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Articles 91 - 120 of 4868

Full-Text Articles in Physical Sciences and Mathematics

Graphitic Carbon Nitride With Thermally-Induced Nitrogen Defects: An Efficient Process To Enhance Photocatalytic H2production Performance, Guangzhi Dong, Yun Wen, Huiqing Fan, Chao Wang, Zhenxiang Cheng, Mingchang Zhang, Jiangwei Ma, Shujun Zhang Jan 2020

Graphitic Carbon Nitride With Thermally-Induced Nitrogen Defects: An Efficient Process To Enhance Photocatalytic H2production Performance, Guangzhi Dong, Yun Wen, Huiqing Fan, Chao Wang, Zhenxiang Cheng, Mingchang Zhang, Jiangwei Ma, Shujun Zhang

Australian Institute for Innovative Materials - Papers

Graphitic carbon nitride (g-C3N4, CN) with nitrogen vacancies was synthesized by a controlled thermal etching method in a semi-closed air-conditioning system. The defect-modified g-C3N4shows an excellent photocatalytic performance demonstrated by water splitting under visible light irradiation. With proper heat-treatment durations such as 2 h (CN2) and 4 h (CN4) at 550 °C, the hydrogen production rates significantly increase to 100 µmol h-1and 72 µmol h-1, which are 11 times and 8 times the rate of the pristine CN (8.8 µmol h-1) respectively. The excellent hydrogen production performance of nitrogen defect modified CN2 is due to the synergy effect of the …

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Understanding High-Rate K+-Solvent Co-Intercalation In Natural Graphite For Potassium-Ion Batteries, Lin Li, Luojia Liu, Zhe Hu, Yong Lu, Qiannan Liu, Song Jin, Qiu Zhang, Shuo Zhao, Shulei Chou Jan 2020

Understanding High-Rate K+-Solvent Co-Intercalation In Natural Graphite For Potassium-Ion Batteries, Lin Li, Luojia Liu, Zhe Hu, Yong Lu, Qiannan Liu, Song Jin, Qiu Zhang, Shuo Zhao, Shulei Chou

Australian Institute for Innovative Materials - Papers

© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Graphite shows great potential as an anode material for rechargeable metal-ion batteries because of its high abundance and low cost. However, the electrochemical performance of graphite anode materials for rechargeable potassium-ion batteries needs to be further improved. Reported herein is a natural graphite with superior rate performance and cycling stability obtained through a unique K+-solvent co-intercalation mechanism in a 1 m KCF3SO3 diethylene glycol dimethyl ether electrolyte. The co-intercalation mechanism was demonstrated by ex situ Fourier transform infrared spectroscopy and in situ X-ray diffraction. Moreover, the structure of the [K-solvent]+ complexes …

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Twins Or The Omega Phase: Which Is It In High Carbon Steels?, Gilberto Casillas, Wenwen Song, Azdiar Adil Gazder Jan 2020

Twins Or The Omega Phase: Which Is It In High Carbon Steels?, Gilberto Casillas, Wenwen Song, Azdiar Adil Gazder

Australian Institute for Innovative Materials - Papers

© 2020 Acta Materialia Inc. Electron diffraction coupled with aberration-corrected (AC) scanning transmission electron microscopy (STEM) is used to image, identify and confirm the structure producing double diffracted spots seen in electron diffraction patterns in twinned high-carbon steels. The experimental and simulated data show that regions comprising: (i) overlaps between a twin and the matrix or, (ii) overlapping twins, create projected structures that are similar to the ω phase observed in other metastable bcc systems. Thus, AC STEM is proficient in the definitive identification of twins in bcc high carbon steels or nanoscale phases in metastable bcc systems.

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Controlled Hydrogenation Into Defective Interlayer Bismuth Oxychloride Via Vacancy Engineering, Dandan Cui, Kang Xu, Xingan Dong, Dongdong Lv, Fan Dong, Weichang Hao, Yi Du, Jun Chen Jan 2020

Controlled Hydrogenation Into Defective Interlayer Bismuth Oxychloride Via Vacancy Engineering, Dandan Cui, Kang Xu, Xingan Dong, Dongdong Lv, Fan Dong, Weichang Hao, Yi Du, Jun Chen

Australian Institute for Innovative Materials - Papers

Hydrogenation is an effective approach to improve the performance of photocatalysts within defect engineering methods. The mechanism of hydrogenation and synergetic effects between hydrogen atoms and local electronic structures, however, remain unclear due to the limits of available photocatalytic systems and technical barriers to observation and measurement. Here, we utilize oxygen vacancies as residential sites to host hydrogen atoms in a layered bismuth oxychloride material containing defects. It is confirmed theoretically and experimentally that the hydrogen atoms interact with the vacancies and surrounding atoms, which promotes the separati30on and transfer processes of photo-generated carriers via the resulting band structure. The …

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A Wearable Sensor For The Detection Of Sodium And Potassium In Human Sweat During Exercise, Paolo Pirovano, Matthew Dorrian, Akshay Shinde, Andrew Donohoe, Aidan Brady, Niall Moyna, Gordon G. Wallace, Dermot Diamond, Margaret Mccaul Jan 2020

A Wearable Sensor For The Detection Of Sodium And Potassium In Human Sweat During Exercise, Paolo Pirovano, Matthew Dorrian, Akshay Shinde, Andrew Donohoe, Aidan Brady, Niall Moyna, Gordon G. Wallace, Dermot Diamond, Margaret Mccaul

Australian Institute for Innovative Materials - Papers

© 2020 The Author(s) The SwEatch platform, a wearable sensor for sampling and measuring the concentration of electrolytes in human sweat in real time, has been improved in order to allow the sensing of two analytes. The solid contact ion-sensitive electrodes (ISEs) for the detection of Na+ and K+ have been developed in two alternative formulations, containing either poly(3,4-ethylenedioxythiophene) (PEDOT) or poly(3-octylthiophene-2,5-diyl) (POT) as a conductive polymer transducing component. The solution-processable POT formulation simplifies the fabrication process, and sensor to sensor reproducibility has been improved via partial automation using an Opentron® automated pipetting robot. The resulting electrodes showed good sensitivity …

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Ultrahigh Electromechanical Coupling And Its Thermal Stability In (Na1/2bi1/2)Tio3-Based Lead-Free Single Crystals, Chao Chen, Li Yang, Xingan Jiang, Xiaokun Huang, Xiaoyi Gao, Na Tu, Kaizheng Shu, Xiangping Jiang, Shujun Zhang, Haosu Luo Jan 2020

Ultrahigh Electromechanical Coupling And Its Thermal Stability In (Na1/2bi1/2)Tio3-Based Lead-Free Single Crystals, Chao Chen, Li Yang, Xingan Jiang, Xiaokun Huang, Xiaoyi Gao, Na Tu, Kaizheng Shu, Xiangping Jiang, Shujun Zhang, Haosu Luo

Australian Institute for Innovative Materials - Papers

© 2020 by the authors. Licensee MDPI, Basel, Switzerland. In this work, we report the ultrahigh electromechanical coupling performance of NBT-6BT-KNN lead-free single crystal at room temperature. The thickness mode electromechanical coupling coefficient (kt) and the 31 mode electromechanical coupling coefficient (k31) reach 69.0% and 45.7%, respectively, which are superior to the PZT-5H lead-based ceramics of kt ~ 60% and k31~39%. In addition, the evolution of the crystal structure and domain morphology is revealed by Raman scattering spectra, a polarizing microscope and piezoelectric force microscopy characterization.

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Nodal Ring Spin Gapless Semiconductor: New Member Of Spintronic Materials, Tie Yang, Zhenxiang Cheng, Xiaotian Wang, Xiaolin Wang Jan 2020

Nodal Ring Spin Gapless Semiconductor: New Member Of Spintronic Materials, Tie Yang, Zhenxiang Cheng, Xiaotian Wang, Xiaolin Wang

Australian Institute for Innovative Materials - Papers

Both spin gapless semiconductors (SGSs) and nodal ring states (NRSs) have aroused great scientific interest in recent years due to their unique electronic properties and high application potential. However, since their advent, all SGSs and NRSs have been predicted in independent materials. In this work, we proposed a novel type of material, nodal ring spin gapless semiconductor (NRSGS), which combines both states of the SGSs and NRSs. The synthesized material Mg2VO4 is selected as a potential candidate. Detailed band structure analysis reveals that there are gapless crossings in the spin-up direction, which are from multiple topological nodal rings located exactly …

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Optimum Electrical And Dielectric Performance Of Multi-Walled Carbon Nanotubes Doped Disposed Transformer Oil, Nur Suhaimi, Muhamad Din, Abdul Rahman, Mardhiah Hamid, Nur Amin, Wan Zamri, Jian Li Wang Jan 2020

Optimum Electrical And Dielectric Performance Of Multi-Walled Carbon Nanotubes Doped Disposed Transformer Oil, Nur Suhaimi, Muhamad Din, Abdul Rahman, Mardhiah Hamid, Nur Amin, Wan Zamri, Jian Li Wang

Australian Institute for Innovative Materials - Papers

© 2020 by the authors. This paper intends to prepare a nanofluid sample by suspending Multi-walled Carbon Nanotubes (MWCNTs) at 0.005g/L concentration and analyze the behavior of electrical and dielectric properties based on the International Electrotechnical Commision test method. In order to validate the effectiveness of MWCNT nanofluid, alternating current breakdown voltage (BDV), negative polarity lightning impulse (LI), dielectric permittivity, dissipation factor (DF), DC resistivity and Raman structural measurement are executed accordingly. In the following, an analysis of the statistical distribution using the two-parameterWeibull distribution law of BDV and LI are evaluated at four experimental conditions to predict the probability …

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Recent Progress On Understanding And Constructing Reliable Na Anode For Aprotic Na-O2 Batteries: A Mini Review, Shuo Zhao, Lin Li, Fujun Li, Shulei Chou Jan 2020

Recent Progress On Understanding And Constructing Reliable Na Anode For Aprotic Na-O2 Batteries: A Mini Review, Shuo Zhao, Lin Li, Fujun Li, Shulei Chou

Australian Institute for Innovative Materials - Papers

© 2020 The Authors Aprotic Na-O2 batteries attract increasing attention for the low charging/discharging overpotentials, high energy density, and low cost. Significant progress has been achieved in the battery system, but challenges remain in constructing reliable Na anodes. This review presents an overview of the fundamental understanding of Na anodes in aprotic Na-O2 batteries, including chemical reactivity of Na metal and dendrite formation mechanism. The constructing strategies are summarized as mechanical reinforcement of separators, electrolyte modifications, and electrode structure and material design. Perspectives are envisioned for the further development of durable Na anodes for aprotic Na-O2 batteries.

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Supercritical Co2-Constructed Intralayer [Bi2o2]2+Structural Distortion For Enhanced Co2 Electroreduction, Yannan Zhou, Pengfei Yan, Jun Jia, Suoying Zhang, Xiaoli Zheng, Li Zhang, Bin Zhang, Jun Chen, Weichang Hao, Gongji Chen, Qun Xu, Buxing Han Jan 2020

Supercritical Co2-Constructed Intralayer [Bi2o2]2+Structural Distortion For Enhanced Co2 Electroreduction, Yannan Zhou, Pengfei Yan, Jun Jia, Suoying Zhang, Xiaoli Zheng, Li Zhang, Bin Zhang, Jun Chen, Weichang Hao, Gongji Chen, Qun Xu, Buxing Han

Australian Institute for Innovative Materials - Papers

© 2020 The Royal Society of Chemistry. Inducing crystal distortion in two-dimensional (2D) materials to increase the number of active sites is of great significance in improving the intrinsic activity of electrocatalysts for the CO2 reduction reaction (CO2RR). Developing 2D materials as thin as possible is required for this goal. Herein, taking layered BiOCl as a prototype model, we achieved the intralayer [Bi2O2]2+ structural distortion by using supercritical CO2 as a solvent to reduce the number of interlayer chlorine atoms involved in the reaction. Contrary to expectations, further CO2RR experiments indicate that thick nanoplates exhibit a high faradaic efficiency of …

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Magnetic Modulation Of Terahertz Waves Via Spin-Polarized Electron Tunneling Based On Magnetic Tunnel Junctions, Zuanming Jin, Jugeng Li, Wenjie Zhang, Chenyang Guo, Caihua Wan, Xiufeng Han, Zhenxiang Cheng, C Zhang, Alexey Balakin, Alexander Shkurinov, Yan Peng, Guohong Ma, Yiming Zhu, Jianquan Yao, Songlin Zhuang Jan 2020

Magnetic Modulation Of Terahertz Waves Via Spin-Polarized Electron Tunneling Based On Magnetic Tunnel Junctions, Zuanming Jin, Jugeng Li, Wenjie Zhang, Chenyang Guo, Caihua Wan, Xiufeng Han, Zhenxiang Cheng, C Zhang, Alexey Balakin, Alexander Shkurinov, Yan Peng, Guohong Ma, Yiming Zhu, Jianquan Yao, Songlin Zhuang

Australian Institute for Innovative Materials - Papers

© 2020 American Physical Society. Magnetic tunnel junctions (MTJs) are a key technology in modern spintronics because they are the basis of read-heads of modern hard disk drives, nonvolatile magnetic random access memories, and sensor applications. In this paper, we demonstrate that tunneling magnetoresistance can influence terahertz (THz) wave propagation through a MTJ. In particular, various magnetic configurations between parallel state and antiparallel state of the magnetizations of the ferromagnetic layers in the MTJ have the effect of changing the conductivity, making a functional modulation of the propagating THz electromagnetic fields. Operating in the THz frequency range, a maximal modulation …

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Coupling N2 And Co2 In H2o To Synthesize Urea Under Ambient Conditions, Chen Chen, Xiaorong Zhu, Xiaojian Wen, Yangyang Zhou, Ling Zhou, Hao Li, Li Tao, Qiling Li, Shiqian Du, Tingting Liu, Dafeng Yan, Chao Xie, Yuqin Zou, Yanyong Wang, Ru Chen, Jia Huo, Yafei Liu, Jun Cheng, Hui Su, Xu Zhao, Weiren Cheng, Qinghua Liu, Hongzhen Lin, Jun Luo, Jun Chen, Mingdong Dong, Kai Cheng, Conggang Li, Shuangyin Wang Jan 2020

Coupling N2 And Co2 In H2o To Synthesize Urea Under Ambient Conditions, Chen Chen, Xiaorong Zhu, Xiaojian Wen, Yangyang Zhou, Ling Zhou, Hao Li, Li Tao, Qiling Li, Shiqian Du, Tingting Liu, Dafeng Yan, Chao Xie, Yuqin Zou, Yanyong Wang, Ru Chen, Jia Huo, Yafei Liu, Jun Cheng, Hui Su, Xu Zhao, Weiren Cheng, Qinghua Liu, Hongzhen Lin, Jun Luo, Jun Chen, Mingdong Dong, Kai Cheng, Conggang Li, Shuangyin Wang

Australian Institute for Innovative Materials - Papers

© 2020, The Author(s), under exclusive licence to Springer Nature Limited. The use of nitrogen fertilizers has been estimated to have supported 27% of the world’s population over the past century. Urea (CO(NH2)2) is conventionally synthesized through two consecutive industrial processes, N2 + H2 → NH3 followed by NH3 + CO2 → urea. Both reactions operate under harsh conditions and consume more than 2% of the world’s energy. Urea synthesis consumes approximately 80% of the NH3 produced globally. Here we directly coupled N2 and CO2 in H2O to produce urea under ambient conditions. The process was carried out using an …

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Ac Loss And Contact Resistance Of Different Cicc Cable Patterns: Experiments And Numerical Modeling, Anvar Valiyaparambil Abdulsalam, J Qin, Y Wu, T Bagni, A Devred, T Haugan, Md. Shahriar Al Hossain, C Zhou, Arend Nijhuis Jan 2020

Ac Loss And Contact Resistance Of Different Cicc Cable Patterns: Experiments And Numerical Modeling, Anvar Valiyaparambil Abdulsalam, J Qin, Y Wu, T Bagni, A Devred, T Haugan, Md. Shahriar Al Hossain, C Zhou, Arend Nijhuis

Australian Institute for Innovative Materials - Papers

© 2020 The Author(s) For upcoming nuclear fusion energy reactors, like the China Fusion Engineering Test Reactor (CFETR) and EU-DEMO, the superconducting Cable-In-Conduit Conductors (CICC) are in the design phase, and the operating conditions like electromagnetic forces can be higher than in previous devices like ITER. The prototype conductors for the Central Solenoid (CS) coils in the CFETR, for example, are designed to produce a peak field of 19.9 T and are expected to be made of high current density Nb3Sn strands. Investigations are also ongoing on the application of bismuth strontium calcium copper oxide (BSCCO) and MgB2 strands for …

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A Self‐Assembled Co2 Reduction Electrocatalyst: Posy‐Bouquet‐Shaped Gold‐Polyaniline Core‐Shell Nanocomposite, Amruthalakshmi Vijayakumar, Yong Zhao, Jinshuo Zou, Kezhong Wang, Chong Yong Lee, Douglas Macfarlane, Caiyun Wang, Gordon G. Wallace Jan 2020

A Self‐Assembled Co2 Reduction Electrocatalyst: Posy‐Bouquet‐Shaped Gold‐Polyaniline Core‐Shell Nanocomposite, Amruthalakshmi Vijayakumar, Yong Zhao, Jinshuo Zou, Kezhong Wang, Chong Yong Lee, Douglas Macfarlane, Caiyun Wang, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

© 2020 Wiley-VCH GmbH Here it was demonstrated that the decoration of gold (Au) with polyaniline is an effective approach in increasing its electrocatalytic reduction of CO2 to CO. The core-shell-structured gold-polyaniline (Au−PANI) nanocomposite delivered a CO2-to-CO conversion efficiency of 85 % with a high current density of 11.6 mA cm−2. The polyaniline shell facilitated CO2 adsorption, and the subsequent formation of reaction intermediates on the gold core contributed to the high efficiency observed.

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Fully 3d Printed Soft Microactuators For Soft Microrobotics, Manav Tyagi, Geoffrey M. Spinks, Edwin W. Jager Jan 2020

Fully 3d Printed Soft Microactuators For Soft Microrobotics, Manav Tyagi, Geoffrey M. Spinks, Edwin W. Jager

Australian Institute for Innovative Materials - Papers

© 2020 IOP Publishing Ltd. The feasibility of additive manufacturing actuating microstructures and microdevices with small dimension is presented. Using a custom-built extrusion 3D printer and CAD model of the device structure, bilayer microactuators driven by hydrogels are fabricated down to a size of 300 × 1000 μm2, with a minimum thickness of 30 μm. To explore the limitations of the 3D printing process, microactuators with a width of 300 μm and lengths ranging from 1000 to 5000 μm are manufactured and thereafter operated to demonstrate the feasibility of the process. Similarly, microrobotic devices consisting of a passive rigid body …

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Tuning Interface Bridging Between Mose2 And Three-Dimensional Carbon Framework By Incorporation Of Moc Intermediate To Boost Lithium Storage Capability, Jing Chen, Yilin Luo, Wenchao Zhang, Yun Qiao, Xinxin Cao, Xuefang Xie, Haoshen Zhou, Anqiang Pan, Shuquan Liang Jan 2020

Tuning Interface Bridging Between Mose2 And Three-Dimensional Carbon Framework By Incorporation Of Moc Intermediate To Boost Lithium Storage Capability, Jing Chen, Yilin Luo, Wenchao Zhang, Yun Qiao, Xinxin Cao, Xuefang Xie, Haoshen Zhou, Anqiang Pan, Shuquan Liang

Australian Institute for Innovative Materials - Papers

© 2020, The Author(s). Highlights: MoSe2/MoC/C multiphase boundaries boost ionic transfer kinetics.MoSe2 (5–10 nm) with rich edge sites is uniformly coated in N-doped framework.The obtained MoSe2 nanodots achieved ultralong cycle performance in LIBs and high capacity retention in full cell. Abstract: Interface engineering has been widely explored to improve the electrochemical performances of composite electrodes, which governs the interface charge transfer, electron transportation, and structural stability. Herein, MoC is incorporated into MoSe2/C composite as an intermediate phase to alter the bridging between MoSe2- and nitrogen-doped three-dimensional (3D) carbon framework as MoSe2/MoC/N–C connection, which greatly improve the structural stability, electronic conductivity, …

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Controllable S-Vacancies Of Monolayered Mo–S Nanocrystals For Highly Harvesting Lithium Storage, Linlin Fan, Shulai Lei, Hirbod Kheimeh, Longsheng Zhong, Alibek Kakimov, Jingjing Wang, Jun Chen, Dezheng Liu, Liang Huang, Junhua Hu, Liangxu Lin, Xifei Li Jan 2020

Controllable S-Vacancies Of Monolayered Mo–S Nanocrystals For Highly Harvesting Lithium Storage, Linlin Fan, Shulai Lei, Hirbod Kheimeh, Longsheng Zhong, Alibek Kakimov, Jingjing Wang, Jun Chen, Dezheng Liu, Liang Huang, Junhua Hu, Liangxu Lin, Xifei Li

Australian Institute for Innovative Materials - Papers

© 2020 Elsevier Ltd Two-dimensional (2D) monolayers are promising in electrochemical energy storages (EES), while their performance is still far below than that can be exploited. Understanding 2D monolayers, particularly thin nanocrystals (NCs) with and without surface modifications in EES would be interesting. This work demonstrates how monolayered molybdenum sulfide (Mo–S) NCs with S vacancies perform as a promising anode material to improve many aspects of lithium-ion batteries (LIBs), by utilizing their metallicity, multi-layer adsorption, minimized self-discharge and fast 2D capacitive processes. By way of examples, we demonstrate an increasing trend of the energy capacity and improved lithium diffusion kinetics …

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Alkali-Metal Sulfide As Cathodes Toward Safe And High-Capacity Metal (M = Li, Na, K) Sulfur Batteries, Huiling Yang, Binwei Zhang, Yunxiao Wang, Konstantin K. Konstantinov, Hua-Kun Liu, Shi Xue Dou Jan 2020

Alkali-Metal Sulfide As Cathodes Toward Safe And High-Capacity Metal (M = Li, Na, K) Sulfur Batteries, Huiling Yang, Binwei Zhang, Yunxiao Wang, Konstantin K. Konstantinov, Hua-Kun Liu, Shi Xue Dou

Australian Institute for Innovative Materials - Papers

© 2020 Wiley-VCH GmbH Rechargeable alkali-metal–sulfur (M–S) batteries, because of their high energy density and low cost, have been recognized as one of the most promising next-generation energy storage technologies. Nevertheless, the dissolution of metal polysulfides in organic liquid electrolytes and safety issues related to the metal anodes are greatly hindering the development of the M–S batteries. Alkali-metal sulfides (M2Sx) are emerging as cathode materials, which can pair with various safe nonalkali-metal anodes, such as silicon and tin. As a result, the combined M2Sx cathode-based M–S batteries can achieve high capacity as well as safety, thereby providing a more feasible …

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Ultrafast Electron Transport In Metallic Antiferromagnetic Mn2au Thin Films Probed By Terahertz Spectroscopy, Zuanming Jin, Shunyi Ruan, Xiaofeng Zhou, Bangju Song, Cheng Song, Xianzhe Chen, Feng Pan, Yan Peng, C Zhang, Guohong Ma, Yiming Zhu, Songlin Zhuang Jan 2020

Ultrafast Electron Transport In Metallic Antiferromagnetic Mn2au Thin Films Probed By Terahertz Spectroscopy, Zuanming Jin, Shunyi Ruan, Xiaofeng Zhou, Bangju Song, Cheng Song, Xianzhe Chen, Feng Pan, Yan Peng, C Zhang, Guohong Ma, Yiming Zhu, Songlin Zhuang

Australian Institute for Innovative Materials - Papers

The ultrafast electron transport is central to the requirement of all-electrically controlled spintronics in metallic collinear antiferromagnetic (AFM) Mn2Au thin films within the terahertz (THz) range. Here we use the THz time-domain spectroscopy to measure the conductivity spectra of Mn2Au thin films with different thicknesses and temperatures. We demonstrate an onset of carrier localization in Mn2Au with decreasing the film thickness from 15 to 5 nm. By using optical pump-THz probe spectroscopy, we found the surface trapping states in the thinnest Mn2Au film limit its photoconductivity significantly. The DC conductivity and scattering time become larger and longer with decreasing temperature …

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3d Printed Soft Pneumatic Bending Sensing Chambers For Bilateral And Remote Control Of Soft Robotic Systems, Charbel Tawk, Marc In Het Panhuis, Geoffrey M. Spinks, Gursel Alici Jan 2020

3d Printed Soft Pneumatic Bending Sensing Chambers For Bilateral And Remote Control Of Soft Robotic Systems, Charbel Tawk, Marc In Het Panhuis, Geoffrey M. Spinks, Gursel Alici

Australian Institute for Innovative Materials - Papers

© 2020 IEEE. This work reports on soft pneumatic bending sensing chambers that are directly 3D printed without requiring any support material and postprocessing using a low-cost and open-source fused deposition modeling (FDM) 3D printer and a commercially available soft thermoplastic polyurethane (TPU). These bending sensing chambers have multiple advantages including very fast response to any change in their internal volume, linearity, negligible hysteresis, repeatability, reliability, stability over time, long lifetime and very low power consumption. The performance of these soft sensing chambers is accurately predicted and optimized using finite element modeling (FEM) and a hyperelastic material model for the …

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Topographical And Compositional Engineering Of Core-Shell Ni@Pt Orr Electro-Catalysts, Gerard Leteba, David R. G Mitchell, Pieter Levecque, Eric Van Steen, Candace Lang Jan 2020

Topographical And Compositional Engineering Of Core-Shell Ni@Pt Orr Electro-Catalysts, Gerard Leteba, David R. G Mitchell, Pieter Levecque, Eric Van Steen, Candace Lang

Australian Institute for Innovative Materials - Papers

© 2020 The Royal Society of Chemistry. Complex faceted geometries and compositional anisotropy in alloy nanoparticles (NPs) can enhance catalytic performance. We report on the preparation of binary PtNi NPs via a co-thermolytic approach in which we optimize the synthesis variables, which results in significantly improved catalytic performance. We used scanning transmission electron microscopy to characterise the range of morphologies produced, which included spherical and concave cuboidal core-shell structures. Electrocatalytic activity was evaluated using a rotating disc electrode (1600 rpm) in 0.1 M HClO4; the electrocatalytic performance of these Ni@Pt NPs showed significant (∼11-fold) improvement compared to a commercial Pt/C …

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Highly Flexible Reduced Graphene Oxide@Polypyrrole-Polyethylene Glycol Foam For Supercapacitors, Chaoyue Cai, Jialong Fu, Chengyan Zhang, Cheng Wang, Rui Sun, Shufang Guo, Fan Zhang, Mingyan Wang, Yuqing Liu, Jun Chen Jan 2020

Highly Flexible Reduced Graphene Oxide@Polypyrrole-Polyethylene Glycol Foam For Supercapacitors, Chaoyue Cai, Jialong Fu, Chengyan Zhang, Cheng Wang, Rui Sun, Shufang Guo, Fan Zhang, Mingyan Wang, Yuqing Liu, Jun Chen

Australian Institute for Innovative Materials - Papers

© 2020 The Royal Society of Chemistry. A flexible and free-standing 3D reduced graphene oxide@polypyrrole-polyethylene glycol (RGO@PPy-PEG) foam was developed for wearable supercapacitors. The device was fabricated sequentially, beginning with the electrodeposition of PPy in the presence of a PEG-borate on a sacrificial Ni foam template, followed by a subsequent GO wrapping and chemical reduction process. The 3D RGO@PPy-PEG foam electrode showed excellent electrochemical properties with a large specific capacitance of 415 F g-1 and excellent long-term stability (96% capacitance retention after 8000 charge-discharge cycles) in a three electrode configuration. An assembled (two-electrode configuration) symmetric supercapacitor using RGO@PPy-PEG electrodes exhibited …

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Improved Na Storage And Coulombic Efficiency In Tip2o7@C Microflowers For Sodium Ion Batteries, Jun Pan, Nana Wang, Lili Li, Feng Zhang, Zhenjie Cheng, Yanlu Li, Jian Yang, Yitai Qian Jan 2020

Improved Na Storage And Coulombic Efficiency In Tip2o7@C Microflowers For Sodium Ion Batteries, Jun Pan, Nana Wang, Lili Li, Feng Zhang, Zhenjie Cheng, Yanlu Li, Jian Yang, Yitai Qian

Australian Institute for Innovative Materials - Papers

© 2020, Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature. Ti-based anode materials in sodium ion batteries have attracted extensive interests due to its abundant resources, low toxicity, easy synthesis and long cycle life. However, low Coulombic efficiency and limited specific capacity affect their applications. Here, cubic-phase TiP2O7 is examined as anode materials, using in-situ/ex-situ characterization techniques. It is concluded that the redox reactions of Ti4+/Ti3+ and Ti3+/Ti0 consecutively occur during the discharge/charge processes, both of which are highly reversible. These reactions make the specific capacity of TiP2O7 even higher than the case of TiO2 that only …

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Fabrication Of Heterostructured Uio-66-Nh2 /Cnts With Enhanced Activity And Selectivity Over Photocatalytic Co2 Reduction, Xiaojun Wang, Guorui Yang, Guodong Chai, Muhammad Nasir, Silan Wang, Xing Zheng, Caiyun Wang, Wei Yan Jan 2020

Fabrication Of Heterostructured Uio-66-Nh2 /Cnts With Enhanced Activity And Selectivity Over Photocatalytic Co2 Reduction, Xiaojun Wang, Guorui Yang, Guodong Chai, Muhammad Nasir, Silan Wang, Xing Zheng, Caiyun Wang, Wei Yan

Australian Institute for Innovative Materials - Papers

© 2020 Hydrogen Energy Publications LLC Developing photocatalysts with superior efficiency and selectivity is an important issue for photocatalytic converting CO2. Hierarchically heterostructured one-dimensional nanomaterials represent a kind of promising catalysts for photocatalytic CO2 reduction on account of the high surface area and synthetic effect between different components. Herein, we synthesized UIO-66-NH2/carbon nanotubes (CNTs) heterostructures via a hydrothermal method, and investigated their photocatalytic performance. The element mapping, X-ray diffraction, and X-ray photoelectron spectroscopy collectively confirmed that the UIO-66-NH2 was successfully loaded on the surface of the CNTs. The specific surface area of the UIO-66-NH2/CNTs is 1.5 times higher than that …

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Highly Ordered Macroporous Dual-Element-Doped Carbon From Metal-Organic Frameworks For Catalyzing Oxygen Reduction, Wei Xia, Michelle Hunter, Jiayu Wang, Guoxun Zhu, Sarah Warren, Yingji Zhao, Yoshio Bando, Debra Searles, Yusuke Yamauchi, Jing Tang Jan 2020

Highly Ordered Macroporous Dual-Element-Doped Carbon From Metal-Organic Frameworks For Catalyzing Oxygen Reduction, Wei Xia, Michelle Hunter, Jiayu Wang, Guoxun Zhu, Sarah Warren, Yingji Zhao, Yoshio Bando, Debra Searles, Yusuke Yamauchi, Jing Tang

Australian Institute for Innovative Materials - Papers

© The Royal Society of Chemistry 2020. Multiple heteroatom-doped carbons with 3D ordered macro/meso-microporous structures have not been realized by simple carbonization of metal-organic frameworks (MOFs). Herein, ordered macroporous phosphorus- and nitrogen-doped carbon (M-PNC) is prepared successfully by carbonization of double-solvent-induced MOF/polystyrene sphere (PS) precursors accompanied with spontaneous removal of the PS template, followed by post-doping. M-PNC shows a high specific surface area of 837 m2g−1, nitrogen doping of 3.17 at%, and phosphorus doping of 1.12 at%. Thanks to the hierarchical structure, high specific surface area, and multiple heteroatom-doping, M-PNC exhibits unusual catalytic activity as an electrocatalyst for the oxygen …

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Tunable Magnetic Anisotropy And Dzyaloshinskii-Moriya Interaction In An Ultrathin Van Der Waals Fe3gete2/In2se3 Heterostructure, Dong Chen, Wei Sun, Hang Li, Jian Li Wang, Yuanxu Wang Jan 2020

Tunable Magnetic Anisotropy And Dzyaloshinskii-Moriya Interaction In An Ultrathin Van Der Waals Fe3gete2/In2se3 Heterostructure, Dong Chen, Wei Sun, Hang Li, Jian Li Wang, Yuanxu Wang

Australian Institute for Innovative Materials - Papers

© Copyright © 2020 Chen, Sun, Li, Wang and Wang. The promise of future spintronic devices with nanoscale dimension, high-density, and low-energy consumption motivates the search for van der Waals heterostructure that stabilize topologically protected whirling spin textures such as magnetic skyrmions and domain walls. To translate these compelling features into practical devices, a key challenge lies in achieving effective manipulation of the magnetic anisotropy energy and the Dzyaloshinskii-Moriya (DM) interaction, the two key parameters that determine skyrmions. Through the first-principles calculation, we demonstrate that the polarization-induced broken inversion symmetry in the two-dimensional Fe3GeTe2/In2Se3 multiferroic heterostructure does cause an interfacial …

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Lead-Free Antiferroelectric Agnbo3: Phase Transitions And Structure Engineering For Dielectric Energy Storage Applications, Jing Gao, Qiang Li, Shujun Zhang, Jing-Feng Li Jan 2020

Lead-Free Antiferroelectric Agnbo3: Phase Transitions And Structure Engineering For Dielectric Energy Storage Applications, Jing Gao, Qiang Li, Shujun Zhang, Jing-Feng Li

Australian Institute for Innovative Materials - Papers

© 2020 Author(s). The development of electronic materials for storing electrical energy is a thriving research field, where the materials used in batteries, supercapacitors, dielectric capacitors have attracted extensive interest in last decades. The dielectric capacitors showing unique characteristics such as high power density and large charge/discharge rate have been actively studied, where the antiferroelectrics demonstrate great potentials for dielectric energy storage applications by storing and releasing energy upon a reversible electric-field induced antiferroelectric-ferroelectric phase transition. Recently, lead-free antiferroelectric AgNbO3 has emerged as a promising candidate to substitute conventional lead-based antiferroelectrics (such as PbZrO3) in energy storage applications. The phase …

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Promoted Photocharge Separation In 2d Lateral Epitaxial Heterostructure For Visible-Light-Driven Co2 Photoreduction, Li Wang, Xue Zhao, Dongdong Lv, Chuangwei Liu, Weihong Lai, Chunyi Sun, Zhongmin Su, Xun Xu, Weichang Hao, Shi Xue Dou, Yi Du Jan 2020

Promoted Photocharge Separation In 2d Lateral Epitaxial Heterostructure For Visible-Light-Driven Co2 Photoreduction, Li Wang, Xue Zhao, Dongdong Lv, Chuangwei Liu, Weihong Lai, Chunyi Sun, Zhongmin Su, Xun Xu, Weichang Hao, Shi Xue Dou, Yi Du

Australian Institute for Innovative Materials - Papers

Photocarrier recombination remains a big barrier for the improvement of solar energy conversion efficiency. For 2D materials, construction of heterostructures represents an efficient strategy to promote photoexcited carrier separation via an internal electric field at the heterointerface. However, due to the difficulty in seeking two components with suitable crystal lattice mismatch, most of the current 2D heterostructures are vertical heterostructures and the exploration of 2D lateral heterostructures is scarce and limited. Here, lateral epitaxial heterostructures of BiOCl @ Bi2O3 at the atomic level are fabricated via sonicating-assisted etching of Cl in BiOCl. This unique lateral heterostructure expedites …

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Simple Preparation Of Nitrogen-Doped Tio2 And Its Performance In Selective Oxidation Of Benzyl Alcohol And Benzylamine Under Visible Light, Mattawan Japa, Doldet Tantraviwat, Witchaya Phasayavan, Andrew Nattestad, Jun Chen, Burapat Inceesungvorn Jan 2020

Simple Preparation Of Nitrogen-Doped Tio2 And Its Performance In Selective Oxidation Of Benzyl Alcohol And Benzylamine Under Visible Light, Mattawan Japa, Doldet Tantraviwat, Witchaya Phasayavan, Andrew Nattestad, Jun Chen, Burapat Inceesungvorn

Australian Institute for Innovative Materials - Papers

N-doped TiO2, denoted as T_400, was prepared simply by the facile thermal hydrolysis of TiOSO4 using NH4OH as both a precipitating agent and a nitrogen source. Compared to TiO2 without nitrogen doping, T_400 provides superior photocatalytic activity toward the selective oxidation of benzyl alcohol and benzylamine under visible light irradiation, with > 85 % conversion and > 95 % selectivity to benzaldehyde and N-benzylidenebenzylamine products, respectively. The increased photoactivity of T_400 is ascribed to enhanced visible-light absorption and efficient photogenerated charge transfer and separation as supported by UV–vis DRS, photoelectrochemical and VB-XPS results. The catalyst can …

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Nanofibers-Based Piezoelectric Energy Harvester For Self-Powered Wearable Technologies, Fatemeh Mokhtari, Mahnaz Shamshirsaz, Masoud Latifi, Javad Foroughi Jan 2020

Nanofibers-Based Piezoelectric Energy Harvester For Self-Powered Wearable Technologies, Fatemeh Mokhtari, Mahnaz Shamshirsaz, Masoud Latifi, Javad Foroughi

Australian Institute for Innovative Materials - Papers

The demands for wearable technologies continue to grow and novel approaches for powering these devices are being enabled by the advent of new energy materials and novel manufacturing strategies. In addition, decreasing the energy consumption of portable electronic devices has created a huge demand for the development of cost-effective and environment friendly alternate energy sources. Energy harvesting materials including piezoelectric polymer with its special properties make this demand possible. Herein, we develop a flexible and lightweight nanogenerator package based on polyvinyledene fluoride (PVDF)/LiCl electrospun nanofibers. The piezoelectric performance of the developed nanogenator is investigated to evaluate effect of the thickness …

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