Physical Sciences and Mathematics Commons^™

Global Nightly Oh And O2 Mesospheric Airglow: Examining A Decade Of Measurements Using The Nasa Saber Satellite Sensor, Jonathan Price, Jordan C. Rozum, Gene Ware, Doran Baker

Browse All Undergraduate research

The SABER instrument aboard the TIMED satellite is a multichannel radiometer and has been continuously measuring the altitude distribution of infrared airglow intensity in the mesosphere on a global basis since 2002. While the majority of these altitude distributions are Gaussian-like, a significant portion exhibit two or more local maxima, suggesting multiple airglow layers. To better understand the cause of this phenomenon, the global and temporal distributions of infrared OH andO2 scans resulting in multiple peak altitude profiles are being examined.

In Situ Surface Voltage Measurements Of Dielectrics Under Electron Beam Irradiation, Joshua L. Hodges, John R. Dennison, Gregory Wilson, Amberly Evans, Alec Sim

All Physics Faculty Publications

New instrumentation has been developed for non- contact, in vacuo measurements of the electron beam-induced surface voltage as a function of time and position for non- conductive spacecraft materials in a simulated space environment. The novel compact system uses two movable capacitive sensor electrodes to measure surface charge distributions on samples, using a non-contact method that has little effect on charge dissipation from sample. Design details, calibration and characterization measurements of the system are presented, with <1 V to >30 kV surface voltage range, <0.5 V voltage resolution, and <1.5 mm spatial resolution. Used in conjunction with the capabilities of an existing ultrahigh vacuum electron emission test chamber, the new instrumentation facilitates measurements of charge accumulation, bulk resistivity, effects of charge depletion and accumulation on yield measurements, electron induced electrostatic breakdown potentials, radiation induced conductivity effects, and the radial dispersion of surface voltage.

Three types of measurements of surface voltage for polyimide (Kapton HNTM) serve to illustrate the research capabilities of the …

Feasibility Of Detecting Spacecraft Charging And Arcing By Remote Sensing, Dale C. Ferguson, Jeremy Murray Krezan, David A. Barton, Jr Dennison, Stephen Gregory

Journal Articles

More than 50 years after the dawn of the space age, most spacecraft still do not have sensors onboard capable of detecting whether they are at potentials likely to put them at risk of severe charging and the concomitant arcing, or, indeed, even capable of detecting when or if they undergo arcing. As a result, anomaly resolution has often been hit or miss, and false diagnoses are probably common. In this paper, a few remote sensing techniques that could be applied for remotely detecting spacecraft charging and/or arcing, and their feasibility, are examined: surface glows from high-energy electron impact, x-rays …

A Study Of Anisotropic Chemical Etching On Crystalline Silicon, Gregory D. Erickson

Physics Capstone Projects

It is known that chemical reaction rates can be different on different crystal planes. KOH is a common etchant for Si and the reaction rate on {100} planes is much faster than the {111} planes. Therefore a square etch window on a (100) Si surface can become an inverse pyramid at some point after KOH etch. However, it is not clear how a 3-­‐dimensional cubic crystal will evolve by KOH etching. In this study we use a dicing saw to create arrays of rectangular crystal pillars of different dimensions in two different orientations followed by 6M KOH etch at 50º …

Low Temperature Cathodoluminescence In Disordered Sio2, Amberly Evans Jensen, Jr Dennison, Gregory Wilson, Justin Dekany

Graduate Student Publications

In recent charging studies, a discernible glow was detected emanating from sample surfaces undergoing electron beam bombardment that resulted from a luminescent effect termed cathodoluminescence. This suggests that some of the materials used as optical elements, structural components, and thermal control surfaces in the construction of space-based observatories might luminesce when exposed to sufficiently energetic charged particle fluxes from the space plasma environment. A central focus of our experiments was the temperature dependence of the luminescent behavior. Here, an overview of our experimental results is given, as well as a qualitative model to describe the luminescent behavior. We look at …

Ultrahigh Vacuum Cryostat System For Extended Low Temperature Space Environment Testing, Justin Dekany, Robert H. Johnson, Gregory Wilson, Amberly Evans Jensen, Jr Dennison

Graduate Student Publications

The range of temperature measurements have been significantly extended for an existing space environment simulation test chamber used in the study of electron emission, sample charging and discharge, electrostatic discharge and arcing, electron transport, and luminescence of spacecraft materials. This was accomplished by incorporating a new two- stage, closed-cycle helium cryostat which has an extended sample temperature range from450 K, with long-term controlled stability of

Paleolimnological Analysis Of The History Of Metals Contamination In The Great Salt Lake, Utah, Wayne A. Wurtsbaugh, Katrina Moser, Peter R. Leavitt

Wayne A. Wurtsbaugh

Three sediment cores from the Great Salt Lake were analyzed to determine the magnitude and timing for the deposition of 21 metal contaminants. In the main lake (Gilbert Bay) concentrations of copper, lead, zinc, cadmium, silver, molybdenum, tin, mercury and others began increasing in the sediments in the late 1800s or early 1900s and peaked in the 1950s. These increases were coincident with increases in mining and smelting activities for these metals in Utah. Contamination indices in the 1950s were 20-60 fold above background concentrations for silver, copper, lead and molybdenum, and <15-fold for most other metals. Since the 1950s, concentrations of most metals in the sediments have decreased 2-5 fold coincident with decreases in mining and improved smelting technologies. Nevertheless concentrations for many metals in surficial sediments are still above acceptable criteria established for freshwater ecosystems. In contrast to most metals, concentrations of selenium and arsenic were stable or increasing slightly in the Gilbert Bay sediments. In a coring site located in Farmington Bay near an EPA Superfund Site discharge canal, concentrations of metals were high and showed no indication of decreasing in more recent sediments. Surficial sediments from additional sites in the Great Salt Lake indicated that metals were more concentrated towards the southern end of the lake where the primary sources of contamination were located.

Strongly Bound Noncovalent (So3)N:H2co Complexes (N = 1, 2), L. M. Azofra, I. Alkorta, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

The potential energy surfaces (PES) for the SO3:H2CO and (SO3)2:H2CO complexes were thoroughly examined at the MP2/aug-cc-pVDZ computational level. Heterodimers and trimers are held together primarily by SO chalcogen bonds, supplemented by weaker CHO and/or OC bonds. The nature of the interactions is probed by a variety of means, including electrostatic potentials, AIM, NBO, energy decomposition, and electron density redistribution maps. The most stable dimer is strongly bound, with an interaction energy exceeding 10 kcal mol(-1). Trimers adopt the geometry of the most stable dimer, with an added SO3 molecule situated so as to interact with both of the original …

Effects Of Charge And Substituent On The S∙∙∙N Chalcogen Bond, U. Adhikari, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

Neutral complexes containing a S···N chalcogen bond are compared with similar systems in which a positive charge has been added to the S-containing electron acceptor, using high-level ab initio calculations. The effects on both XS···N and XS+···N bonds are evaluated for a range of different substituents X = CH3, CF3, NH2, NO2, OH, Cl, and F, using NH3 as the common electron donor. The binding energy of XMeS···NH3 varies between 2.3 and 4.3 kcal/mol, with the strongest interaction occurring for X = F. The binding is strengthened by a factor of 2–10 in charged XH2S+···NH3 complexes, reaching a maximum of …

Competition Between Lone Pair-Π, Halogen Bond, And Hydrogen Bond In Adducts Of Water With Perhalogenated Alkenes C2clnf4-N (N = 0-4), U. Adhikari, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

A thorough search of the potential energy surface is carried out for heterodimers of water with C2ClnF4−n. Three different types of interactions are observed. Structures dominated by a lone pair–π interaction have the highest binding energies, and are stabilized by charge transfer from O lone pairs of H2O to the Csingle bondC π* antibonding orbital of the alkene. Halogen-bonded O⋯Cl complexes are slightly less strongly bound, followed by OH⋯X hydrogen bonds. The replacements of Cl by F atoms have only small effects upon binding energies. Inclusion of vibrational and entropic effects removes the clear energetic superiority of lp–π binding energies. …

Substituent Effects In The Noncovalent Bonding Of So2 To Molecules Containing A Carbonyl Group. The Dominating Role Of The Chalcogen Bond, L. M. Azofra, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

The SO2 molecule is paired with a number of carbonyl-containing molecules, and the properties of the resulting complexes are calculated by high-level ab initio theory. The global minimum of each pair is held together primarily by a S···O chalcogen bond wherein the lone pairs of the carbonyl O transfer charge to the π* antibonding SO orbital, supplemented by smaller contributions from weak CH···O H-bonds. The binding energies vary between 4.2 and 8.6 kcal/mol, competitive with even some of the stronger noncovalent forces such as H-bonds and halogen bonds. The geometrical arrangement places the carbonyl O atom above the plane of …

Interaction Between Temozolomide And Water: Preferred Binding Sites, O. E. Kasende, A. Matondo, M. Muzomwe, J. T. Muya, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

Computational methods are used to predict the most favorable site of temozolomide towards attack by a water molecule. The energetics of the various complexes are presented as well as their geometries, including perturbations of each subunit caused by the presence of the other. Molecular electrostatic potential and Natural Bond Orbital (NBO) data are used to understand the interactions which conclude the terminal amide group is the preferred attack site where water can act as simultaneous proton donor and acceptor. Other potential proton acceptor N atoms within the aromatic ring structure represent weaker binding sites. Some of the less strongly bound …

The Mtr4 Ratchet Helix And Arch Domain Both Function To Promote Rna Unwinding, Lacy L. Taylor, Ryan N. Jackson, Megi Rexhepaj, Alejandra Klauer King, Lindsey K. Lott, Ambro Van Hoof, Sean J. Johnson

Chemistry and Biochemistry Faculty Publications

Mtr4 is a conserved Ski2-like RNA helicase and a subunit of the TRAMP complex that activates exosomemiated 3-5 turnover in nuclear RNA surveillance and processing pathways. Prominent features of the Mtr4 structure include a four-domain ring-like helicase core and a large arch domain that spans the core. The ‘ratchet helix’ is positioned to interact with RNA substrates as they move through the helicase. However, the contribution of the ratchet helix in Mtr4 activity is poorly understood. Here we show that strict conservation along the ratchet helix is particularly extensive for Ski2-like RNA helicases compared to related helicases. Mutation of residues …

Electrodeposited Nickel-Sulfide Films As Competent Hydrogen Evolution Catalysts In Neutral Water, N. Jiang, L. Bogoev, M. Popova, S. Gul, J. Yano, Y. Sun

Chemistry and Biochemistry Faculty Publications

The development of low-cost, efficient, and robust electrocatalysts of the hydrogen evolution reaction (HER) is a crucial step toward the conversion and storage of sustainable and carbon-neutral energy resources, such as solar energy. Not only the HER catalysts need to be composed of inexpensive elements, they are also desirable to be prepared at low energy cost. In this work, we report that nickel-sulfide (Ni-S) films prepared by facile potentiodynamic deposition are active HER catalysts in aqueous media. Notably, the Ni-S films showed catalytic activity in water with a wide range of pH values (0 to 14), as well as in …

Complexation Of N So2 Molecules (N=1,2,3) With Formaldehyde And Thioformaldehyde, L. M. Azofra, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

Ab initio and density functional theory calculations are used to examine complexes formed between H2CO and H2CS with 1, 2, and 3 molecules of SO2. The nature of the interactions is probed by a variety of means, including electrostatic potentials, natural bond orbital, atoms in molecules, energy decomposition, and electron density redistribution maps. The dimers are relatively strongly bound, with interaction energies exceeding 5 kcal/mol. The structures are cyclic, containing both a O/S⋯S chalcogen bond and a CH⋯O H-bond. Addition of a second SO2 molecule leads to a variety of heterotrimer structures, most of which resemble the original dimer, where …

Complexes Containing Co2 And So2. Mixed Dimers, Trimers And Tetramers, L. M. Azofra, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

Mixed dimers, trimers and tetramers composed of SO2 and CO2 molecules are examined by ab initio calculations to identify all minimum energy structures. While AIM formalism leads to the idea of a pair of C···O bonds in the most stable heterodimer, bound by some 2 kcal mol(-1), NBO analysis describes the bonding in terms of charge transfer from O lone pairs of SO2 to the CO π* antibonding orbitals. The second minimum on the surface, just slightly less stable, is described by AIM as containing a single O···O chalcogen bond. The NBO picture is that of two transfers in opposite …

An Exploration Of The Ozone Dimer Potential Energy Surface, L. M. Azofra, I. Alkorta, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

The (O3)2 dimer potential energy surface is thoroughly explored at the ab initio CCSD(T) computational level. Five minima are characterized with binding energies between 0.35 and 2.24 kcal/mol. The most stable may be characterized as slipped parallel, with the two O3 monomers situated in parallel planes. Partitioning of the interaction energy points to dispersion and exchange as the prime contributors to the stability, with varying contributions from electrostatic energy, which is repulsive in one case. Atoms in Molecules analysis of the wavefunction presents specific O⋯O bonding interactions, whose number is related to the overall stability of each dimer. All internal …

An Advanced Mesospheric Temperature Mapper For High-Latitude Airglow Studies, Pierre-Dominique Pautet, Michael J. Taylor, William R. Pendleton Jr., Yucheng Zhao, Tao Yuan, R. Esplin, D. Mclain

Publications

Over the past 60 years, ground-based remote sensing measurements of the Earth’s mesospheric temperature have been performed using the nighttime hydroxyl (OH) emission, which originates at an altitude of ∼87  km∼87  km. Several types of instruments have been employed to date: spectrometers, Fabry–Perot or Michelson interferometers, scanning-radiometers, and more recently temperature mappers. Most of them measure the mesospheric temperature in a few sample directions and/or with a limited temporal resolution, restricting their research capabilities to the investigation of larger-scale perturbations such as inertial waves, tides, or planetary waves. The Advanced Mesospheric Temperature Mapper (AMTM) is a novel infrared digital imaging …

Stability Of Traveling-Wave Solutions For A Schrodinger System With Power-Type Nonlinearities, Nghiem Nguyen, Rushun Tian, Zhi-Qiang Wang

Mathematics and Statistics Faculty Publications

In this article, we consider the Schrodinger system with powertype nonlinearities, (Formula presented) where j = 1,...,m, u_j are complex-valued functions of (x, t) 2 R^N+1, a, b are real numbers. It is shown that when b > 0, and a + (m - 1)b > 0, for a certain range of p, traveling-wave solutions of this system exist, and are orbitally stable.

A Shortcut For Multiple Testing On The Directed Acyclic Graph Of Gene Ontology, Garrett Saunders, John R. Stevens, S. Clay Isom

Mathematics and Statistics Faculty Publications

Background: Gene set testing has become an important analysis technique in high throughput microarray and next generation sequencing studies for uncovering patterns of differential expression of various biological processes. Often, the large number of gene sets that are tested simultaneously require some sort of multiplicity correction to account for the multiplicity effect. This work provides a substantial computational improvement to an existing familywise error rate controlling multiplicity approach (the Focus Level method) for gene set testing in high throughput microarray and next generation sequencing studies using Gene Ontology graphs, which we call the Short Focus Level.

Results: The Short Focus …

Significant Impacts Of Radiation Physics In The Wrf Model On The Precipitation And Dynamics Of The West African Monsoon, R. Li, J. Jin, Shih-Yu (Simon) Wang, R. R. Gillies

Plants, Soils, and Climate Faculty Publications

Precipitation from the West African Monsoon (WAM) provides food security and supports the economy in the region. As a consequence of the intrinsic complexities of the WAM’s evolution, accurate simulations of the WAM and its precipitation regime, through the application of regional climate models, are challenging. We used the coupled Weather Research and Forecasting (WRF) and Community Land Model (CLM) to explore impacts of radiation physics on the precipitation and dynamics of the WAM. Our results indicate that the radiation physics schemes not only produce biases in radiation fluxes impacting radiative forcing, but more importantly, result in large bias in …

Could The 2012 Drought In Central U. S. Have Been Anticipated?, Shih-Yu (Simon) Wang, Danny Barandiaran, Kyle Hilburn, Paul Houser

Plants, Soils, and Climate Faculty Publications

This paper summarizes research related to the 2012 record drought in the central United States conducted by members of the NEWS (NASA (National Aeronautics and Space Administration) Energy and Water cycle Study) Working Group. Past drought patterns were analyzed for signal coherency with latest drought and the contribution of long-term trends in the Great Plains low-level jet, an important regional circulation feature of the spring rainy season in the Great Plains. Long-term changes in the seasonal transition from rainy spring into dry summer were also examined. Potential external forcing from radiative processes, soil-air interactions, and ocean teleconnections were assessed as …

Coupling Of Pre-Monsoon Tropical Cyclones With The Monsoon Onset In Myanmar, B. O. Fosu, Shih-Yu (Simon) Wang

Plants, Soils, and Climate Faculty Publications

The pre-monsoon tropical cyclone (TC) activity and the monsoon evolution in the Bay of Bengal (BoB) are both influenced by the Madden–Julian Oscillation (MJO), but the two do not always occur in unison. This study examines the conditions that allow the MJO to modulate the monsoon onset in Myanmar and TC activity concurrently. Using the APHRODITE gridded precipitation and the ERA-Interim reanalysis datasets, composite evolutions of monsoon rainfall and TC genesis are constructed for the period of 1979–2010. It is found that the MJO exhibits a strong interannual variability in terms of phase and intensity, which in some years modulate …

Global Eastward Propagation Signals Associated With The 4-5-Year Enso Cycle, Shih-Yu (Simon) Wang, X. Jiang, B. Fosu

Plants, Soils, and Climate Faculty Publications

Longitude-time evolution of sea surface temperature anomalies (SSTA) reveals a slow southeastward propagation from the western North Pacific (WNP) around 20°N to the Niño-3.4 region in the equatorial Central Pacific. The propagation is manifested as a narrow, southwest-northeast oriented SSTA band across the subtropical North Pacific, and its journey takes about 2–3 years. The propagating SSTA appears to engage the initiation of the El Niño–Southern Oscillation (ENSO). The anomalies of surface winds, sea level pressure, outgoing longwave radiation, and velocity potential all exhibit a concurrent and distinct eastward propagation, one that appears to be circumglobal and is coupled with the …

Monitoring Of Livestock Grazing Effects On Bureau Of Land Management Land, Kari E. Veblen

Wildland Resources Faculty Publications

Public land management agencies, such as the Bureau of Land Management (BLM), are charged with managing rangelands throughout the Western United States for multiple uses such as livestock grazing and conservation of sensitive species and their habitats. Monitoring of condition and trends of these rangelands, particularly with respect to effects of livestock grazing, provide critical information for effective management of these multi-use landscapes. We therefore investigated the availability of livestock grazing-related quantitative monitoring data and qualitative region-specific Land Health Standards (LHS) data across BLM grazing allotments in the Western United States. We then queried university and federal rangeland science experts …

A Tree-Ring Based Reconstruction Of Logan River Streamflow In Northern Utah, Eric B. Allen, Tammy M. Rittenour, R. Justin Derose, Matthew F. Bekker, Roger Kjelgren, Brendan M. Buckley

Wasatch Dendroclimatology Research

[1] We created six new tree-ring chronologies in northern Utah, which were used with preexisting chronologies from Utah and western Wyoming to reconstruct mean annual flow for the Logan River, the largest tributary of the regionally important Bear River. Two reconstruction models were developed, a “Local” model that incorporated two Rocky Mountain juniper chronologies located within the basin, and a “Regional” model that also included limber pine and pinyon pine chronologies from a larger area. The Local model explained 48.2% of the variability in the instrumental record and the juniper chronologies better captured streamflow variability than Douglas-fir collected within the …

A Tree-Ring Based Reconstruction Of Logan River Streamflow, Northern Utah, Eric B. Allen, Tammy M. Rittenour, R. Justin Derose, Matthew F. Bekker, Roger Kjelgren, Brendan M. Buckley

Geosciences Faculty Publications

We created six new tree‐ring chronologies in northern Utah, which were used with preexisting chronologies from Utah and western Wyoming to reconstruct mean annual flow for the Logan River, the largest tributary of the regionally important Bear River. Two reconstruction models were developed, a “Local” model that incorporated two Rocky Mountain juniper chronologies located within the basin, and a “Regional” model that also included limber pine and pinyon pine chronologies from a larger area. The Local model explained 48.2% of the variability in the instrumental record and the juniper chronologies better captured streamflow variability than Douglas‐fir collected within the Logan …

Physics 2710 – Example Exam Iii, David Peak

Exams

No abstract provided.

Mid-Latiude Rayleigh-Mie-Raman Lidar For Observations From 15 To 120 Km, Vincent B. Wickwar, Leda Sox, Joshua P. Herron, Matthew T. Emerick

Posters

Rayleigh lidar opened a portion of the atmosphere, from 30 to 90 km, to ground-based observations. Rayleigh-scatter observations were made at the Atmospheric Lidar Observatory (ALO) at Utah State University (USU) from 1993–2004 between 45 and 90 km. The lidar consisted of a 0.44-m diameter mirror, a frequency-doubled Nd:YAG laser opera'ng at 532-nm at 30- Hz at either 18- or 24-W, giving power- aperture products (PAPs) of 2.7- or 3.6- Wm2, respec'vely, and one detector channel. An example of what was accomplished with this system is shown as part of Fig. 1. The temperature climatology was based on ~5000 hours …

Unified Model Of Charge Transport In Insulating Polymeric Materials, Alec Sim

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Charge transport, charging, and subsequent electrostatic discharge due to interactions with the space environment are primary concerns of spacecraft designers. Developing a physical understanding of the interactions of charge with the multitude of materials that spacecraft are composed of is a critical step in understanding and mitigating both short-term and long-term spacecraft degradation. In particular, the study of charge transport in highly insulating materials is critical as they store charge longer, with higher capacity, and with greater destructive capability than other materials.

The Utah State University Materials Physics Group, with the funding of the NASA James Webb Space Telescope project …