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Articles 1201 - 1230 of 3840

Full-Text Articles in Physical Sciences and Mathematics

Semantics Of Perception: Towards A Semantic Web Approach To Machine Perception, Cory Andrew Henson, Amit P. Sheth Jan 2012

Semantics Of Perception: Towards A Semantic Web Approach To Machine Perception, Cory Andrew Henson, Amit P. Sheth

Kno.e.sis Publications

The acts of observation and perception provide the building blocks for all human knowledge (Locke, 1690); they are the processes from which all ideas are born; and the sole bond connecting ourselves to the world around us. Now, with the advent of sensor networks capable of observation, this world may be directly accessible to machines. Missing from this vision, however, is the ability of machines to glean semantics from observation; to apprehend entities from detected qualities; to perceive. The systematic automation of this ability is the focus of machine perception -- the ability of computing machines to sense and interpret …


Extracting Diverse Sentiment Expressions With Target-Dependent Polarity From Twitter, Lu Chen, Wenbo Wang, Meenakshi Nagarajan, Shaojun Wang, Amit P. Sheth Jan 2012

Extracting Diverse Sentiment Expressions With Target-Dependent Polarity From Twitter, Lu Chen, Wenbo Wang, Meenakshi Nagarajan, Shaojun Wang, Amit P. Sheth

Kno.e.sis Publications

This study focuses on automatic extraction of sentiment expressions associated with given targets from Twitter. It addresses one of the key challenges in this work: Wide diversity and informal nature of sentiment expressions that cannot be trivially enumerated or captured using predefined lexical patterns.


On The Role Of Social Identity And Cohesion In Characterizing Online Social Communities, Hemant Purohit, Yiye Ruan, David Fuhry, Srinivasan Parthasarathy, Amit P. Sheth Jan 2012

On The Role Of Social Identity And Cohesion In Characterizing Online Social Communities, Hemant Purohit, Yiye Ruan, David Fuhry, Srinivasan Parthasarathy, Amit P. Sheth

Kno.e.sis Publications

Two prevailing theories for explaining social group or community structure are cohesion and identity. The social cohesion approach posits that social groups arise out of an aggregation of individuals that have mutual interpersonal attraction as they share common characteristics. These characteristics can range from common interests to kinship ties and from social values to ethnic backgrounds. In contrast, the social identity approach posits that an individual is likely to join a group based on an intrinsic self-evaluation at a cognitive or perceptual level. In other words group members typically share an awareness of a common category membership. In this work …


Towards Cloud Mobile Hybrid Application Generation Using Semantically Enriched Domain Specific Languages, Ajith Harshana Ranabahu, Amit P. Sheth, Ashwin Manjunatha, Krishnaprasad Thirunarayan Jan 2012

Towards Cloud Mobile Hybrid Application Generation Using Semantically Enriched Domain Specific Languages, Ajith Harshana Ranabahu, Amit P. Sheth, Ashwin Manjunatha, Krishnaprasad Thirunarayan

Kno.e.sis Publications

The advancements in computing have resulted in a boom of cheap, ubiquitous, connected mobile devices as well as seemingly unlimited, utility style, pay as you go computing resources, commonly referred to as Cloud computing. Taking advantage of this computing landscape, however, has been hampered by the many heterogeneities that exist in the mobile space as well as the Cloud space.

This research attempts to introduce a disciplined methodology to develop Cloud-mobile hybrid applications by using a Domain Specific Language (DSL) centric approach to generate applications. A Cloud-mobile hybrid is an application that is split between a Cloud based back-end and …


Alignment-Based Querying Of Linked Open Data, Amit Krishna Joshi, Prateek Jain, Pascal Hitzler, Peter Z. Yeh, Kunal Verma, Amit P. Sheth, Mariana Damova Jan 2012

Alignment-Based Querying Of Linked Open Data, Amit Krishna Joshi, Prateek Jain, Pascal Hitzler, Peter Z. Yeh, Kunal Verma, Amit P. Sheth, Mariana Damova

Kno.e.sis Publications

The Linked Open Data (LOD) cloud is rapidly becoming the largest interconnected source of structured data on diverse domains. The potential of the LOD cloud is enormous, ranging from solving challenging AI issues such as open domain question answering to automated knowledge discovery. However, due to an inherent distributed nature of LOD and a growing number of ontologies and vocabularies used in LOD datasets, querying over multiple datasets and retrieving LOD data remains a challenging task. In this paper, we propose a novel approach to querying linked data by using alignments for processing queries whose constituent data come from heterogeneous …


Semantics And Ontologies For Earthcube, Gary Berg-Cross, Isabel F. Cruz, Michael Dean, Timothy Finin, Mark Gahegan, Pascal Hitzler, Hook Hau, Krzysztof Janowicz, Naicong Li, Philip Murphy, Bryce Nordgren, Leo Obrst, Mark Schildhauer, Amit P. Sheth, Krishna Sinha, Anne Thessen, Nancy Wiegand, Ilya Zaslavasky Jan 2012

Semantics And Ontologies For Earthcube, Gary Berg-Cross, Isabel F. Cruz, Michael Dean, Timothy Finin, Mark Gahegan, Pascal Hitzler, Hook Hau, Krzysztof Janowicz, Naicong Li, Philip Murphy, Bryce Nordgren, Leo Obrst, Mark Schildhauer, Amit P. Sheth, Krishna Sinha, Anne Thessen, Nancy Wiegand, Ilya Zaslavasky

Kno.e.sis Publications

Semantic technologies and ontologies play an increasing role in scientific workflow systems and knowledge infrastructures. While ontologies are mostly used for the semantic annotation of metadata, semantic technologies enable searching metadata catalogs beyond simple keywords, with some early evidence of semantics used for data translation. However, the next generation of distributed and interdisciplinary knowledge infrastructures will require capabilities beyond simple subsumption reasoning over subclass relations. In this work, we report from the EarthCube Semantics Community by highlighting which role semantics and ontologies should play in the EarthCube knowledge infrastructure. We target the interested domain scientist and, thus, introduce the value …


The Ontology For Parasite Lifecycle (Opl): Towards A Consistent Vocabulary Of Lifecycle Stages In Parasitic Organisms, Priti Parikh, Jie Zheng, Flora J. Logan-Klumpler, Christian J. Stoeckert, Pantelis Topalis, Anna Protasio, Amit P. Sheth, Mark Carrington, Matthew Berriman, Satya S. Sahoo Jan 2012

The Ontology For Parasite Lifecycle (Opl): Towards A Consistent Vocabulary Of Lifecycle Stages In Parasitic Organisms, Priti Parikh, Jie Zheng, Flora J. Logan-Klumpler, Christian J. Stoeckert, Pantelis Topalis, Anna Protasio, Amit P. Sheth, Mark Carrington, Matthew Berriman, Satya S. Sahoo

Kno.e.sis Publications

Background

Genome sequencing of many eukaryotic pathogens and the volume of data available on public resources have created a clear requirement for a consistent vocabulary to describe the range of developmental forms of parasites. Consistent labeling of experimental data and external data, in databases and the literature, is essential for integration, cross database comparison, and knowledge discovery. The primary objective of this work was to develop a dynamic and controlled vocabulary that can be used for various parasites. The paper describes the Ontology for Parasite Lifecycle (OPL) and discusses its application in parasite research.

Results

The OPL is based on …


Photorefractive Thin Films And Polymers For Use In Organic-Inorganic Hybrid Cells, Steven Harris Buller Jan 2012

Photorefractive Thin Films And Polymers For Use In Organic-Inorganic Hybrid Cells, Steven Harris Buller

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Two classes of materials were investigated as possible replacements for the bulk photorefractive windows in inorganic-organic hybrid cells: thin films and polymers. Each material was fabricated and subsequently characterized using two different methods due to their different stages of development. The thin films were characterized by X-ray diffraction while the polymers were characterized by two-beam coupling. Thin films of strontium barium niobate and potassium niobate were grown, using pulsed laser deposition, on four different substrates. It was found that it was possible to grow a thin film of potassium niobate in the correct orientation to replace a bulk photorefractive window. …


Behavioral Signature-Based Framework For Identifying Unsatisfiable Variable Mappings Between Digital Designs, Vaibhav Uday Tendulkar Jan 2012

Behavioral Signature-Based Framework For Identifying Unsatisfiable Variable Mappings Between Digital Designs, Vaibhav Uday Tendulkar

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Throughout its design process (from specification to implementation) a digital circuit goes through a variety of structural changes. These changes are introduced primarily due to the use of automated tools in the design process. Checking whether the Boolean functions representing the two designs are equivalent is thus necessary to verify if a design implementation adheres to its specification. Combinational Equivalence Checking (CEC) - a process of determining whether two combinational design functions are equiv-alent, has been one of the most researched Boolean matching problems. The well-known CEC techniques that have been proposed adopt some kind of a formal approach such …


Facile Synthesis Of Functionalized Poly (Arylene Ether Sulfone)S, Mehmet Tatli Jan 2012

Facile Synthesis Of Functionalized Poly (Arylene Ether Sulfone)S, Mehmet Tatli

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The synthesis of poly(arylene ether sulfone)s, with a pendant aryl iodide, was achieved via nucleophilic aromatic substitution (NAS) polycondensation of 3-iodo-3',5'-difluoro-diphenylsulfone (2) with Bisphenol-A. Monomer 2 was prepared by the reaction of 3, 5-difluorodiphenylsulfone with N-iodosuccinimide (NIS). Model reactions indicated that the iodo group was stable to NAS conditions. Both GC/MS analysis and NMR spectroscopy indicated quantitative displacement of the two fluorine atoms while the iodo group remained untouched. Furthermore, the modification of the iodo polymer was achieved via Suzuki-Miyaura cross-coupling reaction with phenyl, naphthyl, and phenylacetyl boronic acids. The thermal properties of the polymers were evaluated via DSC and …


Direct Optimization Of Ranking Measures For Learning To Rank Models, Li Li Guo Jan 2012

Direct Optimization Of Ranking Measures For Learning To Rank Models, Li Li Guo

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The main challenge in learning-to-rank for information retrieval is the difficulty to di- rectly optimize ranking measures to automatically construct a ranking model from training data. It is mainly due to the fact that the ranking measures are determined by the order of ranked documents rather than the specific values of ranking model scores, thus they are non-convex, nondifferentiable and discontinuous. To address this issue, listwise approaches have been proposed where loss functions are defined either by exploiting a probabilistic model or by optimizing upper bounds or smoothed approximations of ranking measures. Even though very promising results have been achieved, …


Evaluating The Effect Of Hyporheic Exchange On Intake Temperatures Of Open-Loop Geothermal Wells In Glacigenic Outwash Aquifers, Nathan Grigsby Jan 2012

Evaluating The Effect Of Hyporheic Exchange On Intake Temperatures Of Open-Loop Geothermal Wells In Glacigenic Outwash Aquifers, Nathan Grigsby

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Subsurface heat flow was simulated to study the effect of hyporheic exchange on groundwater intake temperatures of open-loop geothermal wells in glacigenic-outwash aquifers in the North American midcontinent. The model represents an aquifer kilometers wide, on the order of 100m thick, and directly connected to a perennial river. The aquifer has bimodal hydraulic conductivity with a geometric mean on the order of 100m/day, an effective thermal conductivity of 2.33W/mK, and specific heats on the order of 106J/(m^3 K) for water and 103J/kgK for solids. The aquifer is initially set to a temperature of 12.85 °C and the river is fixed …


Poly(Arylene) Ethers Prepared From Functionalized 3,5-Difluorotriphenylphosphine Oxide, Courtney M. Sutherland Jan 2012

Poly(Arylene) Ethers Prepared From Functionalized 3,5-Difluorotriphenylphosphine Oxide, Courtney M. Sutherland

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The di-iodinated derivative of 3,5-difluorotriphenyl phosphine oxide, 3,5-DiFTPO-I2, was synthesized for the modification of poly(arylene ether phosphine oxide)s, PAEPOs. The di-iodinated monomer was polymerized to afford the di-iodinated polymer, a pre-cursor for tailoring solubility and the thermal properties of the PAEPO derivatives via functionalization. The di-iodinated polymer was post-functionalized via the Suzuki Miyaura cross coupling reaction with a variety of boronic acids. The successful conversion of the iodo groups, along with the immense number of possible functional groups that can be introduced to the di-iodinated polymer makes PAEPO-derivative a highly useful thermoplastic with a wide range of potential uses.

The …


Why Is There Such A High Concentration Of Vertebrate Remains Within A Bone-Bed Along Clapp Creek, Williamsburg County, South Carolina?, Jennifer R. Soehner Jan 2012

Why Is There Such A High Concentration Of Vertebrate Remains Within A Bone-Bed Along Clapp Creek, Williamsburg County, South Carolina?, Jennifer R. Soehner

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A phosphatic bone-bed occurs along Clapp Creek in Kingstree, South Carolina, within the east-central portion of the coastal plain. The location of the research site is within the Chicora Member of the Williamsburg Formation. The paleoenvironment of this site was most likely a complex estuary with microenvironments that included tidal channels, tidal deltas, tidal flats, marshes and subtidal bays. The high diversity and large time span in the bone-bed is explained by the transgressive environment and storm deposits. The phosphate content of the bone-bed is from the calcium phosphate occurring in the coprolites of carnivores and the higher concentration of …


Computational Investigations Of The Adsorption Of Molecular Hydrogen On Graphene-Based Nanopore Model, Jared Duncan Jan 2012

Computational Investigations Of The Adsorption Of Molecular Hydrogen On Graphene-Based Nanopore Model, Jared Duncan

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Computational modeling using classical grand canonical Monte Carlo simulations and first-principles calculations were carried out to study the adsorption of molecular hydrogen on nanoporous carbon modeled by the slit- pore geometry. It has previously been shown that hydrogen adsorption on pristine porous carbon has dependence on pore size and that an optimum pore size, which exhibits the maximum mass uptake, exists. There have been suggestions that doping graphitic nanocarbon structures with Pd enhances their adsorption capacity. The pore-size dependence of this change in adsorption brought about by Pd and the conditions at which improvement in adsorption can occur have not …


Enhancing Description Logics For Rules Coverage, David Carral Martinez Jan 2012

Enhancing Description Logics For Rules Coverage, David Carral Martinez

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This thesis is a formal study on how to extend the set of logic constructors of description logics languages, used for knowledge representation in the Semantic Web field to capture some of the previously exclusive rules expressivity. Description Logics, the logics underpinning the Web Ontology Language OWL, and rules are currently the most prominent paradigms used for modeling knowledge for the Semantic Web. While both of these approaches are based on classical logic, the paradigms also differ significantly, so that naive combinations result in undesirable properties such as undecidability. Recent work has shown that many rules can in fact be …


Reservoir Characterization And Seismic Expression Of The Clinton Interval Over Dominion's Gabor Gas Storage Field In North-East Ohio, Scott Michael Bey Jan 2012

Reservoir Characterization And Seismic Expression Of The Clinton Interval Over Dominion's Gabor Gas Storage Field In North-East Ohio, Scott Michael Bey

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In northeastern Ohio, an interval of interbedded sandstone and shale between the Queenston Shale and the Dayton Formation (both in the Silurian System) has long been referred to as the "Clinton interval". The Clinton interval has produced oil and gas for over a century, but has been converted locally to gas storage. Within the Clinton interval, reservoirs are commonly compartmentalized, in part because the sandstones are discontinuous but also because fractures enhance permeability in portions of otherwise continuous sandstones. The goal of this study is to characterize the Clinton interval within the Gabor gas storage field of Dominion East Ohio …


Characterization Of Structured Nanomaterials Using Terahertz Frequency Radiation, Andrew John Niklas Jan 2012

Characterization Of Structured Nanomaterials Using Terahertz Frequency Radiation, Andrew John Niklas

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Measurements that use terahertz frequency radiation to characterize materials are beneficial for scientists trying to determine the physical parameters that govern the interaction of electromagnetic waves and matter at those frequencies. Results will be presented of time domain terahertz spectroscopy measurements taken in forward and backward scattering directions from vertically aligned arrays of multi-walled carbon nanotubes and thin films of perforated copper. The intent of this research is to both corroborate results from independent research groups conducting similar experiments and to further increase understanding in the scientific community with respect to carbon nanotube reflection phenomena at terahertz frequencies.


Micro-Raman Imaging And Hyperspectral Analysis Of Tibiotarsi From Chick Embryos Exposed To Sublethal Doses Of Platinum Group Metals, Adam Christopher Stahler Jan 2012

Micro-Raman Imaging And Hyperspectral Analysis Of Tibiotarsi From Chick Embryos Exposed To Sublethal Doses Of Platinum Group Metals, Adam Christopher Stahler

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Platinum group metals (PGMs), i.e., Pd, Pt and Rh, are found at pollutant levels in the environment. PGMs accumulate in plant and animal tissues, and little is known about their toxicity. Our previous studies have shown that chick embryos exposed to 1.0 mL PGM solutions of 5.0 ppm (LD50) and higher exhibited severe skeletal deformities. This work hypothesized that 1.0 ppm sublethal doses of PGMs would negatively impact the mineralization process in tibiotarsi. One milliliter of 1.0 ppm of Pd(II), Pt(IV), Rh(III) aqueous salt solutions and a PGM-mixture were injected into the air sac of the eggs …


Central Arctic Lithostratigraphy: Implication For Sediment Transport And Paleoceanography, Edward Augustus Council Iii Jan 2012

Central Arctic Lithostratigraphy: Implication For Sediment Transport And Paleoceanography, Edward Augustus Council Iii

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Multiple cores from the Arctic were analyzed by XRF methods to determine the western Arctic lithostratigraphy as expressed in its geochemistry. In general, glacial and interglacial events have distinctly different chemistry. During glacial events, the sediments have elevated Ti, Fe, Rb, and Zr concentrations and depressed Sr and Mn concentrations. The opposite is true of the brown layers, where Ti, Fe, Rb and Zr are lower with higher levels of Mn and Sr. These data indicate that there are 18 chemically unique lithologic units (LUs) that exist among MIS-1 to MIS-16 age sediments. Isopach maps indicate two general depositional patterns …


Human Action Recognition By Principal Component Analysis Of Motion Curves, Daniel Stephen Chivers Jan 2012

Human Action Recognition By Principal Component Analysis Of Motion Curves, Daniel Stephen Chivers

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Human action recognition is used to automatically detect and recognize actions per- formed by humans in a video. Applications include visual surveillance, human-computer interaction, and robot intelligence, to name a few. An example of a surveillance application is a system that monitors a large public area, such as an airport, for suspicious activity. In human-machine interaction, computers may be controlled by simple human actions. For example, the motion of an arm may instruct the computer to rotate a 3-D model that is being displayed. Human action recognition is also an important capability of intelligent robots that interact with humans.

General …


Change In Shoreline Position For Two Consecutive Years Using Lidar Along The Outer Banks, North Carolina, Rachel Marie Taylor Jan 2012

Change In Shoreline Position For Two Consecutive Years Using Lidar Along The Outer Banks, North Carolina, Rachel Marie Taylor

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The signal of shoreline change for the Outer Banks, North Carolina is non-stationary. A baseline, west of the first line of dunes, is created for each 5 km section and shore-perpendicular profiles constructed every 20 meters in the alongshore direction. The profiles are obtained from two light detection and ranging (LIDAR) surveys performed in June 22, 2006 and July 7 and 8, 2007.

For five selected sections of coast, Fourier analysis of the shoreline change signal indicates the signal is self-affine i.e. the mean is not stationary, but changes with position along the signal (Malumud and Turcotte, 1999) with a …


Cathodic Deposition Of Triangular Tungsten Clusters From Ionic Liquids: An Explorative Study, Linda N. Ubadigbo Jan 2012

Cathodic Deposition Of Triangular Tungsten Clusters From Ionic Liquids: An Explorative Study, Linda N. Ubadigbo

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In the present work, the triangular tungsten clusters {[W3O2(O2CCH3)6](H2O)3}(CF3SO3)2 and {[W3O2(O2CCH2CH3)6](H2O)3}(BF4)2. 5.5H2O were dissolved in both hydrophobic and hydrophilic ionic liquids (ILs) and subjected to a cathodic potential of roughly 2V. It was proposed that successful deposition of these metal clusters on a platinum electrode would yield Pt-supported anodic catalysts which could be used in ethanol fuel cells (EFCs). Visual examination of the electrode surfaces indicated that a film had been deposited, however, the surface with W3(CF3SO3)2 quickly oxidized when removed from the IL. Therefore, SEM imaging and EDX analysis of the W3(BF4)2 surface were performed. The data indicated that …


Degradation Of Chlorinated Hydrocarbons In Groundwater Passing Through The Treatment Wetland At Wright-Patterson Air Force Base: Analysis Of Results Collected During 2001-'06, Annamarie F. Therrien Jan 2012

Degradation Of Chlorinated Hydrocarbons In Groundwater Passing Through The Treatment Wetland At Wright-Patterson Air Force Base: Analysis Of Results Collected During 2001-'06, Annamarie F. Therrien

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Constructed wetlands are an efficient and cost effective means for chlorinated aliphatic hydrocarbon remediation, and will therefore continue to gain momentum as an accepted treatment by the US EPA (U.S. EPA, 1995; Amarante, 2000; Lien, 2001; WETPOL, 2009). The treatment options for chlorinated aliphatic hydrocarbons (CAHs), including wetlands, capitalize on aerobic/anaerobic interfaces in which bacterially mediated reduction-oxidation reactions degrade pollutants (Li, 1997; Bradley, 1998; Lorah and Voytek, 2004; Amon, 2007; Imfeld, 2008). In August 2000, researchers at Wright State University (WSU) combined efforts with the United States Air Force Institute of Technology (AFIT) to construct a pilot-scale upward-flow treatment wetland …


Entropy Optimal Orthogonal Matrices, Akhilesh Pathak Jan 2012

Entropy Optimal Orthogonal Matrices, Akhilesh Pathak

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The entropy of an orthogonal matrix is defined by the Gadiyar, Maini, Padma and Sharatchandra who have re-defined Hadamard matrices as the orthogonal matrices that saturate the bound for entropy. They also presented numerical results for maximal entropy for dimension n = 3; 5. We prove the results analytically for n 0(mod 4); n = 3 and construct local extremums for n = 5; 6; 10; 2p; 3p, where p is prime. We also provide cojectures on necessary conditions for optimality and optimal matrices based on the prime factorization of the order.


Abstraction Driven Application And Data Portability In Cloud Computing, Ajith Harshana Ranabahu Jan 2012

Abstraction Driven Application And Data Portability In Cloud Computing, Ajith Harshana Ranabahu

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Cloud computing has changed the way organizations create, manage, and evolve their applications. While many organizations are eager to use the cloud, tempted by substantial cost savings and convenience, the implications of using clouds are still not well understood. One of the major concerns in cloud adoption is the vendor lock-in of applications, caused by the heterogeneity of the numerous cloud service offerings. Vendor locked applications are difficult, if not impossible to port from one cloud system to another, forcing cloud service consumers to use undesired or suboptimal solutions. This dissertation investigates a complete and comprehensive solution to address the …


Assessing The Drivers Of Adaptive Radiation In A Complex Of Gall Midges: A Multitrophic Perspective On Ecological Speciation, Jeremy J. Heath Jan 2012

Assessing The Drivers Of Adaptive Radiation In A Complex Of Gall Midges: A Multitrophic Perspective On Ecological Speciation, Jeremy J. Heath

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Natural enemies as selective forces maintaining and shaping morphological, physiological, and behavioral divergence in adaptive radiations have received very little attention. Until recently, the focus has been on primary resource competition as a major driver of trait divergence in adaptive radiations. Here I consider the role of natural enemies specifically in driving trait divergence in a complex of gall midges in the nominal species Asteromyia carbonifera (Diptera: Cecidomyiidae), which appears to be in the throes of an incipient adaptive radiation on its host plant, goldenrod (Solidago). This galler uses a symbiotic fungus (Botryosphaeria dothidae) as a …


Student Fact Book, Fall 2012, Thirty-Sixth Annual Edition, Wright State University, Office Of Student Information Systems, Wright State University Jan 2012

Student Fact Book, Fall 2012, Thirty-Sixth Annual Edition, Wright State University, Office Of Student Information Systems, Wright State University

Wright State University Student Fact Books

The student fact book has general demographic information on all students enrolled at Wright State University for Fall Quarter, 2012.


The Synthesis Of Room-Temperature Ionic Liquids And Their Metathesis Reactions With Dilithium Phthalocyanine, Andrew Michael Beauchamp Jan 2012

The Synthesis Of Room-Temperature Ionic Liquids And Their Metathesis Reactions With Dilithium Phthalocyanine, Andrew Michael Beauchamp

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A series of alkoxyalkylammonium salts has been synthesized for use in metathesis reactions with dilithium phthalocyanine. The salts, which were ionic liquids at or near room temperature, were synthesized by a nucleophilic substitution of tris[2-(2-methoxyethoxy)ethyl]amine and iodomethane, iodoethane, bromoethane, 1-bromo-propane, 1-bromo-2-(2-methoxyethoxy)ethane, and [2-[2-(2-methoxyethoxy)ethoxy]-ethoxy] p-toluenesulfonate in yields ranging from 67% - 88%. The methyl, ethyl, propyl and tetra[2-(2-methoxyethoxy)ethyl]ammonium salts were obtained for use in metathesis reactions. The salts were liquid at room temperature, with the exception of tetra[2-(2-methoxyethoxy)ethyl]ammonium bromide which was found to melt at 46° and were thermally stable to approximately 200°. The four salts were used in metathesis reactions …


Cometabolic Degradation Of Halogenated Aliphatic Hydrocarbons By Aerobic Microorganisms Naturally Associated With Wetland Plant Roots, Madelyn M. Smith Jan 2012

Cometabolic Degradation Of Halogenated Aliphatic Hydrocarbons By Aerobic Microorganisms Naturally Associated With Wetland Plant Roots, Madelyn M. Smith

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Wetland systems provide both anaerobic (reducing) and aerobic (oxidizing) zones for the biodegradation of chlorinated aliphatic hydrocarbons (CAH). In particular, wetland plant roots provide micro-oxidizing environments for methanotrophic bacteria from the presence of methane, which is produced in anaerobic zones, and oxygen, which is brought to the subsurface by roots of wetland plants; this shows the potential for cometabolic degradation of common organic pollutants.

This study explored the natural attenuation of CAHs by methanotrophic bacteria naturally associated with roots of the common wetland plant, Carex comosa. Root microcosms were amended with varying concentrations of methane; trichloroethene; cis 1,2-dichloroethene; 1,2-dichloroethane; or …