Physical Sciences and Mathematics Commons^™

Mapping Valley Bottom Confinement At The Network Scale, Gary R. O'Brien, Joseph Michael Wheaton, Kirstie Fryirs, William W. Macfarlane, Gary Brierley, Kelly Whitehead, Jordan T. Gilbert, Carol Volk

Watershed Sciences Faculty Publications

In this article, we demonstrate the application of a continuous confinement metric across entire river networks. Confinement is a useful metric for characterizing and discriminating valley setting. At the reach scale, valley bottom confinement is measured and quantified as the ratio of the length of channel confined on either bank by a confining margin divided by the reach length. The valley bottom is occupied by the contemporary floodplain and/or its channel(s); confining margins can be any landform or feature that makes up the valley bottom margin, such as bedrock hillslopes, terraces, fans, or anthropogenic features such as stopbanks or constructed …

Photochemistry On The Bottom Side Of The Mesospheric Na Layer, Tao Yuan, Wuhu Feng, John M. C. Plane, Daniel R. Marsh

All Physics Faculty Publications

Lidar observations of the mesospheric Na layer have revealed considerable diurnal variations, particularly on the bottom side of the layer, where more than an order-of-magnitude increase in Na density has been observed below 80 km after sunrise. In this paper, multi-year Na lidar observations are utilized over a full diurnal cycle at Utah State University (USU) (41.8o N, 111.8o W) and a global atmospheric model of Na with 0.5 km vertical resolution in the mesosphere and lower thermosphere (WACCM-Na) to explore the dramatic changes of Na density on the bottom side of the layer. Photolysis of the principal reservoir NaHCO3 …

The Water Entry Of A Sphere In A Jet, Nathan B. Spiers, Jesse Belden, Zhao Pan, Sean Holekamp, George Badlissi, Matthew Jones, Tadd T. Truscott

Mechanical and Aerospace Engineering Faculty Publications

The forces on an object impacting the water are extreme in the early moments of water entry and can cause structural damage to biological and man-made bodies alike. These early-time forces arise primarily from added mass, peaking when the submergence is much less than one body length. We experimentally investigate a means of reducing impact forces on a rigid sphere by placing the sphere inside a jet of water so that the jet strikes the quiescent water surface prior to entry of the sphere into the pool. The water jet accelerates the pool liquid and forms a cavity into which …

Ground, Proximal, And Satellite Remote Sensing Of Soil Moisture, Ebrahim Babaeian, Morteza Sadeghi, Scott B. Jones, Carsten Montzka, Harry Vereecken, Markus Tuller

Plants, Soils, and Climate Faculty Publications

Soil moisture (SM) is a key hydrologic state variable that is of significant importance for numerous Earth and environmental science applications that directly impact the global environment and human society. Potential applications include, but are not limited to, forecasting of weather and climate variability; prediction and monitoring of drought conditions; management and allocation of water resources; agricultural plant production and alleviation of famine; prevention of natural disasters such as wild fires, landslides, floods, and dust storms; or monitoring of ecosystem response to climate change. Because of the importance and wide‐ranging applicability of highly variable spatial and temporal SM information that …

Volcanic Stratigraphy And Age Model Of The Kimama Deep Borehole (Project Hotspot): Evidence For 5.8 Million Years Of Continuous Basalt Volcanism, Central Snake River Plain, Idaho, Katherine E. Potter, Duane E. Champion, Robert A. Duncan, John W. Shervais

Geosciences Faculty Publications

The Snake River Plain of central Idaho represents the world’s best example of a mantle hotspot track impinging upon continental crust and provides a record of bimodal volcanism extending over 12 Ma to the present. Project Hotspot recovered almost 2 km of continuous drill core from the Kimama borehole, located in central Idaho on the axial volcanic zone. The Kimama drill core represents the most complete record of mafic volcanism along the Yellowstone–Snake River Plain hotspot track.

A total of 432 basalt flow units, representing 183 basalt flows, 78 basalt flow groups, and 34 super groups, along with 42 sediment …

Is Grassfed Meat And Dairy Better For Human And Environmental Health?, Frederick D. Provenza, Scott L. Kronberg, Pablo Gregorini

Wildland Resources Faculty Publications

The health of livestock, humans, and environments is tied to plant diversity—and associated phytochemical richness—across landscapes. Health is enhanced when livestock forage on phytochemically rich landscapes, is reduced when livestock forage on simple mixture or monoculture pastures or consume high-grain rations in feedlots, and is greatly reduced for people who eat highly processed diets. Circumstantial evidence supports the hypothesis that phytochemical richness of herbivore diets enhances biochemical richness of meat and dairy, which is linked with human and environmental health. Among many roles they play in health, phytochemicals in herbivore diets protect meat and dairy from protein oxidation and lipid …

A Performance Comparison Of Machine Learning Algorithms For Arced Labyrinth Spillways, Fernando Salazar, Brian M. Crookston

Publications

Labyrinth weirs provide an economic option for flow control structures in a variety of applications, including as spillways at dams. The cycles of labyrinth weirs are typically placed in a linear configuration. However, numerous projects place labyrinth cycles along an arc to take advantage of reservoir conditions and dam alignment, and to reduce construction costs such as narrowing the spillway chute. Practitioners must optimize more than 10 geometric variables when developing a head–discharge relationship. This is typically done using the following tools: empirical relationships, numerical modeling, and physical modeling. This study applied a new tool, machine learning, to the analysis …

Public Perceptions Of The Health Risks Of Extreme Heat Across Us States, Counties, And Neighborhoods, Peter D. Howe, Jennifer R. Marlon, Xinran Wang, Anthony Leiserowitz

Environment and Society Faculty Publications

Extreme heat is the leading weather-related cause of death in the United States. Many individuals, however, fail to perceive this risk, which will be exacerbated by global warming. Given that awareness of one’s physical and social vulnerability is a critical precursor to preparedness for extreme weather events, understanding Americans’ perceptions of heat risk and their geographic variability is essential for promoting adaptive behaviors during heat waves. Using a large original survey dataset of 9,217 respondents, we create and validate a model of Americans’ perceived risk to their health from extreme heat in all 50 US states, 3,142 counties, and 72,429 …

Hexacoordinated Tetrel-Bonded Complexes Between Tf4 (T = Si, Ge, Sn, Pb) And Nch. Competition Between Σ- And Π-Holes, Mariusz Michalczyk, Wiktor Zierkiewicz, Rafal Wysokiński, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

In order to accommodate the approach of two NCH bases, a tetrahedral TF4 molecule (T=Si,Ge,Sn,Pb) distorts into an octahedral structure in which the two bases can be situated either cis or trans to one another. The square planar geometry of TF4, associated with the trans arrangement of the bases, is higher in energy than its see-saw structure which corresponds to the cis trimer. On the other hand, the square geometry offers an unobstructed path of the bases to the π-holes above and below the tetrel atom so enjoys a higher interaction energy than is the case for the σ-holes approached …

Molecular Rotation In 3 Dimensions At An Air/Water Interface Using Femtosecond Time Resolved Sum Frequency Generation, Yi Rao, Yuqin Qian, Gang-Hua Deng, Ashlie Kinross, Nicholas J. Turro, Kenneth B. Eisenthal

Chemistry and Biochemistry Faculty Publications

This paper presents the first study of the rotations of rigid molecules in 3 dimensions at the air/water interface, using the femtosecond time resolved sum frequency generation (SFG) technique. For the purpose of this research, the aromatic dye molecule C153 was chosen as an example of a molecule having two functional groups that are SFG active, one being the hydrophilic −−C==O group and the other the hydrophobic −−CF₃ group. From polarized SFG measurements, the orientations of the two chromophores with respect to the surface normal were obtained. On combining these results with the known relative orientation of the two …

Park And Neighborhood Attributes Associated With Park Use: An Observational Study Using Unmanned Aerial Vehicles, Keunhyun Park

Landscape Architecture and Environmental Planning Faculty Publications

As the world becomes more urbanized, neighborhood parks are becoming an increasingly important venue where people engage in physical and social activities. Using park-use data collected by unmanned aerial vehicles (UAVs), the aim of this study is to account for park use in light of park attributes and neighborhood conditions. The role of the built environment near a park receives particular attention as it is understudied in the literature. A regression model shows that neighborhood park utilization is positively associated with park attributes (i.e., larger area, a playground, a creek/pond, quality maintenance, and organized activities) and neighborhood attributes (i.e., fewer …

Prediction Of Stress Increase At Ultimate In Unbonded Tendons Using Sparse Principal Component Analysis, Eric Mckinney, Minwoo Chang, Marc Maguire, Yan Sun

Mathematics and Statistics Faculty Publications

While internal and external unbonded tendons are widely utilized in concrete structures, an analytical solution for the increase in unbonded tendon stress at ultimate strength, Δ������, is challenging due to the lack of bond between strand and concrete. Moreover, most analysis methods do not provide high correlation due to the limited available test data. The aim of this paper is to use advanced statistical techniques to develop a solution to the unbonded strand stress increase problem, which phenomenological models by themselves have done poorly. In this paper, Principal Component Analysis (PCA), and Sparse Principal Component Analysis (SPCA) are employed on …

Drones And “Ghost Guns”: Unregulated Legal Space, Tori Bodine

Research on Capitol Hill

Law enforcement agencies are fighting a two - pronged battle when it comes to emerging technologies: keeping up with new ways criminals are using technology and developing effective ways to combat these innovations, while balancing these challenges against preserving the individual liberties of law - abiding citizens. This conflict is especially apparent with regard to criminal use of commercial drones and the developing fringe market surrounding homemade untraceable firearms (“ghost guns”).

Pantropical Climate Interactions, Wenju Cai, Lixin Wu, Matthieu Lengaigne, Tim Li, Shayne Mcgregor, Jong-Seong Kug, Jin-Yi Yu, Malte F. Stuecker, Agus Santoso, Xichen Li, Yoo-Geun Ham, Yoshimitsu Chikamoto, Benjamin Ng, Michael J. Mcphaden, Yan Du, Et Al.

Plants, Soils, and Climate Faculty Publications

The El Niño–Southern Oscillation (ENSO), which originates in the Pacific, is the strongest and most well-known mode of tropical climate variability. Its reach is global, and it can force climate variations of the tropical Atlantic and Indian Oceans by perturbing the global atmospheric circulation. Less appreciated is how the tropical Atlantic and Indian Oceans affect the Pacific. Especially noteworthy is the multidecadal Atlantic warming that began in the late 1990s, because recent research suggests that it has influenced Indo-Pacific climate, the character of the ENSO cycle, and the hiatus in global surface warming. Discovery of these pantropical interactions provides a …

Transition State Interactions In A Promiscuous Enzyme: Sulfate And Phosphate Monoester Hydrolysis By Pseudomonas Aeruginosa Arylsulfatase, Bert Van Loo, Ryan Berry, Usa Boonyuen, Mark F. Mohamed, Marko Golicnik, Alvan C. Hengge, Florian Hollfelder

Chemistry and Biochemistry Faculty Publications

Pseudomonas aeruginosa arylsulfatase (PAS) hydrolyses sulfate and, promiscuously, phosphate monoesters. Enzyme-catalyzed sulfate transfer is crucial to a wide variety of biological processes, but detailed studies of the mechanistic contributions to its catalysis are lacking. We present linear free energy relationships (LFERs) and kinetic isotope effects (KIEs) of PAS and active site mutants that suggest a key role for leaving group (LG) stabilization. In LFERs PAS^_WT has a much less negative Brønsted coefficient (ß_{leaving group} ^obs-Enz=-0.33) than the uncatalyzed reaction (ß_{leaving group} ^obs=-1.81). This situation is diminished when cationic active site groups are exchanged for alanine. …

Structural And Functional Characterization Of Sulfonium Carbon-Oxygen Hydrogen Bonding In The Deoxyamino Sugar Methyltransferase Tyim1, Robert J. Fick, Scott Horowitz, Brandon G. Mcdole, Mary C. Clay, Ryan A. Mehl, Hashim M. Al-Hashimi, Steve Scheiner, Raymond C. Trievel

Chemistry and Biochemistry Faculty Publications

The N-methyltransferase TylM1 from Streptomyces fradiae catalyzes the final step in the biosynthesis of the deoxyamino sugar mycaminose, a substituent of the antibiotic tylosin. The high-resolution crystal structure of TylM1 bound to the methyl donor S-adenosylmethionine (AdoMet) illustrates a network of carbon-oxygen (CH•••O) hydrogen bonds between the substrate’s sulfonium cation and residues within the active site. These interactions include hydrogen bonds between the methyl and methylene groups of the AdoMet sulfonium cation and the hydroxyl groups of Tyr14 and Ser120 in the enzyme. To examine the functions of these interactions, we generated Tyr14 to phenylalanine (Y14F) and Ser120 to alanine …

Radar Studies Of Height-Dependent Equatorial F Region Vertical And Zonal Plasma Drifts, S. A. Shidler, F. S. Rodrigues, B. G. Fejer, M. A. Milla

All Physics Faculty Publications

We present the results of an analysis of long-term measurements of ionospheric F region E × B plasma drifts in the American/Peruvian sector. The analysis used observations made between 1986 and 2017 by the incoherent scatter radar of the Jicamarca Radio Observatory. Unlike previous studies, we analyzed both vertical and zonal components of the plasma drifts to derive the geomagnetically quiet time climatological variation of the drifts as a function of height and local time. We determine the average behavior of the height profiles of the drifts for different seasons and distinct solar flux conditions. Our results show good agreement …

Pace And Process Of Active Folding And Fluvial Incision Across The Kantishna Hills Anticline, Central Alaska, A. M. Bender, R. O. Lease, P. J. Haeussler, Tammy M. Rittenour, L. B. Corbett, P. R. Bierman, M. W. Caffee

Geosciences Faculty Publications

Rates of northern Alaska Range thrust system deformation are poorly constrained. Shortening at the system's west end is focused on the Kantishna Hills anticline. Where the McKinley River cuts across the anticline, the landscape records both Late Pleistocene deformation and climatic change. New optically stimulated luminescence and cosmogenic 10Be depth profile dates of three McKinley River terrace levels (~22, ~18, and ~14–9 ka) match independently determined ages of local glacial maxima, consistent with climate‐driven terrace formation. Terrace ages quantify rates of differential bedrock incision, uplift, and shortening based on fault depth inferred from microseismicity. Differential rock uplift and incision (≤1.4 …

Examination Of The Climate Factors That Reduced Wheat Yield In Northwest India During The 2000s, Avik Mukherjee, Shih-Yu (Simon) Wang, Parichart Promchote

Plants, Soils, and Climate Faculty Publications

In India, a significant reduction of wheat yield would cause a widespread impact on food security for 1.35 billion people. The two highest wheat producing states, Punjab and Haryana in northern India, experienced a prolonged period of anomalously low wheat yield during 2002–2010. The extent of climate variability and change in influencing this prolonged reduction in wheat yield was examined. Daily air temperature (T_max and T_ave) was used to calculate the number of days above optimum temperature and growing degree days (GDD) anomaly. Two drought indices, the standard precipitation and evapotranspiration index and the radiation-based precipitation index, …

Data From Analysis Of Mesosphere Secular Trends And Episodic Variability, 9/3/1993 To 8/5/2003, Troy A. Wynn, Vincent B. Wickwar, Joshua P. Herron

Browse all Datasets

The database examined here covers a time span from September 1993 to August 2003 and an altitude range of 45 to 90 km, and contains 593 nightly temperature profiles. We examine our data for secular warming and cooling and decadal scale (solar cycle) variations by applying three different models to the data.

Comparison Of Σ-Hole And Π-Hole Tetrel Bonds In Complexes Of Borazine With Th3f And F2to/H2to (T=C,Si,Ge), Jingru Zhang, Qingze Hu, Qing-Zhong Li, Steve Scheiner, Shufeng Liu

Chemistry and Biochemistry Faculty Publications

The complexes between borazine and TH3F/F2TO/H2TO (T=C, Si, Ge) are investigated with high-level quantum chemical calculations. Borazine has three sites of negative electrostatic potential: the N atom, the ring center, and the H atom of the B-H bond, while TH3F and F2TO/H2TO provide the σ-hole and π-hole, respectively, for the tetrel bond. The N atom of borazine is the favored site for both the σ and π-hole tetrel bonds. Less stable dimers include a σ-tetrel bond to the borazine ring center and to the BH proton. The π-hole tetrel-bonded complexes are more strongly bound than aretheirσ-hole counterparts. Due to the …

Switchable Aromaticity In An Isostructural Mn Phthalocyanine Series Isolated In Five Separate Redox States, Camden Hunt, Madeline Peterson, Cassidy Anderson, Tieyan Chang, Guang Wu, Steve Scheiner, Gabriel Ménard

Chemistry and Biochemistry Faculty Publications

The synthesis and characterization of a new phthalocyanine(Pc) Mn-nitride complex, (OEtPc)MnN (2; OEtPc= 1,4,8,11,15,18,22,25-octaethoxy-Pc), as well as its stable, readily accessible oxidized (2+ and 22+) and reduced (2-, 22-) congeners is reported. This unique isostructural series displays switchable aromatic character spanning the aromatic (2), non-aromatic (22+), and antiaromatic (22-) triad, in addition to the open-shell radical states (2+, 2-). All complexes were structurally characterized and displayed significant structural distortions at the redox extrema (22+, 22-) consistent with proposed [16 or 18]annulene π ring circuit models. Spectroscopic and computational studies further support these models. This isolated, fully characterized, isostructural series spanning …

Factors That Influence Mathematical Creativity, Joseph S. Kozlowski, Scott A. Chamberlin, Eric Mann

Mathematics and Statistics Faculty Publications

Creativity is a psychological construct that has gained research popularity (Akgul & Kaveci, 2016), however it remains a challenging one to define. The variety of definitions promulgated to understand creativity hints at the complexity of the mental process. Furthermore, as a subset of creativity, domain-specific mathematical creativity has also garnered a variety of definitions. The transdisciplinary research on creativity (Sriraman & Haavold, 2017) is seminal in this world of fast-paced innovation, invention, solution, and synthesis. Considering every human being with at least average cognitive abilities possesses the ability to think creatively (Baran, 2011), developing students’ creative talents and abilities must …

A Re-Emergent Analysis Of Early Algebraic Learning, Steven Boyce, Diana Moss

Extension Research

In this paper, we discuss a novel approach for collaborative retrospective analysis. One researcher was directly involved in a classroom teaching experiment, adopting an emergent perspective as an interpreter-witness of classroom interactions during a four-week algebra instructional unit with sixth-grade students. The other researcher experienced and analyzed the data in reverse chronological order. We describe how this re-emergent perspective revealed aspects of students’ early algebraic reasoning.

Genetic Loci Associated With Salt Tolerance In Advanced Breeding Populations Of Tetraploid Alfalfa Using Genome-Wide Association Studies, Xiang-Ping Liu, Charles Hawkins, Michael D. Peel, Long-Xi Yu

Plants, Soils, and Climate Faculty Publications

Many agricultural lands in the western United States consist of soil with high concentrations of salt, which is detrimental to alfalfa (Medicago sativa L.) growth and production, especially in the region where water resource is limited. Developing alfalfa varieties with salt tolerance is imperative for sustainable production under increasing soil salinity. In the present study, we used advanced alfalfa breeding populations and evaluated five traits related to salt tolerance including biomass dry weight (DW) and fresh weight (FW), plant height (PH), leaf relative water content (RWC), and stomatal conductance (SC) under control and salt stress. Stress susceptibility index (SSI) …

Soil And Vegetation Survey Of Antelope Pasture, Curlew Grazing Allotment, Oneida County, Id, Merran Owen, Kari E. Veblen, Thomas A. Monaco, Janis Boettinger

Wildland Resources Faculty Publications

Antelope Pasture, located in the Black Pine Valley of Oneida County, Idaho, is a 1500-acre portion of the Curlew Grazing Allotment, managed by the Pocatello Field Office of the BLM (Figure 1). The pasture is heavily invaded with exotic annuals such as cheatgrass (Bromus tectorum), halogeton (Halogeton glomeratus), and clasping pepperweed (Lepidium perfoliatum), and grazing is temporarily discontinued. Land-use history of the pasture includes livestock grazing, possible homesteading and cultivation of Agropyron cristatum (crested wheatgrass).

Catalytic Mechanism For The Conversion Of Salicylate Into Catechol By The Flavin-Dependent Monooxygenase Salicylate Hydroxylase, Débora M. A. Costa, Stefanya V. Gómez, Simara S. De Araújo, Mozart S. Pereira, Rosemeire B. Alves, Denize C. Favaro, Alvan C. Hengge, Ronaldo A. P. Nagem, Tiago A. S. Brandão

Chemistry and Biochemistry Faculty Publications

Salicylate hydroxylase (NahG) is a flavin-dependent monooxygenase that catalyzes the decarboxylative hydroxylation of salicylate into catechol in the naphthalene degradation pathway in Pseudomonas putida G7. We explored the mechanism of action of this enzyme in detail using a combination of structural and biophysical methods. NahG shares many structural and mechanistic features with other versatile flavin-dependent monooxygenases, with potential biocatalytic applications. The crystal structure at 2.0 Å resolution for the apo form of NahG adds a new snapshot preceding the FAD binding in flavin-dependent monooxygenases. The k_cat/K_m for the salicylate reaction catalyzed by the holo form is …

Exploring Mortality Rates For Major Causes Of Death In Korea, Hyo Jung Oh, Donng Min Yang, Chong Hyuck Kim, Jae Gyu Jeon, Nam Hyung Jung, Chan Young Kim, Jurgen Symanzik, Hyo Won Oh, Akugizibwe Edwin, Seong Ii Jo, Jeong Yong Ahn

Mathematics and Statistics Faculty Publications

Background: The trends and patterns of the mortality rates for causes of death are meaningful information. They can provide a basis for national demographic and health care policies by identifying the number, causes, and geographical distribution of deaths.

Objective: To explore and analyze the characteristics of the mortality rates for major causes of death in Korea.

Methods: Some common data analysis methods were used to describe the data. We also used some visualization techniques such as heat maps and line plots to present mortality rates by gender, age, and year.

Results: Our analysis shows the crude …

Dual Geometry Schemes In Tetrel Bonds: Complexes Between Tf4(T = Si, Ge, Sn) And Pyridine Derivatives, Wiktor Zierkiewicz, Mariusz Michalczyk, Rafał Wysokiński, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

When an N-base approaches the tetrel atom of TF4(T = Si, Ge, Sn) the latter moleculedeforms from a tetrahedral structure in the monomer to a trigonal bipyramid. The base can situateitself at either an axial or equatorial position, leading to two different equilibrium geometries.The interaction energies are considerably larger for the equatorial structures, up around 50 kcal/mol,which also have a shorter R(T··N) separation. On the other hand, the energy needed to deform thetetrahedral monomer into the equatorial structure is much higher than the equivalent deformationenergy in the axial dimer. When these two opposite trends are combined, it is the axial …

Development Of Ultrafast Broadband Electronic Sum Frequency Generation For Charge Dynamics At Surfaces And Interfaces, Gang-Hua Deng, Yuqin Qian, Yi Rao

Chemistry and Biochemistry Faculty Publications

Understandings of population and relaxation of charges at surfaces and interfaces are essential to improve charge collection efficiency for energy conversion, catalysis, and photosynthesis. Existing time-resolved surface and interface tools are limited to either under ultrahigh vacuum or in a narrow wavelength region with the loss of spectral information. There lacks an efficient time-resolved surface/interface-specific electronic spectroscopy under ambient conditions for the ultra fast surface/interface dynamics. Here we developed a novel technique for surface/interface-specific broadband electronic sum frequency generation (ESFG). The broadband ESFG was based on a stable two-stage BiB₃O₆ crystal-based optical parametric amplifier, which generates a …