Physical Sciences and Mathematics Commons^™

Nearest Neighbor Foreign Exchange Rate Forecasting With Mahalanobis Distance, Vindya Kumari Pathirana

USF Tampa Graduate Theses and Dissertations

Foreign exchange (FX) rate forecasting has been a challenging area of study in the past. Various linear and nonlinear methods have been used to forecast FX rates. As the currency data are nonlinear and highly correlated, forecasting through nonlinear dynamical systems is becoming more relevant. The nearest neighbor (NN) algorithm is one of the most commonly used nonlinear pattern recognition and forecasting methods that outperforms the available linear forecasting methods for the high frequency foreign exchange data. The basic idea behind the NN is to capture the local behavior of the data by selecting the instances having similar dynamic behavior. …

Assessment Of Public Health Risks Associated With Petrochemical Emissions Surrounding An Oil Refinery, Erin L. Pulster

USF Tampa Graduate Theses and Dissertations

Refinery operations have been associated with a wide variety of atmospheric emissions consisting of criteria air pollutants, volatile organic components, hazardous air pollutants as well as other pollutants. With approximately 100 oil refineries in the Wider Caribbean region (WCR), hydrocarbons in this region pose significant environmental and human health risks. One of the oldest and largest refineries in the WCR is the Isla Refineriá, which is located on the island of Curaçao, and has been the basis of historical debates and conflict between the public and the local government over the environmental and human health risks. This research aims to …

Modeling Intrusive Geometries Of A Shallow Crustal Intrusion: New Evidence From Mount Ellsworth, Utah, Nathan Nushart

USF Tampa Graduate Theses and Dissertations

Surface displacements resulting from upper-crustal intrusion of melt are a paramount concern for communities and facilities located in or near active volcanic areas (e.g. Campi Flegrei, Yucca Mtn.). Study of active intrusions such as Campi Flegrei, Italy west of Mt. Vesuvius, is limited to remote observations through geophysical/geodetic procedures. While the surface displacement due to melt emplacement at depth can easily be determined, the geometries and depth of intrusions are often based on simplified assumptions (e.g. spheres and prolate or oblate ellipsoids). These models benefit from data constraining both the geometries of the individual intrusions, and the kinematics and mechanics …

Theoretical Investigations Of Gas Sorption And Separation In Metal-Organic Materials, Tony Pham

USF Tampa Graduate Theses and Dissertations

Metal--organic frameworks (MOFs) are porous crystalline materials that are synthesized from rigid organic ligands and metal-containing clusters. They are highly tunable as a number of different structures can be made by simply changing the organic ligand and/or metal ion. MOFs are a promising class of materials for many energy-related applications, including H₂ storage and CO₂ capture and sequestration. Computational studies can provide insights into MOFs and the mechanism of gas sorption and separation. Theoretical studies on existing MOFs are performed to determine what structural characteristics leads to favorable gas sorption mechanisms. The results from these studies can provide …

Organic-Inorganic Hybrid Materials Based On Oxyanion Linkers For Selective Adsorption Of Polarizable Gases, Mona Hanafy Mohamed

USF Tampa Graduate Theses and Dissertations

The separation of industrially important gases into pure supplies that can be used for many practical applications is based mainly on energy intensive methods such as the cryogenic distillation which is costly and energy intensive. Therefore other routes have been introduced to industrial separation of gases such as the selective adsorption using porous solid materials. Zeolites and activated carbon are the most widely used recyclable energy-efficient porous solid materials for industrial gas separations, however the low uptake and selectivity hurdles their commercialization in some separation applications. Metal organic frameworks (MOFs) have been extensively studied as solid porous materials in term …

Ground-Coupled Air Waves: A Seismological Case Study Of The Explosion Quakes Of The 2007 Eruption Of Pavlof Volcano, Alaska, Cassandra Marie Smith

USF Tampa Graduate Theses and Dissertations

An abnormally high number of explosion quakes were noted during the monitoring effort for the 2007 eruption of Pavlof Volcano on the Alaskan Peninsula. In this study we manually counted the explosion quakes from their characteristic ground-coupled air waves. This study makes an effort at better quantifying the number of explosion quakes and how the characteristic ground-coupled air waves are affected by wind direction and wind speed. Additionally this study investigates how the ground coupled air waves might be used in a monitoring or analysis effort by calculating energy release and gas mass release. Over 3.2x10⁴ quakes were recorded. …

Biosynthesis Of Long-Chain Fatty Acid Amides, Kristen A. Jeffries

USF Tampa Graduate Theses and Dissertations

The vast variety of long-chain fatty acid amides identified in biological systems is intriguing. The general structure of a fatty acid amide is R-CO-NH-X, where R is an alkyl group and X is derived from an immense variety of biogenic amines. Although structurally simple, the bioactivities of these molecules as signaling lipids are very diverse and have just recently begun to emerge in the literature. Interest in the long-chain fatty acid amides dramatically increased following the identification and characterization of one specific N-acylethanolamine, N-arachidonoylethanolamine (anandamide), as the endogenous ligand for the cannabinoid receptors in the mammalian brain. Since …

A Composite Spatial Model Incorporating Groundwater Vulnerability And Environmental Disturbance To Guide Land Management, Johanna L. Kovarik

USF Tampa Graduate Theses and Dissertations

Research has long recognized and studied the dynamics of groundwater processes. More recently, groundwater dependent ecosystems (GDEs) are being recognized for their diversity and vulnerability to anthropogenic impact. Groundwater in karst landscapes presents a distinctive situation where flow through the subsurface often moves rapidly on the scale of days and weeks as opposed to years or millennia in other systems. This distinctive situation of karst systems and their vulnerability to human impacts necessitate an integrated and multifaceted approach for the management of these important resources. However, development of such an approach is complicated by the difficulty of obtaining detailed data …

Glaciological Applications Of Terrestrial Radar Interferometry, Denis Voytenko

USF Tampa Graduate Theses and Dissertations

Terrestrial Radar Interferometry (TRI) is a relatively new ground-based technique that combines the precision and spatial resolution of satellite interferometry with the temporal resolution of GPS. Although TRI has been applied to a variety of fields including bridge and landslide monitoring, it is ideal for studies of the highly-dynamic terminal zones of marine-terminating glaciers, some of which are known to have variable velocities related to calving and/or ocean-forced melting. My TRI instrument is the Gamma Portable Radar Interferometer, which operates at 17.2 GHz (1.74 cm wavelength), has two receiving antennas for DEM (digital elevation model) generation, and images the scenes …

Enhanced Magnetoimpedance And Microwave Absorption Responses Of Soft Ferromagnetic Materials For Biodetection And Energy Sensing, Jagannath Devkota

USF Tampa Graduate Theses and Dissertations

A combination of magnetic sensors with magnetic nanoparticles offers a promising approach for highly sensitive, simple, and rapid detection of cancer cells and biomolecules. The challenge facing the field of magnetic biosensing is the development of low-cost devices capable of superconducting quantum interference device (SQUID)-like field sensitivity at room temperature. In another area of interest, improving the sensitivity of existing electromagnetic field sensors for microwave energy sensing applications is an important and challenging task. In this dissertation, we have explored the excellent magnetoimpedance and microwave absorption responses of soft ferromagnetic amorphous ribbons and microwires for the development of high-performance magnetic …

Metal Organic Frameworks (Mofs) And Porous Organic Polymers (Pops) For Heterogeneous Asymmetric Catalysis, Youngran Ji

USF Tampa Graduate Theses and Dissertations

The administration of enantiopure drugs brings advantages such as improved efficacy, more predictable pharmacokinetics and reduced toxicity from the point of view of the pharmaceutical area.[1] For this reason, a tremendous amount of supply and demand for enantiomeric pure compounds has been shown not only in market, but industry and academia.[^2-4] According to the industry publication Genetic Engineering and Biotechnology News (GEN) in 2014, 22 billion dollars were accounted for enantiopure form of drugs such as Sovaldi® (Sofosbuvir), Crestor® (Rosuvastatin), and Advair® (fluticasone/salmeterol).

The fact that one enantiomer can be pharmacologically effective whereas the other enantiomer can be …

Development Of Orally Bioavailable 4(1H)-Quinolones And 1,2,3,4-Tetrahydroacridin-9(10H)-Ones With Potent Anti-Malarial Activity, Jordany Richarlson Maignan

USF Tampa Graduate Theses and Dissertations

Although Malaria rates are on the decline due to the efforts of the World Health Organization and other organizations dedicated to the eradication of this disease, a relaxed attitude towards the development of new antimalarial entities would be flawed. Due to the emergence of resistance in the parasite, the almost 50% world-wide reduction in malarial death rates that have been produced over the past 15 years are threatening to be lost

New drugs are urgently needed and our approach focuses on the re-evaluation and optimization of the historic antimalarial ICI 56,780. Due to its causal prophylactic activity, along with its …

Low Dimensionality Effects In Complex Magnetic Oxides, Paula J. Lampen Kelley

USF Tampa Graduate Theses and Dissertations

Complex magnetic oxides represent a unique intersection of immense technological importance and fascinating physical phenomena originating from interwoven structural, electronic and magnetic degrees of freedom. The resulting energetically close competing orders can be controllably selected through external fields. Competing interactions and disorder represent an additional opportunity to systematically manipulate the properties of pure magnetic systems, leading to frustration, glassiness, and other novel phenomena while finite sample dimension plays a similar role in systems with long-range cooperative effects or large correlation lengths. A rigorous understanding of these effects in strongly correlated oxides is key to manipulating their functionality and device performance, …

Mapping Robinia Pseudoacacia Forest Health Conditions By Using Combined Spectral, Spatial, And Textural Information Extracted From Ikonos Imagery And Random Forest Classifier, Hong Wang, Yu Zhao, Ruiliang Pu

School of Geosciences Faculty and Staff Publications

The textural and spatial information extracted from very high resolution (VHR) remote sensing imagery provides complementary information for applications in which the spectral information is not sufficient for identification of spectrally similar landscape features. In this study grey-level co-occurrence matrix (GLCM) textures and a local statistical analysis Getis statistic (Gi), computed from IKONOS multispectral (MS) imagery acquired from the Yellow River Delta in China, along with a random forest (RF) classifier, were used to discriminate Robina pseudoacacia tree health levels. Specifically, eight GLCM texture features (mean, variance, homogeneity, dissimilarity, contrast, entropy, angular second moment, and correlation) were first calculated from …

Multi-Year Observations Of Breiðamerkurjökull, A Marine-Terminating Glacier In Southeastern Iceland, Using Terrestrial Radar Interferometry, Denis Voytenko, Timothy H. Dixon, Ian M. Howat, Noel Gourmelen, Chad Lembke, Charles L. Werner, Santiago De La Peña, Björn Oddsson

School of Geosciences Faculty and Staff Publications

Terrestrial radar interferometry (TRI) is a new technique for studying ice motion and volume change of glaciers. TRI is especially useful for temporally and spatially dense measurements of highly dynamic glacial termini. We conducted a TRI survey of Breiðamerkurjökull, a marine-terminating glacier in Iceland, imaging its terminus near the end of the melt season in 2011, 2012 and 2013. The ice velocities were as high as 5 m d−1, with the fastest velocities near the calving front. Retreat of the glacier over the 3 year observation period was accompanied by strong embayment formation. Iceberg tracking with the radar shows high …

Did Shell-Crushing Crabs Trigger An Escalatory Arms Race In The Aftermath Of A Late Neogene Regional Mass Extinction Event? An Experimental Test, Lisa B. Whitenack, Gregory S. Herbert

School of Geosciences Faculty and Staff Publications

A regional mass extinction event in the late Neogene western Atlantic is widely thought to have generated evolutionary opportunities for survivors, including enemy-related adaptation (escalation). The Strombus alatus species complex is one potential example of this phenomenon. Strombid gastropods are abundant in the Plio-Pleistocene fossil record and Recent in subtropical Florida, and the percentage of these shells bearing a row of short spines on the last whorl increased from nearly zero to almost 100% over this time. As shell ornamentation is one of the most frequently cited defenses against both peeling and crushing predators, we exposed live spined and spineless …

Groundwater Lowering And Stream Incision Rates In The Central Appalachian Mountains Of West Virginia, Usa, Gregory S. Springer, Holly A. Poston, Ben Hardt, Harold D. Rowe

International Journal of Speleology

Surface channel incision rates are of broad geomorphological interest because they set the boundary conditions for landscape change by affecting changes in local relief and hillslope angles. We report groundwater table lowering rates associated with subsurface Buckeye Creek and the surface channel of Spring Creek in southeastern West Virginia, USA. The mountainous watersheds have drainage areas of 14 km² and 171 km², respectively. The lowering rates are derived from U/Th-dating of stalagmites and the paleomagnetostratigraphy of clastic sediments in Buckeye Creek Cave. The oldest stalagmites have a minimum age of 0.54 Ma and we use a minimum …

Kirkland D.W., 2014 - Role Of Hydrogen Sulfide In The Formation Of Cave And Karst Phenomena In The Guadalupe Mountains And Western Delaware Basin, New Mexico And Texas, Leslie A. Melim

International Journal of Speleology

No abstract provided.

Radiaxial-Fibrous And Fascicular-Optic Mg-Calcitic Cave Cements: A Characterization Using Electron Backscattered Diffraction (Ebsd), Detlev K. Richter, Adrian Immenhauser, Rolf Dieter Neuser, Augusto Mangini

International Journal of Speleology

Electron backscattered diffraction (EBSD) applied to crystal fabric research in speleothems aids in our understanding of the origin of those fabrics. A significant advantage of this approach is the three dimensional data set of crystal c-axes. Here, we show a rare case of both convergent (radiaxial-fibrous) and divergent (fascicular-optic) orientations of the c-axes in pool calcites. The seemingly defective structure of the calcite lattice resulting in radiaxial-fibrous crystal orientations is probably caused by differential incorporation of Mg during crystal growth. The observation that radiaxial-fibrous and fascicular-optic fabrics co-exist in the same pool environment is remarkable and documents the complexity of …

Structural And Hydrological Controls On The Development Of A River Cave In Marble (Tapagem Cave - Se Brazil), William Sallun Filho, Bruna Medeiros Cordeiro, Ivo Karmann

International Journal of Speleology

Tapagem Cave (or Devil’s Cave) is a river cave developed in the dolomite marble karst of the Serra do André Lopes (State of São Paulo, southeastern Brazil). Although this region is a plateau with significant variation in elevation and a humid subtropical climate, the cave is an anomalous feature in the André Lopes karst because there are few other caves. The marble, which is in a synclinal structure with subjacent phyllites, is a karst aquifer perched above the regional base level (Ribeira River) and has little allogenic recharge. The cave developed on a secondary anticline on the northwest flank of …

Speleoclimate Dynamics In Santana Cave (Petar, São Paulo State, Brazil): General Characterization And Implications For Tourist Management, Heros Augusto Santos Lobo, Paulo Cesar Boggiani, José Alexandre De Jesus Perinotto

International Journal of Speleology

Show caves provide tourists with the opportunity to have close contact with natural underground spaces. However, visitation to these places also creates a need for management measures, mainly the definition of tourist carrying capacity. The present work describes the results of climate monitoring and atmospheric profiling performed in Santana Cave (Alto Ribeira State and Tourist Park – PETAR, Brazil) between 2008 and 2011. Based on the results, distinct preliminary zones with different levels of thermal variation were identified, which classify Santana Cave as a warm trap. Two critical points along the tourist route (Cristo and Encontro Halls) were identified where …

A Study Of Fe3O4 Magnetic Nanoparticle Rf Heating In Gellan Gum Polymer Under Various Experimental Conditions For Potential Application In Drug Delivery, Gabriel Marcus

USF Tampa Graduate Theses and Dissertations

Magnetic nanoparticles (MNPs) have found use in a wide variety of biomedical applications including hyperthermia, imaging and drug delivery. Certain physical properties, such as the ability to generate heat in response to an alternating magnetic field, make these structures ideal for such purposes. This study's objective was to elucidate the mechanisms primarily responsible for RF MNP heating and determine how such processes affect polymer solutions that might be useful in drug delivery. 15-20 nm magnetite (Fe₃O₄) nanoparticles at 0.2% and 0.5% concentrations were heated with RF fields of different strengths (200 Oe, 400 Oe and 600 …

Earthquake And Tsunami Forecasts: Relation Of Slow Slip Events To Subsequent Earthquake Rupture, Timothy H. Dixon, Yan Jiang, Rocco Malservisi, Robert Mccaffrey, Nicholas Voss, Marino Protti, Victor Gonzalez

School of Geosciences Faculty and Staff Publications

The 5 September 2012 Mw 7.6 earthquake on the Costa Rica subduction plate boundary followed a 62-y interseismic period. High-precision GPS recorded numerous slow slip events (SSEs) in the decade leading up to the earthquake, both up-dip and down-dip of seismic rupture. Deeper SSEs were larger than shallower ones and, if characteristic of the interseismic period, release most locking down-dip of the earthquake, limiting down-dip rupture and earthquake magnitude. Shallower SSEs were smaller, accounting for some but not all interseismic locking. One SSE occurred several months before the earthquake, but changes in Mohr–Coulomb failure stress were probably too small to …

Range Of Horizontal Transport And Residence Time Of Nitrate In A Mature Karst Vadose Zone, Jiri Kamas, Jiri Bruthans, Helena Vysoka, Miroslav Kovařík

International Journal of Speleology

Nitrate concentrations in drips in Amaterska, Spolecnak, and Holstejnska caves situated below a 25 to 120 m thick vadose zone in the Moravian Karst, Central Europe were studied during several periods from 1992. Each cave runs below a land-use boundary between fertilized lands and forest, which enabled study of the range of horizontal components of nitrate transport in the vadose zone. Parts of the fertilized land were turned into grassland in 1998 and 2003, and the cave drips were sampled both prior and after the changes in land use. The mean residence time of nitrate is - 30 m thick …

Hairy Stalagmites, A New Biogenic Root Speleothem From Botswana, Gerhard C. Du Preez, Paolo Forti, Gerhard Jacobs, Anine Jordaan, Louwrens Tiedt

International Journal of Speleology

Ngamiland in northwestern Botswana hosts the Gcwihaba Caves which present unique subterranean environments and host speleothems never before recorded. Cave atmospheric conditions can be extreme with temperatures as high as 28°C and relative humidity nearing 99.9%. Within Dimapo and Diviner’s Caves peculiar root speleothems that we named ‘Hairy Stalagmites’ were found. These stalagmites are closely associated with the roots of Namaqua fig (Ficus cordata) trees that enter the cave environment in search of water. Pieces of broken stalagmites were sampled from Dimapo Cave for further investigations. Stereo and electron microscopy revealed that the Hairy Stalagmites consist of multiple …

High-Resolution Digital 3d Models Of Algar Do Penico Chamber: Limitations, Challenges, And Potential, Ivo Silvestre M.Sc., José I. Rodrigues Phd, Mauro Figueiredo Phd, Cristina Veiga-Pires Phd

International Journal of Speleology

The study of karst and its geomorphological structures is important for understanding the relationships between hydrology and climate over geological time. In that context, we conducted a terrestrial laser-scan survey to map geomorphological structures in the karst cave of Algar do Penico in southern Portugal. The point cloud data set obtained was used to generate 3D meshes with different levels of detail, allowing the limitations of mapping capabilities to be explored.

In addition to cave mapping, the study focuses on 3D-mesh analysis, including the development of two algorithms for determination of stalactite extremities and contour lines, and on the interactive …

Chemistry Graduate Teaching Assistants' Experiences In Academic Laboratories And Development Of A Teaching Self-Image, Todd Adam Gatlin

USF Tampa Graduate Theses and Dissertations

Graduate teaching assistants (GTAs) play a prominent role in chemistry laboratory instruction at research based universities. They teach almost all undergraduate chemistry laboratory courses. However, their role in laboratory instruction has often been overlooked in educational research. Interest in chemistry GTAs has been placed on training and their perceived expectations, but less attention has been paid to their experiences or their potential benefits from teaching.

This work was designed to investigate GTAs' experiences in and benefits from laboratory instructional environments. This dissertation includes three related studies on GTAs' experiences teaching in general chemistry laboratories. Qualitative methods were used for each …

Can Xrf Scanning Of Speleothems Be Used As A Non-Destructive Method To Identify Paleoflood Events In Caves?, Martin Finné, Malin Kylander, Meighan Boyd, Hanna S. Sundqvist, Ludvig Löwemark

International Journal of Speleology

We have developed a novel, quick and non-destructive method for tracing flood events in caves through the analysis of a stalagmite thick section with an XRF core scanner. The analyzed stalagmite has multiple horizons of fine sediments from past flood events intercalated with areas of cleaner calcite. Flood events detected from the elemental XRF core scanning data show good agreement with the position of flood horizons identified in petrographic thin sections. The geochemical composition of the individual flood layers shows that in certain cases the clay horizons had a distinct geochemical fingerprint suggesting that it may be possible to distinguish …

Microstratigraphic Logging Of Calcite Fabrics In Speleothems As Tool For Palaeoclimate Studies, Silvia Frisia

International Journal of Speleology

The systematic documentation of calcite fabrics in stalagmites and flowstones provides robustness to palaeoclimate interpretation based on geochemical proxies, but it has been neglected because it is difficult to transform crystal morphologies into numerical values, and construct fabric time series. Here, general criteria that allow for coding fabrics of calcite composing stalagmites and flowstones is provided. Being based on known models of fabric development, the coding ascribes sequential numbers to each fabric, which reflect climate-related parameters, such as changes in drip rate variability, bio-mediation or diagenetic modifications. Acronyms are proposed for Columnar types, Dendritic, Micrite, Microsparite and Mosaic fabrics, whose …

Exploring Variability In Population Dynamics And The Influence Of Environmental Factors On Recruitment Of An Estuarine Fish, Elizabeth Herdter Smith

USF Tampa Graduate Theses and Dissertations

The focus of this dissertation was to explore variability in population dynamics and environmental factors influential to recruitment of spotted seatrout in Florida with the end goal of testing the incorporation of select environmental variables into the current regional stock assessment models for spotted seatrout. In Chapter 2, I compared the age and size structure of six estuary populations of this species and determined whether there was significant spatial covariation in recruitment. The results of this chapter indicated that the dynamics of each local estuary population are governed more likely by environmental factors than genetic similarities. Further, they suggest that …