Physical Sciences and Mathematics Commons^™

Study On Dioxygen Binding To Heme Using Scan Functional, Zegnet Yimer Muhammed

Open Access Theses & Dissertations

Density functional theory, a quantum mechanical based electronic structure method with GGA-PBE and MGG-SCAN functionals, are used to investigate the structure and energies of singlet, triplet, and quintet spin states of FeP (iron Porphyrin), FePIm (imidazole iron porphyrin), and FePImO2 (dioxygen imidazole iron porphyrin) systems. The binding and release of dioxygen to and from hemoglobin (Hb) are the most crucial reaction takes place in human body to sustain the existence of life. FePImO2 is used to model this phenomenon. When O2 binds to FePIm, the system undergoes a conformational change. i.e. from domed structure of FePIm in which the Fe …

Uranium-Series And Strontium Isotope Ratios In Soils From Basse-Terre Island, French Guadeloupe: Insights For Rapid Soil Formation And Impact Of Dust In A Tropical Volcanic Setting, Yvette Pereyra

Open Access Theses & Dissertations

Chemical weathering of silicate rocks generates soils that contain mineral nutrients, sustain ecosystems, modify water chemistry in the hydrosphere, and regulate the global carbon cycle. Understanding the timescales of soil formation and sources of soil mineral nutrients has great implications for securing the future of agriculture and food production. However, few tools are currently available to directly quantify the rates of chemical weathering and timescales of soil formation. Uranium-series isotopes fractionate during chemical weathering and the activity ratios of (234U/238U), (230Th/238U), (238U/232Th) and (230Th/232Th) have great potential to constrain the rates and timescales of chemical weathering and soil formation in …

Combining Interval And Probabilistic Uncertainty In Engineering Applications, Andrew Martin Pownuk

Open Access Theses & Dissertations

In many practical application, we process measurement results and expert estimates. Measurements and expert estimates are never absolutely accurate, their result are slightly different from the actual (unknown) values of the corresponding quantities. It is therefore desirable to analyze how this measurement and estimation inaccuracy affects the results of data processing. There exist numerous methods for estimating the accuracy of the results of data processing under different models of measurement and estimation inaccuracies: probabilistic, interval, and fuzzy. To be useful in engineering applications, these methods should provide accurate estimate for the resulting uncertainty, should not take too much computation time, …

Modeling Of Piezoelectric Traveling Wave Rotary Ultrasonic Motors With The Finite Volume Method, Ivan Arturo Renteria Marquez

Open Access Theses & Dissertations

In 1983 Toshiiku Sashida developed a new motor concept called Piezoelectric Traveling Wave Rotary Ultrasonic Motor (PTRUSM). The advantages of these motors include high torque at low speed, absence of a generated magnetic field, and high potential for miniaturization. Unfortunately PTRUSMs have some disadvantages that limit the areas of applications for these types of motors. The disadvantages are a short operating life (about 1000 hours), small output power, and the need of a complex motor controller.

On one hand, these motors have been used in satellites, mobile phones, photocopiers, robotic arms, telescopes, automobiles, and camera autofocusing. On the other hand, …

Pre-Tuned Principal Component Regression And Several Variants, Pei Wang

Open Access Theses & Dissertations

The regression coecient estimates from ordinary least squares (OLS) have a low probability of being close to the real value when there is a multicollinearity problem in the design matrix. In order to combat this problem, many regularized methods have been introduced. Principal components regression (PCR) is an important analysis tool for dealing with multicollinearity and high-dimensionality. In conventional PCR, the rst step is to change the original predictors to orthogonal principal components (PC's) by a linear transformation. These PC's correspond to the eigenvalues which are sorted in a decreasing order. The next step is to regress the response on …

Predicting The Water Quality Of Shallow Arctic Ponds Using Remote Sensing, Gabriela Tarin

Open Access Theses & Dissertations

Barrow, Alaska is in a region dominated by Arctic tundra of which a substantial part is covered by lakes and ponds. Despite their dominance in the landscape, freshwater ecosystems in the Arctic have been insufficiently studied. It is clear that furthering understanding of how Arctic water bodies are responding to warming will depend on the analysis of changes in the concentration of organic and inorganic constituents in the water; however, scientists are faced with the task of sampling many remote sites in a relatively hostile environment. Thus, the exploration and incorporation of remote methods for monitoring changes in water quality. …

A New Test For The Mean Vector In High Dimensional Setting, Behzad Aalipur Hafshejani

Open Access Theses & Dissertations

Traditional statistical data analysis mostly includes methods and techniques to deal with problems in which there are many observations but a few variables. Nonetheless, the current inclination is toward more observations but also, toward more variables. Today's observations gathered on individuals are images, curves, or even movies. Unfortunately many traditional methods do not work well in high dimensional settings. As an example Hotelling's test which is well known and widely used in the literature does not work when it comes to high dimensional problems. Consequently statisticians are making an effort to find remedies or new approaches to multivariate mean testing. …

Effects Of Citric Acid Coated And Uncoated Cerium Oxide Nanoparticles In Tomato (Solanum Lycopersicum) Plants, Ana Cecilia Barrios

Open Access Theses & Dissertations

This research was performed to examine the physiological and biochemical effects of bare (nCeO2) and citric acid coated (nCeO2+CA) cerium oxide nanoparticles in tomato (Solanum lycopersicum). Plants were germinated and grown to full maturity in soil amended with 0-500 mg/kg and periodically analyzed using ICP-OES/MS and other spectroscopic and biochemical techniques. Although Ce in tissues increased as the external nCeO2 increased, there were no visible signs of toxicity. In mature plants, nCeO2 induced developmental changes and altered nutritional quality (essential elements) in fruits. On the other hand, nCeO2+CA affected fruit carbohydrate composition (sugars and starch). This study gives insights on …

Seismic Modeling, Rock Physics, Avo And Seismic Attribute Analysis For Illuminating Sandstone Facies Of The Late Ordovic Ian Mamuniyat Reservoir, R-Field, Murzuq Basin-Libya, Yousf Milad Abushalah

Open Access Theses & Dissertations

The Late Ordovician Mamuniyat Formation is the main hydrocarbon reservoir in the R-Field in Murzuq Basin, SW Libya. The Lower Mamuniyat, which is the only unit that was encountered in the study area, is composed of sandstone facies called Clean Mamuniyat and shaly sandstone facies called Dirty Mamuniyat. One major problem with the development of the R-Field is the difficulty of distinguishing the two units so this project was aimed to develop better methods for distinguishing between the two units of the Lower Mamuniyat. The other problem is to distinguish the transgressive shaly facies of the Bir Tlacsin, which has …

Creating Multi-Functional G-Code For Multi-Process Additive Manufacturing, Efrain Aguilera Jr

Open Access Theses & Dissertations

Additive manufacturing (AM) started over thirty years ago and with it a manufacturing revolution that moves industrial production into the personal home. With recent interest shifting into multi-functional parts fabricated through AM technologies, unified systems are being developed. Merging different manufacturing technologies into one single machine is a challenge but undergoing research has shown promise in the development of multi-functional systems. Concurrent work is being done in the software, automation, and hardware aspect of multi-functional systems. An effort to use industry compatible Computer Aided Design (CAD) software to design multi-functional parts including circuits, micro-machining, and foil embedding then exporting and …

Sparse Matrix Diagonalization In The Nrlmol Electronic Structure Code, Md Mahmudulla Hassan

Open Access Theses & Dissertations

Density functional theory (DFT) based simulations are playing a major role in quantum mechanical studies of materials ranging from molecules, nanoparticles to the biological systems as they offer insights that are not directly accessible from experiments and also due to their ability to make sufficiently accurate predictions. The DFT implementation in the NRLMOL electronic structure code employs Gaussian basis sets to express the Kohn-Sham orbitals. A major computationally demanding task in the electronic structure calculations is solution of the generalized eigenvalue problem, that is the determination of nontrivial solutions (λ, c) of Hc = λOc where H and O are …

Controls On Carbonate Sedimentation And Sequence Stratigraphic Framework Of The Lower Permian (Wolfcampian) Hueco Formation (Upper-Middle And Gastropod Intervals), Robledo Shelf, Western Orogrande Basin, New Mexico, Matthew S. Harder

Open Access Theses & Dissertations

On the western margin of the Pennsylvanian/Permian Orogrande Basin, two composite measured sections in the Lower Permian upper interval of the Middle Member of the Hueco Limestone were analyzed in regards to depositional environment, facies and sequence stratigraphy. This can elucidate where potential unconventional reservoirs can be found in the Wolfcamp Shale of the Permian Basin. Based on these analyses, 12 lithofacies were identified, including 9 carbonate lithofacies: 1) fenestral dolomudstone, 2) peloidal dolomudstone, 3) ostracode foraminifera packstone, 4) foraminifera peloidal grainstone, 5) skeletal intraclast grainstone, 6) phylloid algal peloidal grainstone, 7) echinoderm phylloid algal packstone, 8) echinoderm bivalve brachiopod …

Spatiotemporal Variability Of Plant Phenology In Drylands: A Case Study From The Northern Chihuahuan Desert, Naomi Robin Luna

Open Access Theses & Dissertations

With global change, which includes climate change, there is a sense of urgency to understand how shifts in climate will affect ecosystems. Although several studies have improved understanding of how and why some ecosystems respond, most studies have not explored simultaneous responses of different land cover types throughout a given region. Dryland ecosystems, such as the Chihuahuan Desert, appear to respond to climate variability and currently make up about 40% of global land surface area. It is expected that drylands will expand to cover 60% of land surface area on earth by mid-century making this ecosystem more critical to global …

The Origin Of Anomalous Carbonate Units Outcropping At The Salt Sediment Interface Of The Southern End Of Gypsum Valley Salt Wall, Paradox Basin, Colorado, Allison M. Mast

Open Access Theses & Dissertations

Understanding structural, stratigraphic, and petrographic complexities at the salt-sediment interface of diapirs has important implications in accurately assessing hydrocarbon reservoir quality and near-diapir trap geometries, and may aid in more accurate predictions for locating the true margin of salt in diapiric layered evaporites. The southwest margin of the exhumed Gypsum Valley Salt Wall, Paradox Basin, southwest Colorado, provides a rare view of this interface where onlapping and overlapping wedges of Late Permian and Jurassic halokinetic sequences overlie an angular unconformity truncating near-vertical, highly deformed carbonate beds formerly mapped as Pennsylvanian Honaker Trail Formation. This study investigates three possible alternative origins …

Adjoint Fuzzy Partition And Generalized Sampling Theorem, Irina Perfilieva, Michal Holčapek, Vladik Kreinovich

Departmental Technical Reports (CS)

A new notion of adjoint fuzzy partition is introduced and the reconstruction of a function from its F-transform components is analyzed. An analogy with the Nyquist-Shannon-Kotelnikov sampling theorem is discussed.

Geology And Mineralization Controls Surrounding The Palmarejo Mining District - A Compilation Of Remote And Hands On Exploration Techniques, Castulo Molina Sotelo

Open Access Theses & Dissertations

Exploration is the base of the mining industry, and it is often taken as synonymous with "finding a mine". In reality it is a more complex process; where the selection, evaluation, screening and testing of successively smaller areas lead to the discovery of an economic deposit. Once the deposit is found, the economic factors become more important than the geological ones, and then the exploration becomes a tool to give sustainability to the mining operation through time.

The silver and gold deposits of the world-class Palmarejo District are typical, intermediate sulfidation- style epithermal, precious metal occurrences, hosted in Cretaceous- to …

A Geophysical Investigation At The Potrillo Maar, Manuel Moncada Gutierrez

Open Access Theses & Dissertations

The Potrillo Volcanic Field (PVF) is a unique geological site located in Doña Ana County the southernmost part of New Mexico, and part of northern part of Chihuahua, Mexico. The main feature of the southern PVF is Potrillo Maar. This maar-volcano straddles the international boundary between United States and Mexico and lies within the southern part of the Rio Grande Rift. The Potrillo Maar was formed about 20,000 years ago in three major events that formed basalt lava flows and ejecta deposits that consist of crustal and mantle xenoliths.

The purpose of this Thesis is to determine the area of …

Application Of Secondary Analyses On Industrial Data Sets, Luis G. Perez

Open Access Theses & Dissertations

Secondary analysis on quantitative data sets is the in-depth analysis of relationships, trends, patterns or behaviors that are not obvious from a superficial examination of data but that can be very germane in the application of that data. The present work presents a framework for investigators to use in applying secondary analysis on big data that correlates to the research topic. The framework can facilitate the illumination of possible data behaviors or patterns that could be useful in arriving at an answer to a question. Behavior of monitored equipment (analyzers, meters, etc.) can easily be depicted and can be used …

Application Of Uranium And Strontium Isotopes As Salinity And Paleo-Environmental Conditions Tracers:Insight From The Rio Grande River And Pedogenic Carbonates In Drylands Soils Of Southwest, Usa., Syprose Nyachoti

Open Access Theses & Dissertations

South New Mexico and west Texas regions of the northern Chihuahua Desert are characteristic of low annual rainfall and high potential evapotranspiration rates. Soils in these arid and semi-arid regions are abundant of pedogenic carbonates of various stages of development. Both surface and ground water resource in the area have high salt content; the Rio Grande river, which flows through the region is known for its high salinity downstream. Due to increasing population in cities of the region thus high food demand, irrigation activities along the river valley have enhanced crop productivity. High evapotranspiration rates and intense saline flood irrigation …

Reconstructing Dinosaur Foot Tracks And Identifying New Footprints Using Structure From Motion Photogrammetry, Valeria V. Martinez

Open Access Theses & Dissertations

The use of 3-D Structure from Motion models to study fossils is a relatively new technique that has an advantage over traditional field methods, such as plaster casts or collecting samples, because it is non-destructive and can be easily shared with a wide audience. It is also ideal for use with persons with disabilities because it does not require field access and it can be manipulated for optimum computer viewing or printed with a 3-D printer for tactile examination as needed. Our study focused on a known site in Cristo Rey, New Mexico where Cretaceous Iguanadon and Ankylosaur footprints have …

The Use Of Remote Sensing Technologies And Models To Study Pollutants In Pdn Region, Suhail Mahmud

Open Access Theses & Dissertations

Using a suite of modeling techniques and instrumentation we study the atmospheric pollutants in the PdN Region. The first objective of this work was to measure hemi-spherically integrated, spectrally resolved solar photon flux (actinic flux) between the wavelengths 300 and 700 nm, and use the measured actinic flux to improve air quality simulations. Actinic flux was measured in the PdN region in order to calculate photolysis rate coefficients for different pollutants. The improved photolysis rate coefficients were then integrated into a photochemical air quality model (CAMx) in order to improve air quality forecasting. We present the simulations performed for a …

New Organosilicon Chemistry, Paulina Elena Gonzalez Navarro

Open Access Theses & Dissertations

The formation of siloxymethylamine intermediates R3SiOCH 2NMe2, 1, as initial products of the reduction of DMF by hydrosilanes catalyzed by Mo(CO)5NMe3 has been reported. These siloxymethylamines can react with R’3SiH to form trimethylamine and disiloxanes, and with chlorosilanes to form disiloxanes and ClCH 2NMe2, Eschenmoser’s salt. I shall illustrate, in Chapter 1, how attempts to react 1, formed in situ in the presence of chlorosilanes R’3SiCl in the hope producing heterosilyl disiloxanes, R3SiOSiR’3, was not successful but led to a newly discovered activation of the Si-Cl bond by DMF.

In Chapter 2, we surmised that 1 acts as a transient …

A Decision Making Approach For Selection Of Sustainable Pavements In Texas By Integrating Life Cycle Cost Analysis (Lcca), Life Cycle Assessment (Lca) Of Environmental And Social Impacts, Sundeep Inti

Open Access Theses & Dissertations

A sustainable pavement can be defined as the one that minimally impacts future economic opportunities, social conditions, human health, and the environment and still fulfills the engineering objectives. Although a pavement as outlined above is not yet entirely feasible, continual effort from every stakeholder with a vision of achieving sustainable development is essential for the future of society. In this study, one such effort was initiated by proposing a framework for selection of pavement design based on sustainable development.

The concept of sustainability is widely believed to be founded on three criteria: economic, environmental, and social standards. Since the purpose …

Equation Of State Of A Dense And Magnetized Neutron System, Md Masud

Open Access Theses & Dissertations

Neutron stars (NSs) are the windows to check the validation of physical laws at extreme conditions, for example, at very high densities and strong magnetic fields and thus to reach the equations of state (EoS) for a better understanding of the structure as well as the composition of the NSs. In our investigations, it is found that the system's (NSs) pressure becomes anisotropic due to the breaking of rotational symmetry in the presence of strong magnetic fields, which even can be significantly sufficient to lead into the deformation of NSs or to destroy itself.

Environmental Dynamics: A Compendium Of Rhetorical Application, Annalisa Perez

Open Access Theses & Dissertations

Technology, albeit exceedingly useful, has exponentially exacerbated the communications dilemma between the technical and the non-technical. Additionally, based on a current new understanding of the term environmental, it can no longer be fully defined by terms such as air, water, waste, or purification. Rather, the meaning of environmental has been globally transformed in several ways. The term environmental is encompassing an expansion of understanding and is further defined with words such as essence, perception, rapport and multi-dimensional spaces. This work, Environmental Dynamics: A Compendium of Rhetorical Application (EDC), provides a framework where communication can be enhanced in areas where communication …

Fabrication And Testing Of Cfrp Composites With Embedded Piezoelectric Particles For Temperature Sensing And Energy Harvesting, Emilio Tarango Valles

Open Access Theses & Dissertations

As a part of this world's continuous evolution and technological advancements, smart materials and functional composites have become an attractive topic. In many cases, these new functional composites are replacing the traditional engineering material due to their customizable mechanical properties. This Thesis analyzes and demonstrates the signal response, sensing capabilities and structural properties from Carbon/Glass Fiber Reinforced Plastic Composites (CFRP) with embedded Lead Zirconate Titanate Particles (PZT). The added PZT particles function as actuators, giving the composites a functionality. The PZT quantity inside each composite was variated to study better and characterize the mechanical and electrical properties; the variations were …

Complex Gleason Measures And The Nemytsky Operator, Miguel Angel Valles

Open Access Theses & Dissertations

This Thesis is devoted to generalize previous results on Gleason measures

to complex Gleason measures, and to develop a functional calculus

for complex measures in relation to the Nemytsky operator. Furthermore

we present the interpretation of our results in the field of quantum

mechanics, some concrete examples and further extensions of several

theorems.

Reliable And Secure Scada Framework For Residential Microgrid Communications, Goutham Krishna Chalamasetty

Open Access Theses & Dissertations

Cyber security is one of the major needs for electric power industry like many other industries and organizations. The advancements in technology provide numerous benefits to power industry as well as benefits cyber attackers to perform different cyber-attacks on the industry. Power system is a complex physical entity that deals with power generation, distribution, and transmission. In general, no individual or company or an organization can bear a one hour power cut, which shows the need for reliability in electric power industry.

In order to develop a reliable and secure Supervisory Control and Data Acquisition (SCADA) communication network, this Thesis …

Structural And Stratigraphic Development Of A Salt Diapir Shoulder, Gypsum Valley, Colorado, Joshua Coleman Mcfarland

Open Access Theses & Dissertations

A salt shoulder is a low-angle segment of the salt-sediment interface where the margin of a passive diapir steps abruptly inboard. The Late Triassic Chinle Formation overlies caprock on the northeastern margin of Gypsum Valley (GV) at the salt-sediment interface in the natural amphitheater of Bridge Canyon. Modern erosion of the Dolores River has created 3D outcrop of the salt shoulder, expressed by a 500 meter wide, sub-horizontal platform that dips abruptly into the subsurface to the northeast toward the Dry Creek minibasin. Within Bridge Canyon, seven facies associations have been recognized and interpreted within the Chinle Formation: 1) non-caprock …

Tectonostratigraphic Evolution Of A Suprasalt Minibasin, Oligocene - Miocene Western Slope Of The Gulf Of Mexico, Felix Alan Ramirez

Open Access Theses & Dissertations

The petroleum industry has focused Gulf of Mexico exploration efforts on salt-related geologic provinces in search of major hydrocarbon accumulations. This work has led to recognition of the influence that salt tectonics has had on play elements of the petroleum system in the producing salt basins. In particular, the complex depositional patterns of the reservoir rocks controlled by shifting depocenters resulting from the accommodation space generated by salt withdrawal from minibasins.

The focus of this research is to understand the structural and stratigraphic components that controlled the evolution of an Oligocene - Miocene suprasalt minibasin located in the upper continental …