Physical Sciences and Mathematics Commons^™

The Adaptive Cycle: More Than A Metaphor, Shana M. Sundstrom, Craig R. Allen

School of Natural Resources: Faculty Publications

The adaptive cycle and its extension to panarchy (nested adaptive cycles) has been a useful metaphor and conceptual model for understanding long-term dynamics of change in ecological and social–ecological systems. We argue that adaptive cycles are ubiquitous in complex adaptive systems because they reflect endogenously generated dynamics as a result of processes of self-organization and evolution. We synthesize work from a wide array of fields to support this claim. If dynamics of growth, conservation, collapse and renewal are endogenous dynamics of complex adaptive systems, then there ought to be signals of system change over time that reflect this. We describe …

Chronology Of Dune Development In The White River Badlands, Northern Great Plains, Usa, P. E. Baldauf, P. A. Burkhart, Paul R. Hanson, M. Miles, Ashley Larsen

School of Natural Resources: Faculty Publications

Aeolian dune field chronologies provide important information on drought history on the Great Plains. The White River Badlands (WRB) dunes are located approximately 60 km north of the Nebraska Sand Hills (NSH), in the western section of the northern Great Plains. Clifftop dunes, sand sheets, and stabilized northwest-southeast trending parabolic dunes are found on upland mesas and buttes, locally called tables. The result of this study is a dune stabilization history determined from samples collected from stratigraphic exposures and dune crests. Thirty-seven OSL ages, from this and previous investigations, show three periods of dune activity: 1) ~21,000 years ago to …

Modeled And Measured Ecosystem Respiration In Maize–Soybean Systems Over 10 Years, Ming Zhan, Adam Liska, Anthony Nguy-Robertson, Andrew E. Suyker, Matthew P. Pelton, Haishun Yang

Adam Liska Papers

Crop residue is an abundant resource for the potential production of biofuels, but a better understanding of its use on net carbon emissions must be developed to mitigate climate change. This analysis combines two established crop growth models (Hybrid-Maize and SoySim) with a simple soil and crop residue respiration model to estimate daily ecosystem respiration (ERe) from maize and soybean; ERe was estimated to be the sum of CO₂ emissions from the oxidation of the growing crop, crop residue, and soil organic carbon (SOC). Model-estimated CO₂ fluxes from irrigated continuous maize and irrigated maize–soybean cropping systems in eastern …

An Overview Of Capillary Electrophoresis (Ce) In Clinical Analysis, David S. Hage

David Hage Publications

The development and general applications of capillary electrophoresis (CE) in the field of clinical chemistry are discussed. It is shown how the early development of electrophoresis was closely linked to clinical testing. The rise of gel electrophoresis in clinical chemistry is described, as well as the eventual developments that lead to the creation and the use of modern CE. The general principles of CE are reviewed and the potential advantages of this method in clinical testing are examined. Finally, an overview is presented of several areas in which CE has been developed and is currently being explored for use with …

Twenty-Three Unsolved Problems In Hydrology (Uph) – A Community Perspective, Günter Blöschl, Christopher M. U. Neale, A Cast Of Thousands

Daugherty Water for Food Global Institute: Faculty Publications

This paper is the outcome of a community initiative to identify major unsolved scientific problems in hydrology motivated by a need for stronger harmonisation of research efforts. The procedure involved a public consultation through online media, followed by two workshops through which a large number of potential science questions were collated, prioritised, and synthesised. In spite of the diversity of the participants (230 scientists in total), the process revealed much about community priorities and the state of our science: a preference for continuity in research questions rather than radical departures or redirections from past and current work. Questions remain focused …

Impact Of The Application Of Domestic Wastewater By Subsurface Drip Irrigation On The Soil Solution In Sugarcane Cultivation, Aline Azevedo Nazário, Ivo Zution Gonçalves, Eduardo Augusto Agnellos Barbosa, Leonardo Nazário Silva Dos Santos, Daniel Rodrigues Cavalcante Feitosa, Edson Eiji Matsura

Daugherty Water for Food Global Institute: Faculty Publications

The agricultural use of domestic sewage is a viable alternative for recycling nutrients; however, there is concern regarding the impact of its use due to the concentration of chemical elements present in this type of effluent. The use of principal component analysis determines the existence or lack of anomalous samples and the relations between measured variables and their relative contribution among samples that help in monitoring the impact of the use of effluents on soil chemical components. Thus, the objective of this work was to identify nutrient ions present in the soil solution during the first ratoon sugarcane irrigated with …

Public Attitudes About Private Forest Management And Government Involvement In The Southeastern United States, Melissa M. Kreye, Renata Rimsaite, Damian C. Adams

Daugherty Water for Food Global Institute: Faculty Publications

In the southern United States the country’s top wood-producing region, factors such as intergenerational land transfer and population spillover from urban areas have resulted in forestland conversion and reduced production of critical ecosystem services associated with forest systems (e.g., timber, clean water supply, wildlife habitat). Public attitudes, which drive forestland policy prescriptions, may also be evolving due to the way people experience and perceive forests (e.g., recreation), and think about the role of government in private forest decisions. These changes have significant implications for forestland management and the forest-based economy, both locally and globally. We present the results of a …

Mapping Regional Turbulent Heat Fluxes Via Assimilation Of Modis Land Surface Temperature Data Into An Ensemble Kalman Smoother Framework, Xinlei He, Tongren Xu, Sayed M. Bateni, Christopher M. U. Neale, Shaomin Liu, Thomas Auligne, Kaicun Wang, Shoudong Zhu

Daugherty Water for Food Global Institute: Faculty Publications

Estimation of turbulent heat fluxes via variational data assimilation (VDA) approaches has been the subject of several studies. The VDA approaches need an adjoint model that is difficult to derive. In this study, remotely sensed land surface temperature (LST) data from the Moderate Resolution Imaging Spectroradiometer (MODIS) are assimilated into the heat diffusion equation within an ensemble Kalman smoother (EnKS) approach to estimate turbulent heat fluxes. The EnKS approach is tested in the Heihe River Basin (HRB) in northwest China. The results show that the EnKS approach can estimate turbulent heat fluxes by assimilating low temporal resolution LST data from …

Domain-Wall Tunneling Electroresistance Effect, M. Li, L. L. Tao, And E. Y. Tsymbal

Evgeny Tsymbal Publications

No abstract provided.

Two-Dimensional Spin-Valley Locking Spin Valve, L. L. Tao And E. Y. Tsymbal

Evgeny Tsymbal Publications

No abstract provided.

Magnetoelectric Control Of Topological Phases In Graphene, H. Takenaka, S. Sandhoefner, A. A. Kovalev, And E. Y. Tsymbal

Evgeny Tsymbal Publications

No abstract provided.

Ferroelectric Tunnel Junctions Enhanced By A Polar Oxide Barrier Layer, Q. Yang, L. L. Tao, E. Y. Tsymbal, And V. Alexandrov

Evgeny Tsymbal Publications

No abstract provided.

Atomic-Scale Control Of Magnetism At The Titanite-Manganite Interfaces, H. Wang, X. Chi, Z. R. Liu, H. Y. Yoong, L. L. Tao, J. X. Xiao, R. Guo, J. X. Wang, Z. L. Dong, P. Yang, C. J. Sun, J. Wang, G. M. Chow, E. Y. Tsymbal, H. Tian, And J. S. Chen

Evgeny Tsymbal Publications

No abstract provided.

Controlling The Magnetic Properties Of Lamno3/Srtio3 Heterostructures By Stoichiometry And Electronic Reconstruction: Atomic-Scale Evidence, M. S. Li, C. H. Tang, T. R. Paudel, D. S. Song, W. M. Lü, K. Han, Z. Huang, S. W. Zeng, X. R. Wang, P. Yang, Ariando, J. S. Chen, T. Venkatesan, E. Y. Tsymbal, C. J. Li, And S. J. Pennycook

Evgeny Tsymbal Publications

No abstract provided.

Agricultural Water Transfers In The Western United States, Richael Young, Nicholas Brozovic

Daugherty Water for Food Global Institute: Faculty Publications

Irrigation for agricultural production represents the largest consumptive use of water in the western United States. Understanding the ways in which agricultural producers respond to physical and institutional water scarcity is therefore key to managing water risk. One of the important risk management tools available to agricultural producers is the ability to transfer water across space and time. Water transfers range from very informal handshake agreements between neighbors to very formal transfers of real property across large distances with mandatory state and federal reporting. Given the range of potential water transfer mechanisms, there are significant knowledge gaps on the variety, …

2019 Nebraska Water Productivity Report, Mesfin Mekonnen, Christopher Michael Usher Neale, Chittaranjan Ray, Galen E. Erickson, Adam Liska, Haishun Yang, Thiago L. Romanelli, Arjen Y. Hoekstra

Daugherty Water for Food Global Institute: Faculty Publications

Nebraska’s agricultural production is diverse and vast, ranking the state fourth in total value of agricultural products in the U.S. The state is a national leader in terms of agricultural production: it is the third largest producer of corn and second largest in cattle production. Nebraska is also the second largest producer of ethanol and distillers’ grains. The production and use of these three commodities are highly interlinked. Corn is a major input in livestock feed and the ethanol industry. Ethanol plants then produce distillers’ grains as a co-product that is also used as livestock feed, thus forming what the …

Comparative Study Of Topological Hall Effect And Skyrmions In Nimnin And Nimnga, Wenyong Zhang, Balamurugan Balasubramanian, Ahsan Ullah, Rabindra Pahari, Xingzhong Li, Lanping Yue, Shah R. Valloppilly, Andrei Sokolov, Ralph Skomski, David J. Sellmyer

Nebraska Center for Materials and Nanoscience: Faculty Publications

A nonequilibrium rapid-quenching method has been used to fabricate NiMnIn and NiMnGa alloys that are chemically and morphologically similar but crystallographically and physically very different. NiMnGa crystallizes in a Ni2In-type hexagonal structure, whereas NiMnIn is a cubic Heusler alloy. Both alloys yield a topological Hall effect contribution corresponding to bubble-type skyrmion spin structures, but it occurs in much lower magnetic fields in NiMnIn as compared to NiMnGa. The effect is unrelated to net Dzyaloshinskii-Moriya interactions, which are absent in both alloys due to their inversion-symmetric crystal structures. Based on magnetic-force microscopy, we explain the difference between the two alloys by …

Structure And Magnetism Of Co2ge Nanoparticles, Onur Tosun, Frank M. Abel, Balamurugan Balasubramanian, Ralph Skomski, David J. Sellmyer, George C. Hadjipanayis

Nebraska Center for Materials and Nanoscience: Faculty Publications

The structural and magnetic properties of Co₂Ge nanoparticles (NPs) prepared by the cluster-beam deposition (CBD) technique have been investigated. As-made particles with an average size of 5.5 nm exhibit a mixture of hexagonal and orthorhombic crystal structures. Thermomagnetic measurements showed that the as-made particles are superparamagnetic at room temperature with a blocking temperature (T_B) of 20 K. When the particles are annealed at 823 K for 12 h, their size is increased to 13 nm and they develop a new orthorhombic crystal structure, with a Curie temperature (T_C) of 815 K. This …

Medium-Dependent Antibacterial Properties And Bacterial Filtration Ability Of Reduced Graphene Oxide, Alexander Gusev, Olga Zakharova, Dmitry S. Muratov, Nataliia S. Vorobeva, Mamun Sarker, Iaroslav Rybkin, Daniil Bratashov, Evgeny Kolesnikov, Aleš Lapanje, Denis V. Kuznetsov, Alexander Sinitskii

Nebraska Center for Materials and Nanoscience: Faculty Publications

Toxicity of reduced graphene oxide (rGO) has been a topic of multiple studies and was shown to depend on a variety of characteristics of rGO and biological objects of interest. In this paper, we demonstrate that when studying the same dispersions of rGO and fluorescent Escherichia coli (E. coli) bacteria, the outcome of nanotoxicity experiments also depends on the type of culture medium. We show that rGO inhibits the growth of bacteria in a nutrition medium but shows little effect on the behavior of E. coli in a physiological saline solution. The observed effects of rGO on E. …

Crystal Structure, Magnetism And Magnetocaloric Properties Of Mn2−XSn0.5Ga0.5 (X=0, 0.3, 0.5, 0.8) Alloys, H. Qian, Rabindra Pahari, K. Schroeder, Shah R. Valloppilly, Y. Huh, Pavel V. Lukashev, J. Hu, Parashu Kharel, David J. Sellmyer

Nebraska Center for Materials and Nanoscience: Faculty Publications

Magnetic refrigeration based on the magnetocaloric effect has attracted recent attention due to advantages such as high efficiency and environmental friendliness. We have investigated the structural, magnetic and magnetocaloric properties of Mn_2−xSn_0.5Ga_0.5 (x=0, 0.3, 0.5, 0.8) alloys prepared using arc-melting and meltspinning techniques with prospects for magnetic refrigeration. The Mn_2−xSn_0.5Ga_0.5 alloys, except for Mn_1.2Sn_0.5Ga_0.5, have a single-phase hexagonal crystal structure. The Mn_1.2Sn_0.5Ga_0.5 alloy also contains a small amount of MnSn₂ impurity phase. The Curie temperature and high-field (30 kOe) …

Skew-Symmetric Splitting Of High-Order Central Schemes With Nonlinear Filters For Computational Aeroacoustics Turbulence With Shocks, Bjorn Sjögreen, Helen C. Yee, Alan A. Wray

United States National Aeronautics and Space Administration: Publications

A class of high-order nonlinear filter schemes by Yee et al. (J Comput Phys 150:199–238, 1999), Sjögreen and Yee (J Comput Phys 225:910–934, 2007), and Kotov et al. (Commun Comput Phys 19:273–300, 2016; J Comput Phys 307:189–202, 2016) is examined for long-time integrations of computational aeroacoustics (CAA) turbulence applications. This class of schemes was designed for an improved nonlinear stability and accuracy for long-time integration of compressible direct numerical simulation and large eddy simulation computations for both shock-free turbulence and turbulence with shocks. They are based on the skew-symmetric splitting version of the high-order central base scheme in conjunction with …

Role Of Water On The Rotational Dynamics Of The Organic Methylammonium Cation: A First Principles Analysis, Ross D. Hoehn, Joseph S. Francisco, Sabre Kais, Ali Kachmar

Chemistry Department: Faculty Publications

Understanding the degradation mechanisms of lead-halide perovskites (CH₃NH₃PbI₃) under exposure to liquid/aerosol water is an essential problem within the photovoltaic community. Herein we investigate both the static and the dynamic properties of the methylammonuim cation (MA) as it coordinates with invading water molecules (MA.(H₂O)_n, n = 1, 2, 3, 4) using both stationary state quantum mechanics and first principle molecular dynamics simulations. Various solvation structures of MA were characterized by their stabilization energies, dipoles, and Maximally-Localized Wannier Function (MLWF) centers. Calculation – and analysis – of vibrational shifts in the …

The Inductive Effect In Organic Chemistry, Charles A. Kingsbury

Chemistry Department: Faculty Publications

The subtle difference between the successive polarization model and the flow of electrons through sigma bonds is explored, as well as the alternating charge model of Pople and the pervasive field model. The present paper is concerned with the ability of alkyl groups to serve as sigma inductive electron donors.

Catalytic Mechanism Of Amyloid-Β Peptide Degradation By Insulin Degrading Enzyme: Insights From Qm/Mm Mp2 Calculation, Rui Lai, Wei-Jen Tang, Hui Li

Chemistry Department: Faculty Publications

Insulin degrading enzyme (IDE), a metalloprotease that degrades amyloid-β (Aβ) peptides and insulin, is associated with Alzheimer’s disease and diabetes. The mechanism of IDE catalyzed degrading of Aβ peptides, which is of fundamental importance in the design of therapeutic methods for Alzheimer’s disease, has not been fully understood. In this work, combined quantum mechanics and molecular mechanics (QM/MM) style Møller-Plesset second order perturbation theory (MP2) geometry optimization calculations are performed to investigate the catalytic mechanism of the Aβ40 Phe19-Phe20 peptide bond cleavage by human IDE. The analyses using QM/MM MP2 optimization suggest that a …

In-Situ-Investigation Of Enzyme Immobilization On Polymer Brushes, Meike Koenig, Ulla König, Klaus-Jochen Eichhorn, Martin Muller, Manfred Stamm, Petra Uhlmann

Chemistry Department: Faculty Publications

Herein, we report on the use of a combined setup of quartz-crystal microbalance, with dissipation monitoring and spectroscopic ellipsometry, to comprehensively investigate the covalent immobilization of an enzyme to a polymer layer. All steps of the covalent reaction of the model enzyme glucose oxidase with the poly(acrylic acid) brush by carbodiimide chemistry, were monitored in-situ. Data were analyzed using optical and viscoelastic modeling. A nearly complete collapse of the polymer chains was found upon activation of the carboxylic acid groups with N-(3-Dimethylaminopropyl)-N′-ethylcarbodiimide and N-Hydroxysuccinimide. The reaction with the amine groups of the enzyme occurs simultaneously with re-hydration of the …

Insights Into Gemcitabine Resistance And The Potential For Therapeutic Monitoring, Teklab Gebregiworgis, Fatema Bhinderwala, Vinee Purohit, Nina V. Chaika, Pankaj K. Singh, Robert Powers

Chemistry Department: Faculty Publications

Introduction—Gemcitabine is an important component of pancreatic cancer clinical management. Unfortunately, acquired gemcitabine resistance is widespread and there are limitations to predicting and monitoring therapeutic outcomes.

Objective—To investigate the potential of metabolomics to differentiate pancreatic cancer cells that develops resistance or respond to gemcitabine treatment.

Results—We applied 1D ¹H and 2D ¹H-¹³C HSQC NMR methods to profile the metabolic signature of pancreatic cancer cells. ¹³C₆-glucose labeling identified thirty key metabolites uniquely altered between wild-type and gemcitabine-resistant cells upon gemcitabine treatment. Gemcitabine resistance was observed to reprogram glucose metabolism and to enhance the pyrimidine …

Assessment Of Chronic Low-Dose Elemental And Radiological Exposures Of Biota At The Kanab North Uranium Mine Site In The Grand Canyon Watershed, Danielle Cleveland, Jo Ellen Hinck, Julia S. Lankton

United States Geological Survey: Staff Publications

High-grade U ore deposits are in various stages of exploitation across the Grand Canyon watershed, yet the effects of U mining on ecological and cultural resources are largely unknown. Wecharacterized the concentrations of Al, As, Bi, Cd, Co, Cu, Fe, Pb, Hg, Mo, Ni, Se, Ag, Tl, Th, U, and Zn, gross alpha and beta activities, and U and Th radioisotopes in soil, vegetation (Hesperostipa comata, Artemisia tridentata, Tamarix chinensis), and rodents (Peromyscus maniculatus, P. boylii) to waste material at the Kanab North mine, a mine with decades-long surficial contamination, and compared the concentrations (P<0.01) to those at a premining site (Canyon Mine). Rodent tissues were also analyzed for radium-226 and microscopic lesions. Radioactivities and some elemental concentrations (e.g., Co, Pb, U) were greater in the Kanab North mine biological samples than in Canyon Mine biota, indicating a mining-related elemental signature. Mean rodent Ra-226 (111 Bq/kg dry weight [dry wt]) was 3 times greater than expected, indicating radioactive disequilibrium. Multiple soil sample U concentrations exceeded a screening benchmark, growth inhibition thresholds for sensitive plants, and an EC20 for a soil arthropod. Lesions associated with metals exposure were also observed more frequently in rodents at Kanab North than those at Canyon Mine but could not be definitively attributed to U mining. Our results indicate that Kanab North biota have taken up U mining-related elements owing to chronic exposure to surficial contamination. However, no literature-based effects thresholds for small rodents were exceeded, and only a few soil and vegetation thresholds for sensitive species were exceeded; therefore, adverse effects to biota from U mining-related elements at Kanab North are unlikely despite chronic exposure.

Chaco Canyon, New Mexico: A Caretaker City And A Pilgrimage Destination, Larry Benson, Deanna N. Grimstead, John R. Stein, David A. Roth, Terry I. Plowman

United States Geological Survey: Staff Publications

Some Southwestern archaeologists continue to ascribe to the hypothesis that Chaco was agriculturally productive to the point that it could support at least a few thousand full-time residents. This paper suggests an alternative hypothesis; i.e., Chaco was marginally productive and could only support a few hundred permanent residents. Isotopic analysis of mammal teeth found in trenches cut through platform mounds fronting Pueblo Bonito indicate the possibility that much of the meat consumed by Chacoan residents and visitors came from higher elevation sites bordering the San Juan Basin. We suggest that resident population estimates based on great house room numbers and …

Coastal Wetlands: A Synthesis, Charles S. Hopkinson, Eric Wolanski, Mark M. Brinson, Donald R. Cahoon, Gerardo M.E. Perillo

United States Geological Survey: Staff Publications

What are coastal wetland ecosystems, what are their limits of distribution, and where do they exist in the overall coastal landscape? There are several general definitions for wetlands, but the Ramsar definition is likely the most broadly encompassing (http://www.ramsar. org/), whereas others are more focused definitions tailored to country-specific protection and management policies (Mitsch and Gosselink, 2006). We offer a very general approach rather than a precise definition: coastal wetlands are ecosystems that are found within an elevation gradient that ranges between subtidal depths where light penetrates to support photosynthesis of benthic plants to the landward edge where the sea …

Promoting Change In Common Tern (Sterna Hirundo) Nest Site Selection To Minimize Construction Related Disturbance., Peter C. Mcgowan, Jeffery D. Sullivan, Carl R. Callahan, William Schultz, Jennifer L. Wall, Diann J. Prosser

United States Geological Survey: Staff Publications

Due to the many challenges facing waterbird populations (Jia et al. 2018, Wetlands International 2018), it has become common practice to limit disturbance to breeding colonies whenever possible to maximize reproductive success. While this may require often unpopular management techniques including beach closures (Jorgensen et al. 2015, Mayo et al. 2015) and predator removal (Neuman et al. 2004, Stocking et al. 2017), such actions are sometimes necessary for the success of the colony. However, there are instances when eliminating disturbance is not possible and birds must be attracted to a new site. A common method for attracting waterbirds to a …