Physical Sciences and Mathematics Commons^™

The Effects Of Beta Transition On Dielectric Breakdown In Ldpe, Tyler Kippen, Allen Andersen, Jr Dennison

Presentations

No abstract provided.

Phenological Mismatch In Coastal Western Alaska May Increase Summer Season Greenhouse Gas Uptake, Katharine C. Kelsey, A. Joshua Leffler, Karen H. Beard, Ryan T. Choi, Joel A. Schmutz, Jeffery M. Welker

Wildland Resources Faculty Publications

High latitude ecosystems are prone to phenological mismatches due to climate change- driven advances in the growing season and changing arrival times of migratory herbivores. These changes have the potential to alter biogeochemical cycling and contribute to feedbacks on climate change by altering greenhouse gas (GHG) emissions of carbon dioxide (CO₂), methane (CH₄) and nitrous oxide (N₂O) through large regions of the Arctic. Yet the effects of phenological mismatches on gas fluxes are currently unexplored. We used a three-year field experiment that altered the start of the growing season and timing of grazing to …

Characterizing The Effects Of Radiation On Muscle Cells, Lori Caldwell, Charles Harding, Eryn Hanson, Jr Dennison, Elizabeth Vargis

Presentations

No abstract provided.

Zonally Symmetric Oscillations Of The Thermosphere At Planetary Wave Periods, Jeffrey M. Forbes, Xiaoli Zhang, Astrid Maute, Maura E. Hagan

All Physics Faculty Publications

New mechanisms for imposing planetary wave (PW) variability on the ionosphere‐thermosphere system are discovered in numerical experiments conducted with the National Center for Atmospheric Research thermosphere‐ionosphere‐electrodynamics general circulation model. First, it is demonstrated that a tidal spectrum modulated at PW periods (3–20 days) entering the ionosphere‐thermosphere system near 100 km is responsible for producing ±40 m/s and ±10–15 K PW period oscillations between 110 and 150 km at low to middle latitudes. The dominant response is broadband and zonally symmetric (i.e., “S0”) over a range of periods and is attributable to tidal dissipation; essentially, the ionosphere‐thermosphere system “vacillates” in response …

Second Order Fully Discrete Energy Stable Methods On Staggered Grids For Hydrodynamic Phase Field Models Of Binary Viscous Fluids, Yuezheng Gong, Jia Zhao, Qi Wang

Mathematics and Statistics Faculty Publications

We present second order, fully discrete, energy stable methods on spatially staggered grids for a hydrodynamic phase field model of binary viscous fluid mixtures in a confined geometry subject to both physical and periodic boundary conditions. We apply the energy quadratization strategy to develop a linear-implicit scheme. We then extend it to a decoupled, linear scheme by introducing an intermediate velocity term so that the phase variable, velocity field, and pressure can be solved sequentially. The two new, fully discrete linear schemes are then shown to be unconditionally energy stable, and the linear systems resulting from the schemes are proved …

Magnetic Properties Of Acenes And Their O-Quinone Derivatives: Computer Simulation, A. A. Starikova, A. G. Starikov, R. M. Minyaev, Alexander I. Boldyrev, V. I. Minkin

Chemistry and Biochemistry Faculty Publications

Quantum chemical study (DFT UB3LYP/6-311++G(d,p)) of the structure and properties of acenes functionalized with two o-benzoquinone groups and their complexes with sodium cations has been performed. An increase in the number of fused rings has been shown to result in the stabilization of biradicaloid state of acenes and the switching of the character of exchange interactions between redox-active moieties from antiferromagnetic to ferromagnetic. The obtained results allow one to consider o-quinone acene derivatives as a basis for designing magnetoactive compounds.

Emissions Of Organic Compounds From Produced Water Ponds I: Characteristics And Speciation, Seth N. Lyman, Marc L. Mansfield, Huy N. Q. Tran, Jordan D. Evans, Colleen Jones, Trevor O'Neil, Ric Bowers, Ann Smith, Cara Keslar

Chemistry and Biochemistry Faculty Presentations

We measured fluxes of methane, a suite of non-methane hydrocarbons (C2–C11), light alcohols, and carbon dioxide from oil and gas produced water storage and disposal ponds in Utah (Uinta Basin) and Wyoming (Upper Green River Basin) United States during 2013–2016. In this paper, we discuss the characteristics of produced water composition and air-water fluxes, with a focus on flux chamber measurements. In companion papers, we will (1) report on inverse modeling methods used to estimate emissions from produced water ponds, including comparisons with flux chamber measurements, and (2) discuss the development of mass transfer coefficients to estimate emissions and place …

Site Conditions Determine A Key Native Plant’S Contribution To Invasion Resistance In Grasslands, Kristin B. Hulvey, Brittany J. Teller

Wildland Resources Faculty Publications

Many plant invasion studies in grasslands suggest that resident plants that share functional traits with invaders can reduce invasion by competing for limiting resources. However, since invasion studies often occur in highly controlled plots or microcosms, it is unclear how heterogeneous site conditions alter competitive interactions under realistic scenarios. To explore how landscape heterogeneity affects biotic resistance provided by competitive resident plants, we conducted a field‐based experiment across four sites in California grasslands. Plots contained naturally occurring populations of native Hemizonia congesta, but differed in other characteristics, including litter cover, annual grass cover, soil moisture, and species richness. We invaded …

Introducing And Evaluating A Knowledge Transfer Approach To Support Problem Solving In And Around Protected Areas, Brady J. Mattsson, Marie Fischborn, Mark W. Brunson, Harald Vacik

Environment and Society Faculty Publications

Protected areas (PAs) can generate many benefits inside and outside their borders, and achieving objectives for diverse stakeholders raises many challenges. There are many examples of successful PA management around the globe, although a systematic and comprehensive approach to developing and sharing these solutions has been lacking. We present “solutioning” as a structured process of peer-learning, which can inform management strategies in and around protected areas. We explain how the PANORAMA—Solutions for a Healthy Planet initiative has put solutioning into practice through an interactive community and web portal to learn about protected area solutions around the globe. Unlike other web …

Mxin Differentially Regulates Monomeric And Oligomeric Species Of The Shigella Type Three Secretion System Atpase Spa47, Heather B. Case, Nicholas E. Dickenson

Chemistry and Biochemistry Faculty Publications

Shigella rely entirely on the action of a single type three secretion system (T3SS) to support cellular invasion of colonic epithelial cells and to circumvent host immune responses. The ATPase Spa47 resides at the base of the Shigella needle-like type three secretion apparatus (T3SA), supporting protein secretion through the apparatus and providing a likely means for native virulence regulation by Shigella and a much needed target for non-antibiotic therapeutics to treat Shigella infections. Here, we show that MxiN is a differential regulator of Spa47 and that its regulatory impact is determined by the oligomeric state of the Spa47 ATPase, with …

High Resolution Monitoring Of River Bluff Erosion Reveals Failure Mechanisms And Geomorphically Effective Flows, Sara A. Kelly, Patrick Belmont

Watershed Sciences Faculty Publications

Using a combination of Structure from Motion and time lapse photogrammetry, we document rapid river bluff erosion occurring in the Greater Blue Earth River (GBER) basin, a muddy tributary to the sediment-impaired Minnesota River in south central Minnesota. Our datasets elucidated dominant bluff failure mechanisms and rates of bluff retreat in a transient system responding to ongoing streamflow increases and glacial legacy impacts. Specifically, we document the importance of fluvial scour, freeze–thaw, as well as other drivers of bluff erosion. We find that even small flows, a mere 30% of the two-year recurrence interval flow, are capable of causing bluff …

Halogen, Chalcogen, And Pnicogen Bonding Involving Hypervalent Atoms, Steve Scheiner, Jia Lu

Chemistry and Biochemistry Faculty Publications

The additional substituents arising from hypervalency present a number of complicating issues for the formation of noncovalent bonds. The XF5 molecule (X=Cl, Br, I) was allowed to form a halogen bond with NH3 as base. Hypervalent chalcogen bonding is examined by way of YF4 and YF6 (Y=S, Se, Te), and ZF5 (Z=P, As, Sb) is used to model pnicogen bonding. Pnicogen bonds are particularly strong, with interaction energies approaching 50 kcal/mol, and also involve wholesale rearrangement from trigonal bipyramidal in the monomer to square pyramidal in the complex, subject to a large deformation energy. YF4 chalcogen bonding is also strong, …

D-Region Vlf Monitoring System, Jonh Carlos Mojica Decena

Physics Capstone Projects

The use of VLF signals to monitor the changes that occur in the ionosphere resulting from solar variability, has helped to understand how different ionospheric layers depend upon the Sun. These different ionospheric layer responses play a significant role in determining space weather impacts. Our system was created to be a permanent monitor to study the effects on the D-region of the ionosphere and explore any major impacts due to sun radiation exposure. The use of inexpensive equipment proved to be effective and the key point in the creation of this system.

Data From: Polar Topside Ionosphere During Geomagnetic Storms: Comparison Of Isis-Ii With Tdim, Jan J. Sojka, Dan Rice, Michael David, Robert W. Schunk, Robert Benson, H. G. James

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Output files from runs of the TDIM ionospheric model used for calculations and electron density profiles from ISIS-II and TDIM used in figures in the article in Radio Science.

Electron Injection From A Carboxylic Anchoring Dye To Tio2 Nanoparticles In Aprotic Solvents, Hui Fang, Yuhao Wu, Danielle L. Kuhn, Brendan G. Delacy, Yi Rao, Hai-Lung Dai

Chemistry and Biochemistry Faculty Publications

Injection of photoexcited electrons in the para-Ethyl Red dye to TiO₂ nanoparticles (Anatase, 40 nm diameter) is characterized by transient absorption on ultrafast time scales. This study focuses on understanding the effect of aprotic solvents on the injection rate. Transient absorption at 1900 cm⁻¹ is probed following a 400 nm pulse which excites the electronic transition of p-ER adsorbed on TiO₂ through its carboxylic group. Measurements conducted in three different solvents show that electron injection lifetimes are in the 250–300 fs range but display a trend in correlation with solvent polarity: the electron injection lifetime is the …

Alluvial Substrate Mapping By Automated Texture Segmentation Of Recreational-Grade Side Scan Sonar Imagery, Daniel Hamill, Daniel Buscombe, Joseph Michael Wheaton

Watershed Sciences Faculty Publications

Side scan sonar in low-cost ‘fishfinder’ systems has become popular in aquatic ecology and sedimentology for imaging submerged riverbed sediment at coverages and resolutions sufficient to relate bed texture to grain-size. Traditional methods to map bed texture (i.e. physical samples) are relatively high-cost and low spatial coverage compared to sonar, which can continuously image several kilometers of channel in a few hours. Towards a goal of automating the classification of bed habitat features, we investigate relationships between substrates and statistical descriptors of bed textures in side scan sonar echograms of alluvial deposits. We develop a method for automated segmentation of …

Electrolyzer Design For Flexible Decoupled Water Splitting And Organic Upgrading With Electron Reservoirs, Wei Li, Nan Jiang, Bo Hu, Xuan Liu, Fuzhan Song, Guanqun Han, Taylor J. Jordan, Tanner B. Hanson, T. Leo Liu, Yujie Sun

Chemistry and Biochemistry Faculty Publications

The Bigger Picture

Electrocatalytic water splitting is a green approach to producing clean H₂ fuel, especially when it is driven by renewable energy sources. Conventional water electrolysis always produces H₂ and O₂ simultaneously under corrosive acidic or alkaline conditions with large voltage inputs, posing safety concerns of H₂/O₂ mixing. Therefore, it is desirable to develop a new electrolyzer design for decoupled water splitting in an eco-friendly neutral solution with small voltage inputs to enable separated H₂ and O₂ evolution. Herein, we report (ferrocenylmethyl)trimethylammonium chloride and Na₄[Fe(CN)₆] as proton-independent …

Benthic Meiofaunal Community Response To The Cascading Effects Of Herbivory Within An Algal Halo System Of The Great Barrier Reef, Quinn R. Ollivier, Edward Hammill, David J. Booth, Elizabeth M.P. Madin, Charles Hinchliffe, Alastair R. Harborne, Catherine E. Lovelock, Peter I. Macreadie, Trisha Brooke Atwood

Watershed Sciences Faculty Publications

Benthic fauna play a crucial role in organic matter decomposition and nutrient cycling at the sediment-water boundary in aquatic ecosystems. In terrestrial systems, grazing herbivores have been shown to influence below-ground communities through alterations to plant distribution and composition, however whether similar cascading effects occur in aquatic systems is unknown. Here, we assess the relationship between benthic invertebrates and above-ground fish grazing across the ‘grazing halos’ of Heron Island lagoon, Australia. Grazing halos, which occur around patch reefs globally, are caused by removal of seagrass or benthic macroalgae by herbivorous fish that results in distinct bands of unvegetated sediments surrounding …

A Network Model For Primary Production Highlights Linkages Between Salmonid Populations And Autochthonous Resources, W. Carl Saunders, Nicolaas Bouwes, Peter Mchugh, Chris E. Jordan

Watershed Sciences Faculty Publications

Spatial variation in fish densities across river networks suggests that the influence of food and habitat resources on assemblages varies greatly throughout watersheds. Conceptual models predict that in situ primary production should vary with river characteristics, but the influence of autochthonous resource availability on the capacity for river reaches to support fish is poorly understood. We estimated primary production throughout the South Fork and Middle Fork of the John Day River, Oregon, by measuring diel cycles in dissolved oxygen (DO) during July 2013. Using these data, we (1) evaluated the extent to which juvenile salmonid abundance and resource limitation correlated …

Effects Of Acoustic Coupling Layer Electrical Conductivity On Pulsed Electroacoustic Measurements, Zachary Gibson, Jr Dennison, Lee Pearson, Erick Griffiths, Anthony Pearson

Posters

The spatial resolution of Pulsed Electroacoustic (PEA) measurements can be limited by the acoustic thickness of the coupling material coupling the sample to the detector assembly. Our investigations studied the effect of adhesive material and thickness to optimize the quality of the PEA signal.

Electron Parallel Closures For The 3 + 1 Fluid Model, Jeong-Young Ji, Ilon Joseph

All Physics Faculty Publications

Linear closures are obtained for arbitrary collisionality for the 3 þ 1 fluid model which includes the evolution of density, flow velocity, and pressure both parallel and perpendicular to a preferred direction, usually a magnetic field. A large set of 6400 moment equations is solved to provide closures that are accurate in the collisional regime and well into the collisionless regime. The closures in the collisionless limit are determined by solving the kinetic equation with a model collision operator. Simple fits for the kernel functions that define the closures are obtained for arbitrary collisionality in wave number space. The results …

Multi-Instrumented Observations Of The Equatorial F-Region During June Solstice: Large-Scale Wave Structures And Spread-F, Fabiano S. Rodrigues, Dustin A. Hickey, Weijia Zhan, Carlos R. Martinis, B. G. Fejer, Marco A. Milla, Juan F. Arratia

All Physics Faculty Publications

Typical equatorial spread-F events are often said to occur during post-sunset, equinox conditions in most longitude sectors. Recent studies, however, have found an unexpected high occurrence of ionospheric F-region irregularities during June solstice, when conditions are believed to be unfavorable for the development of plasma instabilities responsible for equatorial spread-F (ESF). This study reports new results of a multi-instrumented investigation with the objective to better specify the occurrence of these atypical June solstice ESF in the American sector and better understand the conditions prior to their development. We present the first observations of June solstice ESF events …

Partitioning The Effects Of Eco-Evolutionary Feedbacks On Community Stability, Swati Patel, Michael H. Cortez, Sebastian J. Schreiber

Mathematics and Statistics Faculty Publications

A fundamental challenge in ecology continues to be identifying mechanisms that stabilize community dynamics. By altering the interactions within a community, eco-evolutionary feedbacks may play a role in community stability. Indeed, recent empirical and theoretical studies demonstrate that these feedbacks can stabilize or destabilize communities and, moreover, that this sometimes depends on the relative rate of ecological to evolutionary processes. So far, theory on how eco-evolutionary feedbacks impact stability exists only for a few special cases. In our work, we develop a general theory for determining the effects of eco-evolutionary feedbacks on stability in communities with an arbitrary number of …

Electron Transfer To Nitrogenase In Different Genomic And Metabolic Backgrounds, Saroj Poudel, Daniel R. Colman, Kathryn R. Fixen, Rhesa N. Ledbetter, Yanning Zheng, Natasha Pence, Lance C. Seefeldt, John W. Peters, Caroline S. Harwood, Eric S. Boyd

Chemistry and Biochemistry Faculty Publications

Nitrogenase catalyzes the reduction of dinitrogen (N₂) using low-potential electrons from ferredoxin (Fd) or flavodoxin (Fld) through an ATP-dependent process. Since its emergence in an anaerobic chemoautotroph, this oxygen (O₂)-sensitive enzyme complex has evolved to operate in a variety of genomic and metabolic backgrounds, including those of aerobes, anaerobes, chemotrophs, and phototrophs. However, whether pathways of electron delivery to nitrogenase are influenced by these different metabolic backgrounds is not well understood. Here, we report the distribution of homologs of Fds, Flds, and Fd-/Fld-reducing enzymes in 359 genomes of putative N₂ fixers (diazotrophs). Six distinct lineages …

Experimental Study Of Gravitational Mixing Of Supercritical Co2, Dennis L. Newell, J. William Carey, Scott N. Backhaus, Peter Lichtner

Geosciences Faculty Publications

CO₂ injection into saline aquifers for sequestration will initially result in buoyant supercritical (sc)CO₂ trapped beneath the caprock seal. During this period, there is risk of CO₂ migration out of the reservoir along wellbore defects or fracture zones. Dissolution of the scCO₂ plume into brine results in solubility trapping and reduces this risk, but based on diffusion alone, this mechanism could take thousands of years. Gravitational (density-induced) mixing of CO₂-saturated brine is shown to significantly accelerate this process in computational studies, but few experimental efforts have confirmed the phenomenon. Here, constant-pressure, 3-dimensional bench-scale experiments …

Implications Of Monomer Deformation For Tetrel And Pnicogen Bonds, Wiktor Zierkiewicz, Mariusz Michalczyk, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

A series of TF₄ and ZF₅ molecules (T = Si, Ge, Sn and Z = P, As, Sb) were allowed to engage in tetrel and pnicogen bonds, respectively, with NH₃, pyrazine, and HCN. The interaction energies are quite large, approaching 50 kcal mol^-1 in some cases. The formation of each complex is accompanied by substantial geometrical deformation of the Lewis acid to accommodate the approaching base. The energy associated with this monomer rearrangement is the largest for the smaller central atoms Si and P, where it exceeds 20 kcal mol^-1. The total reaction …

Steric Crowding In Tetrel Bonds, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

The tetravalent character of tetrel atoms leaves only limited room for an incoming nucleophile to approach and engage in a noncovalent bond with a tetrel atom. Any such approach can only occur at the expense of internal geometric distortions. The balance between attractive forces and repulsive steric crowding was studied for a series of Lewis acids of the type FTR₃ (T = Si, Ge, Sn, Pb) which were allowed to interact with various bases. The strength and other properties of the tetrel bond are examined as the R groups are made progressively larger, varying from H and CH_{3 …}

Evidence For Cyclical Fractional Crystallization, Recharge, And Assimilation In Basalts Of The Kimama Drill Core, Central Snake River Plain, Idaho: 5.5-Million-Years Of Petrogenesis In A Mid-Crustal Sill Complex, Katherine E. Potter, John W. Shervais, Eric H. Christiansen, Scott K. Vetter

Geosciences Faculty Publications

Basalts erupted in the Snake River Plain of central Idaho and sampled in the Kimama drill core link eruptive processes to the construction of mafic intrusions over 5.5 Ma. Cyclic variations in basalt composition reveal temporal chemical heterogeneity related to fractional crystallization and the assimilation of previously-intruded mafic sills. A range of compositional types are identified within 1,912 m of continuous drill core: Snake River olivine tholeiite (SROT), low K SROT, high Fe-Ti, and evolved and high K-Fe lavas similar to those erupted at Craters of the Moon National Monument. Detailed lithologic and geophysical logs document 432 flow units comprising …

Direct Effects Of Warming Increase Woody Plant Abundance In A Subarctic Wetland, Lindsay G. Carlson, Karen H. Beard, Peter B. Adler

Wildland Resources Faculty Publications

Both the direct effects of warming on a species’ vital rates and indirect effects of warming caused by interactions with neighboring species can influence plant populations. Furthermore, herbivory mediates the effects of warming on plant community composition in many systems. Thus, determining the importance of direct and indirect effects of warming, while considering the role of herbivory, can help predict long-term plant community dynamics. We conducted a field experiment in the coastal wetlands of western Alaska to investigate how warming and herbivory influence the interactions and abundances of two common plant species, a sedge, Carex ramenskii, and a dwarf …

Mesospheric Densities And Temperatures Derived From 11 Years Of Data Acquired With The Rayleigh-Scatter Lidar At The Atmospheric Lidar Observatory At Utah State University, Vincent B. Wickwar, Joshua P. Herron

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Frequent observations were carried out with the Rayleigh-scatter lidar at Utah State University’s Atmospheric Lidar Observatory (41.742572° N, 111.808273° W, and 1466 m) from August 1993 through December 2004. Of 964 nights observed, a total of 839 nights were judged good for deriving temperatures. These 839 were reduced to obtain all-night relative neutral densities and absolute temperatures. These results extend from 45 to ≤ 95 km, thereby covering the mesosphere. This netCDF file starts by giving the number of nights included in the file. For each night, the netCDF file then provides defining parameters and derived profiles, as defined below. …