Physical Sciences and Mathematics Commons^™

Desorption Hysteresis In Five Ion Exchanged Montmorillonites, Jerry Paul Fairley

UNLV Theses, Dissertations, Professional Papers, and Capstones

It is generally believed that the formation of recalcitrant (slowly desorbing) fractions of volatile organic compounds (VOCs) in soils is due to diffusion of compounds to sorption sites inaccessible to bulk fluid. The exact nature of these sites, however, is not well understood. In clay minerals, researchers favor two probable areas for the storage of persistent contamination; sites between the clay lamella, or sites with clay particle aggregates.

To test the hypothesis that recalcitrant fractions are formed in interlamellar spaces, a Na/Ca Montmorillonite (Smectite) was ion exchanged with five different cations (K⁺, Na⁺, Ca⁺, …

Electron-Energy And –Angular Distributions In The Double Photoionization Of Helium, R. Wehlitz, Franz Heiser, Oliver Hemmers, B. Langer, A. Menzel, U. Becker

Environmental Studies Faculty Publications

Photoelectron spectra of helium have been measured at different angles and at various energies above the double-ionization threshold up to 120 eV to investigate the behavior of the energy and angular distributions, of shake-off electrons. Both energy and angular distributions clearly show a U-shaped profile which turns to a flat curve near threshold pointing to a uniform intensity distribution over the kinetic energy for all angles in this excitation energy regime. Our results for the angular-distribution asymmetry parameter indicate qualitative agreement with theoretical predictions but fail to provide them quantitatively.

Surface Structure Of √3x√3r 30 Cl/Ni(111) Determined Using Low-Temperature Angle-Resolved-Photoemission Extended Fine Structure, Li-Qiong Wang, Z. Hussain, Z. Q. Huang, A. E. Schach Von Wittenau, Dennis W. Lindle, D. A. Shirley

Chemistry and Biochemistry Faculty Research

A surface structural study of the √3 × √3 R30° Cl/Ni(111) adsorbate system was made using low-temperature angle-resolved photoemission extended fine structure. The experiments were performed along two emission directions, [111] and [110], and at two temperatures, 120 and 300 K. The multiple-scattering spherical-wave analysis determined that the Cl atom adsorbs in the fcc threefold hollow site, 1.837(8) Å above the first nickel layer, with a Cl-Ni bond length of 2.332(6) Å, and an approximate 5% contraction between the first and the second nickel layers (the errors in parentheses are statistical standard deviations only).

The Sloan Sag: A Mid-Miocene Volcanotectonic Depression, North-Central Mccullough Mountains, Southern Nevada, Hayden L. Bridwell

UNLV Theses, Dissertations, Professional Papers, and Capstones

In the Hidden Valley area of the north-central McCullough Mountains, southern Nevada, mid-Miocene andesite and dacite domes, flows and pyroclastic units (the Sloan volcanics) partially fill a sag in the underlying Hidden Valley volcanics. The 13.5 km diameter sag formed during and/or after the eruption of the Sloan volcanics. Sagging was accommodated by a combination of movement on the McCullough Wash fault system, and subsidence into evacuated chambers.

Major, trace and rare-earth element geochemistry suggests that the rocks of the Sloan volcanics belong to four groups, each of which were produced by partial melting of chemically distinct sources. With the …

Anisotropy Of Polarized X-Ray Emission From Molecules, S. H. Southworth, Dennis W. Lindle, R. Mayer, P. L. Cowan

Chemistry and Biochemistry Faculty Research

Strongly anisotropic, polarized Cl K-V x-ray emission from gas-phase CF₃Cl has been observed following resonant excitation with a linearly polarized x-ray beam. Distinctively different angular distributions are observed for x-ray emission involving molecular orbitals of different symmetries. A classical model of the x-ray absorption-emission process accurately describes the observed radiation patterns.

Measurement Of The Ratio Of Double-To-Single Photoionization Of Helium At 2.8 Kev Using Synchrotron Radiation, Jon C. Levin, Dennis W. Lindle, N. Keller, R. D. Miller, Y. Azuma, N. Berrah Mansour, H. G. Berry, Ivan A. Sellin

Chemistry and Biochemistry Faculty Research

We report the first measurement of the ratio of double-to-single photoionization of helium well above the double-ionization threshold. Using a time-of-flight technique, we find He⁺⁺/He⁺=1.6±0.3% at hν=2.8 keV. This value lies between calculations by Amusia (2.3%) and by Samson, who predicts 1.2% by analogy with electron-impact ionization cross sections of singly charged ions. Good agreement is obtained with older shake calculations of Byron and Joachain, and of Åberg, who predict 1.7%.

Molecular-Orbital Studies Via Satellite-Free X-Ray Fluorescence: Cl-K Absorption And K–Valence-Level Emission Spectra Of Chlorofluoromethanes, Rupert C. Perera, P. L. Cowan, Dennis W. Lindle, R. E. Lavilla, T. Jach, R. D. Deslattes

Chemistry and Biochemistry Faculty Research

X-ray absorption and emission measurements in the vicinity of the chlorine K edge of the three chlorofluoromethanes have been made using monochromatic synchrotron radiation as the source of excitation. By selectively tuning the incident radiation to just above the Cl 1s single-electron ionization threshold for each molecule, less complex x-ray-emission spectra are obtained. This reduction in complexity is attributed to the elimination of multielectron transitions in the Cl K shell, which commonly produce satellite features in x-ray emission. The resulting "satellite-free" x-ray-emission spectra exhibit peaks due only to electrons in valence molecular orbitals filling a single Cl 1s vacancy. These …

Polarized X-Ray-Emission Studies Of Methyl Chloride And The Chlorofluoromethanes, Dennis W. Lindle, P. L. Cowan, T. Jach, R. E. Lavilla, R. D. Deslattes, Rupert C. Perera

Chemistry and Biochemistry Faculty Research

A new technique sensitive to molecular orientation and geometry, and based on measuring the polarization of x-ray emission, has been applied to the Cl-containing molecules methyl chloride (CH₃Cl) and the chlorofluoromethanes (CF₃Cl, CF₂Cl₂, and CFCl₃) in the gas phase. Upon selective excitation using monochromatic synchrotron radiation in the Cl K-edge (Cl 1s) near-threshold region, polarization-selective x-ray emission studies reveal highly polarized molecular valence x-ray fluorescence for all four molecules. The degree and the orientation of the polarized emission are observed to be sensitive to the incident excitation energy near …

High-Resolution Photoelectron Spectrometry Study Of Conjugate Shakeup Processes In The Li 1s Threshold Region, B. Langer, J. Viefhaus, Oliver Hemmers, A. Menzel, U. Becker

Environmental Studies Faculty Publications

Partial cross sections and angular-distribution asymmetry parameters of diagram and satellite lines associated with Li 1s photoionization were measured using synchrotron-radiation excitation. Special emphasis was given to a high-resolution study of the ¹P and ³P conjugate shakeup satellite lines testing qualitative predictions of the conjugate shakeup model: increasing σ and decreasing β values towards threshold, both being verified. Comparison with recent relaxed Hartree-Fock calculations shows good agreement for the ¹P satellite, but demonstrates also that the present theory does not seem to be able to describe the cross-section behavior of the ³P satellite correctly.

Littoral And Limnetic Zooplankton Communities In Lake Mead, Nevada-Arizona, Usa, Patrick J. Sollberger, Larry J. Paulson

Publications (WR)

Zooplankton were collected from adjacent littoral and limnetic sites in Lake Mead, Nevada-Arizona, USA. Limnetic species dominated both littoral and limnetic zooplankton communities; littoral species rarely exceeded 2% of monthly total zooplankton densities. Low species richness of littoral taxa and high similarity in species composition between littoral and limnetic habitats appeared to result from uniform horizontal physical and chemical environments, due to horizontal mixing, and from the absence aquatic macrophytes.

Significant differences in spatial distribution occurred in phytoplankton biomass, total zooplankton density, and fish "abundances; highest concentrations of these factors occurred nearest an inflow high in nutrients and progressively declined …

Direct Determination Of Molecular-Orbital Symmetry Of H2s Using Polarized X-Ray Emission, R. Mayer, Dennis W. Lindle, S. H. Southworth, P. L. Cowan

Chemistry and Biochemistry Faculty Research

X-ray emission from the molecule H₂S is strongly polarized following excitation of a sulfur K-shell electron to an unoccupied subthreshold molecular orbital with a polarized x-ray beam. Changes in the polarization of the emission spectrum are observed as the incident beam's energy is swept across the subthreshold absorption resonance. The previously unresolved absorption resonance is shown experimentally to be primarily associated with a molecular orbital of b₂ symmetry, but with a high-excitation-energy component due to an orbital with a₁ symmetry. Satellite emission intensity is shown to depend on the primary photon energy and is therefore associated …

Lake Mead Nutrient Enhancement Project, Peter D. Vaux, Larry J. Paulson, Nevada Department Of Wildlife, National Oceanic And Atmospheric Administration

Publications (WR)

The Lake Mead Fertilization Project is a research program designed to investigate the potential for using large-scale artificial fertilization to enhance the game fisheries of this reservoir through an increase in the population of threadfin shad, the system's primary forage species. A substantial decline in the population of largemouth bass, together with poor condition of adult striped bass, are the two major issues affecting the Lake Mead game fisheries. Both issues have been hypothesized to be a result of an inadequate amount of forage in the reservoir. Previous studies have in turn suggested that a major factor limiting the shad …

Hydrogeology And Hydrogeochemistry Of The Shallow Alluvial Aquifer Zone, Las Vegas Valley, Nevada, Harry Stephen Wild Jr.

UNLV Theses, Dissertations, Professional Papers, and Capstones

In Las Vegas Valley, Nevada, the shallow alluvial aquifer zone is a possible source of contamination to the principal alluvial aquifers that provide 30% of the public drinking water supply for the valley. Development of the principal aquifers has lowered pressure head in the principal aquifers and created the potential for downward seepage from the shallow aquifer zone. This study was undertaken to characterize the hydrogeology and hydrogeochemistry of the shallow alluvial aquifer zone and to compare the hydrogeochemistry of the shallow and principal alluvial aquifer zones.

A 37 well shallow ground water monitoring network was established and water-level, water-quality, …

Argon-Photoion–Auger-Electron Coincidence Measurements Following K-Shell Excitation By Synchrotron Radiation, Jon C. Levin, C. Biedermann, N. Keller, L. Liljeby, C.-S. O, R. T. Short, Ivan A. Sellin, Dennis W. Lindle

Chemistry and Biochemistry Faculty Research

Argon photoion spectra have been obtained for the first time in coincidence with K-LL and K-LM Auger electrons, as a function of photon energy. The simplified charge distributions which result exhibit a much more pronounced photon-energy dependence than do the more complicated noncoincident spectra. In the near-K-threshold region, Rydberg shakeoff of np levels, populated by resonant excitation of K electrons, occurs with significant probability, as do double-Auger processes and recapture of the K photoelectron through postcollision interaction.

Enhancement And Monitoring Of The Procambarus Clarkii Population In Lake Mead, Mikell Beth Hager

Publications (WR)

Procambarus clarkii are found in extremely low numbers throughout Lake Mead, AZ-NV. The crayfish are an important dietary component for game fish. Enhancement of the crayfish population would broaden the fishery forage base. Crayfish were stocked and monitored in a study cove on Saddle Island to determine if the Procambarus clarkii population could be enhanced. A trapping survey of the area after the following reproductive season yielded low numbers of crayfish. A comparison of pre-stocking and post-stocking catch per trap day (CPTD) values revealed no significant increase in the population. Procambarus clarkii growth is limited by environmental factors in Lake …

Stromatolites Of The Lower Cambrian Deep Spring Formation; Mount Dunfee, Esmeralda County, Nevada, Lynn Oliver

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Middle Member of the Lower Cambrian Deep Spring Formation at Mount Dunfee, Nevada contains a diverse assemblage of stromatolites that formed on a tide- and storm-dominated, siliciclastic-influenced, carbonate shelf. The stromatolites formed in a shallow subtidal environment within and near active oolite shoals under strongly focused currents. The stromatolites occur in four different lithofacies: (1) bioherms of digitate stromatolites, (2) bioherms and biostromes of inclined stromatolites, (3) isolated forms of massive and hemispheroidal stromatolites, and (4) a biostrome of cryptomicrobial boundstones. The first three lithofacies are interpreted as microbial reefs. They had topographic relief, formed in active agitated waters, …

Effects Of Ambient Lake Mohave Temperatures On Development, Oxygen Consumption, And Hatching Success Of The Razorback Sucker, Michael A. Bozek, Larry J. Paulson, Gene R. Wilde

Publications (WR)

Spawning of razorback suckers, Xyrauchen texanus, in Lake Mohave occurred from 10-22° C and larvae were collected at water temperatures from 10-15° C in 1982 and 1983. In the laboratory, hatching success was similar from 12-20° C, but reduced hatching success was found at 10° C while none hatched at 8°C. Development rate and oxygen consumption were positively related to incubation temperature. Direct effects of ambient Lake Mohave water temperatures on hatching success of razorback sucker embryos are considered minimal. Historical spawning temperatures for the species are hypothesized based upon successful incubation temperatures and comparison to the white sucker, …

Introduction And Enhancement Of Vegetative Cover At Lake Mead, Jennifer S. Haley, Lisa K. Croft, Suzanne E. Leavitt, Larry J. Paulson

Publications (WR)

Studies done by the Nevada Department of Wildlife (NDOW) and the Arizona Fish and Game between 1978 and 1981 indicate that inadequate cover may be limiting the production and survival of largemouth bass at the Lake Mead National Recreation Area (LMNRA). As a result of these studies, NDOW initiated a contract in 1986 with the Lake Mead Research Center (LMRC) to investigate means of improving habitat for game fish by introducing natural and/or artificial cover.

During Phase I (1986-1987) of this contract, the shoreline of Lake Mead was surveyed for aquatic and terrestrial plant growth. Also during this time, submerged …

Late-Holocene Earthflows Of The Willard Playa/Dune Complex, Estancia Valley, New Mexico: A Geomorphic Response To Climatic Change, Kurt A. Goebel

UNLV Theses, Dissertations, Professional Papers, and Capstones

Late-middle to late Holocene dune sediment that overlies Pleistocene lacustrine sediment marks the onset of xeric conditions in the Estancia Valley, central New Mexico. Incised into the underlying lacustrine sediments, the modern deflation basins are enclosed by parabolic dunes composed of clay and gypsum derived from the underlying sediment.

Located on the in-facing dune slopes of the deflation basins, the most striking geomorphic feature of this dune complex are numerous elongated scars. These relict scars document a geomorphically distinct earthflow event. Arroyos that cut into flow scars expose eolian earthflow sediment overlying lacustrine deposits. In the zone of depletion, erosional-flow …

Temporal And Spatial Patterns Of Abundance Of Age 0 Threadfin Shad (Dorosoma Petenense) In Overton Arm, Lake Mead, William Lee Pelle

Publications (WR)

Temporal and spatial patterns of age 0 threadfin shad (Dorosoma petenense) abundance and growth, in the Overton Arm of Lake Mead, were examined to evaluate the effects of resource availability on the young fish. This was part of a larger, game fishery enhancement study (Lake Mead Fertilization Project), designed to assess feasability of increasing survivorship of larval/juvenile shad by boosting phosphate levels, thereby increasing algal and zooplankton biomass, during the shad spawning period. Shad are the primary forage base for the striped bass (Morone saxatilis) and black bass (Macropterus salmoides) fisheries. Weekly samples were …

The Geology And Structural Significance Of The Arch Mountain Area, Northern Black Mountains, Mohave County, Arizona, Edward Eschner

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Arch Mountain area of northwestern Mohave County, Arizona, is typified by rocks that range from Precambrian to Quatemary in age. Arch mountain is a north-trending horst bounded on the west by the Petroglyph Wash graben and on the east by the Virgin Basin. A low-angle normal fault, herein named the Arch Mountain detachment fault, is exposed for 6 km along strike just below the ridge crest of Arch Mountain, and it is typified by a 2-20 cm thick zone of hematite-impregnated breccia and cataclasite. The detachment fault places an upper plate of Precambrian gneiss, Paleozoic quartzite, shale and dolomite, …

Total Maximum Daily Loads And Waste Load Allocations For Las Vegas Bay: Rationale And Calulations, State Of Nevada: Division Of Environmental Protection

Publications (WR)

In September 1987 the Nevada Division of Environmental Protection revised Water Quality Standards for Las Vegas Wash (LVW) and Lake Mead. Standards were set for chlorophyll-a and unionized ammonia in Las Vegas Bay (LVB) (NDEP 1987). The 1986 and 1987 LVB data showed non-achievement of both the chlorophyll-a and unionized ammonia standard which triggered an analysis of total phosphorus and total ammonia Total Maximum Daily Loads and Waste Load Allocations which are presented in this report.

This report is separated into three sections:

1. 1987 Las Vegas Bay Water Quality Conditions and Seasonal Periodicity.

2. Concentration Estimates at Northshore Road …

Limnological Monitoring Data For Lake Mead During 1988, Suzanne E. Leavitt, Larry J. Paulson, State Of Nevada: Division Of Environmental Protection

Publications (WR)

Limnological monitoring was conducted in Las Vegas Bay and Boulder Basin from April to December of 1988. The purpose of the monitoring was to (i) document possible changes in water quality resulting from decreased phosphorus loading and increased ammonia in Las Vegas Wash, and (ii) establish a data base for evaluating the adequacy of water quality standards.

Red Swamp Crayfish Ecology In Lake Mead, Suzanne E. Leavitt, Jennifer Stephens Haley, Mikell Hager, Donald H. Baepler, Nevada Department Of Wildlife

Publications (WR)

Red swamp crayfish (Procambarus clarkii) were trapped in Flamingo Wash, an urban wash of Las Vegas, during four periods of 1988. Life history and reproductive success were determined. The trapped crayfish were marked and released into a study cove in Lake Mead as part of an experimental stocking program. Retrap data from the study cove were used to determine life history, habitat preferences, and movement patterns of the stocked crayfish. In addition, a literature search was done on red swamp crayfish ecology, including food preferences, life history, habitat preferences and fish predation.

Riparian Plant Water Relations Along The North Fork Of The Kings River, California, J. L. Nachlinger, S. D. Smith, R. J. Risser

Life Sciences Faculty Research

Plant water relations of five obligate ripar-ian species were studied along California's North Fork Kings River. Diurnal stomatal conductance, transpi-ration, and xylem pressure potentials were measured throughout the 1986 growing season and in mid-season in 1987. Patterns were similar for all species although absolute values varied considerably. Maximum stomatal conductance occurred early in the day and season during favorable environmental conditions and decreased as air temperature and the vapor pressure difference between the leaf and air increased. Maximum transpiration rates occurred in mid-morning and mid-summer resulting in estimated daily water losses per unit sunlit leaf area of 163-328 mol H2O …

Water Relations Of Obligate Riparian Plants As A Function Of Streamflow Diversion On The Bishop Creek Watershed, S. D. Smith, J. L. Nachlinger, A. B. Wellington, C. A. Fox

Life Sciences Faculty Research

We investigated the water relations of obli-gate riparian plants on paired diverted and undiverted reaches on Bishop Creek, Eastern Sierra Nevada. Ri-parian plants on diverted reaches had reduced stomatal conductance and water potential compared to plants on undiverted reaches in a dry year, but not in a high runoff year. Juvenile plants on diverted reaches had reduced stomatal conductance and lower midday water potentials relative to surrounding mature trees, a trend that was not observed on undiverted reaches. Plants on diverted reaches possessed significantly smaller, thicker leaves and a reduced total leaf area relative to trees on streamside reaches. Reduced …

An Isotopic Analysis Of The Hydrology And Riparian Vegetation Water Sources On Bishop Creek, M. L. Space, J. W. Hess, S. D. Smith

Life Sciences Faculty Research

Five power generation plants along an eleven kilometer stretch divert Bishop Creek water for hydro-electric power. Stream diversion may be adversely affecting the riparian vegetation. Stable isotopic analysis is employed to determine surface water/ground-water interactions along the creek. surface water originates primarily from three headwater lakes. Discharge into Bishop Creek below the headwaters is primarily derived from ground water. The average δD and δ18O values are significantly different for surface water and ground water that an isotopic analysis can delineate between these two components of flow. Therefore isotopic shifts along the creek can determine gaining reaches. In addition, by knowing …

Temporal And Spatial Variation In Pelagic Fish Abundance In Lake Mead Determined From Echograms, Gene R. Wilde, Larry J. Paulson

Publications (WR)

Echograms have been used extensively to locate and estimate the relative abundance of marine fish stocks (Cushing 1973). In freshwater, echograms have been used to describe vertical (Netsch et al. 1971; Eggers 1978; O'Brien et al. 1984; Matthews et al. 1985), spatial (O'Brien et al. 1984; Wanjala et al. 1986) and temporal (Baker and Paulson 1983) patterns in fish abundance. Although most uses of echograms have been qualitative, Mullan and Applegate (1969) and Matthews et al. (1985) obtained relative estimates of fish abundance by counting targets (fish) on echograms. However, neither Mullan and Applegate (1969) nor Matthews et al. (1985) …

Characterization Of The Aquatic Environment In Lake Mead Near The Proposed Spring Canyon Pumped-Storage Project, And Assessment Of Potential Aquatic Impacts, Charles R. Liston, Stephen J. Grabowski, Bureau Of Reclamation

Publications (WR)

A pumped storage system consists of an upper reservoir and lower reservoir separated by an elevation difference. During low demand energy periods such as nights and weekends water is pumped from the lower to the upper reservoir using available energy from conventional steam electric power plants. During high energy demand periods, such as mornings and afternoons of weekdays, upper reservoir water is allowed to drop back down through the same system of water conduits and turbines, generating electricity to conveniently meet abrupt electrical energy requirements. The same water turbines thus act both as pumps and as conventional hydroelectric turbines.

Because …

Environmental Assessment Of Las Vegas Wash And Lake Mead Artificial Wetlands Demonstration Project, John R. Baker, R. M. Gersberg, U.S. Environmental Protection Agency

Publications (WR)

The effective use of artificial wetlands for treatment of municipal wastewater is well documented; however, design and economic data for artificial wetlands development are limited (Gersberg et al., 1984a). This is due partly to regional differences in climate, soils, and vegetation and partly to the desired waste treatment. As a result, specific treatment levels and cost benefits relative to the use of an artificial wetlands for a particular site cannot be evaluated adequately without a pilot demonstration project. Las Vegas Wash receives sewage effluent from the Las Vegas metropolitan area and has been designated as a wetlands community park. Las …