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Articles 1021 - 1050 of 7340
Full-Text Articles in Physical Sciences and Mathematics
Student Insights Report, Fall 2019, The Center For Student Analytics
Student Insights Report, Fall 2019, The Center For Student Analytics
Publications
For the past three years, the staff of the Center for Student Analytics have worked to discover and expose meaningful, data-informed insights into what helps students succeed at Utah State University. The following pages highlight 20 of the most useful insights we found provided here in small sets that will be useful to students, faculty, staff, university leadership, parents, and even prospective students. As you explore this report, we encourage you to see the student data as a window into USU itself. While big data helps us understand how individual students are performing, it tells us a great deal more …
Stormtime Thermospheric Neutral Winds Obtained From A Data Assimilation Model, Ludger Scherliess
Stormtime Thermospheric Neutral Winds Obtained From A Data Assimilation Model, Ludger Scherliess
Funded Research Records
No abstract provided.
Theoretical Studies Of Ir And Nmr Spectral Changes Induced By Sigma-Hole Hydrogen, Halogen, Chalcogen, Pnicogen, And Tetrel Bonds In A Model Protein Environment, Mariusz Michalczyk, Wiktor Zierkiewicz, Rafał Wysokiński, Steve Scheiner
Theoretical Studies Of Ir And Nmr Spectral Changes Induced By Sigma-Hole Hydrogen, Halogen, Chalcogen, Pnicogen, And Tetrel Bonds In A Model Protein Environment, Mariusz Michalczyk, Wiktor Zierkiewicz, Rafał Wysokiński, Steve Scheiner
Chemistry and Biochemistry Faculty Publications
Various types of σ-hole bond complexes were formed with FX, HFY, H2FZ, and H3FT (X = Cl, Br, I; Y = S, Se, Te; Z = P, As, Sb; T = Si, Ge, Sn) as Lewis acid. In order to examine their interactions with a protein, N-methylacetamide (NMA), a model of the peptide linkage was used as the base. These noncovalent bonds were compared by computational means with H-bonds formed by NMA with XH molecules (X = F, Cl, Br, I). In all cases, the A–F bond, which lies opposite the base and is responsible for …
A Near Horizon Extreme Binary Black Hole Geometry, Jacob Ciafre, Maria J. Rodriguez
A Near Horizon Extreme Binary Black Hole Geometry, Jacob Ciafre, Maria J. Rodriguez
All Physics Faculty Presentations
A new solution of four-dimensional vacuum General Relativity is presented. It describes the near horizon region of the extreme (maximally spinning) binary black hole system with two identical extreme Kerr black holes held in equilibrium by a massless strut. This is the first example of a non-supersymmetric, near horizon extreme binary black hole geometry of two uncharged black holes. The black holes are co-rotating, their relative distance is fixed, and the solution is uniquely specified by the mass. Asymptotically, the geometry corresponds to the near horizon extreme Kerr (NHEK) black hole. The binary extreme system has finite entropy.
Simultaneous In Situ Measurements Of Small-Scale Structures In Neutral, Plasma, And Atomic Oxygen Densities During The Wadis Sounding Rocket Project, Boris Strelnikov, Martin Eberhart, Martin Friedrich, Jonas Hedin, Mikhail Khaplanov, Gerd Baumgarten, Bifford P. Williams, Tristan Staszak, Heiner Asmus, Irina Strelnikova, Ralph Latteck, Mykhaylo Grygalashvyly, Franz-Josef Lübken, Josef Höffner, Raimund Wörl, Jörg Gumbel, Stefan Löhle, Stefanos Fasoulas, Markus Rapp, Aroh Barjatya, Michael J. Taylor, Pierre-Dominique Pautet
Simultaneous In Situ Measurements Of Small-Scale Structures In Neutral, Plasma, And Atomic Oxygen Densities During The Wadis Sounding Rocket Project, Boris Strelnikov, Martin Eberhart, Martin Friedrich, Jonas Hedin, Mikhail Khaplanov, Gerd Baumgarten, Bifford P. Williams, Tristan Staszak, Heiner Asmus, Irina Strelnikova, Ralph Latteck, Mykhaylo Grygalashvyly, Franz-Josef Lübken, Josef Höffner, Raimund Wörl, Jörg Gumbel, Stefan Löhle, Stefanos Fasoulas, Markus Rapp, Aroh Barjatya, Michael J. Taylor, Pierre-Dominique Pautet
Publications
In this paper we present an overview of measurements conducted during the WADIS-2 rocket campaign. We investigate the effect of small-scale processes like gravity waves and turbulence on the distribution of atomic oxygen and other species in the mesosphere–lower thermosphere (MLT) region. Our analysis suggests that density fluctuations of atomic oxygen are coupled to fluctuations of other constituents, i.e., plasma and neutrals. Our measurements show that all measured quantities, including winds, densities, and temperatures, reveal signatures of both waves and turbulence. We show observations of gravity wave saturation and breakdown together with simultaneous measurements of generated turbulence. Atomic oxygen inside …
On Video Analysis Of Omnidirectional Bee Traffic: Counting Bee Motions With Motion Detection And Image Classification, Vladmir Kulyukin, Sarbajit Mukherjee
On Video Analysis Of Omnidirectional Bee Traffic: Counting Bee Motions With Motion Detection And Image Classification, Vladmir Kulyukin, Sarbajit Mukherjee
Computer Science Faculty and Staff Publications
Omnidirectional bee traffic is the number of bees moving in arbitrary directions in close proximity to the landing pad of a given hive over a given period of time. Video bee traffic analysis has the potential to automate the assessment of omnidirectional bee traffic levels, which, in turn, may lead to a complete or partial automation of honeybee colony health assessment. In this investigation, we proposed, implemented, and partially evaluated a two-tier method for counting bee motions to estimate levels of omnidirectional bee traffic in bee traffic videos. Our method couples motion detection with image classification so that motion detection …
Large‐Amplitude Mountain Waves In The Mesosphere Observed On 21 June 2014 During Deepwave: 1.Wave Development, Scales, Momentum Fluxes, And Environmental Sensitivity, Michael J. Taylor, Pierre-Dominique Pautet, David C. Fritts, Bernd Kaifler, Steven M. Smith, Yucheng Zhao, Neal R. Criddle, Pattilyn Mclaughlin, William R. Pendleton Jr., Michael P. Mccarthy, Gonzalo Hernandez, Stephen D. Eckermann, James Doyle, Markus Rapp, Ben Liley, James M. Russell Iii
Large‐Amplitude Mountain Waves In The Mesosphere Observed On 21 June 2014 During Deepwave: 1.Wave Development, Scales, Momentum Fluxes, And Environmental Sensitivity, Michael J. Taylor, Pierre-Dominique Pautet, David C. Fritts, Bernd Kaifler, Steven M. Smith, Yucheng Zhao, Neal R. Criddle, Pattilyn Mclaughlin, William R. Pendleton Jr., Michael P. Mccarthy, Gonzalo Hernandez, Stephen D. Eckermann, James Doyle, Markus Rapp, Ben Liley, James M. Russell Iii
Publications
A remarkable, large‐amplitude, mountain wave (MW) breaking event was observed on the night of 21 June 2014 by ground‐based optical instruments operated on the New Zealand South Island during the Deep Propagating Gravity Wave Experiment (DEEPWAVE). Concurrent measurements of the MW structures, amplitudes, and background environment were made using an Advanced Mesospheric Temperature Mapper, a Rayleigh Lidar, an All‐Sky Imager, and a Fabry‐Perot Interferometer. The MW event was observed primarily in the OH airglow emission layer at an altitude of ~82 km, over an ~2‐hr interval (~10:30–12:30 UT), during strong eastward winds at the OH altitude and above, which weakened …
Chalcogen Bonding Of Two Ligands To Hypervalent Yf4 (Y=S, Se, Te, Po), Wiktor Zierkiewicz, Rafal Wysokiński, Mariusz Michalczyk, Steve Scheiner
Chalcogen Bonding Of Two Ligands To Hypervalent Yf4 (Y=S, Se, Te, Po), Wiktor Zierkiewicz, Rafal Wysokiński, Mariusz Michalczyk, Steve Scheiner
Chemistry and Biochemistry Faculty Publications
The ability of two NH3 ligands to engage in simultaneous chalcogen bonds to a hypervalent YF4 molecule, with Y=S, Se, Te, Po, is assessed via quantum calculations. The complex can take on one of two different geometries. The cis structure places the two ligands adjacent to one another ina pseudo-octahedral geometry, held there by a pair of σ-hole chalcogen bonds. The bases can also lie nearly opposite one another, in a distorted octahedron containing one π-hole and one strained σ-hole bond. The cis geometry is favored for Y=S, while Te,and Po tend toward the trans structure; they are nearly equally …
"Collaborative Research: Cedar--Airglow Imaging Of Gravity Wave And Instability Dynamics,", Michael Taylor
"Collaborative Research: Cedar--Airglow Imaging Of Gravity Wave And Instability Dynamics,", Michael Taylor
Funded Research Records
No abstract provided.
Evaluation Of The Geothermal Potential Of The Western Snake River Plain Based On A Deep Corehole On The Mountain Home Afb Near Mountain Home, Idaho, Thomas E. Lachmar, Thomas G. Freeman, James Andrew Kessler, Joseph F. Batir, James P. Evans, Dennis L. Nielson, John W. Shervais, Xiwei Chen, Douglas R. Schmitt, David D. Blackwell
Evaluation Of The Geothermal Potential Of The Western Snake River Plain Based On A Deep Corehole On The Mountain Home Afb Near Mountain Home, Idaho, Thomas E. Lachmar, Thomas G. Freeman, James Andrew Kessler, Joseph F. Batir, James P. Evans, Dennis L. Nielson, John W. Shervais, Xiwei Chen, Douglas R. Schmitt, David D. Blackwell
Geosciences Faculty Publications
A geothermal exploration corehole was drilled to a total depth of 1821.5 m on the Mountain Home Air Force Base near Mountain Home, Idaho. The corehole was used to collect an unusually large amount of data, including uniaxial compressive stress (UCS) experiments on core samples, to evaluate the geothermal potential of the western Snake River Plain. In addition, unlike many exploration holes in this region, a fluid entry was encountered at 1745.3 m and flowed artesian to the surface. A maximum temperature of 149.4 °C was calculated for the entry. A temperature log run on the corehole from 3 to …
Computational Insights Into Mg-Cl Complex Electrolytes For Rechargeable Magnesium Batteries, Jared B. Moss, Liping Zhang, Kevin V. Nielson, Yujing Bi, Chao Wu, Steve Scheiner, Tianbiao Leo Liu
Computational Insights Into Mg-Cl Complex Electrolytes For Rechargeable Magnesium Batteries, Jared B. Moss, Liping Zhang, Kevin V. Nielson, Yujing Bi, Chao Wu, Steve Scheiner, Tianbiao Leo Liu
Chemistry and Biochemistry Faculty Publications
DFT calculations were conducted to provide insightful and unprecedented thermodynamic insights on tetrahydrofuran (THF) solvation, isomerization, chlorination, and complexation of possible Mg-Cl coordination species for the popular Mg-Cl electrolytes. Computational results using the M06-2x functional with the 6-31+G(d) basis set indicate trigonal bipyramidal e, e-cis-tbp-MgCl2(THF)3 dichloride species and octahedral [MgCl(THF)5]+ monochloride species are the dominant mononuclear species. These two can combine to form the active dinuclear species, [(μ-Cl)3Mg2(THF)6]+ with a free energy -6.30 kcal/mol, which is calculated to be the dominant Mg-Cl species in solution. Two mono-cation species, [(μ-Cl)3Mg2(THF)6]+ and [MgCl(THF)5]+ have comparable LUMO energies, thus both of them can …
(0,1)-Matrices, Discrepancy And Preservers, Leroy B. Beasley
(0,1)-Matrices, Discrepancy And Preservers, Leroy B. Beasley
Mathematics and Statistics Faculty Publications
Let m and n be positive integers, and let R = (r1, . . . , rm) and S = (s1, . . . , sn) be nonnegative integral vectors. Let A(R,S) be the set of all m × n (0, 1)-matrices with row sum vector R and column vector S. Let R and S be nonincreasing, and let F(R) be the m × n (0, 1)-matrix, where for each i, the ith row of F(R, …
Anisotropic Singlet Fission In Single Crystalline Hexacene, Dezheng Sun, Gang-Hua Deng, Bolei Xu, Enshi Xu, Xia Li, Yajing Wu, Yuqin Qian, Yu Zhong, Colin Nuckolls, Avetik R. Harutyunyan, Hai-Lung Dai, Gugang Chen, Hanning Chen, Yi Rao
Anisotropic Singlet Fission In Single Crystalline Hexacene, Dezheng Sun, Gang-Hua Deng, Bolei Xu, Enshi Xu, Xia Li, Yajing Wu, Yuqin Qian, Yu Zhong, Colin Nuckolls, Avetik R. Harutyunyan, Hai-Lung Dai, Gugang Chen, Hanning Chen, Yi Rao
Chemistry and Biochemistry Faculty Publications
Singlet fission is known to improve solar energy utilization by circumventing the Shockley-Queisser limit. The two essential steps of singlet fission are the formation of a correlated triplet pair and its subsequent quantum decoherence. However, the mechanisms of the triplet pair formation and decoherence still remain elusive. Here we examined both essential steps in single crystalline hexacene and discovered remarkable anisotropy of the overall singlet fission rate along different crystal axes. Since the triplet pair formation emerges on the same timescale along both crystal axes, the quantum decoherence is likely responsible for the directional anisotropy. The distinct quantum decoherence rates …
Large‐Amplitude Mountain Waves In The Mesosphere Observed On 21 June 2014 During Deepwave: 2. Nonlinear Dynamics, Wave Breaking, And Instabilities, David C. Fritts, Ling Wang, Michael J. Taylor, Pierre-Dominique Pautet, Neal R. Criddle, Bernd Kaifler, Stephen D. Eckermann, Ben Liley
Large‐Amplitude Mountain Waves In The Mesosphere Observed On 21 June 2014 During Deepwave: 2. Nonlinear Dynamics, Wave Breaking, And Instabilities, David C. Fritts, Ling Wang, Michael J. Taylor, Pierre-Dominique Pautet, Neal R. Criddle, Bernd Kaifler, Stephen D. Eckermann, Ben Liley
Publications
Weak cross‐mountain flow over the New Zealand South Island on 21 June 2014 during the Deep Propagating Gravity Wave Experiment (DEEPWAVE) led to large‐amplitude mountain waves in the mesosphere and lower thermosphere. The mesosphere and lower thermosphere responses were observed by ground‐based instruments in the lee of the Southern Alps supporting DEEPWAVE, including an Advanced Mesosphere Temperature Mapper, a Rayleigh lidar, an All‐Sky Imager, and a Fabry‐Perot Interferometer. The character of the mountain wave responses at horizontal scales of ~30–90 km reveals strong “sawtooth” variations in the temperature field suggesting large vertical and horizontal displacements leading to mountain wave overturning. …
Collaborative Research: Development And Application Of A Framework For Integrated Geodynamic Earth Models, Anthony Lowry
Collaborative Research: Development And Application Of A Framework For Integrated Geodynamic Earth Models, Anthony Lowry
Funded Research Records
No abstract provided.
Why Weightlifters Grunt: A Classroom Exercise That Introduces Students To Evolution, H. Charles Romesburg
Why Weightlifters Grunt: A Classroom Exercise That Introduces Students To Evolution, H. Charles Romesburg
Environment and Society Faculty Publications
A classroom exercise is described in which college students take part in creating and supporting an evolutionary hypothesis that explains effort grunting. The exercise holds their interest throughout and readies them to understand hypotheses of animal and plant evolution. It informs them about the dependence of cultural evolution upon biological evolution, and it connects widely to curricula.
Innovations In (U–Th)/He, Fission Track, And Trapped Charge Thermochronometry With Applications To Earthquakes, Weathering, Surface‐Mantle Connections, And The Growth And Decay Of Mountains, Alexis K. Ault, Cécile Gautheron, Georgina E. King
Innovations In (U–Th)/He, Fission Track, And Trapped Charge Thermochronometry With Applications To Earthquakes, Weathering, Surface‐Mantle Connections, And The Growth And Decay Of Mountains, Alexis K. Ault, Cécile Gautheron, Georgina E. King
Geosciences Faculty Publications
A transformative advance in Earth science is the development of low‐temperature thermochronometry to date Earth surface processes or quantify the thermal evolution of rocks through time. Grand challenges and new directions in low‐temperature thermochronometry involve pushing the boundaries of these techniques to decipher thermal histories operative over seconds to hundreds of millions of years, in recent or deep geologic time and from the perspective of atoms to mountain belts. Here we highlight innovation in bedrock and detrital fission track, (U–Th)/He, and trapped charge thermochronometry, as well as thermal history modeling that enable fresh perspectives on Earth science problems. These developments …
Spectroscopic Description Of The E1 State Of Mo Nitrogenase Based On Mo And Fe X‑Ray Absorption And MöSsbauer Studies, Casey Van Stappen, Roman Davydov, Zhi-Yong Yang, Ruixi Fan, Yisong Guo, Eckhard Bill, Lance C. Seefeldt, Brian M. Hoffman, Serena Debeer
Spectroscopic Description Of The E1 State Of Mo Nitrogenase Based On Mo And Fe X‑Ray Absorption And MöSsbauer Studies, Casey Van Stappen, Roman Davydov, Zhi-Yong Yang, Ruixi Fan, Yisong Guo, Eckhard Bill, Lance C. Seefeldt, Brian M. Hoffman, Serena Debeer
Chemistry and Biochemistry Faculty Publications
Mo nitrogenase (N2ase) utilizes a two-component protein system, the catalytic MoFe and its electron-transfer partner FeP, to reduce atmospheric dinitrogen (N2) to ammonia (NH3). The FeMo cofactor contained in the MoFe protein serves as the catalytic center for this reaction and has long inspired model chemistry oriented toward activating N2. This field of chemistry has relied heavily on the detailed characterization of how Mo N2ase accomplishes this feat. Understanding the reaction mechanism of Mo N2ase itself has presented one of the most challenging problems in bioinorganic chemistry because of the ephemeral nature of its …
From The Signature Theorem To Anomaly Cancellation, Andreas Malmendier, Michael T. Schultz
From The Signature Theorem To Anomaly Cancellation, Andreas Malmendier, Michael T. Schultz
Mathematics and Statistics Faculty Publications
We survey the Hirzebruch signature theorem as a special case of the Atiyah–Singer index theorem. The family version of the Atiyah–Singer index theorem in the form of the Riemann–Roch–Grothendieck–Quillen (RRGQ) formula is then applied to the complexified signature operators varying along the universal family of elliptic curves. The RRGQ formula allows us to determine a generalized cohomology class on the base of the elliptic fibration that is known in physics as (a measure of) the local and global anomaly. Combining several anomalous operators allows us to cancel the local anomaly on a Jacobian elliptic surface, a construction that is based …
Generalized Near Horizon Extreme Binary Black Hole Geometry, Jacob Ciafre, Shahar Hadar, Erin Rickenbach, Maria J. Rodriguez
Generalized Near Horizon Extreme Binary Black Hole Geometry, Jacob Ciafre, Shahar Hadar, Erin Rickenbach, Maria J. Rodriguez
All Physics Faculty Publications
We present a new vacuum solution of Einstein’s equations describing the near horizon region of two neutral, extreme (zero-temperature), corotating, nonidentical Kerr black holes. The metric is stationary, asymptotically near horizon extremal Kerr (NHEK), and contains a localized massless strut along the symmetry axis between the black holes. In the deep infrared, it flows to two separate throats which we call “pierced-NHEK” geometries: each throat is NHEK pierced by a conical singularity. We find that in spite of the presence of the strut for the pierced-NHEK geometries the isometry group SL(2,R)×U(1) is restored. We find the physical parameters and entropy.
Yang-Mills Sources For Biconformal Gravity, Walter Davis Muhwezi
Yang-Mills Sources For Biconformal Gravity, Walter Davis Muhwezi
Physics Capstone Projects
We present a gauge formulation of Yang-Mills matter sources for Biconformal gravity. Biconformal gravity is a 2n-dimensional conformal gauge theory with a curvature linear action that has been shown to reproduce scale invariant general relativity on the cotangent bundle of n-dimensional space time. We present a generalization of Yang-Mills theories in biconformal space and show that the field equations with sources reduce the Yang-Mills sector to n-dimensional Yang-Mills theory in curved spacetime. We compute the restrictive conditions on the energy-momentum tensor required by the gravitational field equations.
Status And Prospects Of Organic Redox Flow Batteries Toward Sustainable Energy Storage, Jian Luo, Bo Hu, Maowei Hu, Yu Zhao, T. Leo Liu
Status And Prospects Of Organic Redox Flow Batteries Toward Sustainable Energy Storage, Jian Luo, Bo Hu, Maowei Hu, Yu Zhao, T. Leo Liu
Chemistry and Biochemistry Faculty Publications
Redox flow batteries (RFBs) are regarded a promising technology for large-scale electricity energy storage to realize efficient utilization of intermittent renewable energy. Redox -active materials are the most important components in the RFB system because their physicochemical and electrochemical properties directly determine their battery performance and energy storage cost. Designable, tunable, and potentially low-cost redox-active organic compounds are promising alternatives to traditional redox-active inorganic compounds for RFB applications. Herein, the representative designs of redox-active molecules, recent development of organic RFBs (ORFBs), and advantages/disadvantages of different ORFB are reviewed. Especially the relationship between redox-active molecules’ physicochemical properties and their battery performance …
A Structural Based Feature Extraction For Detecting The Relation Of Hidden Substructures In Coral Reef Images, Mahmood Sotoodeh, Mohammad Reza Moosavi, Reza Boostani
A Structural Based Feature Extraction For Detecting The Relation Of Hidden Substructures In Coral Reef Images, Mahmood Sotoodeh, Mohammad Reza Moosavi, Reza Boostani
Computer Science Student Research
In this paper, we present an efficient approach to extract local structural color texture features for classifying coral reef images. Two local texture descriptors are derived from this approach. The first one, based on Median Robust Extended Local Binary Pattern (MRELBP), is called Color MRELBP (CMRELBP). CMRELBP is very accurate and can capture the structural information from color texture images. To reduce the dimensionality of the feature vector, the second descriptor, co-occurrence CMRELBP (CCMRELBP) is introduced. It is constructed by applying the Integrative Co-occurrence Matrix (ICM) on the Color MRELBP images. This way we can detect and extract the relative …
Monitoring Ambient Laboratory Conditions With A Raspberry Pi, Joshua Boman
Monitoring Ambient Laboratory Conditions With A Raspberry Pi, Joshua Boman
Physics Capstone Projects
Precise experimental devices and measurements can be sensitive to changing physical conditions in the lab. The purpose of this research was to develop a standardized computer automated package to monitor and record changes in laboratory conditions, including ambient temperature, atmospheric pressure, relative humidity, light intensity, motion, and power outages. The computer-interfaced device was based around an inexpensive Raspberry Pi microcomputer and commercially available sensors. The Raspberry Pi uploads the sensor data to a file used by LabVIEW to further analyze, plot and display the calibrated sensor data in real time and trigger alarms. This capability allows the Material Physics Research …
Vibronic Fingerprint Of Singlet Fission In Hexacene, Gang-Hua Deng, Qianshun Wei, Jian Han, Yuqin Qian, Jun Luo, Avetik R. Harutyunyan, Gugang Chen, Hongtao Bian, Hanning Chen, Yi Rao
Vibronic Fingerprint Of Singlet Fission In Hexacene, Gang-Hua Deng, Qianshun Wei, Jian Han, Yuqin Qian, Jun Luo, Avetik R. Harutyunyan, Gugang Chen, Hongtao Bian, Hanning Chen, Yi Rao
Chemistry and Biochemistry Faculty Publications
Singlet fission has the great potential to overcome the Shockley–Queisser thermodynamic limit and thus promotes solar power conversion efficiency. However, the current limited understandings of detailed singlet fission mechanisms hinder a further improved design of versatile singlet fission materials. In the present study, we combined ultrafast transient infrared spectroscopy with ab initio calculations to elucidate the roles played by the vibrational normal modes in the process of singlet fission for hexacene. Our transient infrared experiments revealed three groups of vibrational modes that are prominent in vibronic coupling upon photoexcitation. Through our computational study, those normal modes with notable Franck-Condon shifts …
Effects Of Halogen, Chalcogen, Pnicogen, And Tetrel Bonds On Ir And Nmr Spectra, Jia Lu, Steve Scheiner
Effects Of Halogen, Chalcogen, Pnicogen, And Tetrel Bonds On Ir And Nmr Spectra, Jia Lu, Steve Scheiner
Chemistry and Biochemistry Faculty Publications
Complexes were formed pairing FX, FHY, FH2Z, and FH3T (X = Cl, Br, I; Y = S, Se, Te; Z = P, As, Sb; T = Si, Ge, Sn) with NH3 in order to form an A⋯N noncovalent bond, where A refers to the central atom. Geometries, energetics, atomic charges, and spectroscopic characteristics of these complexes were evaluated via DFT calculations. In all cases, the A–F bond, which is located opposite the base and is responsible for the σ-hole on the A atom, elongates and its stretching frequency undergoes a shift to the red. This …
Cloud Cover And Delayed Herbivory Relative To Timing Of Spring Onset Interact To Dampen Climate Change Impacts On Net Ecosystem Exchange In A Coastal Alaskan Wetland, A. Joshua Leffler, Karen H. Beard, Katharine C. Kelsey, Ryan T. Choi, Joel A. Schmutz, Jeffrey M. Welker
Cloud Cover And Delayed Herbivory Relative To Timing Of Spring Onset Interact To Dampen Climate Change Impacts On Net Ecosystem Exchange In A Coastal Alaskan Wetland, A. Joshua Leffler, Karen H. Beard, Katharine C. Kelsey, Ryan T. Choi, Joel A. Schmutz, Jeffrey M. Welker
Wildland Resources Faculty Publications
Rapid warming in northern ecosystems over the past four decades has resulted in earlier spring, increased precipitation, and altered timing of plant–animal interactions, such as herbivory. Advanced spring phenology can lead to longer growing seasons and increased carbon (C) uptake. Greater precipitation coincides with greater cloud cover possibly suppressing photosynthesis. Timing of herbivory relative to spring phenology influences plant biomass. None of these changes are mutually exclusive and their interactions could lead to unexpected consequences for Arctic ecosystem function. We examined the influence of advanced spring phenology, cloud cover, and timing of grazing on C exchange in the Yukon–Kuskokwim Delta …
Electronic Transmutation: An Aid For The Rational Design Of New Chemical Materials Using The Knowledge Of Bonding And Structure Of Neighboring Elements, Katie A. Lundell
Electronic Transmutation: An Aid For The Rational Design Of New Chemical Materials Using The Knowledge Of Bonding And Structure Of Neighboring Elements, Katie A. Lundell
All Graduate Theses and Dissertations, Spring 1920 to Summer 2023
Everything in the universe is made up of elements from the periodic table. Each element has its own role that it plays in the formation of things it makes up. For instance, pencil lead is graphite. A series of honeycomb-like structures made up of carbon stacked on top of one another. Carbon’s neighbor to the left, boron doesn’t like to form such stacked honeycomb-like structures. But, what if there was a way to make boron act like carbon so it did like to form such structures? That question is the basis of the electronic transmutation concept presented in this dissertation. …
Machine Learning Techniques As Applied To Discrete And Combinatorial Structures, Samuel David Schwartz
Machine Learning Techniques As Applied To Discrete And Combinatorial Structures, Samuel David Schwartz
All Graduate Theses and Dissertations, Spring 1920 to Summer 2023
Machine Learning Techniques have been used on a wide array of input types: images, sound waves, text, and so forth. In articulating these input types to the almighty machine, there have been all sorts of amazing problems that have been solved for many practical purposes.
Nevertheless, there are some input types which don’t lend themselves nicely to the standard set of machine learning tools we have. Moreover, there are some provably difficult problems which are abysmally hard to solve within a reasonable time frame.
This thesis addresses several of these difficult problems. It frames these problems such that we can …
Towards Conjunctive Management Of Surface Water And Groundwater In The Mediterranean, Matthew Lagod
Towards Conjunctive Management Of Surface Water And Groundwater In The Mediterranean, Matthew Lagod
All Graduate Plan B and other Reports, Spring 1920 to Spring 2023
One of the fundamental principles of integrated water resources management is the interconnected nature of water in the hydrological cycle, including the interactions between surface water and groundwater. Although scientists have long recognized these interactions, in many cases they are not reflected in natural resources policies and management practices. As a result, the allocation of water resources by public authorities may not be optimal, and may furthermore lead to long-term degradation of water resources and the ecosystems they sustain. In response to this and to growing pressure on water resources from increasing human populations, water experts have developed a body …