Physical Sciences and Mathematics Commons^™

Synthesis Of Metal Oxide Surfaces And Interfaces With Crystallographic Control Using Solid-Liquid-Vapor Etching And Vapor-Liquid-Solid Growth, Beth S. Guiton, Lei Yu

Chemistry Faculty Patents

The present invention provides integrated nanostructures comprising a single-crystalline matrix of a material A containing aligned, single-crystalline nanowires of a material B, with well-defined crystallographic interfaces are disclosed. The nanocomposite is fabricated by utilizing metal nanodroplets in two subsequent catalytic steps: solid-liquid-vapor etching, followed by vapor-liquid-solid growth. The first etching step produces pores, or “negative nanowires” within a single-crystalline matrix, which share a unique crystallographic direction, and are therefore aligned with respect to one another. Further, since they are contained within a single, crystalline, matrix, their size and spacing can be controlled by their interacting strain fields, and the array …

Epidemiologic Evaluation Of Nhanes For Environmental Factors And Periodontal Disease, P. Emecen-Huja, H. -F. Li, J. L. Ebersole, J. Lambert, Heather M. Bush

Biostatistics Faculty Publications

Periodontitis is a chronic inflammation that destroys periodontal tissues caused by the accumulation of bacterial biofilms that can be affected by environmental factors. This report describes an association study to evaluate the relationship of environmental factors to the expression of periodontitis using the National Health and Nutrition Examination Study (NHANES) from 1999–2004. A wide range of environmental variables (156) were assessed in patients categorized for periodontitis (n = 8884). Multiple statistical approaches were used to explore this dataset and identify environmental variable patterns that enhanced or lowered the prevalence of periodontitis. Our findings indicate an array of environmental variables were …

Crystal Structure Of Zymonic Acid And A Redetermination Of Its Precursor, Pyruvic Acid, Dominik Heger, Alexis J. Eugene, Sean R. Parkin, Marcelo I. Guzman

Chemistry Faculty Publications

The structure of zymonic acid (systematic name: 4-hy­droxy-2-methyl-5-oxo-2,5-di­hydro­furan-2-carb­oxy­lic acid), C₆H₆O₅, which had previously eluded crystallographic determination, is presented here for the first time. It forms by intra­molecular condensation of parapyruvic acid, which is the product of aldol condensation of pyruvic acid. A redetermination of the crystal structure of pyruvic acid (systematic name: 2-oxo­propanoic acid), C₃H₄O₃, at low temperature (90 K) and with increased precision, is also presented [for the previous structure, see: Harata et al. (1977). Acta Cryst. B33, 210–212]. In zymonic acid, the hy­droxy­lactone ring …

Tumor Heterogeneity As A Predictor Of Response To Neoadjuvant Chemotherapy In Locally Advanced Rectal Cancer, Alissa Greenbaum, David R. Martin, Therese J. Bocklage, Ji-Hyun Lee, Scott A. Ness, Ashwani Rajput

Pathology and Laboratory Medicine Faculty Publications

BACKGROUND: Neoadjuvant chemoradiotherapy (nCRT) is the standard of care for locally advanced adenocarcinoma of the rectum, but it is currently unknown which patients have disease that will respond. This study tested the correlation between response to nCRT and intratumoral heterogeneity using next-generation sequencing assays.

PATIENTS AND METHODS: DNA was extracted from formalin-fixed, paraffin-embedded biopsy samples from a cohort of patients with locally advanced rectal adenocarcinoma (T3/4 or N1/2 disease) who received nCRT. High read-depth sequencing of > 400 cancer-relevant genes was performed. Tumor mutations and variant allele frequencies were used to calculate mutant-allele tumor heterogeneity (MATH) scores as measures of intratumoral …

Mineralogy And Chemistry Of Rare Earth Elements In Alkaline Ultramafic Rocks And Fluorite In The Western Kentucky Fluorspar District, Warren H. Anderson

Report of Investigations--KGS

Rare earth elements, or REE, are used in modern society in televisions, computers, cellphones, military equipment, and smart weapons systems. These metals are also used by the medical industry in magnetic resonance imaging and in medical products.

The igneous rocks in the Western Kentucky Fluorspar District of the New Madrid Rift System are considered alkaline ultramafic rocks that are slightly enriched in REE. These rocks are rare and only occur in several hundred locations in the world. They have a complex history of emplacement, fractionation, metasomatism, and alteration, and are overprinted with Mississippi Valley-type mineralization. They are classified as lamprophyres …

Measuring Up: A Case For Redrawing The System Boundaries Of Sustainability At The University Of Kentucky, Brent Sturlaugson, Rebekah Radtke, Anita Lee-Post

Architecture Faculty Publications

The primary goal of this paper is to examine the role that sustainability assessment and reporting plays in creating a sustainable campus for academic excellence. A prototype sustainability assessment and reporting system is developed for triple bottom line impact analysis of the built environment of the newly expanded and renovated Gatton College of Business and Economics at the University of Kentucky. The prototype system utilizes a toolkit to collect environmental, social, and economic data of the building's built environment for sustainable design performance analyses. The system also employs a comprehensive set of sustainability metrics to measure and report the building's …

Triperyleno[3,3,3]Propellane Triimides: Achieving A New Generation Of Quasi-D3h Symmetric Nanostructures In Organic Electronics, Lingling Lv, Josiah Roberts, Chengyi Xiao, Zhenmei Jia, Wei Jiang, Chad Risko, Lei Zhang

Chemistry Faculty Publications

Rigid three-dimensional (3D) polycyclic aromatic hydrocarbons (PAHs), in particular 3D nanographenes, have garnered interest due to their potential use in semiconductor applications and as models to study through-bond and through-space electronic interactions. Herein we report the development of a novel 3D-symmetric rylene imide building block, triperyleno[3,3,3]propellane triimides (6), that possesses three perylene monoimide subunits fused on a propellane. This building block shows several promising characteristics, including high solubility, large π-surfaces, electron-accepting capabilities, and a variety of reactive sites. Further, the building block is compatible with different reactions to readily yield quasi-D_3h symmetric nanostructures (9, …

Charting The Space Of 3d Cfts With A Continuous Global Symmetry, Anatoly Dymarsky, Joao Penedones, Emilio Trevisani, Alessandro Vichi

Physics and Astronomy Faculty Publications

We study correlation functions of a conserved spin-1 current J_μ in three dimensional Conformal Field Theories (CFTs). We investigate the constraints imposed by permutation symmetry and current conservation on the form of three point functions ⟨J_μJ_νO_Δ,ℓ⟩ and the four point function ⟨J_μJ_νJ_ρJ_σ⟩ and identify the minimal set of independent crossing symmetry conditions. We obtain a recurrence relation for conformal blocks for generic spin-1 operators in three dimensions. In the process, we improve several technical points, facilitating the use of recurrence relations. By applying …

Using Numerical Models Of Dewatering At Coal Ash Impoundments To Understand Cost And Schedule, Peter Bell, Joel Thompson, Don Fuller

World of Coal Ash Proceedings

No abstract provided.

Investigating Ccr Units And Evaluating The Physical Properties Of Ponded Ccr, David Skeggs, Zahra Aghazadeh, Rachel Combs

World of Coal Ash Proceedings

No abstract provided.

Demonstration Of “No Migration” Alternative Performance Standard For Ccr Facilities In Arid To Semi- Arid Regions Using Unsaturated Zone Modeling, James Aiken, Katy Lindstom

World of Coal Ash Proceedings

No abstract provided.

Coal Combustion Residuals Management Using Geotextile Containers- Considerations For Various Options, Randall Wilcox, Gregg Lebster, Bryan Hamilton, Thomas Stephens

World of Coal Ash Proceedings

No abstract provided.

State Vs Federal Ccr Rule Regulations: Comparisons And Impacts, Nicole Kron, Eric Nelson

World of Coal Ash Proceedings

No abstract provided.

Continuous, Real-Time Tss Monitoring Verifies Effluent Quality And Coal Ash Management Performance While Reducing Compliance Costs, Dave Fraley, Chris Bauman, Dave Donahue

World of Coal Ash Proceedings

No abstract provided.

Effect Of Coal Fly Ash On Agricultural Crops :Second Phase Showcase Project On Use Of Fly Ash In Agriculture In And Around Thermal Power Station Areas Of National Thermal Power Corporation Ltd., India., K. Arivazhagan, M. Ravichandran, S.K. Dube, V.K. Mathur

World of Coal Ash Proceedings

No abstract provided.

Advantages Of Single Source Contracting In-Plant Ccr Services, Kevin Foody, Marcella Funderburg, Blake Whittington

World of Coal Ash Proceedings

No abstract provided.

Design And Construction Of A Ccr Landfill Adjacent To The Missouri River, Thomas Gredell, Jeffrey Fouse, Jay Ellington

World of Coal Ash Proceedings

No abstract provided.

Geochemical Tools For Groundwater Monitoring At Coal Fired Utilities, Jeff Gillow, Bruce Sass, Hari Parthasarathy

World of Coal Ash Proceedings

No abstract provided.

Bottom Ash Handling Conversions – Lessons Learned, Dustin Doerr

World of Coal Ash Proceedings

No abstract provided.

Encapsulation Of Thermoevaporation Brines Using Coal Combustion Residuals, Dale Prentice, Kirk Ellison, Gaurav Sant

World of Coal Ash Proceedings

No abstract provided.

Recycling Of Coal Ash In Agriculture: Use Of Vermicomposting Biotechnology, G.N. Chattopadhyay, Gourab Roy, Wasim Iftikar

World of Coal Ash Proceedings

No abstract provided.

Surface Water And Groundwater Mixing In Alluvial Floodplains: A Significant Issue For Understanding Contaminant Transport At Coal Ash Facilities Adjacent To Rivers, Joel Thompson, Peter Bell, John Griggs

World of Coal Ash Proceedings

No abstract provided.

Alternate Source Demonstration Considerations Within The Appalachian Basin, Joseph Robb, Larry Mastera

World of Coal Ash Proceedings

No abstract provided.

Locating And Permitting A Ccr Landfill Adjacent To The Missouri River, Paul Reitz, Thomas Gredell, Jay Ellington

World of Coal Ash Proceedings

No abstract provided.

Is Zero Solid Waste Possible For Fly Ash Produced From Any Coal-Fired Power Plant?, Jinder Jow, Yang Dong, Shuqiang Ding, Li Qiao

World of Coal Ash Proceedings

No abstract provided.

Groundwater Corrective Action Assessment Using Fate And Transport Modeling, Brian Hennings, Glenn Luke, Jacob Walczak

World of Coal Ash Proceedings

No abstract provided.

The Application Of Natural Attenuation At Coal Combustion Residual (Ccr) Sites, Ryan Fimmen, Allison Kreinberg

World of Coal Ash Proceedings

No abstract provided.

Coal Ash 2.0: The Calculus Of The Ore Body, Claudio Arato

World of Coal Ash Proceedings

No abstract provided.

Extensive Real Time Monitoring Of Ash Response To Construction-Induced Activity, Anita Perry, Alex Rudy, Kenny Campbell, Ryan Smith

World of Coal Ash Proceedings

No abstract provided.

Alkali-Silica Reaction Of Geopolymer Concrete Made Of Circulating Fluidized Bed Combustion Fly Ash, Chang-Seon Shon, Dong-Un Lee

World of Coal Ash Proceedings

No abstract provided.