Physical Sciences and Mathematics Commons^™

Determinants Of Neighborhood Exposure To Extreme Heat: A Spatial Examination Of El Paso And Juárez, 2010, Faraj Mohamad Aboargob

Open Access Theses & Dissertations

Numerous studies have been conducted on the modification of local weather by the urban environment. In studying urban environmental effects on the urban heat island (UHI), researchers have investigated influences such as land use, vegetation density, topography, population density, and neighborhood socioeconomic status. Many studies have used data collected from field observations, while other studies relied solely on computer modeling. This Dissertation research used a spatial analysis approach, which has been less widely employed, to investigate neighborhood level biophysical, built environmental and socio-demographic determinants of the El Paso and Juárez UHI. The research utilized inexpensive data obtained from US and …

Preparation Of Cobalt/Nickel Molybdenum Sulfide Catalysts Supported By Aqueous Media Soluble Multi-Wall Carbon Nanotubes., Hassan Ahmad Bleibel

Open Access Theses & Dissertations

Multi-walled carbon nanotubes (MWCNTs) have been subjected to chemical treatment in order to introduce hydrophilic functional groups on their surfaces. These covalently bonded groups did enhance the solubility of MWCNTs in aqueous media as expected. Functionalized MWCNTs were characterized using FTIR, Raman spectroscopy, TGA, X-ray diffraction, dispersion test and TEM. Then, functionalized MWCNTs were incorporated in the hydrothermal synthesis method of transition metal sulfide catalysts (CoMo, NiMo, and Ethylenediamine-CoMo Sulfides). Catalysts were characterized using X-ray diffraction, TEM, SEM, N2 Gas adsorption-desorption, elemental analysis, and Hydrodesulfurization (HDS) reaction of dibenzothiophene (DBT). The objective was to study the functionalized MWCNTs' effect; being …

Multiplicity Adjustments For Respecification Searches In Structural Equation Models, John Appiah Kubi

Open Access Theses & Dissertations

Structural Equation Modeling (SEM), as a statistical modeling technique, is one of the most comprehensive and flexible approaches to data analysis currently available. Its use has been increasing steadily over the past few decades. Generally, it refers to a family of

techniques that employs the analysis of covariance to establish relationships among a set of variables. It allows researchers (or users) to assess the adequacy of their hypothesized models with their sample data. Often times, in assessing their models, researchers are not

only interested in the overall fit of their model but they are also interested in knowing which proposed …

Size-Dependent Transitions In Grafted Polymer Brushes, Courtney Bosse

Open Access Theses & Dissertations

ABSTRACT

Finding probabilities in order to solve for the most likely configuration of a grafted polymer chain is easily calculated by solving a random walk problem, starting form a given point (the surface). A property of the random walk is used to describe the partition function of a polymer in terms of a sum over possible loops configurations, which simplifies tremendously the problem of calculating the partition function of the grafted polymer. Instead of solving the non-interacting random walk that has been well studied in the theory of the probability, the focus is on the problem of self-interacting random walks, …

Quark Fluctuations In A Chiral Model In The Presence Of A Magnetic Field, Lidens Cheng

Open Access Theses & Dissertations

Understanding the nature of the chiral and deconfinement phase transitions, the location of the critical point, and the properties in its vicinity are among the most important problems in the field of QCD. The purpose of this thesis is to use the two-flavor Nambu-Jona-Lasinio model in the presence of a magnetic field at the chiral limit to study the phase boundary where the spontaneously broken chiral symmetry is restored. At small chemical potential, the phase boundary exhibits a second-order phase transition. On the other hand, at large chemical potential and appropriate coupling constant, the phase boundary exhibits a first-order phase …

Investigation Of The Radiative Heat Release Factor Of Premixed Oxy-Syngas Flames, Martin De La Torre

Open Access Theses & Dissertations

A significant part of the United States is being powered by combustion devises relying on coal since it is abundant and is a high emitting source of electricity per unit energy, however; the burning of this fuel is responsible for a significant contribution for the pollutant emissions causing global warming. Because coal is one of the main sources of energy in the U.S. and around the globe, the scientific community has been investigating ways to meet current and future governmental emission requirements. It is now well established that radiating heat from the flame is a major contributor of the heat …

Functional Data Analysis To Guide A Conditional Likelihood Regression In A Case-Crossover Study Investigating Whether Social Characteristics Modify The Health Effects Of Air Pollution, Juana Maribel Herrera Hernandez

Open Access Theses & Dissertations

In this study we are focused on exploring whether social characteristics modify the relationship between air pollution and hospitalizations due to asthma or chronic pulmonary obstructive disease (COPD) in El Paso, Tx. The case-crossover design with conditional regression analysis was used, here the controls and the case are the same subject at different

times and has the advantage of removing confounding by permanently confounding factors. Social characteristics are included in the models as interactions with the pollutants, variables included are age, sex, ethnicity and insurance status as indicator for the socio-economic status. The pollutant's lags were chosen using the historical …

Rbd2po4: Room Temprature Synthesis, Chemical And Structural Stablity Upon Heating, Masoud Mollaee

Open Access Theses & Dissertations

Monoclinic RbD2PO4 polycrystals were synthesized via the room temperature crystallization of RbH2PO4 dissolved in D2O. Powder x-ray diffraction (XRD) data collected at T=25 ºC indicate that this deuterated compound crystallizes in space group P21/m with unit cell parameters a=7.688í?, b=6.192í?, c=4.781í? and β=109.02°, and is isomorphic with the intermediate-temperature phase of its hydrogenated counterpart rubidium dihydrogen phosphate (RDP). We found no evidence of previously reported [Phase Transitions 80, 17 (2007)] polymorphic phase transition in rubidium dideuterium phosphate (DRDP) upon heating from room temperature to 210 ºC. All lattice parameters vary smoothly within this temperature range, demonstrating that the P21/m phase …

Photochemical Synthesis Of Amino Acid And Peptide Oxo-Esters, Alfredo Ornelas

Open Access Theses & Dissertations

Amino acid and peptide oxo-esters have played an important role in peptide chemistry for many years. Various amino acid esters are commonly used as protecting groups for peptide synthesis in solution. Moreover, activated phenyl ester derivatives have been used for chemical ligation of peptides. However, the synthesis of amino acid and peptide oxo-esters is commonly performed under acidic or basic conditions. Under acidic conditions, acid-sensitive protecting groups may be cleaved, and under basic conditions racemization of amino acid esters is a common problem. Here we present the photochemical synthesis of amino acid and peptide oxo-esters. Based on the photochemical properties …

Upgrades To Nrlmol Code, Luis Basurto

Open Access Theses & Dissertations

This project consists of performing upgrades to the massively parallel NRLMOL electronic structure code in order to enhance its performance by increasing its flexibility by: a) Utilizing dynamically allocated arrays, b) Executing in a parallel environment sections of the program that were previously executed in a serial mode, c) Exploring simultaneous concurrent executions of the program through the use of an already existing MPI environment; thus enabling the simulation of larger systems than it is currently capable of performing. Also developed was a graphical user interface that will allow less experienced users to start performing electronic structure calculations by aiding …

Changes In Net Ecosystem Production Over The Past 40 Years In Arctic Tundra Ponds Near Barrow, Alaska: Application Of Historic And Modern Techniques, Nickole Ann Miller

Open Access Theses & Dissertations

Arctic environments have gained interest recently due to their sensitivity to climate change. As warming has created longer growing seasons, extended ice-free periods as well as permafrost thaw, the production in freshwater ecosystems has the potential to be greatly impacted. It is hypothesized that as climate change and warming occurs, increases in primary production will occur and ponds will become carbon sinks. Net ecosystem production (NEP) was determined using phytoplankton and periphyton samples collected weekly during the growing season (June - August) from arctic tundra ponds near Barrow, Alaska. Enrichment with 14C was used to determine both weekly photosynthetic rates …

Structural, Optical And Electrical Properties Of Yttrium-Doped Hafnium Oxide Nanocrystalline Thin Films, Abhilash Kongu

Open Access Theses & Dissertations

Hafnium oxide (HfO2) has emerged as the most promising high-k dielectric for Metal-Oxide-Semiconductor (MOS) devices and has been highlighted as the most suitable dielectric materials to replace silicon oxide because of its comprehensive performance. In the present research, yttrium-doped HfO2 (YDH) thin films were fabricated using RF magnetron sputter deposition onto Si (100) and quartz with a variable thickness. Cross-sectional scanning electron microscopy coupled with Filmetrics revealed that film thickness values range from 700 A° to 7500 A°. Electrical properties such as AC Resistivity and current-voltage (I-V) characteristics of YDH films were studied. YDH films that were relatively thin (<1500 A°) crystallized in monoclinic phase while thicker films crystallized in cubic phase. The band gap (Eg) of the films was calculated from the optical measurements. The band gap was found to be ∼5.60 eV for monoclinic while it is ∼6.05 eV for cubic phase of YDH films. Frequency dependence of the electrical resistivity (ρac) and the total conductivity of the films were measured. Resistivity decreased (by three orders of magnitude) with increasing frequency from 100 Hz to 1 MHz, attributed due to the hopping mechanism in YDH films. Whereas, while ρac∼1Ω-m at low frequencies (100 Hz), it decreased to ∼ 104 Ω-cm at higher frequencies (1 MHz). Aluminum (Al) metal electrodes were deposited to fabricate a thin film capacitor with YDH layer as dielectric film thereby employing Al-YDH-Si capacitor structure. The results indicate that the capacitance of the films decrease with increasing film thickness. A detailed analysis of the electrical characteristics of YDH films is presented.

Synthetic Asphaltene As A Novel Dye In Dye Sensitized Solar Cells Dsscs, Hassan Sharif

Open Access Theses & Dissertations

This dissertation approves the possibility of the first time use of synthetic asphaltene as new dye in dye sensitized solar cells. In which the conversion efficiency of synthetic asphaltene DSSC has improved up to 2.0 %. Synthetic asphaltene sample was prepared from the starting material as in literature and applied for various solar cell parameters of TiO2 based dyesensitized solar cell DSSC. DSSCs were fabricated using the synthetic asphaltene as dye. Different variables and parameters were carried out to test the photovoltaic performance of the cells, these parameters include open-circuit voltage, short-circuit current; fill factor. The first result was obtained …

Pressure And Heat Flux Effects On The Heat Transfer Characteristics Of Liquid Methane, Chance Paul Garcia

Open Access Theses & Dissertations

The heat transfer effects on liquid methane are investigated with the use of a carbo-thermal rig at the Center for Space Exploration Technology Research (cSETR) located at the University of Texas at El Paso (UTEP). The cSETR carbo-thermal rig design approach is presented along with the design of a methane condensing mobile unit (MCMU) to supply the laboratory and rig with liquid methane. The proposed research will generate useful insight in to heat transfer coefficient behavior, non-dimensional correlations, different flow conditions, varied inlet conditions, and varied heat flux for a subscale test article applicable to a regenerative cooled rocket engine …

Geology And Geochemistry Of The Sierra Blanca Rare Earth Complex, Sierra Blanca, Texas, Nicole Kyger

Open Access Theses & Dissertations

With an increasing standard of living comes an increase in demand for high tech goods, environmentally friendly (green) and military technologies, and the inherent need to procure the necessary raw materials. Demand for the rare earth elements (REE) is on the rise, and there is no foreseeable decline in the need for accessible deposits. Between 2010 and present, the United States Congress has heard numerous reports on the importance of REE, and in 2012 the Department of Defense(DoD)declared REE a critical resource, with implications for national security. The Sierra Blanca laccoliths, 150 kilometers southeast of El Paso, TX represent a …

Propagation Of Interval And Probabilistic Uncertainty In Cyberinfrastructure-Related Data Processing And Data Fusion, Christian Servin

Open Access Theses & Dissertations

Data uncertainty affects the results of data processing. So, it is necessary to find out how the data uncertainty propagates into the uncertainty of the results of data processing. This problem is especially important when cyberinfrastructure enables us to process large amounts of heterogeneous data. In the ideal world, we should have an accurate description of data uncertainty, and well-justified efficient algorithms to propagate this uncertainty. In practice, we are often not yet in this ideal situation: the description of uncertainty is often only approximate, and the algorithms for uncertainty propagation are often not well-justified and not very computationally efficient. …

An Evaluation Of The Cerro Process As An Efficient Ro Concentrate Management System, Guillermo Guadalupe Delgado

Open Access Theses & Dissertations

The Concentrate Enhanced Recovery Reverse Osmosis (CERRO) Process is a new method to treat RO concentrate and brackish water with high concentrations of silica and calcium sulfate. Prior investigations have shown that the CERRO process can treat this kind of water without fouling or scaling the membranes, but the main factors that allow the system to operate in such conditions were not studied. The research presented here is an evaluation of the CERRO process as an efficient RO concentrate management system. The parameters of operation of the system were evaluated and improved. The precipitation of calcium sulfate was identified as …

Scalar Polarization Operator In A Superfluid Medium, Sajib Kumar Barman

Open Access Theses & Dissertations

A QCD-inspired effective theory of fermions is considered to study superfluidity. We calculate the quark propagator in a theory with fermion-fermion condensate at finite density. In this theory color degrees of freedom are absent and the quark-quark interaction is modeled through a Yukawa interaction term. Since the diquark condensate is neutral, the system is a superfluid. To study the response of this superfluid to the scalar field propagation, we find the scalar polarization operator of the system.

Integrated Geological And Geophysical Studies Of The Indio Mountains And Hueco Bolson, West Texas, Pawan Budhathoki

Open Access Theses & Dissertations

This Dissertation consists of two different projects. The first project describes the results of an outcrop based sequence stratigraphic study of the Albian Cox Sandstone in the Indio Mountains of west Texas. The depositional environment of the Cox Sandstone ranges from shallow marine to the coastal plain deposited in four sequences where sequence 1 and sequence 2 consists of transgressive system tracts (TST) followed by highstand system tracts (HST). The highstand system tract (HST) is missing in sequence 3 and the transgressive systems tract is missing in sequence 4. The Cox changes in thickness from 320 m in the northern …

Lead And Associated Heavy Metal Distribution In El Paso, Texas, Ali Ragab Elkekli

Open Access Theses & Dissertations

Contamination by lead and other heavy metals is one of the most important environmental concerns of today, locally and globally. This issue has led scientists and researchers to study the effect of heavy metals and their distribution in the environment. The aim of the present research is to document the concentration and geographic distribution of heavy metals in El Paso.

The selected heavy metals in the El Paso soil are lead, cadmium, chromium, zinc, antimony and copper. The soil sample for the study was collected during a previous community lead study (RO1 ESO11367; 2001-2006). 500 superficial soils samples were collected …

Urban Impact Of Dissolved Metals In The Paso Del Norte Segment Of The Rio Grande, Sumayeh Ahmad Freiwan

Open Access Theses & Dissertations

The Paso del Norte segment of the Rio Grande experiences two seasons per year; the (wet) irrigation season and the (dry) non-irrigation season. The goal of this study was to improve the understanding of occurrence and contribution of dissolved metals in this region during the non-irrigation season. The objectives of this study were to (1) evaluate the impact of anthropogenic sources of metals on the Rio Grande water quality during the non-irrigation season, and (2) estimate the metal loads carried by the flow to the downstream region of El Paso. In order to evaluate the surface water quality of the …

Reduced-Order Modeling Using Orthogonal And Bi-Orthogonal Wavelet Transforms, Miguel Hernandez Iv

Open Access Theses & Dissertations

It is well known that model reduction methods borrow techniques typically found in data compression, and current state-of-the-art techniques for data compression are based on the wavelet transform. Given these facts, it is surprising that model reduction using wavelets has not received much attention and has not been adequately addressed in the literature. This research seeks to determine if wavelets can be used for model reduction and if wavelet model reduction is a viable alternative to existing model reduction methods.

In this work we propose a novel method for model reduction using wavelets. Specifically, we introduce techniques for deriving wavelet …

Toward New Data And Information Management Solutions For Data-Intensive Ecological Research, Christine Marie Laney

Open Access Theses & Dissertations

Ecosystem health is deteriorating in many parts of the world due to direct and indirect anthropogenic pressures. Generating accurate, useful, and impactful models of past, current, and future states of ecosystem structure and function is a complex endeavor that often requires vast amounts of data from multiple sources and knowledge from collaborating researchers. Ecological data collection has improved rapidly over the past few decades due to the development, innovation, and large scale deployment of automated sensors, which are capable of measuring a gamut of ecosystem properties over broad spatiotemporal scales. Although complex ecosystem models and analyses are increasingly parameterized with …

Crystal Structure, Phase, And Optical Properties Of Yttrium-Doped Hafnium Oxide Nanocrystalline Thin Films, Alejandro Ortega

Open Access Theses & Dissertations

Yttrium-doped hafnium oxide (YDH) nanocrystalline films were produced by sputter-deposition at various substrate times and temperatures, to produce YDH films in a wide range of thicknesses, dYDH∼25 to 1100 nm. The deposition was made onto optical grade quartz and sapphire substrates. Samples deposited on sapphire were subject to post-deposition annealing (PDA) at various times (3-24 hr) and temperatures (1100 - 1500 °C). The effect of d[special characters omitted]YDH on the crystal structure, surface/interface morphology and optical properties of YDH films was investigated. X-ray diffraction analyses revealed the formation of monoclinic phase for relatively thin films (<150nm). The evolution towards stabilized cubic phase with increasing dYDH [special characters omitted]is observed. The scanning electron microscopy results indicate the dense, columnar structure of YDH films as a function of dYDH. Spectrophotometry analyses indicate that the grown YDH films are transparent and exhibit interference fringes. The band gap was found to be ∼ 5.60 eV for monoclinic YDH films while distinct separation and an increase in band gap to 6.03 eV is evident with increasing dYDH and formation cubic YDH films. The PDA films band gaps were found to be between 5.31 and 5.72 eV, all of which exhibit secondary gaps. A correlation between growth conditions, annealing, phase evolution, and optical properties of the YDH nanocrystalline thin films is established.

Refining Molecular Approaches For Bacterial Source Tracking (Bst) In Texas, Joy Truesdale

Open Access Theses & Dissertations

Bacterial source tracking (BST) is a new science that aids in identifying sources of human and animal fecal contamination of environmental water. There are currently two approaches used in BST, library-dependent and library-independent methods. The fecal bacterium E. coli is often used in library dependent methods because it indicates fecal contamination, has been used in human health risk assessments, and has water quality regulatory significance. A disadvantage of E. coli library dependent BST methods is that identification libraries of E. coli isolated from known fecal sources are needed to identify the sources of E. coli isolated from water samples. Further, …

A Block Operator Splitting Method For Heterogeneous Multiscale Poroelasticity, Paul M. Delgado

Open Access Theses & Dissertations

Traditional models of poroelastic deformation in porous media assume relatively homogeneous material properties such that macroscopic constitutive relations lead to accurate results. Many realistic applications involve heterogeneous material properties whose oscillatory nature require multiscale methods to balance accuracy and efficiency in computation.

The current study develops a multiscale method for poroelastic deformation based on a fixed point iteration based operator splitting method and a heterogeneous multiscale method using finite volume and direct stiffness methods. To characterize the convergence

of the operator splitting method, we use a numerical root finding algorithm to determine a threshold surface in a non-dimensional parameter space …

Principal Differential Analysis: Incorporating Covariates Using Kernel Smoothers, Christopher Alfred Dodoo

Open Access Theses & Dissertations

Principal Differential Analysis is a statistical technique which suggests that a given set of functional data curves can be annihilated completely when an estimated linear differential

operator (LDO) is applied (Coddington & Levinson). The novelty of residuals as forcing functions is introduced in PDA.

This thesis builds on PDA with covariates by Jin et al, 2012 by dropping the assumption that the coefficients of the linear differential operator are a product of a function in t and v; the equivalent kernel is used to estimate the coefficient functions at target values. Incorporating covariates with kernel smoothers leads to two …

A Case Study Towards Verification Of The Utility Of Analytical Models In Selecting Checkpoint Intervals, Michael Joseph Harney

Open Access Theses & Dissertations

As high performance computing (HPC) systems grow larger, with increasing numbers of components, failures become more common. Codes that utilize large numbers of nodes and run for long periods of time must take such failures into account and adopt fault tolerance mechanisms to avoid loss of computation and, thus, system utilization. One of those mechanisms is checkpoint/restart. Although analytical models exist to guide users in the selection of an appropriate checkpoint interval, these models are based on assumptions that may not always be true. This thesis examines some of these assumptions, in particular, the consistency of parameters like Mean Time …

Deprivation And Hispanic Health Paradox: Neighborhood Effects On Children's Wheezing In El Paso, Texas, Young-An Kim

Open Access Theses & Dissertations

This study examines the impact of hypothetical health determinants - including objective and relative economic deprivation, as well as foreign-born composition -at the neighborhood-level on respiratory wheezing among Hispanic children in El Paso, Texas while accounting for individual-level covariates based on hierarchical logistic modeling (HLM). Due to El Paso's majority Latino/a population, focus is placed on the so-called "Hispanic health paradox" through analysis of the impact of neighborhood foreign-born composition on Hispanic children's wheezing. Neighborhood-level variables at the census tract-level are derived from US Census data. The percent of families in poverty and the GINI coefficient for income (income inequality) …

Optimization Of Biomass Logistics System Using Genetic Algorithm And Particle Swarm Optimization For Biofuel Production, Ethel Regina Martinez-Schabez

Open Access Theses & Dissertations

As time goes by, Renewable Energy keeps proving to be an important and potential replacement for fossil fuels. All the different types of Renewable Energy offer a relief to the environmental aftermaths of the prolonged reliance on fossil fuel energy. Bioenergy is one of the types of Renewable Energy that can help by minimizing the emissions of fossil fuels. The Energy Independence and Security Act mandates the use of 21 billion gallons of advanced biofuels including 16 billion gallons of cellulosic biofuels by the year 2022. Biomass and Biofuels can clearly become a significant aid to sustainably supply energy in …