Physical Sciences and Mathematics Commons^™

A Possible Unaccounted Source Of Atmospheric Sulfate Formation: Amine-Promoted Hydrolysis And Non-Radical Oxidation Of Sulfur Dioxide, Shixian Wang, Xiao Cheng Zeng, Hui Li, Joseph S. Francisco

Xiao Cheng Zeng Publications

Numerous field and laboratory studies have shown that amines, especially dimethylamine (DMA), are crucial to atmospheric particulate nucleation. However, the molecular mechanism by which amines lead to atmospheric particulate formation is still not fully understood. Herein, we show that DMA molecules can also promote the conversion of atmospheric SO₂ to sulfate. Based on ab initio simulations, we find that in the presence of DMA, the originally endothermic and kinetically unfavourable hydrolysis reaction between gaseous SO₂ and water vapour can become both exothermic and kinetically favourable. The resulting product, bisulfite NH₂(CH₃)₂⁺ ∙ HSO …

Perpendicular Magnetic Anisotropy In Conducting Nico2O4 Films From Spin-Lattice Coupling, Corbyn Mellinger, Jace Waybright, Xiaozhe Zhang, Caleb Schmidt, Xiaoshan S. Xu

Department of Physics and Astronomy: Faculty Publications

High perpendicular magnetic anisotropy (PMA), a property needed for nanoscale spintronic applications, is rare in oxide conductors. We report the observation of a PMA up to 0.23 MJ/m³ in modestly strained (–0.3%) epitaxial NiCo₂O₄ films which are room-temperature ferrimagnetic conductors. Spin-lattice coupling manifested as magnetoelastic effect was found as the origin of the PMA. The in-plane x²-y² states of Co on tetrahedral sites play crucial role in the magnetic anisotropy and spin-lattice coupling with an energy scale of 1 meV/f.u. The elucidation of the microscopic origin paves a way for engineering oxide conductors …

Final Presentation To The Library Of Congress On Digital Libraries, Intelligent Data Analytics, And Augmented Description, Elizabeth Lorang, Leen-Kiat Soh, Yi Liu, Chulwoo Pack

University of Nebraska-Lincoln Libraries: Conference Presentations and Speeches

This presentation to Library of Congress staff, delivered onsite on January 10, 2020, presents a tour through the demonstration project pursued by the Aida digital libraries research team with the Library of Congress in 2019-2020. In addition to providing an overview and analysis of the specific machine learning projects scoped and explored, this presentation includes a number of high-level take-aways and recommendations designed to influence and inform the Library of Congress's machine learning efforts going forward.

Digital Libraries, Intelligent Data Analytics, And Augmented Description: A Demonstration Project, Elizabeth Lorang, Leen-Kiat Soh, Yi Liu, Chulwoo Pack

UNL Libraries: Faculty Publications

From July 16-to November 8, 2019, the Aida digital libraries research team at the University of Nebraska-Lincoln collaborated with the Library of Congress on “Digital Libraries, Intelligent Data Analytics, and Augmented Description: A Demonstration Project.“ This demonstration project sought to (1) develop and investigate the viability and feasibility of textual and image-based data analytics approaches to support and facilitate discovery; (2) understand technical tools and requirements for the Library of Congress to improve access and discovery of its digital collections; and (3) enable the Library of Congress to plan for future possibilities. In pursuit of these goals, we focused our …

Plains Zebra (Equus Quagga) Behaviour In A Restored Population Reveals Seasonal Resource Limitations, Charli De Vos, Alison J. Leslie, Jason I. Ransom

United States National Park Service: Publications

A once abundant species, plains zebra (Equus quagga), is declining across much of sub-Saharan Africa. Reintroduction efforts at Majete Wildlife Reserve, Malawi, have resulted in rapid population increases, but little is known about how such populations resemble natural populations socially or behaviourally, and what those attributes may reveal about restoration success. Incorporating behavioural knowledge into conservation efforts is an important tool for managing the effects of habitat fragmentation and resource competition. The aim of this study was to quantify the daylight time budget of both family and bachelor bands of reintroduced plains zebra to determine if such behaviours …

Predicting Livestock Depredation Risk By African Lions (Panthera Leo) In A Multi-Use Area Of Northern Tanzania, K. Beattie, E.R. Olson, B. Kissui, A. Kirschbaum, C. Kiffner

United States National Park Service: Publications

Human-wildlife conflicts, especially those involving large carnivores, are of global conservation and livelihood concern and require effective and locally-adapted prevention measures. Risk of lion attack on livestock (i.e., depredation) may vary seasonally and may be associated with variation in wild prey abundance or landscape characteristics. To test these competing hypotheses, we used a resource selection approach, and determined whether prey catchability (indicated by geo-spatial variables), or prey availability (indicated by modeled abundance recorded via camera traps) explained spatial and seasonal variation in livestock depredation risk by African lions on Manyara Ranch Conservancy, a multi-use area in northern Tanzania. Seasonal variation …

Arjen Y. Hoekstra 1967–2019, Davy Vanham, Mesfin Mekonnen, Ashok K. Chapagain

Daugherty Water for Food Global Institute: Faculty Publications

Arjen Hoekstra introduced the water footprint in 20021, building on the concept of virtual water Tony Allan to discuss the role of trade in alleviating water scarcity in the Middle East. He thereby opened a new dimension in the debate around fair and sustainable allocation of freshwater resources. He laid the foundations to show the role of indirect water (that is, water used elsewhere to produce goods we consume) in our daily life beyond our direct use for drinking, cooking or washing. The water footprint is an indicator of direct and indirect water use by a producer or consumer, showing …

Itinerant Ferromagnetism And Intrinsic Anomalous Hall Effect In Amorphous Iron-Germanium, D. S. Bouma, Z. Chen, B. Zhang, F. Bruni, M. E. Flatté, A. Ceballos, R. Streubel, L. W. Wang, R. Q. Wu, F. Hellman

Robert Streubel Papers

The amorphous iron-germanium system (a-Fe_xGe_1-x) lacks long-range structural order and hence lacks a meaningful Brillouin zone. The magnetization of a-Fe_xGe_1-x is well explained by the Stoner model for Fe concentrations x above the onset of magnetic order around x=0.4, indicating that the local order of the amorphous structure preserves the spin-split density of states of the Fe-3d states sufficiently to polarize the electronic structure despite k being a bad quantum number. Measurements reveal an enhanced anomalous Hall resistivity ρ_xy^AH relative to crystalline FeGe; this ρ_xy^AH is compared to density-functional …

Local Adaptation Constrains Drought Tolerance In A Tropical Foundation Tree, Kasey E. Barton, Casey Jones, Kyle F. Edwards, Aaron B. Shiels, Tiffany Knight

United States Department of Agriculture Wildlife Services: Staff Publications

1. Plant species with broad climatic ranges might be more vulnerable to climate change than previously appreciated due to intraspecific variation in climatic stress tolerance. In tropical forests, drought is increasingly frequent and severe, causing widespread declines and altering community dynamics. Yet, little is known about whether foundation tropical trees vary in drought tolerance throughout their distributions, and how intraspecific variation in drought tolerance might contribute to their vulnerability to climate changE.
2. We tested for local adaptation in seedling emergence and establishment with a full-factorial reciprocal transplant experiment including 27 populations and 109,350 seeds along a 3,500 mm precipitation gradient for …

Letetr Positively Regulates 3-Hydroxylation Of The Antifungal Hsaf And Its Analogs In Lysobacter Enzymogenes Oh11, Lingjun Yu, Vimmy Khetrapal, Fengquan Liu, Liangcheng Du

Liangcheng Du Publications

The biocontrol agent Lysobacter enzymogenes OH11 produces several structurally distinct antibiotic compounds, including the antifungal HSAF (Heat Stable Antifungal Factor) and alteramides, along with their 3-dehydroxyl precursors (3-deOH). We previously showed that the 3-hydroxylation is the final step of the biosynthesis and is also a key structural moiety for the antifungal activity. However, the procedure through which OH11 regulates the 3-hydroxylation is still not clear. In OH11, the gene orf3232 was predicted to encode a TetR regulator (LeTetR) with unknown function. Here, we deleted orf3232 and found that the LeTetR mutant produced very little HSAF and alteramides, while the 3-deOH …

Assessing The Hierarchy Of Long-Term Environmental Controls On Diatom Communities Of Yellowstone National Park Using Lacustrine Sediment Records, Victoria Chraibi, Sherilyn C. Fritz

Department of Earth and Atmospheric Sciences: Faculty Publications

An ecosystem’s ability to maintain structure and function following disturbance, defined as resilience, is influenced by a hierarchy of environmental controls, including climate, surface cover, and ecological relationships that shape biological community composition and productivity. This study examined lacustrine sediment records of naturally fishless lakes in Yellowstone National Park to reconstruct the response of aquatic communities to climate and trophic cascades from fish stocking. Sediment records of diatom algae did not exhibit a distinct response to fish stocking in terms of assemblage or algal productivity. Instead, 3 of 4 lakes underwent a shift to dominance by benthic diatom species from …

Data Generated During The 2018 Lapse-Rate Campaign: An Introduction And Overview, Gijs De Boer, Adam Houston, Et Al.

Department of Earth and Atmospheric Sciences: Faculty Publications

Unmanned aircraft systems (UASs) offer innovative capabilities for providing new perspectives on the atmosphere, and therefore atmospheric scientists are rapidly expanding their use, particularly for studying the planetary boundary layer. In support of this expansion, from 14 to 20 July 2018 the International Society for Atmospheric Research using Remotely piloted Aircraft (ISARRA) hosted a community flight week, dubbed the Lower Atmospheric Profiling Studies at Elevation – a Remotely-piloted Aircraft Team Experiment (LAPSE- RATE; de Boer et al., 2020a). This field campaign spanned a 1-week deployment to Colorado’s San Luis Valley, involving over 100 students, scientists, engineers, pilots, and outreach coordinators. …

Power-Over-Tether Uas Leveraged For Nearly Indefinite Meteorological Data Acquisition In The Platte River Basin, Daniel Rico, Carrick Detweiler, Francisco Munoz-Arriola

CSE Conference and Workshop Papers

The integration of unmanned aerial systems (UASs) has increased in the field of agriculture. These systems can provide data that was previously difficult to obtain to help increase efficiency and production. Typical commercial off the shelf (COTS) UASs have significant limitations in the form of small payloads, and short flight times which inhibit their ability to provide significant quantities of useful data. We present the development of a novel power-over-tether UAS that leverages the physical presence of the tether to integrate sensors at multiple altitudes along the tether. The UAS can acquire data nearly indefinitely to sense atmospheric conditions and …

Surface Modification Of Silicon Nanowire Based Field Effect Transistors With Stimuli Responsive Polymer Brushes For Biosensing Applications, Stephanie Klinghammer, Sebastian Rauch, Sebastian Pregl, Petra Uhlmann, Larysa Baraban, Gianaurelio Cuniberti

Chemistry Department: Faculty Publications

We demonstrate the functionalization of silicon nanowire based field effect transistors (SiNW FETs) FETs with stimuli-responsive polymer brushes of poly(N-isopropylacrylamide) (PNIPAAM) and poly(acrylic acid) (PAA). Surface functionalization was confirmed by atomic force microscopy, contact angle measurements, and verified electrically using a silicon nanowire based field effect transistor sensor device. For thermo-responsive PNIPAAM, the physicochemical properties (i.e., a reversible phase transition, wettability) were induced by crossing the lower critical solution temperature (LCST) of about 32 ◦C. Taking advantage of this property, osteosarcomic SaoS-2 cells were cultured on PNIPAAM-modified sensors at temperatures above the LCST, and completely detached by simply cooling. Next, …

Metabolic Changes Associated With Adaptive Resistance To Daptomycin In Streptococcus Mitis-Oralis, Allison Parrett, Joseph M. Reed, Stewart G. Gardner, Nagendra N. Mishra, Arnold S. Bayer, Robert Powers, Greg A. Somerville

Chemistry Department: Faculty Publications

Background: Viridans group streptococci of the Streptococcus mitis-oralis subgroup are important endovascular pathogens. They can rapidly develop high-level and durable non-susceptibility to daptomycin both in vitro and in vivo upon exposure to daptomycin. Two consistent genetic adaptations associated with this phenotype (i.e., mutations in cdsA and pgsA) lead to the depletion of the phospholipids, phosphatidylglycerol and cardiolipin, from the bacterial membrane. Such alterations in phospholipid biosynthesis will modify carbon flow and change the bacterial metabolic status. To determine the metabolic differences between daptomycin-susceptible and non- susceptible bacteria, the physiology and metabolomes of S. mitis-oralis strains 351 (daptomycin-susceptible) and 351-D10 (daptomycin …

Quantitative Nmr-Based Biomedical Metabolomics: Current Status And Applications, Alexandra A. Crook, Robert Powers

Chemistry Department: Faculty Publications

Nuclear Magnetic Resonance (NMR) spectroscopy is a quantitative analytical tool commonly utilized for metabolomics analysis. Quantitative NMR (qNMR) is a field of NMR spectroscopy dedicated to the measurement of analytes through signal intensity and its linear relationship with analyte concentration. Metabolomics-based NMR exploits this quantitative relationship to identify and measure biomarkers within complex biological samples such as serum, plasma, and urine. In this review of quantitative NMR-based metabolomics, the advancements and limitations of current techniques for metabolite quantification will be evaluated as well as the applications of qNMR in biomedical metabolomics. While qNMR is limited by sensitivity and dynamic range, …

Mechanistic Insights Into The Acetate-Accelerated Synthesis Of Crystalline Ceria Nanoparticles, Tamra J Fisher, Deepa Choudhry, Kaitlynn Derr, Soodabeh Azadehranjbar, Dan Stasko, Chin Li Cheung

Chemistry Department: Faculty Publications

Recent increasing uses of ceria in research and industrial applications have fostered continuing developments of efficient routes to synthesize the material. Here we report our investigation of the effects and the mechanistic roles of lithium acetate to accelerate the growth of crystalline ceria nanoparticles in ozone-mediated synthesis. By increasing the mole ratio of the acetate to cerium nitrate in the reactions, the reaction yields of ceria nanoparticles were observed to increase from ca. 10% to up to over 90% by cerium content in 30 min reactions. Microscopy images and Raman spectra of the assynthesized nanoparticles revealed that increasing the acetate …

Chiral Magnetism And High-Temperature Skyrmions In B20-Ordered Co-Si, Balamurugan Balasubramanian, Priyanka Manchanda, Rabindra Pahari, Zhen Chen, Wenyong Zhang, Shah R. Valloppilly, Xingzhong Li, Anandakumar Sarella, Lanping Yue, Ahsan Ullah, Pratibha Dev, David A. Muller, Ralph Skomski, George C. Hadjipanayis, David J. Sellmyer

Nebraska Center for Materials and Nanoscience: Faculty Publications

Magnets with chiral crystal structures and helical spin structures have recently attracted much attention as potential spin-electronics materials, but their relatively low magnetic-ordering temperatures are a disadvantage. While cobalt has long been recognized as an element that promotes high-temperature magnetic ordering, most Co-rich alloys are achiral and exhibit collinear rather than helimagnetic order. Crystallographically, the B20-ordered compound CoSi is an exception due to its chiral structure, but it does not exhibit any kind of magnetic order. Here, we use nonequilibrium processing to produce B20-ordered Co_1+xSi_1−x with a maximum Co solubility of x = 0.043. Above a critical …

Svat4: A Computer Program For Visualization And Analysis Of Crystal Structures, Xingzhong Li

Nebraska Center for Materials and Nanoscience: Faculty Publications

SVAT4 is a computer program for interactive visualization of three-dimensional crystal structures, including chemical bonds and magnetic moments. A wide range of functions, e.g. revealing atomic layers and polyhedral clusters, are available for further structural analysis. Atomic sizes, colors, appearance, view directions and view modes (orthographic or perspective views) are adjustable. Customized work for the visualization and analysis can be saved and then reloaded. SVAT4 provides a template to simplify the process of preparation of a new data file. SVAT4 can generate high-quality images for publication and animations for presentations. The usability of SVAT4 is broadened by a software suite …

Save The Tax Break, Megan Bilstein

Op-Eds from ENSC230 Energy and the Environment: Economics and Policies

Saving 26% on inputting a clean form of energy sounds pretty good to me. According to the U.S. Department of Energy by inputting a solar panel into your house, property, or shop you could have 30% of the cost to install a solar panel system deducted from your federal income taxes, that was in 2019. Come 2020 it decreased to 26% and 22% in 2021 then completely gone in 2022. Unless something is done to save the tax credit this form of renewable energy may be completely forgotten about or put to the side in Nebraska while other forms will …

Lincoln’S Brightest Policy On Solar Energy, Jerin Tekolste

Op-Eds from ENSC230 Energy and the Environment: Economics and Policies

The push towards renewable energy is ubiquitous, with reasons varying from greater independence from foreign energy markets to environmental considerations or sustainable futures. Many countries, states, and cities all around the world are pursuing different ways to better their energy generation and Lincoln is no different. The current policy provides some incentive towards residential solar power but can be improved upon. There are typically three mechanisms used for residential photovoltaic (PV) solar generation: Feed-In Tariffs (FITs), Net Metering, and Net Purchase and Sale. This paper will compare the options Lincoln could use and will conclude with what would be the …

Climate Change In Rwanda, Mig Shyaka

Op-Eds from ENSC230 Energy and the Environment: Economics and Policies

Climate change has become the world’s upmost threat. Different ideas of mitigation and adaptation have been developed to target climate change. These solutions stretch from development and innovation of different technologies like clean energy (solar and wind), to simpler local procedures (planting trees and simple green agroecological practices like farming). However, the need for the rapid action on climate change has created a narrow understanding of the issue and the necessary participation for the process to be smoother in developing and under-developed countries. It can be argued to be the case in some developed countries too.

Swine Slurry Characteristics As Affected By Selected Additives And Disinfectants, Jon Duerschner, Shannon L. Bartelt-Hunt, Kent Eskridge, John E. Gilley, Xu Li, Amy M. Schmidt, Daniel D. Snow

Nebraska Water Center: Faculty Publications

Current swine industry practice is to house animals in confinement facilities which capture and store feces and urine as slurry in pits below the production area. Additives and disinfectants may be introduced into the manure pits. This study was conducted to measure the effects of additives and disinfectants on temporal changes in swine slurry characteristics. Slurry from a commercial swine production facility in southeast Nebraska, USA was collected and transferred to 57 L reactors located within a greenhouse. Selected additives and disinfectants were added to the reactors and physical properties, chemical characteristics, and antibiotic concentrations were monitored for 40 days. …

Applied Injected Air Into Subsurface Drip Irrigation: Plant Uptake Of Pharmaceuticals And Soil Microbial Communities, Matteo D'Alessio, Lisa M. Durso, Clinton Williams, Christopher A. Olson, Chittaranjan Ray, Ellen Paparozzi

Nebraska Water Center: Faculty Publications

The growing global food security crisis is complicated by the need for increased crop production with less arable land and limited water resources. Reuse of treated wastewater for agricultural irrigation is becoming more common, often paired with other conservation measures such as subsurface drip irrigation (SDI). Passively injecting air into SDI systems increases crop yields and overcomes root zone wetting issues. However, when used with treated irrigation water, contaminants in the water might be taken up by the crops. This paper investigates the impact of air-injected water containing caffeine, carbamazepine, and gemfibrozil on plant uptake and soil microbial communities in …

Polarization-Independent Metasurface Lens Based On Binary Phase Fresnel Zone Plate, Jonathan Baine, Jing Tang, Xing Li

Chemistry Department: Faculty Publications

Based on the binary phase Fresnel zone plate (FZP), a polarization-independent metasurface lens that is able to focus incident light with any polarization state, including circular, linear, and elliptical polarizations, has been proposed and investigated. We demonstrate that the metasurface lens consisting of metal subwavelength slits can operate in a wide bandwidth in the visible range, and has a higher focusing efficiency than that of an amplitude FZP lens without phase modulation. A multi-focus FZP metasurface lens has also been designed and investigated. The proposed lens can provide potential applications in integrated nanophotonic devices without polarization limitations.

Measurement Of Single-Diffractive Dijet Production In Proton–Proton Collisions At √S = 8 Tev With The Cms And Totem Experiments, Cms Collaboration, Ekaterina Avdeeva, Kenneth A. Bloom, Daniel Claes, Caleb Fangmeier, Frank Golf, Rebeca Gonzalez Suarez, Rami Kamalieddin, Ilya Kravchenko Dr., Jose Monroy, J. Siado, Gregory Snow, B. Stieger

Kenneth Bloom Publications

Measurements are presented of the single-diffractive dijet cross section and the diffractive cross section as a function of the proton fractional momentum loss ξ and the four-momentum transfer squared t. Both processes pp → pX and pp → Xp, i.e. with the proton scattering to either side of the interaction point, are measured, where X includes at least two jets; the results of the two processes are averaged. The analyses are based on data collected simultaneously with the CMS and TOTEM detectors at the LHC in proton–proton collisions at √s = 8 TeV during a dedicated run with …

Anthropogenic Hydrometeorological Changes At A Regional Scale: Observed Irrigation-Precipitation Feedback (1979-2015) In Nebraska, Usa, Jozsef Szilagyi, Trenton Franz

School of Natural Resources: Faculty Publications

Long-term tendencies in annual, seasonal, and monthly (March) precipitation, evapotranspiration, and air- and dew-point temperature values were correlated with county-level changes in irrigated area across Nebraska over the 1979–2015 period. A statistically significant linear relationship (slope of − 1.65 ± 0.33 mm/decade per % decadal change in irrigated area, with a correlation coefficient of − 0.47) was found between the trends in annual precipitation and irrigated land area. Precipitation dropped by 1 mm annually if the level in irrigation expansion reached about 8% per decade, while the rest of the state enjoyed about a half-millimeter overall increase in annual precipitation …

Niche Modeling Reveals Life History Shifts In Birds At La Brea Over The Last Twenty Millennia, Robert M. Zink, Sebastian Botero-Canola, Helen Martinez, Katelyn M. Herzberg

School of Natural Resources: Faculty Publications

A species presence at a particular site can change over time, resulting in temporally dynamic species pools. Ecological niche models provide estimates of species presence at different time intervals. The avifauna of La Brea includes approximately 120 species dating to approximately 15,000 years ago. Niche models predicted presence at the Last Glacial Maximum for over 90% of 89 landbird species. This confirms that niche modeling produces sensible range estimates at the Last Glacial Maximum. For 97 currently local species that are as yet undocumented at La Brea over 90% were predicted to occur; absence is due to insufficient study, lack …

Sociohydrologic Systems Thinking: An Analysis Of Undergraduate Students’ Operationalization And Modeling Of Coupled Human-Water Systems, Diane Lally, Cory T. Forbes

School of Natural Resources: Faculty Publications

One of the keys to science and environmental literacy is systems thinking. Learning how to think about the interactions between systems, the far-reaching effects of a system, and the dynamic nature of systems are all critical outcomes of science learning. However, students need support to develop systems thinking skills in undergraduate geoscience classrooms. While systems thinking-focused instruction has the potential to benefit student learning, gaps exist in our understanding of students’ use of systems thinking to operationalize and model SHS, as well as their metacognitive evaluation of systems thinking. To address this need, we have designed, implemented, refined, and studied …

An Unseen Synchrony Or Recurrent Resource Pulse Opportunity? Linking Fisheries With Aeroecology, Henry H. Hansen, Mark Pegg, Matthew Van Den Broeke, Doug Watkinson, Eva C. Enders

School of Natural Resources: Faculty Publications

Understanding insect and fish interactions from a spatial and temporal perspec-tive can have implications on large-scale phenology in freshwater systems, yet current information is limited. We employed a novel approach of combining information from acoustic telemetry for six freshwater fish species and weather radar to assess the phenology of mayfly emergence and foraging patterns of freshwater fish. We hypothesized that freshwater fish conduct synchronous movements with annual mayfly hatches as a pulse resource opportunity. Gener-alized additive models were developed to assess movement distance as a func-tion of species and time; before, during, and after annual mayfly hatch events. A cross-section …