Physical Sciences and Mathematics Commons^™

Synthesis Panel Presentation & Discussion, Ernie Estevez, Susan Bell, Shawn M. Landry, Aaron Brown, Lindsay Cross, Holly Greening

School of Geosciences Faculty and Staff Publications

No abstract provided.

Field Observations And Novel Methodologies For Carbon System Assessments In Coastal Waters, Bo Yang

USF Tampa Graduate Theses and Dissertations

Coastal zones receive massive terrestrial inputs of nutrients and organic matter, and play an important role in biogeochemical cycles. The interactions of river inputs, ocean currents, atmospheric exchanges, anthropogenic influences, and biologically active ecosystems make CO₂ system studies in coastal waters highly challenging. This work focuses on improving our understanding of the CO₂ system in coastal waters through (1) development of a new methodology for measurements of CO₂ system parameters in the field; (2) observations of large spatial and temporal CO₂ system variations in coastal waters; and (3) characterization of the influence of organics on CO …

Bio-Photoelectrochemical Solar Cells Incorporating Reaction Center And Reaction Center Plus Light Harvesting Complexes, Houman Yaghoubi

USF Tampa Graduate Theses and Dissertations

Harvesting solar energy can potentially be a promising solution to the energy crisis now and in the future. However, material and processing costs continue to be the most important limitations for the commercial devices. A key solution to these problems might lie within the development of bio-hybrid solar cells that seeks to mimic photosynthesis to harvest solar energy and to take advantage of the low material costs, negative carbon footprint, and material abundance. The bio-photoelectrochemical cell technologies exploit biomimetic means of energy conversion by utilizing plant-derived photosystems which can be inexpensive and ultimately the most sustainable alternative. Plants and photosynthetic …

Bayesian Inference On Longitudinal Semi-Continuous Substance Abuse/Dependence Symptoms Data, Dongyuan Xing

USF Tampa Graduate Theses and Dissertations

Substance use data such as alcohol drinking often contain a high proportion of zeros. In studies examining the alcohol consumption in college students, for instance, many students may not drink in the studied period, resulting in a number of zeros. Zero-inflated continuous data, also called semi continuous data, typically consist of a mixture of a degenerate distribution at the origin (zero) and a right-skewed, continuous distribution for the positive values. Ignoring the extreme non-normality in semi-continuous data may lead to substantially biased estimates and inference. Longitudinal or repeated measures of semi-continuous data present special challenges in statistical inference because of …

Photoacoustic Calorimetry Studies Of The Earliest Events In Horse Heart Cytochrome-C Folding, Tarah A. Word

USF Tampa Graduate Theses and Dissertations

The protein folding problem involves understanding how the tertiary structure of a protein is related to its primary structure. Hence, understanding the thermodynamics associated with the rate-limiting steps for the formation of the earliest events in folding is most crucial to understanding how proteins adopt native secondary and tertiary structures. In order to elucidate the mechanism and pattern of protein folding, an extensively studied protein, Cytochrome-c (Cc), was chosen as a folding system to obtain detailed time-resolved thermodynamic profiles for the earliest events in the protein folding process. Cytochrome-c is an ideal system for understanding the folding process for several …

Radial Versus Othogonal And Minimal Projections Onto Hyperplanes In L_4^3, Richard Alan Warner

USF Tampa Graduate Theses and Dissertations

In this thesis, we study the relationship between radial projections, and orthogonal and minimal projections in l_4^3. Specifically, we calculate the norm of the maximum radial projection and we prove that the hyperplane constant, with respect to the radial projection, is not achieved by a minimal projection in this space. We will also show our numerical results, obtained using computer software, and use them to approximate the norms of the radial, orthogonal, and minimal projections in l_4^3. Specifically, we show, numerically, that the maximum minimal projection is attained for ker{1,1,1} as well as compute the norms for the maximum radial …

Dual 7-Degree-Of-Freedom Robotic Arm Remote Teleoperation Using Haptic Devices, Yu-Cheng Wang

USF Tampa Graduate Theses and Dissertations

A teleoperated system of dual redundant manipulator will be controlled in this thesis. The robot used with the dual redundant manipulator in this thesis is Baxter. Baxter’s redundant robot arms are 7-degree-of-freedom arms. The problem that will be solved in this thesis is optimization of the 7-degree-of-freedom robot arms. The control algorithm of the 7-degree-of-freedom robot arms will be discussed and built. A simulation program will be built to test the control algorithm. Based on the control algorithm, a teleoperation system will be created for Baxter. The controller used is Omni, which is a six-joint haptic device. Omni will also …

Nanomechanical And Nanotribological Characterization Of Sub-Micron Polymeric Spheres, Himanshu Kumar Verma

USF Tampa Graduate Theses and Dissertations

Friction between nanoscale objects has been a subject of great interest and intense research effort for the last two decades. However, the vast majority of the work done in this area has focused upon the sliding friction between two rigid, atomically smooth surfaces. Thus the parameter most explored has been the corrugation in the atomic potentials and how this affects the force required to slide one object across another. In truth, many nanoscale objects whose translation force is of practical interest are more spherical in nature. We hypothesize that the factors that determine the translation force will be related, not …

Dead/Live Microbial Culture Technique, Michael Veri

USF Tampa Graduate Theses and Dissertations

New methodology has been utilized to provoke or increase targeted metabolic pathways in microbes. The low hanging fruit of natural products has been discovered over the last 50 years. To continue finding new metabolites to be used as possible drug candidates, methodology development such as those proposed herein are necessary. This methodology uses extracts from known pathogenic bacteria to elicit production of latent biosynthetic pathways from environmental bacterial isolates that may be active against the original pathogenic strains. A new compound, MAV-1 (1) of the diketopiperazine family (Figure 1) was isolated and identified utilizing these techniques. The structure of MAV-1 …

Insights Into The Challenges Of Modeling The Atmospheric Boundary Layer, Esa-Matti Tastula

USF Tampa Graduate Theses and Dissertations

This work approaches the topic of modeling the atmospheric boundary layer in four research projects, which are summarized below.

i) The diurnal cycles of near-surface meteorological parameters over Antarctic sea ice in six widely used atmospheric reanalyses were validated against observations from Ice Station Weddell. The station drifted from February through May 1992 and provided the most extensive set of meteorological observations ever collected in the Antarctic sea ice zone. For the radiative and turbulent surface fluxes, both the amplitude and shape of the diurnal cycles varied considerably among different reanalyses. Near-surface temperature, specific humidity, and wind speed in the …

Authentication Via Multiple Associated Devices, Jean-Baptiste Subils

USF Tampa Graduate Theses and Dissertations

This thesis presents a practical method of authentication utilizing multiple devices. The factors contributing to the practicality of the method are: the utilization of devices already commonly possessed by users and the amenability to being implemented on a wide variety of devices. The term “device” refers to anything able to perform cryptographic operations, store data, and communicate with another such device.

In the method presented herein, multiple devices need to be associated with a single user to provide this user an identity in the system. A public key infrastructure is used to provide this identity. Each of the devices associated …

Information Technology & Sustainability: An Empirical Study Of The Value Of The Building Automation System, Daphne Marie Simmonds

USF Tampa Graduate Theses and Dissertations

This study examines the environmental and economic effects of green information technology (IT). Green IT describes two sets of IT innovations: one set includes innovations that are implemented to reduce the environmental impact of IT services in organizations; and the other IT to reduce the environmental impact of other organizational processes. The two sets respond to the call for more environmentally friendly or “greener” organizational processes.

I developed and tested a preliminary model. The model applied the resource based view (RBV) of the firm (Wernerfelt 1984) the stakeholder theory (Freeman 1984) and included four constructs: (1) BAS implementation; environmental …

The Effect Of Urbanization On The Embodied Energy Of Drinking Water In Tampa, Florida, Mark Vincent Eli Santana

USF Tampa Graduate Theses and Dissertations

Increasing urbanization has serious implications for resource and energy use. One of these resources is drinking water. The increased amount of impervious surfaces associated with urban development is responsible for increased runoff during rain events, which may have a negative impact on the quality of nearby bodies of water, including drinking water sources. The growing populations associated with urbanization require a higher water demand. In addition, urban drinking water systems use energy to collect, treat, and distribute a safe reliable effluent to users. Therefore, this study focuses on the degree to which urbanization influences the embodied energy of drinking water …

Investigаtiоn Оf 3d Structures Оf Γ-Aaрeрtide Bаsed Peрtidоmimetics, Qiao Qiao

USF Tampa Graduate Theses and Dissertations

Oligomers which have a tendency to form well-defined secondary structures are called foldamers. They offer an attractive opportunity for the design of novel molecules that mimic the structures and functions of proteins and enzymes including biocatalysis and biomolecular recognition. Herein a new class of non-natural γ-AApeptides and their derivatives are synthesized and studied in our lab. Previous studies of γ-AApeptides have revealed that they are highly resistant to proteolysis, and have virtually limitless potential in functional group diversity. However, to improve the bio-activity and explore new bio-applications, the understanding of the folding conformation of γ-AApeptides are necessary. Thus, NMR spectroscopy …

Spatiotemporal Sensing And Informatics For Complex Systems Monitoring, Fault Identification And Root Cause Diagnostics, Gang Liu

USF Tampa Graduate Theses and Dissertations

In order to cope with system complexity and dynamic environments, modern industries are investing in a variety of sensor networks and data acquisition systems to increase information visibility. Multi-sensor systems bring the proliferation of high-dimensional functional Big Data that capture rich information on the evolving dynamics of natural and engineered processes. With spatially and temporally dense data readily available, there is an urgent need to develop advanced methodologies and associated tools that will enable and assist (i) the handling of the big data communicated by the contemporary complex systems, (ii) the extraction and identification of pertinent knowledge about the environmental …

Environmental Sustainability Of Wastewater Treatment Plants Integrated With Resource Recovery: The Impact Of Context And Scale, Pablo K. Cornejo

USF Tampa Graduate Theses and Dissertations

There is an urgent need for wastewater treatment plants (WWTPs) to adapt to a rise in water and energy demands, prolonged periods of drought, climate variability, and resource scarcity. As population increases, minimizing the carbon and energy footprints of wastewater treatment, while properly managing nutrients is crucial to improving the sustainability WWTPs. Integrated resource recovery can mitigate the environmental impact of wastewater treatment systems; however, the mitigation potential depends on various factors such as treatment technology, resource recovery strategy, and system size.

Amidst these challenges, this research seeks to investigate the environmental sustainability of wastewater treatment plants (WWTPs) integrating resource …

Effects Of Disorder And Low Dimensionality On Frozen Dynamics In Ca3co2-Xmnxo6, Brian Wesley Casas

USF Tampa Graduate Theses and Dissertations

Complex oxides represent an intersection of play grounds for the existence of exciting new fundamental physics and materials with potential technological implications. The realization of many exciting properties of these systems rely on the coupling of electronic, structural and magnetic degrees of freedom. Additionally, competing interactions within each type of coupling discussed previously lead to theoretically diverse ground states, which under the application of an external perturbation, can be tuned and probed.

Ca3Co¬2-xMnxO6 represent a quasi-one dimensional Ising spin chain system oriented in an antiferromagnetic triangular lattice. The exotic behavior of the undoped compound Ca3Co2O6 has inspired work on continuing …

A New Microenvironment For The Formation Of Clay Minerals: The Example Of Authigenic Halloysite-7Å And Gibbsite In A Stalactite From Agios Georgios Cave, Kilkis, North Greece, Elena Ifandi, Basilios Tsikouras, Dimitrios Papoulis, Konstantin Hatzipanagiotou, Aspasia Antonelou

International Journal of Speleology

An unusual authigenic origin for halloysite and gibbsite is reported in a stalactite from Agios Georgios Cave, Kilkis. This speleothem includes mostly pure calcite whereas minor areas of Mg-rich calcite and scarce dolomite are present in four growth phases. Abundant pores are created due to imperfect coalescence of the calcite crystals. Several of them contain detrital muscovite, which was presumably transferred from the dripping water, during the formation of speleothem and has been variably altered to halloysite. Several pores in the stalactite contain different mineral assemblages that we interpret as in situ: halloysite-7Å, halloysite + silica, gibbsite + silica and …

Speleogenesis Of The Hermannshöhle Cave System (Austria): Constraints From 230Th/U-Dating And Palaeomagnetic Analysis, Lukas Plan, Andrea Schober, Denis Scholz, Christoph Spötl, Petr Pruner, Pavel Bosák

International Journal of Speleology

Hermannshöhle is a show cave located near Kirchberg/Wechsel in Lower Austria. Together with three nearby and genetically connected caves, it forms the Hermannshöhlen cave system (HHS). With a length of 5 km, the HHS is the longest cave in the Lower Austroalpine unit. It is arranged as an extreme three-dimensional maze on a ground area of 200 x 200 x 82 m. Speleothems are abundant in this cave and represent the focus of this study. Low carbon isotope values indicate the presence of a soil-covered catchment above the HHS during times of speleothem deposition. 28 samples were dated by the …

Simulating A Multi-Phase Tephra Fall Event: Inversion Modelling For The 1707 Hoei Eruption Of Mount Fuji, Japan, Christina Magill, Kazutaka Mannen, Laura J. Connor, Costanza Bonadonna, Charles B. Connor

School of Geosciences Faculty and Staff Publications

Fuji Volcano last erupted in ad 1707 depositing approximately 40 mm of tephra in the area that is now central Tokyo. New high-resolution data describe 17 eruptive phases occurring over a period of 16 days (Miyaji et al., J Volcanol Geotherm Res 207(3–4):113–129, 2011). Inversion techniques were used in order to best replicate geological data and eyewitness accounts, and to estimate eruption source parameters. Inversion results based on data from individual eruptive phases suggest a total erupted mass of 2.09 × 1012 kg. Comparatively, results based on a single data set describing the entire eruption sequence suggest a total …

Finite Element Modelling Predicts Changes In Joint Shape And Cell Behaviour Due To Loss Of Muscle Strain In Jaw Development, Lucy H. Brunt, Joanna L. Norton, Jen A. Bright, Emily J. Rayfield, Chrissy L. Hammond

School of Geosciences Faculty and Staff Publications

Abnormal joint morphogenesis is linked to clinical conditions such as Developmental Dysplasia of the Hip (DDH) and to osteoarthritis (OA). Muscle activity is known to be important during the developmental process of joint morphogenesis. However, less is known about how this mechanical stimulus affects the behaviour of joint cells to generate altered morphology. Using zebrafish, in which we can image all joint musculoskeletal tissues at high resolution, we show that removal of muscle activity through anaesthetisation or genetic manipulation causes a change to the shape of the joint between the Meckel's cartilage and Palatoquadrate (the jaw joint), such that the …

Late Quaternary Speleogenesis And Landscape Evolution In A Tropical Carbonate Island: Pango La Kuumbi (Kuumbi Cave), Zanzibar, Nikos Kourampas, Ceri Shipton, William Mills, Ruth Tibesasa, Henrietta Horton, Mark Horton, Mary Prendergast, Alison Crowther, Katerina Douka, Patrick Faulkner, Llorenç Picornell, Nicole Boivin

International Journal of Speleology

Kuumbi Cave is one of a group of caves that underlie a flight of marine terraces in Pleistocene limestone in eastern Zanzibar (Indian Ocean). Drawing on the findings of geoarchaeological field survey and archaeological excavation, we discuss the formation and evolution of Kuumbi Cave and its wider littoral landscape. In the later part of the Quaternary (last ca. 250,000 years?), speleogenesis and terrace formation were driven by the interplay between glacioeustatic sea level change and crustal uplift at rates of ca. 0.10-0.20 mm/yr. Two units of backreef/reef limestone were deposited during ‘optimal’ (highest) highstands, tentatively correlated with MIS 7 and …

Shaw T. & Alenka ČUk, 2015. Slovene Karst And Caves In The Past, Arrigo A. Cigna

International Journal of Speleology

No abstract provided.

Large-Scale And High-Resolution 3-D Cave Mapping By Terrestrial Laser Scanning: A Case Study Of The Domica Cave, Slovakia, Michal Gallay, Ján Kaňuk, Zdenko Hochmuth, John D. Meneely, Jaroslav Hofierka, Vladimír Sedlák

International Journal of Speleology

Mapping and modelling the complicated geometry of caves is a challenging task that has traditionally been undertaken by tacheometric surveying methods. These methods are excellent for capturing the general shape of a cave system but they are not suitable for high-speed, high-resolution mapping of complex surfaces found in this environment. Terrestrial laser scanning (TLS) technologies can acquire millions of points represented by 3-D coordinates, at very high spatial densities on complex multifaceted surfaces within minutes. In the last few years, advances in measurement speed, reduction in size / cost and increased portability of this technology has revolutionised the collection of …

Space Geodetic Observation Of The Deformation Cycle Across The Ballenas Transform, Gulf Of California, Christina Plattner, Rocco Malservisi, Falk Amelung, Timothy H. Dixon, Matthias Hackl, Alessandro Verdecchia, Peter Lonsdale, Francisco Suarez-Vidal, Javier Gonzalez-Garcia

School of Geosciences Faculty and Staff Publications

The Gulf of California, Mexico, accommodates ~90% of North America‐Pacific plate relative motion. While most of this motion occurs on marine transform faults and spreading centers, several fault segments in the central Gulf come close to peninsular Baja California. Here we present Global Positioning System and interferometric synthetic aperture radar data near the Ballenas transform fault, separating the peninsula from Angel de la Guarda Island. We observe interseismic motion between June 2004 and May 2009 and displacements associated with the 3 August 2009 Mw 6.9 earthquake. From the interseismic data we estimate a locking depth of 9–12.5 km and a …

Underground Fieldwork – A Cultural And Social History Of Cave Cartography And Surveying Instruments In The 19th And At The Beginning Of The 20th Century, Johannes Mattes

International Journal of Speleology

At the turn of the 20^th century, the practical examination of caves went through a radical change. Governmental organizations and private clubs were founded in an attempt to establish speleology as an independent academic subject. In contrast to earlier cave visitors, travelers began entering underground areas and attributing the names of “explorers” or “researchers” to themselves. Fieldwork—especially cave surveying and cartography—became common practice in speleology and such work provided important clues on speleogenesis, which was a controversial issue in the first half of the 20^th century. Due to the fact that speleologists began separating themselves from ordinary …

Review Of Developing Quantitative Literacy Skills In History And The Social Sciences: A Web-Based Common Core Approach By Kathleen W. Craver, Victor J. Ricchezza, H L. Vacher

Numeracy

Kathleen W. Craver. Developing Quantitative Literacy Skills in History and Social Sciences: A Web-Based Common Core Standards Approach (Lantham MD: Rowman & Littlefield Publishing Group, Inc., 2014). 191 pp.
ISBN 978-1-4758-1050-9 (cloth); ISBN …-1051-6 (pbk); ISBN…-1052-3 (electronic).

This book could be a breakthrough for teachers in the trenches who are interested in or need to know about quantitative literacy (QL). It is a resource providing 85 topical pieces, averaging 1.5 pages, in which a featured Web site is presented, described, and accompanied by 2-4 critical-thinking questions purposefully drawing on data from the Web site. The featured Web sites range from …

Mathematics And Humor: John Allen Paulos And The Numeracy Crusade, Paul H. Grawe

Numeracy

John Allen Paulos at minimum gave the Numeracy movement a name through his book Innumeracy: Mathematical Illiteracy and Its Consequences. What may not be so obvious was Paulos’ strong interest in the relationship between mathematics and mathematicians on the one hand and humor and stand-up-comedian joke structures on the other. Innumeracy itself could be seen as a typically mathematical Gotcha joke on American culture generally. In this perspective, a Minnesotan acculturated to Minnesota-Nice Humor of Self-Immolation Proclivities (SImP) looks at the more raw-boned, take-no-prisoners humor style Paulos outlined in Mathematics and Humor and implemented in Innumeracy.

Despite the …

The Math You Need, When You Need It (Tmyn): Leveling The Playing Field, Jennifer M. Wenner, Eric M. D. Baer

Numeracy

The Math You Need, When You Need It (TMYN) is a set of online tutorials designed to help students develop and review mathematical skills that are applied in undergraduate geoscience courses. We present results of a three-year study of more than 4000 students in 106 geoscience courses at a variety of post-secondary schools who were assigned TMYN tutorials as supplemental mathematics instruction. Changes in student scores from pre- to post-test suggest that the support provided by programs such as TMYN can begin to reduce the gap between mathematically well-prepared and underprepared students; in essence, TMYN levels the quantitative playing field …

The Levels Of Conceptual Understanding In Statistics (Locus) Project: Results Of The Pilot Study, Douglas Whitaker, Steven Foti, Tim Jacobbe

Numeracy

The Levels of Conceptual Understanding in Statistics (LOCUS) project (NSF DRL-111868) has created assessments that measure conceptual (rather than procedural) understanding of statistics as outlined in GAISE Framework (Franklin et al., 2007, Guidelines for Assessment and Instruction in Statistics Education, American Statistical Association). Here we provide a brief overview of the LOCUS project and present results from multiple-choice items on the pilot administration of the assessments with data collected from over 3400 students in grades 6-12 across six states. These results help illustrate students’ understanding of statistical topics prior to the implementation of the Common Core State Standards. Using the …