Physical Sciences and Mathematics Commons^™

Indium Doped Zinc Stannate-Pdms Based Piezoelectric Generator For Harvesting Mechanical Energy And Sensory Application, Tamanna Zakia

Theses and Dissertations

Piezoelectric materials are comparatively new among other alternative energy sources. Harvesting waste mechanical energy through these materials can be a potential solution of the increasing energy demand. In response to applied mechanical stress, piezoelectric materials accumulate electric charges on their surface. Upon connecting with a circuit, accumulated charges can flow and generate electricity. Based on this hypothesis piezoelectric nano-generator has been fabricated. Binary semiconducting oxides such as ZnO, TiO2 and SnO2 have attracted immense interest as they have unique properties of electron mobility. However, there is always a need for specially designed semiconductors to better match with the properties. This …

Simulating Motion Success With Muscle Deficiency In A Musculoskeletal Model Using Reinforcement Learning, Daniel Castillo

Theses and Dissertations

Humans possess an extraordinary ability to execute complex movements, captivating the attention of researchers who strive to develop methods for simulating these actions within a physics-based environment. Motion Capture data stands out as a crucial tool among the proven approaches to tackle this challenge. In this research, we explore the effects of decreased muscle force on the body's capacity to perform various tasks, ranging from simple walking to executing complex jumping jacks. Through a systematic reduction of the allowed force applied to individual muscles or muscle groups, we aim to identify the threshold at which the body's muscles tolerate the …

Effects Of Short-Term Exposure To A Pesticide Mixture On Free-Swimming Behavior In Goldfish, Carassius Auratus, Esmirna Cantu, Michelle Rivera, Brittney Lacy, Md Saydur Rahman

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

Highlights

• We observed effects of pesticides exposure on free-swimming behaviors in goldfish.

• Pesticides profoundly impacting natural swimming patterns.

• Behavioral analysis showed a dose- and time-dependent, decrease in distance swam.

• Vertical/horizontal spatial behavioral use both affected under exposure conditions.

Abstract

The prevalence of pesticides in the aquatic environment continues to increase due to anthropogenic activities and poses a threat to aquatic organisms. Notably, the intensive use of pesticides can cause detrimental effects (i.e., chemical stressors) on animal behavior. The aim of this study was to determine the short-term exposure effects (5-day) of an environmentally relevant pesticide mixture (low- and high-dose: metolachlor …

A Novel Technique To Solve Fractional Differential Equations Using Fractional-Order B-Polynomial Basis Set, Md Habibur Rahman

Theses and Dissertations

This thesis uses B-Polynomial bases to solve both one-dimensional and multi-dimensional linear and nonlinear partial differential equations and linear and nonlinear fractional differential equations. The approach involves constructing an operational matrix from the terms of these equations using Caputo's fractional derivative of fractional B-polynomials. This leads to a semi-analytical solution derived from a matrix equation, and the results obtained using this method are compared to analytical and numerical solutions presented by other authors. The method is shown to be effective in calculating approximate solutions for various differential equations and provides a higher accuracy level than finite difference methods. This technique …

A Preliminary Characterization And Assessment Of Mesophotic Octocoral Microbiomes In The Western Gulf Of Mexico, Edward P. Gniffke

Theses and Dissertations

Mesophotic Coral Ecosystems are highly diverse and productive ecosystems in the western Gulf of Mexico which are composed of, in part, by octocorals (subclass Octocorallia). Despite their importance as foundational organisms octocorals are an understudied group in this region, with little known about their microbial community. Ninety-eight Octocoral samples collected from the western and northwestern Gulf of Mexico were sequenced using 16S rRNA sequencing to characterize their microbial communities. The sequenced microbiomes were generally low in diversity composed of a few core microbial taxa. Octocoral group was the main driver of microbiome composition as opposed to depth, season, region, and …

Matrix Completion Problems For The Positiveness And Contraction Through Graphs, Louis C. Christopher

Theses and Dissertations

In this work, we study contractive and positive real matrix completion problems which are motivated in part by studies on sparce (or dense) matrices for weighted sparse recovery problems and rating matrices with rating density in recommender systems. Matrix completions problems also have many applications in probability and statistics, chemistry, numerical analysis (e.g. optimization), electrical engineering, and geophysics. In this paper we seek to connect the contractive and positive completion property to a graph theoretic property. We then answer whether the graphs of real symmetric matrices having loops at every vertex have the contractive completion property if and only if …

Manufacturing Of A Flexible Piezoelectric Nanogenerator By Functionalizing Polyvinylidene Fluoride With Lithium Tantalate And Multiwalled Carbon Nanotubes For Energy Harvesting And Sensing Applications, Islam Uddin Shipu

Theses and Dissertations

Mechanical energy is one of the readily accessible green energy sources that could be employed to meet the small-scale energy requirement. In order to capture mechanical energy, power the next generation of electronic gadgets, and health monitoring flexible piezoelectric nanogenerators made of light weight polymers and carbon nanotubes have drawn a lot of attention. Lithium tantalate (LiTaO3), a ferroelectric substance, was prepared here and utilized to create a flexible piezoelectric nanogenerator (FPNG). A compact piezoelectric nanogenerator that successfully transfers mechanical energy into electricity was then created using lightweight polyvinylidene fluoride (PVDF), multi-walled carbon nanotube (MWCNT), and LiTaO3 nanoparticles. To create …

Organocatalyzed Four-Component On-Water Green Synthesis Of Spiroindolinpyranopyrazole, Tanzida Zubair

Theses and Dissertations

Although many synthetic and natural pharmaceuticals and drug-like compounds contain spiro center(s) in their structures, the synthesis of spiro centers is seen to be an exciting and difficult area of research. The synthesis of spiro compounds and their derivatives was carried out using a four-component process that included reagents like hydrazine hydrate, isatin, malononitrile, and an active methylene compound like ethyl acetoacetate. Microwave irradiation was used in a short time range (5 – 30 min) and moderate temperature (80°C), with water as a solvent, and N, N-Diisopropylethylamine (DIPEA) as a catalyst to give high yield of products. Our process complies …

Open Data From The Third Observing Run Of Ligo, Virgo, Kagra, And Geo, R. Abbott, H. Abe, F. Acernese, Teviet Creighton, Mario C. Diaz, Francisco Llamas, Soma Mukherjee, Gaukhar Nurbek, Volker Quetschke, Wenhui Wang

Physics and Astronomy Faculty Publications and Presentations

The global network of gravitational-wave observatories now includes five detectors, namely LIGO Hanford, LIGO Livingston, Virgo, KAGRA, and GEO 600. These detectors collected data during their third observing run, O3, composed of three phases: O3a starting in 2019 April and lasting six months, O3b starting in 2019 November and lasting five months, and O3GK starting in 2020 April and lasting two weeks. In this paper we describe these data and various other science products that can be freely accessed through the Gravitational Wave Open Science Center at https://gwosc.org. The main data set, consisting of the gravitational-wave strain time series …

Computational And Experimental Study On Undoped And Er-Doped Lithium Tantalate Nanofluorescent Probes, Mkhitar A. Hobosyan, Andrea Pelayo Carvajal, Bhupendra B. Srivastava, Tamanna Zakia, Mohammed Uddin, Karen S. Martirosyan, Eric Rodriguez, Kofi Nketia Ackaah-Gyasi, Nikolaos Dmiakis

Physics and Astronomy Faculty Publications and Presentations

We present a combined density functional theory (DFT) and experimental work on lithium tantalate LiTaO3 (LT) and its Er-doped counterparts. We calculate the electronic and optical properties for both LT and LT:Er+3, with Er occupying either Li or Ta sites, at 4.167 mol%. The generalized gradient approximation (GGA) calculations show that the Er-4 f bands appear closer to the conduction band bottom and to the valance band top, for the first and second doped configurations, respectively. This agrees with changes in the imaginary part of the frequency dependent dielectric function between the doped configurations. There are striking differences between the …

Empowering 5g Mmwave: Leveraging Kml Placemarks For Enhanced Rf Design And Deployment Efficiency, Gustavo A. Fernandez

School of Mathematical and Statistical Sciences Faculty Publications and Presentations

This publication explores the significance of Keyhole Markup Language (KML) in telecommunications, particularly in the context of 5G mmWave RF design and planning. With the advent of 5G mmWave technology, the demand for seamless and efficient network deployments has never been greater. The deployment of small cells and repeaters for 5G mmWave necessitates utmost precision in location accuracy and rapid information exchange during site surveys and evaluations. The challenges of mmWave frequencies, including their limited range and susceptibility to attenuation, intensify the complexity and criticality of this process. Network operators must ensure that the chosen location is devoid of obstacles …

Visualizing Oceanographic Data To Depict Long-Term Changes In Phytoplankton, Patricia S. Thibodeau, Jongsun Kim

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

Oceanographic time series provide an important perspective on environmental processes in ecosystems. The Narragansett Bay Long-Term Plankton Time Series (NBPTS) in Narragansett Bay, Rhode Island, USA, represents one of the longest plankton time series (1959-present) of its kind in the world and presents a unique opportunity to visualize long-term change within an aquatic ecosystem. Phytoplankton represent the base of the food web in most marine systems, including Narragansett Bay. Therefore, communicating their importance to the 2.4 billion people who live within the coastal ocean is critical. We developed a protocol with the goal of visualizing the diversity and magnitude of …

Ortho-Fluoro Effect On The C–C Bond Activation Of Benzonitrile Using Zerovalent Nickel, Sébastien Lachaize, Dominique C. Gallegos, Juliana J. Antonio, Abdurrahman C. Atesin, Tülay A. Ateşin, William D. Jones

Chemistry Faculty Publications and Presentations

The effect of fluoro substitution on the C–C bond activation of aromatic nitriles has been studied by reacting a variety of fluorinated benzonitriles with the nickel(0) fragment [Ni(dippe)] and by locating the reaction intermediates and transition-state structures on the potential energy surface by using density functional theory calculations with the [Ni(dmpe)] fragment (dippe = 1,2-bis(diisopropylphosphino)ethane, dmpe = 1,2-bis(dimethylphosphino)ethane). As in the previous reports, the reaction of fluorinated benzonitriles with the [Ni(dippe)] fragment initially formed an η2-nitrile complex, which then converted to the C–CN bond activation product. Thermodynamic parameters for the equilibrium between these complexes have been determined experimentally in both …

The Rayleigh–Bénard Problem For Water With Maximum Density Effects, Mahanthesh Basavarajappa, Dambaru Bhatta

School of Mathematical and Statistical Sciences Faculty Publications and Presentations

Linear stability and weakly nonlinear stability analyses are developed for Rayleigh–Bénard convection in water near 3.98 °C subject to isothermal boundary conditions. The density–temperature relationship (equation of state) is approximated by a cubic polynomial, including linear, quadratic, and cubic terms. The continuity equation, the Navier–Stokes momentum equation, the equation of state, and the energy equation constitute the governing system. Linear stability analysis is used to investigate how the maximum density property of water affects the onset of convective instability and the choice of unstable wave number for four different types of boundary conditions. Then, a weakly nonlinear stability study is …

A Method For Calculating Lateral Surface Area Of Bistatic Radar Beam Overlap, James I. Murray, Fredrick A. Jenet

Physics and Astronomy Faculty Publications and Presentations

It has been shown that bistatic radars using radio telescopes as receivers can be used to increase the sensitivity of orbital debris measurements over traditional terrestrial monostatic radar. A method to calculate the lateral surface area of a bistatic radar is needed to evaluate the efficacy of a proposed bistatic radar configuration for orbital debris measurements. For over three decades, models of the orbital debris (OD) environment in low Earth orbit (LEO) have been developed to assess the risk posed by OD to spacecraft. While terrestrial radar measures debris 3 mm and larger and in situ measurements provide data for …

Visualization Of Productivity Zones Based On Nitrogen Mass Balance Model In Narragansett Bay, Rhode Island, Jongsun Kim, Myung Hwangbo, Patricia S. Thibodeau, Georgia Rhodes, Emma Hogarth, Stewart Copeland

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

Primary productivity in the coastal regions, linked to eutrophication and hypoxia, provides a critical understanding of ecosystem function. Although primary productivity largely depends on riverine nutrient inputs, estimation of the extent of riverine nutrient influences in the coastal regions is challenging. A nitrogen mass balance model is a practical tool to evaluate coastal ocean productivity to understand biological mechanisms beyond data observations. This study visualizes the biological production zones in Narragansett Bay, Rhode Island, USA, where hypoxia frequently occurs, by applying a nitrogen mass balance model. The Bay is divided into three zones - brown, green, and blue zones - …

Confirmation Of N-Hexane As An Inert Co-Solvent In The Production Of Functionalized Silicon Nanoparticles From Reactive High-Energy Ball Milling, Julie P. Vanegas, Amanda Reusch, Mark J. Fink, Brian S. Mitchell

Chemistry Faculty Publications and Presentations

Alkanes such as n-hexane have been used as co-solvents in the production of functionalized semiconductor nanoparticles from alkenes and alkynes using Reactive High Energy Ball Milling (RHEBM) under the assumption that they are non-reactive under typical milling conditions. In this paper, we report on a comparative study with two hydrocarbon solvents of comparable chain length, 1-hexyne, and n-hexane, and their milling products using three different commercially available silicon precursors, namely single crystal silicon wafers and polycrystalline particles having a nominal size of 4 μm and 1 mm. We found that nanoparticle formation and surface functionalization in all the three silicon …

Noise Analysis Of The Indian Pulsar Timing Array Data Release I, Aman Srivastava, Shantanu Desai, Neel Kolhe, Mayuresh Surnis, Bhal Chandra Joshi, Abhimanyu Susobhanan, Aurélien Chalumeau, Shinnosuke Hisano, Nobleson K, Raghav Girgaonkar

Physics and Astronomy Faculty Publications and Presentations

The Indian Pulsar Timing Array (InPTA) collaboration has recently made its first official data release (DR1) for a sample of 14 pulsars using 3.5 years of uGMRT observations. We present the results of single-pulsar noise analysis for each of these 14 pulsars using the InPTA DR1. For this purpose, we consider white noise, achromatic red noise, dispersion measure (DM) variations, and scattering variations in our analysis. We apply Bayesian model selection to obtain the preferred noise models among these for each pulsar. For PSR J1600−3053, we find no evidence of DM and scattering variations, while for PSR J1909−3744, we find …

Asymptotics And Sign Patterns For Coefficients In Expansions Of Habiro Elements, Ankush Goswami, Abhash Kumar Jha, Byungchan Kim, Robert Osburn

School of Mathematical and Statistical Sciences Faculty Publications and Presentations

We prove asymptotics and study sign patterns for coefficients in expansions of elements in the Habiro ring which satisfy a strange identity. As an application, we prove asymptotics and discuss positivity for the generalized Fishburn numbers which arise from the Kontsevich–Zagier series associated to the colored Jones polynomial for a family of torus knots. This extends Zagier’s result on asymptotics for the Fishburn numbers.

Catalan Numbers As Discrepancies For A Family Of Substitutions On Infinite Alphabets, Dirk Frettlöh, Alexey Garber, Neil Mañibo

School of Mathematical and Statistical Sciences Faculty Publications and Presentations

In this work, we consider a class of substitutions on infinite alphabets and show that they exhibit a growth behaviour which is impossible for substitutions on finite alphabets. While for both settings the leading term of the tile counting function is exponential (and guided by the inflation factor), the behaviour of the second-order term is strikingly different. For the finite setting, it is known that the second term is also exponential or exponential times a polynomial. We exhibit a large family of examples where the second term is at least exponential in n divided by half-integer powers of n, where …

Effect Of Total Population, Population Density And Weighted Population Density On The Spread Of Covid-19 In Malaysia, Hui Shan Wong, Md Zobaer Hasan, Omar Sharif, Azizur Rahman

School of Mathematical and Statistical Sciences Faculty Publications and Presentations

Since November 2019, most countries across the globe have suffered from the disastrous consequences of the Covid-19 pandemic which redefined every aspect of human life. Given the inevitable spread and transmission of the virus, it is critical to acknowledge the factors that catalyse transmission of the disease. This research investigates the relation of the external demographic parameters such as total population, population density and weighted population density on the spread of Covid-19 in Malaysia. Pearson correlation and simple linear regression were utilized to identify the relation between the population-related variables and the spread of Covid-19 in Malaysia using data from …

A Convolutional Neural Network Based Approach To Study The Gravitational Waves From Core-Collapse Supernovae In Ligo's Third Observation Run: Detection Efficiency And Parameter Estimation, Bhawana Sedhai

Theses and Dissertations

Core-Collapse Supernova (CCSN) is one of the most anticipated sources of Gravitational Waves (GW) arriving at the advanced LIGO detectors during the fourth observation run (O4). CCSN are rare, weak and unmodeled having a very low rate of occurrence in our galaxy (estimated 2 per century). Thus, detection of GW from CCSN is a challenging problem. An analysis pipeline used in this study is Multi-Layer Signal Enhancement with cWB and CNN or MuLaSEcC that combines Machine Learning methods with a network of Gravitational Wave detectors to identify and reconstruct signals from core collapse supernovae, while minimizing false alarms through the …

Using Deep Learning For Encrypted Traffic Analysis Of Amazon Echo, Surendra Pathak

Theses and Dissertations

The adoption of the Amazon Echo family of devices in modern homes has become very widespread at the current time, with hundreds of millions of devices sold. Moreover, the global smart speaker market size is growing vigorously and is projected to continue to bigger. Smart speakers allow users hands-free interaction by allowing voice control, promoting human-computer interaction to greater avenues. Though smart speaker can be useful assistant, it has some serious security concerns that need to be studied. In this study, an analysis of the security and privacy concerns of smart speakers is presented along with a passive attack, namely …

Identification Of Heart Disorders With Symbolic Aggregate Approximation, Moses K. Owusu

Theses and Dissertations

This project is an application of the Symbolic Aggregate Approximation (SAX) to 1000 fragments of ECG signals for 45 patients (42% females aged between 23 and 89 years and 58% males aged 32 to 89 years) using data obtained from the MIH-BIH Arrhythmia database to recognize cardiac health disorders. Data include a normal sinus rhythm, pacemaker rhythm and ECG readings for 15 heart disorders, making 17 in total. The aim is to use SAX to classify heart disorders using ECG signal, that analyzes QRS-complexes by first splitting the time series into smaller equally sized segments using the Piecewise Aggregate Approximation …

Applications Of Environmental Dna (Edna) To Detect Subterranean And Aquatic Invasive Species: A Critical Review On The Challenges And Limitations Of Edna Metabarcoding, Sakib Tahmid Rishan, Richard Kline, Md Saydur Rahman

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

The world is struggling to solve a devastating biodiversity loss that not only affects the extinction of treasured species and irreplaceable genetic variation, but also jeopardizes the food production, health, and safety of people. All initiatives aimed to conserve biodiversity rely heavily on the monitoring of both species and populations to get accurate spatial patterns and overall population assessments. Conventional monitoring techniques, such as visual surveys and counting individuals, are problematic due to challenges in identifying cryptic species or immature life stages. Environmental DNA (eDNA) is a relatively new technology that has the potential to be a faster, non-invasive, and …

Advanced Prognostic Modeling For Breast Cancer Patients: Leveraging Data-Driven Approaches For Survival Analysis, Theophilus Gyedu Baidoo

Theses and Dissertations

Breast cancer is the second most prevalent form of cancer in women in the United States. Each year, about 264,000 cases of breast cancer are diagnosed in women and of this number, about 42,000 women lose their lives as reported by the Centers for Disease Control and Prevention. Early detection and effective treatment are crucial for improving survival rates and reducing mortality. This study aimed to explore the influential factors that may risk the survival of women with the disease and compare their predictive abilities using several error and performance metrics. The study uses a dataset from the National Cancer …

Analyzing The On Source Window Of Supernova Sn2019ejj With A Multi Layered Signal Enhancement Algorithm With Coherent Waveburst And A Convolutional Neural Network, Michael Gale Benjamin

Theses and Dissertations

Core collapse supernovae (CCSN) are highly anticipated sources of gravitational waves during the fourth observation run (O4). CCSN signals are weak and unmodeled and the rate of occurrence in our galaxy is very low. Because of this, they provide a greater challenge to detect than previously detected GW sources. CCSN simulations are used to test the detection pipeline in the event a CCSN is detected. CCSN GW signals are often indistinguishable from the noise sources present in GW data. We present a multi layered signal enhancement pipeline which we have applied Machine Learning (ML) techniques. We have used a Convolutional …

Optimizing Convolutional Neural Networks For Transient Detection In Optical Astronomy With Augmented Datasets, Wendy Mendoza

Theses and Dissertations

We present a technique for optical transient detection using artificial neural networks, particularly a Convolutional Neural Network (CNN), a deep learning algorithm. This method analyzes images of the same area of the sky captured by several telescopes, with one image serving as a reference for a probable transient’s epoch and the other as an image from a previous epoch. We train the CNN on simulated sources and test it on actual image data samples using data from the Dr. Cristina V. Torres Memorial Astronomical Observatory and Sloan Digital Sky Survey. This autonomous detection method replaces the standard procedure, which involves …

Integrable Discretizations For A Generalized Sine-Gordon Equation And The Reductions To The Sine-Gordon Equation And The Short Pulse Equation, Han-Han Sheng, Bao-Feng Feng, Guo-Fu Yu

School of Mathematical and Statistical Sciences Faculty Publications and Presentations

In this paper, we propose fully discrete analogues of a generalized sine-Gordon (gsG) equation utx=(1+ν∂2x)sinu. The bilinear equations of the discrete KP hierarchy and the proper definition of discrete hodograph transformations are the keys to the construction. Then we derive semi-discrete analogues of the gsG equation from the fully discrete gsG equation by taking the temporal parameter b→0. Especially, one full-discrete gsG equation is reduced to a semi-discrete gsG equation in the case of ν=−1 (Feng {\it et al. Numer. Algorithms} 2023). Furthermore, N-soliton solutions to the semi- and fully discrete analogues of the gsG equation in the determinant form …

Covering By Planks And Avoiding Zeros Of Polynomials, Alexey Glazyrin, Roman Karasev, Alexandr Polyanskii

School of Mathematical and Statistical Sciences Faculty Publications and Presentations

We note that the recent polynomial proofs of the spherical and complex plank covering problems by Zhao and Ortega-Moreno give some general information on zeros of real and complex polynomials restricted to the unit sphere. As a corollary of these results, we establish several generalizations of the celebrated Bang plank covering theorem. We prove a tight polynomial analog of the Bang theorem for the Euclidean ball and an even stronger polynomial version for the complex projective space. Specifically, for the ball, we show that for every real nonzero d-variate polynomial P of degree n⁠, there exists a point in the …