally cross-validated form of the procedure is used to avoid a costly replicate study and the complications that arise from population selection in such studies (i.e. extraneous variables). I implement this procedure and run extensive simulation studies under increasing levels of dependence among parameters and different data generating …

Impact Of Sanitizers On Salmonella Enterica Contamination And Microbial Populations Of Poultry Processing Reuse Water, Andrew Micciche

Graduate Theses and Dissertations

As human populations increase in numbers, access to clean, fresh water is becoming increasingly difficult to balance between agricultural and municipal demands. Water scarcity is a limiting factor of food production in many countries, whether they are emerging or established economies. In conventional poultry processing systems, access to water is particularly critical for the maintenance and disinfection of processing areas, as well as in processing operations such as scalding, chilling, and carcass washing. The need for sustainable alternatives to single-use water supplies is becoming increasingly more urgent, and as a result, the implementation of water reuse in poultry processing plants …

Possible Schemes For A Single Photon Switch, Hemlin Swaran Rag

Graduate Theses and Dissertations

I consider the effectiveness of a single control photon to route a target photon using two processes: the first one uses the transient excitation of a two-level system and the second one which uses the permanent population transfer in a three-level Λ-system to route the target photon. In the absence of a single control photon and when the system has additional decay channels, I find ways to optimize the success probability of routing with an increasing number of photons in the control field.

The Archaeology Of Mississippian Vulnerability And Resilience In The New Madrid Seismic Zone, Michelle Megan Rathgaber

Graduate Theses and Dissertations

This work examines the vulnerability and resilience of Mississippian people in the Central Mississippi Valley to the large-scale New Madrid seismic zone earthquakes of the late15th to early 16th century. This is done using the theory of eventful archaeology/anthropology to look at cultural materials both before and after an event (such as an earthquake and sand blows) to look for evidence of changes to the schema and resources on which a society relies. If changes are present, the event can be labeled as such, if there are no changes, it means that the society affected did not see the event …

The Paleozoic Sedimentary Rocks Of The Ouachita Mountains And Their Genetic Relationship To The Mississippi Valley-Type Mineralization In The Southern Ozark Region: Insights From Radiogenic Pb Isotopes And Trace Elements Studies, Christophe Wakamya Simbo

Graduate Theses and Dissertations

Cluster of Pb and/or Zn deposits of the well-known Tri-State and Northern Arkansas Mississippi Valley Type (MVT) districts located north of the Arkoma basin and the Ouachita fold-thrust belt in north America are genetically connected to the Pennsylvanian-Permian Ouachita orogeny which triggered a South-North topographic gradient flow of basinal brines, leaching metal rich sediments en route. The objective of the research is twofold. First, to ascertain whether the organic-rich shales and sandstones from the study area provided metals during the mineralization event, which was coeval with the Ouachita orogeny. Second, to assess the depositional environment of the potential source rocks, …

Spatio-Temporal Analysis Of Tree Ring Chronology And Precipitation, Ruizhe Yin

Graduate Theses and Dissertations

Tree ring chronology data is known to reflect regional climate due to the strong impact of rainfall and temperature. Therefore, tree ring data can be used to reconstruct historical climate in order to understand how climate changed in the past and make prediction about the future behavior of the climate. For simplicity, this research only considers the influence of precipitation on tree ring growth within the New England area. A total of 94 measurement sites are used to record tree ring width over 881 years and corresponding precipitation data are given at some locations for 121 years. We developed a …

Automatic Methods To Enhance The Quality Of Colonoscopy Video, Nidhal Kareem Shukur Azawi

Graduate Theses and Dissertations

Colonoscopy is a form of endoscopy because it uses colonoscopy device to help the doctor to understand a colon patient. Enhancing the quality of Colonoscopy images is a challenge because of the wet and dynamic environment inside the colon causes many problems even the colonoscope devise has a good quality. Some of these problems are blurriness, specular highlights shiny areas.

In this work, different kinds of techniques have been investigated in order to improve the quality of colonoscopy images. Also, variety of preprocessing approaches (removing bad images, resizing images, median filtration with and without image resizing) have been conducted to …

The Disk Structure Of Late Type Galaxies: Determining The Black Hole Mass Function Of Low Surface Brightness Galaxies Through Logarithmic Spiral Arm Pitch Angle Measurement, Michael S. Fusco

Graduate Theses and Dissertations

This dissertation pertains to the geometric structure of late type (spiral) galaxies, specifically on the relation between the logarithmic spiral pitch angle of the galactic spiral arms with other properties of the galaxy, such as central Supermassive Black Hole (SMBH) mass. Our work continues a study of the Black Hole Mass Function (BHMF) in local galaxies by recording the pitch angles of spiral galaxies with lower surface brightness than were previously included. We also conduct a case study on the structure of an interestingly shaped galaxy, UGC 4599. Previous studies on the topic of spiral arm pitch angles have measured …

Polarization Properties Of Airy And Ince-Gaussian Laser Beams, Sean Michael Nomoto

Graduate Theses and Dissertations

The description of polarization states of laser light as linear, circular polarization within the paraxial scalar wave approximation is adequate for most applications. However, this description falls short when considering laser light as an electromagnetic wave satisfying Maxwell's equations. An electric field with a constant unit vector for direction of the field and a space dependent complex scalar amplitude in the paraxial wave approximation does not satisfy Maxwell equations which, in general, requires all three Cartesian components of electric and magnetic fields associated for a nonzero laser beam to be nonzero.

Physical observation of passing a linearly polarized laser through …

Adsorption Driven Regolith-Atmospheric Water Vapor Transfer On Mars: An Analysis Of Phoenix Tecp Data, Holly Nicole Farris

Graduate Theses and Dissertations

NASA’s Phoenix mission allowed for investigations of Martian diurnal water vapor cycles through the collection of temperature, relative humidity, and electric conductivity data by the Thermal and Electric Conductivity Probe (TECP) instrument. Using this data and previous experimental data, we propose a regolith-driven adsorption-desorption regime at the Phoenix landing site, where parameters intrinsic to the regolith are controlling localized relative humidity at the surface. To constrain these parameters, we model adsorption as a function of temperature and relative humidity across various Mars-relevant materials, defined by two layer-based adsorption theories: Langmuir (monolayer) and Brunauer-Emmett-Teller or BET (multilayer). Langmuir serves as an …

Consumer Preferences For Sustainable Rice Practices In Nigeria, Glory Esohe Okpiaifo

Graduate Theses and Dissertations

Improving the sustainability of rice production is important given its position as a global staple and its environmental footprint. The adoption of sustainable practices can generate positive externalities such as lower environmental pollution and improved working conditions for rice industry workers that could be capitalized via the design of consumer-based marketing strategies. The Sustainable Rice Platform (SRP) initiative aims at advancing the adoption of sustainable practices in rice production. We assess consumers’ perceptions of the SRP sustainability indicators using the Best-Worst Scaling approach to rank SRP sustainability attributes according to their preference shares and examine the effects of demographic characteristics …

Development Of A Multimode Instrument For Remote Measurements Of Unsaturated Soil Properties, Sean Elliott Salazar

Graduate Theses and Dissertations

The hydromechanical behavior of soil is governed by parameters that include the moisture content, soil matric potential, texture, and the mineralogical composition of the soil. Remote characterization of these and other key properties of the soil offers advantages over conventional in situ or laboratory-based measurements: information may be acquired rapidly over large, or inaccessible areas; samples do not need to be collected; and the measurements are non-destructive. A field-deployable, ground-based remote sensor, designated the Soil Observation Laser Absorption Spectrometer (SOLAS), was developed to infer parameters of bare soils and other natural surfaces over intermediate (100 m) and long (1,000 m) …

Microextrusion 3d Printing Of Optical Waveguides And Microheaters, Edidiong Nseowo Udofia

Graduate Theses and Dissertations

The drive for smaller and more compact devices presents several challenges in materials and fabrication strategies. Although photolithography is a well-developed method for creating microdevices, the disparate requirements in fabrication strategies, material choices, equipment and process complexities have limited its applications. Microextrusion printing (μEP) provides a promising alternative for microfabrication. Compared to the traditional techniques, the attractions lie in the wide range of printable material choice, greater design freedom, fewer processing steps, lower cost for customized production, and the plurality of compatible substrates. However, while extrusion-based 3D printing processes have been successfully applied at the macroscale, this seeming simplicity belies …

Engineered Carbon-Nanocatalyst Composites And Carbon Mixed ‎Matrix Membranes ‎For Water And Wastewater Treatment ‎, Mojtaba Abolhassani

Graduate Theses and Dissertations

Carbonaceous materials such as graphene oxide, and activated ‎carbon have a wide range of ‎applications in water and wastewater treatment due to the high surface ‎area, unique structure, ‎and chemical and thermal stability. Carbon-based materials can be used as a ‎membrane, an ‎adsorbent, a support for nanomaterials, or ‎as a filler within membranes to remove contaminants ‎from water. In this research, the specific carbon materials and how their properties influence their ‎use and performance in ‎specific engineering applications is explored. ‎

Here, membrane filtration and adsorption/degradation of the water and wastewater using carbon-‎based material are investigated. The research firstly focuses …