Physical Sciences and Mathematics Commons^™

Comparison Of The Electrochemical Properties Of Ethanol In Perchloric Acid And Ionic Liquids, Sandra Felix-Balderrama

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1-Ethyl-3-Methylimidazolium Tetrafluroborate (EMImBF₄) and 1-Ethyl-3-Methylimidazlium Bis(trifluoromethanesulfonyl)imide (EMImTFSI) ionic liquids were synthesized and characterized in order to study the electrochemical oxidation of ethanol in these ionic liquids on a platinum surface electrode.

It was found that pure EMImBF₄ exhibits an electrochemical window of 4.4 V,while EMImTFSI exhibits an electrochemical window of 5.0 V.

Electrochemical study of ethanol in perchloric acid showed that the oxidation of ethanol strongly depends on the concentration of ethanol and on the temperature of the solution. The poisoning of the platinum electrode only depends on the concentration of ethanol. At a low concentration of …

Cationic Exchange Reactions Involving Dilithium Phthalocyanine, Morgan M. Hart

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Dilithium phthalocyanine (Li₂Pc) consists of an aromatic macrocycle possessing a doubly negative charge and two Li⁺ counterions. One Li⁺ ion is easily displaceable while the other remains coordinated to the phthalocyanine ring. The displaceable Li⁺ cation can be exchanged with other cations, such as a singly charged tetra-alkyl ammonium cation, by using several variations of a general procedure. It has been demonstrated that tetraalkylammonium lithium phthalocyanines (TAA-LiPcs) can be successfully and reproducibly synthesized with yields ranging from 54.5% up to 64.3%. All TAA-LiPcs demonstrated poor solubilities from approximately <0.2 mg/mL to 5 mg/ml in the solvents tested (with the exception of tetrapropylammonium lithium phthalocyanine and tetrahexylammonium lithium phthalocyanine). All of the TAA-LiPcs synthesized were dark-purple in color, with the exception of tetraheptylammonium lithium phthalocyanine and tetraoctylammonium lithium phthalocyanine. These two compounds were dark - blue in color. Melting points varied greatly from >370.4°C to 157.9°C and depended greatly upon …

"One-Pot" Oligomeric A2 + B3 Approach To Branched Poly(Arylene Ether Sulfone)S: Reactivity Ratio Controlled Polycondensation, Andrea M. Elsen

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The synthesis of fully soluble branched poly(arylene ether)s via an oligomeric A2 + B3 system, in which the A2 oligomers are generated in situ, is presented. This approach takes advantage of the significantly higher reactivity toward nucleophilic aromatic substitution reactions, NAS, of B2, 4-Fluorophenyl sulfone, relative to B3, tris(4-Fluorophenyl) phosphine oxide. The A2 oligomers were synthesized by reaction of Bisphenol-A and B2, in the presence of the B3 unit, at temperatures between 100 and 160 °C, followed by an increase in the reaction temperature to 180 °C at which point the branching unit was incorporated. The presence of branching was …

Semantics Enriched Service Environments, Karthik Rajagopal Gomadam

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During the past seven years services centric computing has emerged as the preferred approach to architect complex software. Software is increasingly developed by integrating remotely existing components, popularly called services. This architectural paradigm, also called Service Oriented Architecture (SOA), brings with it the benefits of interoperability, agility and flexibility to software design and development. One can easily add or change new features to existing systems, either by the addition of new services or by replacing existing ones. Two popular approaches have emerged for realizing SOA. The first approach is based on the SOAP protocol for communication and the Web Service …

Burst Scheduling, Grooming And Qos Provisioning In Optical Burst-Switched Networks, Yuqi Fan

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The demand of network capacity has been increasing steadily with more users than ever connected to the Internet through broadband access and the popularity of video based applications, such as YouTube. Optical wavelength division multiplexing (WDM) networks are expected to form the next-generation backbone network and to fulfill the insatiable appetite for bandwidth.

Wavelength routed WDM optical networks offer the granularity of switching at a fiber, waveband, or a wavelength level. The finest granularity offered is at a wavelength level by provisioning lightpaths for different clients/services. All-optical packet switching is still deemed technically infeasible and its competitiveness as a backbone …

Lithiation Reactions Of 3-(4-Chlorophenyl)Sydnone And 3-(4-Methylphenyl)Sydnone, Nigel Ngonidzashe Chitiyo

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Ortho-iodophenyl sydnones are key intermediates in Sonogashira coupling reactions and the resulting ortho alkynyl sydnones are useful precursors to functionalized sydnonquinolines. In this work, three synthetic routes leading to the synthesis of these versatile intermediates were explored.

Lithiation reactions of 3-(4-chlorophenyl) sydnone and 3-(4-methylphenyl) sydnone followed by trapping with iodine electrophiles yielded the expected disubstituted species 3-(4-chloro-2-iodophenyl)-4-iodosydnone and 3-(4-methyl-2-iodophenyl)-4-iodosydnone in yields ranging from 14% to 75%. Subsequent reduction with sodium sulfite removed the iodine at the C-4 position in both species yielding the ortho iodophenyl sydnones in 80% and 85% yield, respectively.

A surprising result was the discovery that careful …

A Cryptanalysis Methodology For The Reverse Engineering Of Encrypted Information In Images, Allan Anthony Rwabutaza

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Security is an important issue related to the storage and communication of data and information. In data and information security, cryptography and steganography are two of the most common security techniques. On one hand, there is cryptography, which is the secret communication between two parties by message scrambling on the sender's side and message unscrambling on the receiver's side so that only the intended receiver gets the secret message. On the other hand, there is steganography, which is the hiding of information in a medium in such a way that no one other than the sender or the intended receiver …

The 4 X 4 Semantic Model: Exploiting Data, Functional, Non-Functional And Execution Semantics Across Business Process, Workflow, Partner Services And Middleware Services Tiers, Amit P. Sheth, Karthik Gomadam

Kno.e.sis Publications

Business processes in the global environment increasingly encompass multiple partners and complex, rapidly changing requirements. In this context it is critical that strategic business objectives align with and map accurately to systems that support flexible and dynamic business processes. To support the demanding requirements of global business processes, we propose a comprehensive, unifying 4 X 4 Semantic Model that uses Semantic Templates to link four tiers of implementation with four types of semantics. The four tiers are the Business Process Tier, the Workflow Enactment Tier, the Partner Services Tier, and the Middleware Services Tier. The four types of semantics are …

Semantic Sensor Web, Amit P. Sheth, Cory Henson, Krishnaprasad Thirunarayan

Kno.e.sis Publications

No abstract provided.

Capturing Workflow Event Data For Monitoring, Performance Analysis, And Management Of Scientific Workflows, Matthew Valerio, Satya S. Sahoo, Roger Barga, Jared Jackson

Kno.e.sis Publications

To effectively support real-time monitoring and performance analysis of scientific workflow execution, varying levels of event data must be captured and made available to interested parties. This paper discusses the creation of an ontology-aware workflow monitoring system for use in the Trident system which utilizes a distributed publish/subscribe event model. The implementation of the publish/subscribe system is discussed and performance results are presented.

Growing Fields Of Interest: Using An Expand And Reduce Strategy For Domain Model Extraction, Christopher Thomas, Pankaj Mehra, Roger Brooks, Amit P. Sheth

Kno.e.sis Publications

Domain hierarchies are widely used as models underlying information retrieval tasks. Formal ontologies and taxonomies enrich such hierarchies further with properties and relationships associated with concepts and categories but require manual effort; therefore they are costly to maintain, and often stale. Folksonomies and vocabularies lack rich category structure and are almost entirely devoid of properties and relationships. Classification and extraction require the coverage of vocabularies and the alterability of folksonomies and can largely benefit from category relationships and other properties. With Doozer, a program for building conceptual models of information domains, we want to bridge the gap between the vocabularies …

Asymptotic Behavior Of Linearized Viscoelastic Flow Problem, Yinnian He, Yi Li

Yi Li

In this article, we provide some asymptotic behaviors of linearized viscoelastic flows in a general two-dimensional domain with certain parameters small and the time variable large.

Asymptotic Behavior Of Linearized Viscoelastic Flow Problem, Yinnian He, Yi Li

Mathematics and Statistics Faculty Publications

In this article, we provide some asymptotic behaviors of linearized viscoelastic flows in a general two-dimensional domain with certain parameters small and the time variable large.

Nonlinear Magneto-Optic Polarization Rotation With Intense Laser Fields, Paul S. Hsu, Anil K. Patnaik, George R. Welch

Physics Faculty Publications

We have studied the nonlinear Faraday effect with intense linear polarized light in an optically thick atomic rubidium vapor. We demonstrate that the polarization rotation rate (rotation angle per unit magnetic field, in the limit of low field) has a maximum value as the intensity and density are increased. We also show that the optimal sensitivity of an optical magnetometer based on this system reaches a saturation value as the intensity and density are increased.

Morphology Of The Dayside Ionosphere Of Venus: Implications For Ion Outflows, Jane L. Fox

Physics Faculty Publications

The nightside ionosphere of Venus is formed mostly by day-to-night transport of ions below the ionopause, with a small contribution from precipitation of energetic electrons from the wake. This nightward flux of ions should result in dayside ionospheres that are characterized by smaller electron density scale heights at high altitudes than those that are characteristic of diffusive equilibrium. In order to determine both the maximum possible values of the upward fluxes and the upward fluxes implied by comparison of our computed ion and electron density profiles to measurements, we have constructed more than 60 models of the high solar activity …

Relationship Web: Trailblazing, Analytics And Computing For Human Experience, Amit P. Sheth

Kno.e.sis Publications

This panel presentation was give at the 27th International Conference on Conceptual Modeling (ER 2008), Barcelona, Spain, October 20-23, 2008.

Student Fact Book, Fall 2008, Thirty-Second Annual Edition, Wright State University, Office Of Student Information Systems, Wright State University

Wright State University Student Fact Books

The student fact book has general demographic information on all students enrolled at Wright State University for Fall Quarter, 2008.

Ceg 420/620: Computer Architecture, Jack Jean

Computer Science & Engineering Syllabi

No abstract provided.

Ceg 453/653: Embedded Systems, Jack Jean

Computer Science & Engineering Syllabi

No abstract provided.

Ceg 210: Pc Networking I, Karen Meyer

Computer Science & Engineering Syllabi

Introduction to networking technologies including infrastructure and architectures, standards, protocols and directory services, administration, security and management. Integrated lecture and lab.

Ceg 433/633: Operating Systems, Prabhaker Mateti

Computer Science & Engineering Syllabi

Overview of operating systems internals. File-system usage and design, process usage and control, virtual memory, multi user systems, access control. Course projects use C++ language.

Ceg 460/660: Introduction To Software Computer Engineering, Jeffrey Mcdonald

Computer Science & Engineering Syllabi

This course is concerned with the techniques of designing and constructing large programs. Some of the required basic concepts necessarily have to be developed using small programs as examples. To this extent we also study programming-in-the-small. The overall objectives are to present an overview of issues in the development of sot1ware, to discuss terminology, to illustrate via example case studies, and to give sufficiently detailed advice on how to develop quality software. Hands-on experience is emphasized through the use of homework and a class project.

Ceg 724: Computer Vision I, Arthur A. Goshtasby

Computer Science & Engineering Syllabi

This course covers basic techniques for low-level and some mid-level vision. The techniques include: camera calibration, image filtering and edge detection, image segmentation and feature selection, and stereo depth perception.

Ceg 436/636: Mobile Computing, Yong Pei

Computer Science & Engineering Syllabi

Increasingly.. people, computers and microelectronic devices are being linked together to bring to life the communications mantra: anybody, anything, anytime, anywhere. This junior/senior/graduate course provides an in-depth study of networking protocol and system design in the area of wireless networking and mobile computing. It will help engineering and computer science students establish a solid foundation in concepts, architecture, design, and performance evaluation of mobile computing principle, protocols and applications. It will also introduce students to a few hot topics in wireless networking and mobile computing research such as mobile IP, wireless TCP, 802. l l, agent techniques, etc. The course …

Ceg 220: Introduction To C Programming For Engineers I, Jay Dejongh

Computer Science & Engineering Syllabi

This course provides a general introduction to computers as a problem-solving tool using the C programming language. Emphasis is on algorithms and techniques useful to engineers. Topics include data representation, debugging, and program verification. 4 credit hours. Prerequisite: MTH 229 (Calculus I) or EGR 101 (Engineering Mathematics).

Ceg 476/676: Computer Graphics I, Thomas Wischgoll

Computer Science & Engineering Syllabi

By the end of this quarter, you will have learnt techniques for constructing 2-D and 3-D objects
as well as manipulating and rendering the objects using OpenGL.
The outline of the course is as follows:

Introduction

• Geometric primitives
• Attributes of geometric primitives
• Antialiasing techniques
• Homogeneous coordinate system
• 2-D and 3-D viewing transformations
• Structures and hierarchical modeling
• Input devices and interactive techniques
• Visible surface detection methods

Ceg 498: Design Experience, Thomas C. Hartrum

Computer Science & Engineering Syllabi

CEG 498 (Design Experience) is a summative computer engineering design project course that builds upon previous engineering, science, mathematics and communications course work. CEG 498 projects are a minimum of two quarters in length and must be completed in groups of at least three students. Projects are selected under the guidance of the course instructor and are tailored to both student interest and formal classroom preparation. Students are evaluated both on their individual contributions as recorded in a graded engineering journal and on the quality of their collective efforts as reflected in group generated products.

Ceg 355: Introduction To The Design Of Information Technology Systems, Thomas C. Hartrum

Computer Science & Engineering Syllabi

Introduction to the design of information systems comprising modern technologies such as SQL database programming, networks, and distributed computing with CORBA, electronic and hypertext (HTML) documents, and multimedia.

This course is concerned with the techniques of designing and implementing distributed business software. Emphasis is on developing graphical user interfaces (GUIs) using Java Swing classes, storing and accessing data in a relational database using SQL, and implementing a distributed system using CORBA technology. Especially in light of Java and CORBA, there is a focus on object-oriented programming. The overall objective is to make the student aware of the technology available to …

Ceg 720: Computer Architecture I, Soon M. Chung

Computer Science & Engineering Syllabi

Review of sequential computer architecture and study of parallel computers. Topics include memory hierarchy, reduced instruction set computer, pipeline processing, multiprocessing, various parallel computers, interconnection networks, and fault-tolerant computing.

Ceg 402/602: Introduction To Computer Communication, Bin Wang

Computer Science & Engineering Syllabi

This course provides an introduction to basic concepts of communication networks, different types of networks, protocols over different layers, and network applications through lectures, labs, homework, and reading on relevant materials. You will

• Understand networking principles, protocols, and technologies.

• Understand some design and performance issues involved in providing a network service.

• Acquire background for supporting e-commerce, e-government, and e-education.

• Gain hands-on experience with programming techniques for network protocols.

• Obtain background for original research in computer networks.