Physical Sciences and Mathematics Commons^™

Holographic Chern-Simons Defects, Mitsutoshi Fujita, Charles M. Melby-Thompson, René Meyer, Shigeki Sugimoto

Physics and Astronomy Faculty Publications

We study SU(N ) Yang-Mills-Chern-Simons theory in the presence of defects that shift the Chern-Simons level from a holographic point of view by embedding the system in string theory. The model is a D3-D7 system in Type IIB string theory, whose gravity dual is given by the AdS soliton background with probe D7 branes attaching to the AdS boundary along the defects. We holographically renormalize the free energy of the defect system with sources, from which we obtain the correlation functions for certain operators naturally associated to these defects. We find interesting phase transitions when the separation of the …

Ultraviolet Emission Lines Of Si Ii In Quasars—Investigating The "Si Ii Disaster", Sibasish Laha, Francis P. Keenan, Gary J. Ferland, Catherine A. Ramsbottom, Kanti M. Aggarwal

Physics and Astronomy Faculty Publications

The observed line intensity ratios of the Si II λ1263 and λ1307 multiplets to that of Si II λ1814 in the broad-line region (BLR) of quasars are both an order of magnitude larger than the theoretical values. This was first pointed out by Baldwin et al., who termed it the "Si II disaster," and it has remained unresolved. We investigate the problem in the light of newly published atomic data for Si II. Specifically, we perform BLR calculations using several different atomic data sets within the CLOUDY modeling code under optically thick quasar cloud conditions. In addition, …

Simultaneous Metal-Insulator And Antiferromagnetic Transitions In Orthorhombic Perovskite Iridate Sr0.94Ir0.78O2.68 Single Crystals, Hao Zheng, Jsaminka Terzic, Feng Ye, X. G. Wan, D. Wang, Jinchen Wang, Xiaoping Wang, P. Schlottmann, Shujuan Yuan, Gang Cao

Center for Advanced Materials Faculty Publications

The orthorhombic perovskite SrIrO₃ is a semimetal, an intriguing exception in iridates where the strong spin-orbit interaction coupled with electron correlations tends to impose an insulating state. We report results of our investigation of bulk single-crystal S_r0.94Ir_0.78O_2.68 or Ir-deficient, orthorhombic perovskite SrIrO₃. It retains the same crystal structure as stoichiometric SrIrO₃ but exhibits a sharp, simultaneous antiferromagnetic (AFM) and metal-insulator (MI) transition occurring in the basal-plane resistivity at 185 K. Above it, the basal-plane resistivity features an extended regime of almost linear temperature dependence up to 800 K but the strong …

Orion's Veil: Magnetic Field Strengths And Other Properties Of A Pdr In Front Of The Trapezium Cluster, Thomas H. Troland, W. M. Goss, C. L. Brogan, R. M. Crutcher, D. A. Roberts

Physics and Astronomy Faculty Publications

We present an analysis of physical conditions in the Orion Veil, an atomic photon-dominated region (PDR) that lies just in front (≈2 pc) of the Trapezium stars of Orion. This region offers an unusual opportunity to study the properties of PDRs, including the magnetic field. We have obtained 21 cm H i and 18 cm (1665 and 1667 MHz) OH Zeeman effect data that yield images of the line-of-sight magnetic field strength B _los in atomic and molecular regions of the Veil. We find B _los ≈ −50 to −75 μG in the atomic gas across much of the …

Mutation Linked To Autosomal Dominant Nocturnal Frontal Lobe Epilepsy Reduces Low-Sensitivity Α4Β2, And Increases Α5Α4Β2, Nicotinic Receptor Surface Expression, Weston A. Nichols, Brandon J. Henderson, Christopher B. Marotta, Caroline Y. Yu, Chris Richards, Dennis A. Dougherty, Henry A. Lester, Bruce N. Cohen

Chemistry Faculty Publications

A number of mutations in α4β2-containing (α4β2*) nicotinic acetylcholine (ACh) receptors (nAChRs) are linked to autosomal dominant nocturnal frontal lobe epilepsy (ADNFLE), including one in the β2 subunit called β2V287L. Two α4β2* subtypes with different subunit stoichiometries and ACh sensitivities co-exist in the brain, a high-sensitivity subtype with (α4)₂(β2)₃ subunit stoichiometry and a low-sensitivity subtype with (α4)₃(β2)₂ stoichiometry. The α5 nicotinic subunit also co-assembles with α4β2 to form a high-sensitivity α5α4β2 nAChR. Previous studies suggest that the β2V287L mutation suppresses low-sensitivity α4β2* nAChR expression in a knock-in mouse model and also that α5 co-expression …

Assessment Of Streamside Management Zones For Conserving Benthic Macroinvertebrate Communities Following Timber Harvest In Eastern Kentucky Headwater Catchments, Joshua K. Adkins, Christopher D. Barton, Scott Grubbs, Jeffrey W. Stringer, Randall K. Kolka

Forestry and Natural Resources Faculty Publications

Headwater streams generally comprise the majority of stream area in a watershed and can have a strong influence on downstream food webs. Our objective was to determine the effect of altering streamside management zone (SMZ) configurations on headwater aquatic insect communities. Timber harvests were implemented within six watersheds in eastern Kentucky. The SMZ configurations varied in width, canopy retention and best management practice (BMP) utilization at the watershed scale. Benthic macroinvertebrate samples collected one year before and four years after harvest indicated few differences among treatments, although post-treatment abundance was elevated in some of the treatment streams relative to the …

A Randomized, Double-Blind, Placebo-Controlled Phase Ii Trial Investigating The Safety And Immunogenicity Of Modified Vaccinia Ankara Smallpox Vaccine (Mva-Bn®) In 56-80-Year-Old Subjects, Richard N. Greenberg, Christine M. Hay, Jack T. Stapleton, Thomas C. Marbury, Eva Wagner, Eva Kreitmeir, Siegfried Röesch, Alfred Von Krempelhuber, Philip Young, Richard Nichols, Thomas P. Meyer, Darja Schmidt, Josef Weigl, Garth Virgin, Nathaly Arndtz-Wiedemann, Paul Chaplin

Internal Medicine Faculty Publications

Background Modified Vaccinia Ankara MVA-BN^® is a live, highly attenuated, viral vaccine under advanced development as a non-replicating smallpox vaccine. In this Phase II trial, the safety and immunogenicity of Modified Vaccinia Ankara MVA-BN^® (MVA) was assessed in a 56–80 years old population.

Methods MVA with a virus titer of 1 x 10⁸ TCID₅₀/dose was administered via subcutaneous injection to 56–80 year old vaccinia-experienced subjects (N = 120). Subjects received either two injections of MVA (MM group) or one injection of Placebo and one injection of MVA (PM group) four weeks apart. Safety was evaluated …

Evidence For Fluorescent Fe Ii Emission From Extended Low Ionization Outflows In Obscured Quasars, Tinggui Wang, Gary J. Ferland, Chenwei Yang, Huiyuan Wang, Shaohua Zhang

Physics and Astronomy Faculty Publications

Recent studies have shown that outflows in at least some broad absorption line (BAL) quasars are extended well beyond the putative dusty torus. Such outflows should be detectable in obscured quasars. We present four WISE selected infrared red quasars with very strong and peculiar ultraviolet Fe II emission lines: strong UV Fe II UV arising from transitions to ground/low excitation levels, and very weak Fe II at wavelengths longer than 2800 Å. The spectra of these quasars display strong resonant emission lines, such as C IV, Al III and Mg II but sometimes, a lack of non-resonant lines such as …

An Experimental And Theoretical Study Of Ã2A"Π–X~2A' Band System Of The Jet-Cooled Hbbr/Dbbr Free Radical, Mohammed Gharaibeh, Dennis J. Clouthier, Riccardo Tarroni

Chemistry Faculty Publications

The electronic spectra of the HBBr and DBBr free radicals have been studied in depth. These species were prepared in a pulsed electric discharge jet using a precursor mixture of BBr₃ vapor and H₂ or D₂ in high pressure argon. Transitions to the electronic excited state of the jet-cooled radicals were probed with laser-induced fluorescence and the ground state energy levels were measured from the single vibronic level emission spectra. HBBr has an extensive band system in the red which involves a linear-bent transition between the two Renner-Teller components of what would be a ²Π state …

Precision Measurement Of The Radiative Β Decay Of The Free Neutron, M. J. Bales, R. Alarcon, C. D. Bass, E. J. Beise, H. Breuer, J. Byrne, T. E. Chupp, K. J. Coakley, R. L. Cooper, M. S. Dewey, Susan Gardner, T. R. Gentile, D. He, H. P. Mumm, J. S. Nico, B. O'Neill, A. K. Thompson, F. E. Wietfeldt

Physics and Astronomy Faculty Publications

The standard model predicts that, in addition to a proton, an electron, and an antineutrino, a continuous spectrum of photons is emitted in the β decay of the free neutron. We report on the RDK II experiment which measured the photon spectrum using two different detector arrays. An annular array of bismuth germanium oxide scintillators detected photons from 14 to 782 keV. The spectral shape was consistent with theory, and we determined a branching ratio of 0.00335 ± 0.00005[stat] ± 0.00015[syst]. A second detector array of large area avalanche photodiodes directly detected photons from 0.4 to 14 keV. For this …

Dealing With Zero-Numerators In Estimating Drug-Dependence Chances: A Bayesian Approach, Olga A. Vsevolozhskaya, Fernando A. Wagner, James C. Anthony

Biostatistics Presentations

Aims: At CPDD 2015, we applied parametric Hill functions to estimate the probability of drug dependence in relation to the duration of drug-taking experience. A problem we and others have encountered in the estimation of risk of becoming a drug dependence case is an observed point estimate of zero – the so-called “zero-numerator problem.” This problem can be easily observed in certain low risk subgroups even when the sample is large (e.g., the incidence of heroin dependence among 12 year old newly incident heroin users) or with small subgroup sample sizes. In these instances, tan observed zero point estimate …

Observation Of Metallic Surface States In The Strongly Correlated Kitaev-Heisenberg Candidate Na2Iro3, Nasser Alidoust, Chang Liu, Su-Yang Xu, Ilya Belopolski, Tongfei Qi, Minggang Zeng, Daniel S. Sanchez, Hao Zheng, Guang Bian, Madhab Neupane, Yu-Tzu Liu, Stephen D. Wilson, Hsin Lin, Arun Bansil, Gang Cao, M. Zahid Hasan

Center for Advanced Materials Faculty Publications

We report high-resolution angle-resolved photoemission spectroscopy measurements on the honeycomb iridate Na₂IrO₃. Our measurements reveal the existence of a metallic surface band feature crossing the Fermi level with nearly linear dispersion and an estimated surface carrier density of 3.2 x 10¹³ cm^-2, which has not been theoretically predicted or experimentally observed, and provides the first evidence for metallic behavior on the boundary of this material, whereas the bulk bands exhibit a robust insulating gap. We further show the lack of theoretically predicted Dirac cones at the M¯ points of the surface Brillouin …

Performance Of Endophyte Infected Tall Fescue In Europe And North America, Kari Saikkonen, Timothy D. Phillips, Stanley H. Faeth, Rebecca L. Mcculley, Irma Saloniemi, Marjo Helander

Plant and Soil Sciences Faculty Publications

Human assisted plant invasions from Europe to North America have been more common than the reverse. We tested endophyte-mediated performance of tall fescue in parallel three year experiments in Europe and the USA using endophyte infected and uninfected wild and cultivated plants. Experimental plants were subjected to nutrient and water treatments. Whereas endophyte infection increased tall fescue performance in general, the effects of endophytes on plant growth and reproduction varied among plant origins under different environmental conditions. Naturally endophyte-free Finnish cultivar ‘Retu’ performed equally well as ‘Kentucky-31’ in both geographic locations. All Eurasian origin plants performed well in the US. …

New Prospects In Fixed Target Searches For Dark Forces With The Seaquest Experiment At Fermilab, Susan Gardner, R. J. Holt, A. S. Tadepalli

Physics and Astronomy Faculty Publications

An intense 120 GeV proton beam incident on an extremely long iron target generates enormous numbers of light-mass particles that also decay within that target. If one of these particles decays to a final state with a hidden gauge boson, or if such a particle is produced as a result of the initial collision, then that weakly interacting hidden-sector particle may traverse the remainder of the target and be detected downstream through its possible decay to an e⁺ e⁻, μ⁺ μ⁻, or π⁺ π⁻ final state. These conditions can be realized through …

J/Ψ Production At Low Transverse Momentum In P + P And D + Au Collisions At √SNn = 200 Gev, L. Adamczyk, James K. Adkins, G. Agakishiev, M. M. Aggarwal, Z. Ahammed, I. Alekseev, A. Aparin, D. Arkhipkin, E. C. Aschenauer, A. Attri, G. S. Averichev, X. Bai, V. Bairathi, R. Bellwied, A. Bhasin, A. K. Bhati, P. Bhattarai, J. Bielcik, J. Bielcikova, L. C. Bland, I. G. Bordyuzhin, J. Bouchet, J. D. Brandenburg, A. V. Brandin, I. Bunzarov, J. Butterworth, H. Caines, M. Calderón De La Barca Sánchez, J. M. Campbell, D. Cebra, Renee H. Fatemi, Suvarna Ramachandran

Physics and Astronomy Faculty Publications

We report on the measurement of J/ψ production in the dielectron channel at midrapidity (|y| < 1) in p + p and d + Au collisions at √^s_NN = 200 GeV from the STAR experiment at the Relativistic Heavy Ion Collider. The transverse momentum p_Tspectra in p + p for p_T < 4 GeV/c and d + Au collisions for p_T < 3 GeV/c are presented. These measurements extend the STAR coverage for J/ψ production in p + p collisions to low p_T. The ⟨p²_T⟩ from the measured J/ψ invariant …

Anisotropic Softening Of Magnetic Excitations In Lightly Electron-Doped Sr2Iro4, X. Liu, M. P. M. Dean, Z. Y. Meng, M. H. Upton, T. Qi, T. Gog, Y. Cao, J. Q. Lin, D. Meyers, H. Ding, Gang Cao, J. P. Hill

Center for Advanced Materials Faculty Publications

The magnetic excitations in electron-doped (Sr_1−xLa_x)₂IrO₄ with x = 0.03 were measured using resonant inelastic x-ray scattering at the Ir L₃ edge. Although much broadened, well defined dispersive magnetic excitations were observed. Comparing with the magnetic dispersion from the undoped compound, the evolution of the magnetic excitations upon doping is highly anisotropic. Along the antinodal direction, the dispersion is almost intact. On the other hand, the magnetic excitations along the nodal direction show significant softening. These results establish the presence of strong magnetic correlations in electron-doped (Sr_1−xLa_{x …}

Hst Imaging Of The Dusty Filaments And Nucleus Swirl In Ngc4696 At The Centre Of The Centaurus Cluster, A. C. Fabian, S. A. Walker, H. R. Russell, C. Pinto, R. E. A. Canning, P. Salome, J. S. Sanders, G. B. Taylor, E. G. Zweibel, C. J. Conselice, F. Combes, C. S. Crawford, Gary J. Ferland, J. S. Gallagher Iii, N. A. Hatch, R. M. Johnstone, C. S. Reynolds

Physics and Astronomy Faculty Publications

Narrow-band HST imaging has resolved the detailed internal structure of the 10 kpc diameter H α+[N II] emission line nebulosity in NGC4696, the central galaxy in the nearby Centaurus cluster, showing that the dusty, molecular, filaments have a width of about 60 pc. Optical morphology and velocity measurements indicate that the filaments are dragged out by the bubbling action of the radio source as part of the active galactic nucleus feedback cycle. Using the drag force we find that the magnetic field in the filaments is in approximate pressure equipartition with the hot gas. The filamentary nature of the …

Space Telescope And Optical Reverberation Mapping Project. Iv. Anomalous Behavior Of The Broad Ultraviolet Emission Lines In Ngc 5548, M. R. Goad, K. T. Korista, G. De Grosa, G. A. Kriss, R. Edelson, A. J. Barth, Gary J. Ferland, C. S. Kochanek, H. Netzer, B. M. Peterson, M. C. Bentz, S. Bisogni, D. M. Crenshaw, K. D. Denney, J. Ely, M. M. Fausnaugh, C. J. Grier, A. Gupta, K. D. Horne, J. Kaastra, A. Pancoast, L. Pei, R. W. Pogge, A. Skielboe, D. Starkey, M. Vestergaard, Y. Zu, M. D. Anderson, P. Arévalo, C. Bazhaw

Physics and Astronomy Faculty Publications

During an intensive Hubble Space Telescope (HST) Cosmic Origins Spectrograph (COS) UV monitoring campaign of the Seyfert 1 galaxy NGC 5548 performed from 2014 February to July, the normally highly correlated far UV continuum and broad emission line variations decorrelated for ~60–70 days, starting ~75 days after the first HST/COS observation. Following this anomalous state, the flux and variability of the broad emission lines returned to a more normal state. This transient behavior, characterized by significant deficits in flux and equivalent width of the strong broad UV emission lines, is the first of its kind to be unambiguously identified …

Aqueous Photochemistry Of Glyoxylic Acid, Alexis J. Eugene, Sha-Sha Xia, Marcelo I. Guzman

Chemistry Faculty Publications

Aerosols affect climate change, the energy balance of the atmosphere, and public health due to their variable chemical composition, size, and shape. While the formation of secondary organic aerosols (SOA) from gas phase precursors is relatively well understood, studying aqueous chemical reactions contributing to the total SOA budget is the current focus of major attention. Field measurements have revealed that mono-, di-, and oxo-carboxylic acids are abundant species present in SOA and atmospheric waters. This work explores the fate of one of these 2-oxocarboxylic acids, glyoxylic acid, which can photogenerate reactive species under solar irradiation. Additionally, the dark thermal aging …

Partner Interfering Behaviors Affecting Cancer Quality Of Life, Ann L. Coker, Diane R. Follingstad, Lisandra S. Garcia, Heather M. Bush

Obstetrics and Gynecology Faculty Publications

Objective: Because partners are an important and unpaid resource in cancer care, understanding how destructive, controlling or interfering partner behaviors influence women's cancer care may be particularly relevant for health care providers seeking to provide cancer care and enhance recovery. Using a new measure of partner interfering behaviors in cancer care (PIB-C), we investigated whether women with a recent cancer diagnosis who additionally endorsed any PIB-C would report (a) more symptoms of depression and stress, and (b) lower Functional Assessment of Cancer Therapy (FACT-G) and lower Functional Assessment of Chronic Illness Therapy-Spiritual Well-being (FACIT-SP) scale scores indicating poorer quality of …

Farmstead Planning: Old Farm Buildings Repurposed For Better Farming: How To Develop A Complex, Stephen F. Higgins, Lee Moser

Agriculture and Natural Resources Publications

Farming is probably one of the most complex means of earning a living that has been devised. The many components of a farming operation that have to be managed would create an extensive list. Many beef cattle producers might focus on reproduction, nutrition, forages, health, and handling. However, there are many others operational considerations that are just as important.

Pressure-Induced Confined Metal From The Mott Insulator Sr3Ir2O7, Yang Ding, Liuxiang Yang, Cheng-Chien Chen, Heung-Sik Kim, Myung Joon Han, Wei Luo, Zhenxing Feng, Mary Upton, Diego Casa, Jungho Kim, Thomas Gog, Zhidan Zeng, Gang Cao, Ho-Kwang Mao, Michel Van Veenendaal

Physics and Astronomy Faculty Publications

The spin-orbit Mott insulator Sr₃Ir₂O₇ provides a fascinating playground to explore insulator-metal transition driven by intertwined charge, spin, and lattice degrees of freedom. Here, we report high-pressure electric resistance and resonant inelastic x-ray scattering measurements on single-crystal Sr₃Ir₂O₇ up to 63–65 GPa at 300 K. The material becomes a confined metal at 59.5 GPa, showing metallicity in the ab plane but an insulating behavior along the c axis. Such an unusual phenomenon resembles the strange metal phase in cuprate superconductors. Since there is no sign of the collapse of spin-orbit …

Are Consumers Willing To Pay More For Sustainable Products? A Study Of Eco-Labeled Tuna Steak, Guzhen Zhou, Wuyang Hu, Wenchao Huang

Agricultural Economics Faculty Publications

A high demand for seafood leads to overfishing, harms the long-term health of seafood stocks, and threatens environmental sustainability in oceans. Sustainability certification is one of the major sustainability movements and is known as eco-labeling. For instance, in the tuna industry, leading tuna brands have committed to protecting sea turtles by allowing the tracing of the source of their tuna “from catch to can.” This paper relies on an Internet survey on consumers from Kentucky conducted in July 2010. The survey investigates household-level tuna steak (sashimi grade) consumption and examines consumer preferences for eco-labeling (“Certified Turtle Safe” (CTS) in this …

Quantitative Evidence For The Effects Of Multiple Drivers On Continental-Scale Amphibian Declines, Evan H. Campbell Grant, David A. W. Miller, Benedikt R. Schmidt, Michael J. Adams, Staci M. Amburgey, Thierry Chambert, Sam S. Cruickshank, Robert N. Fisher, David M. Green, Blake R. Hossack, Pieter T. J. Johnson, Maxwell B. Joseph, Tracy A. G. Rittenhouse, Maureen E. Ryan, J. Hardin Waddle, Susan C. Walls, Larissa L. Bailey, Gary M. Fellers, Thomas A. Gorman, Andrew M. Ray, David S. Pilliod, Steven J. Price, Daniel Saenz, Walt Sadinski, Erin Muths

Forestry and Natural Resources Faculty Publications

Since amphibian declines were first proposed as a global phenomenon over a quarter century ago, the conservation community has made little progress in halting or reversing these trends. The early search for a “smoking gun” was replaced with the expectation that declines are caused by multiple drivers. While field observations and experiments have identified factors leading to increased local extinction risk, evidence for effects of these drivers is lacking at large spatial scales. Here, we use observations of 389 time-series of 83 species and complexes from 61 study areas across North America to test the effects of 4 of the …

Sdss Iv Manga – Spatially Resolved Diagnostic Diagrams: A Proof That Many Galaxies Are Liers, Francesco Belfiore, Roberto Maiolino, Claudia Maraston, Eric Emsellem, Matthew A. Bershady, Karen L. Masters, Renbin Yan, Dmitry Bizyaev, Médéric Boquien, Joel R. Brownstein, Kevin Bundy, Niv Drory, Timothy M. Heckman, David R. Law, Alexandre Roman-Lopes, Kaike Pan, Letizia Stanghellini, Daniel Thomas, Anne-Marie Weijmans, Kyle B. Westfall

Physics and Astronomy Faculty Publications

We study the spatially resolved excitation properties of the ionized gas in a sample of 646 galaxies using integral field spectroscopy data from the Sloan Digital Sky Survey IV Mapping Nearby Galaxies at Apache Point Observatory (MaNGA) programme. Making use of Baldwin–Philips–Terlevich diagnostic diagrams we demonstrate the ubiquitous presence of extended (kpc scale) low-ionization emission-line regions (LIERs) in both star-forming and quiescent galaxies. In star-forming galaxies LIER emission can be associated with diffuse ionized gas, most evident as extraplanar emission in edge-on systems. In addition, we identify two main classes of galaxies displaying LIER emission: ‘central LIER’ (cLIER) galaxies, where …

Genetic Engineering And Sustainable Crop Disease Management: Opportunities For Case-By-Case Decision-Making, Paul Vincelli

Plant Pathology Faculty Publications

Genetic engineering (GE) offers an expanding array of strategies for enhancing disease resistance of crop plants in sustainable ways, including the potential for reduced pesticide usage. Certain GE applications involve transgenesis, in some cases creating a metabolic pathway novel to the GE crop. In other cases, only cisgenessis is employed. In yet other cases, engineered genetic changes can be so minimal as to be indistinguishable from natural mutations. Thus, GE crops vary substantially and should be evaluated for risks, benefits, and social considerations on a case-by-case basis. Deployment of GE traits should be with an eye towards long-term sustainability; several …

Cpt, Cp, And C Transformations Of Fermions, And Their Consequences, In Theories With B − L Violation, Susan Gardner, Xinshuai Yan

Physics and Astronomy Faculty Publications

We consider the transformation properties of fermions under the discrete symmetries CPT, CP, and C in the presence of B − L violation. We thus generalize the analysis of the known properties of Majorana neutrinos, probed via neutrinoless double beta decay, to include the case of Dirac fermions with B − L violation, which can be probed via neutron-antineutron oscillations. We show that the resulting CPT phase has implications for the interplay of neutron-antineutron oscillations with external fields and sources and consider the differences in the Majorana dynamics of neutrinos and neutrons in the context of theories with …

Investigations Of Metastable Ca2Iro4 Epitaxial Thin-Films: Systematic Comparison With Sr2Iro4 And Ba2Iro4, Maryam Souri, John H. Gruenewald, Jsaminka Terzic, Joseph W. Brill, Gang Cao, Sung S. Ambrose Seo

Physics and Astronomy Faculty Publications

We have synthesized thermodynamically metastable Ca₂IrO₄ thin-films on YAlO₃ (110) substrates by pulsed laser deposition. The epitaxial Ca₂IrO₄ thin-films are of K₂NiF₄-type tetragonal structure. Transport and optical spectroscopy measurements indicate that the electronic structure of the Ca₂IrO₄ thin-films is similar to that of J_eff = 1/2 spin-orbit-coupled Mott insulator Sr₂IrO₄ and Ba₂IrO₄, with the exception of an increased gap energy. The gap increase is to be expected in Ca₂IrO₄ due to its increased octahedral rotation …

Indacenodibenzothiophenes: Synthesis, Optoelectronic Properties And Materials Applications Of Molecules With Strong Antiaromatic Character, Jonathan L. Marshall, Kazuyuki Uchida, Conerd K. Frederickson, Christian Schütt, Andrew M. Zeidell, Katelyn P. Goetz, Tristan W. Finn, Karol Jarolimek, Lev N. Zakharov, Chad Risko, Rainer Herges, Oana D. Jurchescu, Michael M. Haley

Chemistry Faculty Publications

Indeno[1,2-b]fluorenes (IFs), while containing 4n π-electrons, are best described as two aromatic benzene rings fused to a weakly paratropic s-indacene core. In this study, we find that replacement of the outer benzene rings of an IF with benzothiophenes allows the antiaromaticity of the central s-indacene to strongly reassert itself. Herein we report a combined synthetic, computational, structural, and materials study of anti- and syn-indacenodibenzothiophenes (IDBTs). We have developed an efficient and scalable synthesis for preparation of a series of aryl- and ethynyl-substituted IDBTs. NICS-XY scans and ACID calculations reveal an increasingly antiaromatic core from …

Size Effect On The Magnetic Phase In Sr4Ru3O10, Yan Liu, Jiyong Yang, Weike Wang, Haifeng Du, Wei Ning, Langsheng Ling, Wei Tong, Zhe Qu, Zhaorong Yang, Minling Tian, Gang Cao, Yuheng Zhang

Center for Advanced Materials Faculty Publications

High quality Sr₄Ru₃O₁₀ nanoflakes are obtained by the scotch tape-based micro-mechanical exfoliation method. The metamagnetic transition temperature T_m^flake is found to decrease in line with the decrease of thickness, while the ferromagnetic (FM) phase, the ordinary, and anomalous Hall effects (OHE and AHE) are independent on the thickness of the flake. Analysis of the data demonstrates that the AHE reflects the FM nature of Sr₄Ru₃O₁₀, and the decrease of thickness favors the Ru moments aligned in the ab-plane, which induces a decrease of the metamagnetic transition …