Physical Sciences and Mathematics Commons^™

Ab Initio Study Of Fh–Ph3 And Clh–Ph3 Including The Effects Of Electron Correlation, Z. Latajka, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

Ab initio calculations are carried out for FH–PH₃ and ClH–PH₃ using a basis set including two sets of polarization functions. Electron correlation is incorporated via Møller–Plesset perturbation theory to second and (in part) to third orders. The basis set is tested and found to produce satisfactory treatments of subsystem properties including geometries and dipole moments as well as the proton affinity and inversion barrier of PH₃. Electron correlation is observed to markedly enhance the interaction between PH₃ and the hydrogen halides. Its contribution to the complexation energy is 30% …

Effects Of Basis Set And Electron Correlation On The Calculated Properties Of The Ammonia Dimer, Z. Latajka, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

Ab initio calculations are carried out for (NH₃)₂ with a 6‐31G∗∗(1p,2d) basis set containing diffuse polarization functions. Electron correlation is included via second‐order Møller–Plesset perturbation theory (MP2). At the SCF level, the equilibrium R(NN) distance is 3.54 Å and the interaction energy is −2.35 kcal/mol. Inclusion of correlation enhances the attraction substantially, increasing the energy to −4.05 kcal/mol and reducing the intermolecular separation by 0.20 Å. Comparison with previous results at the SCF level demonstrates a variety of errors including exaggerated dipole moments, underestimation of polarization …

Abstracts Of Specialty Conference Papers; Delineation Of Landslide, Flash Flood And Debris Flow Hazards In Utah, B. Kaliser, M. K. Mccarter, R. Pack, J. Newman

Reports

No abstract provided.

Erosion And Sedimentation In Utah: A Guide For Control, C. Earl Israelsen, Eugene K. Israelsen

Reports

No abstract provided.

New Concepts For Preliminary Hydropower Design: The Powermax Slope, Binary Turbine Sizing, And Static Regain, Frank W. Haws, Eugene K. Israelsen

Reports

In Utah during the 1960s, the cost of producing electrical energy was as much, or in some cases more, by hydroelectric generation than by plants using steam from coal fired boilers. The relatively high hydropower cost was generally attributed to maintenance and replacement costs associated with plants that had been build in the 1920s. Utah Power & Light Company during the 1960 period decided not to renew power licenses and to abandon many small hdyroplants. Since 1973, rising coal and related fossil fuel costs have caused steam generation costs to accelerate and have made hydroelectric generation relatively more attractive. However, …

Hydropower Potential At State Dam Logan River, Frank W. Haws

Reports

No abstract provided.

Review And Evaluation Of The Gibson Dome High Level Nuclear Waste Repository Environmental Assessment: Geohydrologic Issues, Christopher J. Duffy, Brad Hall

Reports

Introduction: Background/Authorization: This report is meant to provide a technical review and evaluation of Department of Energy documents concerning groundwater, radionuclide travel time and monitoring issues relative to siting a high level nuclear waste repository in the Gibson Dome area in Southern Utah. in so doing we have, during a relatively short period of time, examined in detail the Department of Energy Guidelines concerning high level nuclear waste disposal (1983) including revisions (1984), and each draft of the Environmental Assessments for Davis and Lavender Canyon, up to and including the fifth draft (dated July 27, 1984). In addition, a large …

Summary Report: Updating The Estimation Of Water Surface Elevation Probabilities And Associated Damages For Great Salt Lake, L. Douglas James, David S. Bowles, D. George Chadwick, J. Paul Riley

Reports

Problem Statement: Rising levels of the Great Salt Lake are severely impacting private and public property. in the private sector, the mineral industry, the railroad, and a number of recreation enterprises are suffering major damages. In the publi sector, the State of Utah is esperiencing large losses inflicted on roads and highways, waterfowl and related wildlife areas, and park and recreation facilities. The lake is partitioned by a semipervious railroad causeway into a north and a south arm with the sourth arm having about twice the water surface area and usually being two or three feet higher because it receibes …

Mst Radar Data-Base Management, Vincent B. Wickwar

All Physics Faculty Publications

No abstract provided.

A Microsystem Sediment-Water Simulation Study For The Proposed Jordanelle Reservoir, Heber City, Utah, United States Department Of The Interior, Bureau Of Reclamation

Water

The technique of microsystem sediment-water simulation was used to predict water quality data for the proposed Jordanelle Reservoir, Heber City, Utah. Simulation microsystems were prepared for four sites located in the north arm of the reservoir basin including two sites located in an abandoned acid mine tailings pond. Data obtained from the tailings pond microsystems indicated that low pH water and high trace metal concentrations will exist in the north arm of the reservoir. These data suggested that some kind of membrane or compacted earth lining will be necessary to seal and contain the mine spoilage. Other sites in the …

Identifying Environmental Features For Land Management Decisions, Annual Report, United States, National Aeronautics And Space Administration

Land Use

This annual report outlines the major accomplishments of the Center for Remote Sensing and Cartography (CRSC) since the annual report was submitted in October 1982, with reference to the semiannual report of March 1983. The past year has been characterized by important progress in the research of digital processing techniques, completion of projects involving integrated remote sensing and environmental analysis, and interesting developments for new and continuing projects. Our computing strength is stronger than ever; we continue to rely primarily on the University of Utah Research Institute's Prime computer and NASA's Earth Resources Laboratory Applications Software (ELAS). We continue to …

An Evaluation Of Trapping Efforts To Capture Bobcats, Coyotes, And Red Fox, John A. Litvaitis, Mark O'Donoghue, Mathew Miller, James A. Sherburne

Wildlife Damage Management Conference

Wildlife biologists are often involved in efforts to capture free-ranging felids and canids. The objective of these efforts is usually to remove individuals causing unwanted or excessive predation, or to obtain study animals. The most common method used to capture carnivores includes some type of leg-hold trap. Numerous references provide information on the technique of leg-hold trapping (Taylor 1971, Musgrove and Blair 1979); however few reports include an evaluation of these methods.

Practices For Protecting And Enhancing Fish And Wildlife On Coal Mined Land In The Uinta-Southwestern Utah Region, Bettina R. Proctor, Science Applications, Inc., Richard W. Thompson, Jane E. Bunin, Kenneth W. Fucik, George R. Tamm, Edward G. Wolf, U.S Department Of The Interior- Fish And Wildlife Service

All U.S. Government Documents (Utah Regional Depository)

This handbook contains information on the best current practices to minimize disturbances and adverse impacts of surface mining on fish and wildlife resources. Current state and federal legislation was reviewed to determine those practices which were most compatible with the best technology currently available, fish and wildlife plans, and reclamation plans for the Uinta-Southwestern region of the U.S. The information presented includes risks, limitations, approximate costs, and maintenance and management requirements of each practice. Plans for the restoration of specific habitats, according to the best current practices, are also included.

Equatorial Disturbance Dynamo Electric Fields, Bela G. Fejer, M. F. Larsen, D. T. Farley

Bela G. Fejer

F-region vertical drift data from Jicamarca, Peru show that equatorial east-west electric fields are sometimes perturbed 16-24 hours after the onset of geomagnetic storms. These disturbance dynamo electric fields, which must be caused primarily by the action of neutral winds at low and middle latitudes, decrease and sometimes even reverse the quiet time electric field pattern during both daytime and nighttime. The long delay excludes the possibility that gravity waves are responsible and suggests that the thermospheric circulation is disturbed. The data also show that after some storms there are no such delayed disturbances, a fact which may be due …

Cow Brain Glutaminase: Purification And Influence Of Phosphate And Borate Ions On Its Activity And Molecular Weight, Mahnaz Badamchian

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

An efficient and simple purification procedure for cow brain glutaminase (L- glutamine amidohydrolase, EC 3.5.1.2) is described. The main steps consisted of acetone extraction and French press treatment in the presence of phosphate ions, precipitation of nucleic acids and lipids by 0.08 % protamine·S04 and high speed centrifugation (300,000xg), ammonium sulfate fractionation, and gel filtration on Sepharose 4B first as the low molecular weight and then as the aggregated form. The yield was 22% and the final preparation had a specific activity of 142 μmoles/min/mg. The purification was more than 8000-fold over crude brain homogenate. The enzyme showed one strong …

Photochemical Energy Storage (Photosensitized Isomerization Of Norbornadiene To Quadricyclane By Copper(I) Complexes), Dennis J. Fife

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

This research has focused on the sensitized photoisomerization step of a solar energy storage system based on the interconversion of norbornadiene (NBD) and quadricyclane (Q). Sensitizers studied in the photoisomerization were arylphosphine complexes of copper(I) halides [(Ph₃P)₃CuX, (MePh₂P)₃CuX, (DIPHOS)CuCl; X = Cl, Br, I and DIPHOS = Ph₂P(CH₂)₂PPh₂]. The lowest electronic excited state of the complexes can be an effective triplet energy sensitizer as evidenced by a maximum quantum yield of 1.0 with (MePh₂P)₃CuX. The sensitization mechanism of the L …

Nothing Succeeds Like Succession: Ecology And The Human Lot, James A. Macmahon

Faculty Honor Lectures

An Honor Lecture provides a rare opportunity for me as a scientist. First, I have the chance to share, and in a sense to justify, my chosen and cherished discipline, ecology, before an eclectic audience. Second, I have a reason to consider my profession in a broader perspective than I normally do, given the pressures of day-to-day teaching, of grantsmanship, and of acting the role of stern taskmaster to my graduate students. I relish the opportunity to dabble, with an ecological perspective, in history, in philosophy, and in other areas. First, I will discuss my discipline in the context of …

United States Department Of The Interior Geological Survey, Utah, Basic Data For Thermal Springs And Wells As Recorded In Geotherm, James D. Bliss

All U.S. Government Documents (Utah Regional Depository)

No abstract provided.

Hydraulic Model Study Of Hyrum Dam Auxiliary Labyrinth Spillway, Kathleen L. Houston, U.S. Department Of The Interior, Bureau Of Reclamation, Division Of Research, Hydraulics Branch

All U.S. Government Documents (Utah Regional Depository)

The updated IDF (inflow design flood) for Hyrum Reservoir could not be passed with the existing hydraulic structures. The labyrinth was the most economical alternative for an auxiliary spillway. The labyrinth spillway, a series of trapezoidal shapes in plan form, would provide the necessary spillway length and capacity within a comparatively small width. The spillway configuration was based on design curves developed in the Bureau of Reclamation Hydraulic Laboratory.

The 1:30 scale model included the upstream approach channel, the labyrinth spillway, and a transition section leading to a long sloping chute. The model confirmed the maximum discharge of the spillway …

Cell-Mediated Immunity Of The Dog Lung And Effects Of Inhaled 239puo2 Or Pulmonary Tumors, Jennifer Baker Galvin

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Cell-mediated immunity (CMI) in the lung has not been well characterized due to the lack of applicable tests. A major objective was to define pulmonary CMI serially in immunized and control lung lobes using the leukocyte procoagulant (LPCA) assay in young adult dogs. This was compared to a standard, but less reproducible CMI assay, macrophage migration inhibition facet (MIF). The CMI response, as measured by the LPCA assay, peaked in the blood 7 days after lung immunization. The pulmonary CMI response measured with cells obtained by bronchial lavage from the immunized and control lung lobes peaked at 9 to 12 …

Microcomputer Algorithms For Prime Number Testing, Susan Dale Barton

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

This paper gives a survey of different methods of prime number testing. Emphasis has been given to algorithms based upon Fermat's Theorem: if p is an odd prime number, then p divides a^p-a. All of the computer programs described in this paper have been written for use on microcomputers and so the feasibility of using microcomputers is also discussed. Finally, numbers of various forms have been considered for primality with special attention given to Mersenne and Fermat numbers. It is hoped that some of the information contained in this paper may provide worthwhile enrichment ideas for mathematics educators.

Cluster Analysis For Acid Rain Data In Norway, Ali Ghafourian

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

This paper gives a description of three well known clustering methods, and discusses the advantages and disadvantages of each. Then, the results of these three clustering methods are compared through examining them on a specific set of data.

Correction Of Bias In Estimating Autocovariance Function, Len-Hong Wu

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The purpose of this thesis was to evaluate a method for reducing the bias of estimation for autocovariance estimators. Two methods are compared, one is the standard method and the other is an adjustment method. The Monte Carlo method is used within comparison.

The bias and the mean squared error of the estimated autocovariance is computed for several time series models and two variations of the adjustment method of estimation. The results indicate some improvement in bias and mean squared error for the new method.

Studies In Peptide Synthesis Towards The Lanthionine Analog Of Des-N-Tetramethyl Triostin A, Ganesh Devdas Kini

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Studies have been carried out towards the synthesis of bicyclic octadidepsipeptide lanthionine 4, an analog of des-N-tetramethyl triostin A. Starting with a symmetrical lanthionine unit 5 (R₁, R₃ = Me; R₂, R₄ = t-butyloxycarbonyl), synthesized from the corresponding cystine by contraction with hexaethylphosphorus triamide, linear octadidepsipeptides 29 and 32 were synthesized.

Attempted cyclizations of 29 and 32 to the bicyclic octapeptide were unsuccessful.

The failure of the symmetrical approach to 4 prompted the synthesis of an unsymmetrical lanthionine unit with appropriate compatible protecting groups. Attempts to synthesize unsymmetrical lanthionines by nucleophilic displacement on …

Effects Of A Wildfire On Seed Rain And Soil Seed Reserve Dynamics Of A Good Condition Sagebrush-Grass Rangeland In Central Utah, Mohamed Ali Hassan

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The objectives of this research were to investigate the ecological importance of soil seed reserves and seed rain on regeneration of a good condition sagebrush-grass range vegetation after a wildfire and draw conclusions leading to better understanding and management of such ecosystems. Investigations were conducted for two successive years on a community where major plants were neither rhizomatous nor sprouting. In such cases soil seed reserves and seed rain have to be the main source of regeneration. In addition to monitoring soil seed reserves and seed rain, vegetation changes during the past two years and the historical conditions of the …

Accidental Releases Of Sour Gas From Wells And Collection Pipelines In The Overthrust Belt: Calculating And Assessing Potential Health And Environmental Risks, D. W. Layton, R. T. Cederwall, Y. E. Ricker, J. H. Shinn, K. D. O'Banion

All U.S. Government Documents (Utah Regional Depository)

Parts of the Overthrust Belt of western Wyoming and adjoining areas in Utah and Idaho contain geologic formations with significant accumulations of oil and natural gas. Some of these formations, though, yield gas that is contaminated with toxic hydrogen sulfide. As a consequence, the development of these so-called sour-gas reservoirs requires special safety procedures and technologies in order to prevent accidental releases of gas to the atmosphere that could cause adverse occupational and public health effects. To improve the analysis and assessment of wells and collection pipelines completed on lands leased from the Federal Government, the Minerals Management Service, Onshore …

Characterization Of Water From Laverkin Springs, Utah, United States Department Of The Interior, Bureau Of Reclamation

Water

Analytical water data obtained from two separate test programs at the LaVerkin Springs site, Washington County, southwestern Utah, were evaluated. During the first analyses, from February 11 through November 6, 1972, water samples were obtained weekly from 14 atmospheric springs. During the second analyses from November 1, 1979 through August 27, 1980, water samples were obtained weekly at aquifer pressure by pumping from a well representative of the 14 springs. Acquired data included characteristics of the water in 1972, and again in 1979-1980, uniformity of the water in the springs tested, variations of these characteristics within the time of year, …

Studies Of Self-Focusing Instability At Arecibo, D. T. Farley, C. Lahoz, Bela G. Fejer

Bela G. Fejer

Precisely simultaneous radar and satellite measurements at the altitude of reflection of a strong HF heating wave above the Arecibo Observatory were made on June 7, 1977. Parametric instabilities produce strong enhancements in the plasma line and ion line incoherent scatter radar echoes. These echoes also exhibit periodic deep fading that is attributed to a self-focusing instability. This explanation was confirmed by the in situ observation of electron density fluctuations with peak-to-peak amplitudes reaching at least 3% and a spatial dependence that corresponded closely to the radar fading pattern, at least for irregularity wavelengths ranging from a few hundred meters …

Interagency Hazard Mitigation: 90-Day Post Flood Recovery Progress Report, Hazard Mitigation Team (Utah)

Elusive Documents

As a result of an extended period of abnormally high precipitation, prolonged snow melt, and subsequent high water tales, Utahns, in 1983 suffered from landslides, debris flows, flooding, and a dam failure. On April 30, 1983, the President determined the Spanish Fork slide-dam and Thistle flood covering Utah, Carbon, and Emery Counties was of sufficient seventy and magnitude to issue a Major Disaster Declaration under Public Law 93-288. The incident period was not closed until July 1, 1983. By the time all flooding had ceased, nineteen additional counties (over 75% of Utah) had been included in the Declaration.

Growth And Activity Of Juvenile Mosquitofish: Temperature And Ration Effects, Wayne A. Wurtsbaugh, J. Cech

Watershed Sciences Faculty Publications

The effects of constant temperatures (10, 15, 20, 25, 30, and 35 C) and ration size on the growth rates and activity of juvenile mosquitofish Gambusia affinis (mean wet weight, about 20 mg) were measured in laboratory experiments. On ad libitum rations of Tubifex spp. worms, food-consumption rates of mosquitofish were very high, ranging from 7% dry body weight/day at 10 C to 83%/day at 35 C. Growth increased from 0% dry body weight/day at 10 C to 21%/day at 30 C and declined slightly at 35 C. Gross efficiencies (100 growth/food consumption) increased from 0 at 10 C to …